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Supporting information
![]() | Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804008414/lh6194sup1.cif |
![]() | Structure factor file (CIF format) https://doi.org/10.1107/S1600536804008414/lh6194Isup2.hkl |
CCDC reference: 239060
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean
(C-C) = 0.008 Å
- Disorder in solvent or counterion
- R factor = 0.075
- wR factor = 0.213
- Data-to-parameter ratio = 15.4
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low ....... 0.98 PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 2.61 PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent ..... ? PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... Cl1 PLAT302_ALERT_4_C Anion/Solvent Disorder ......................... 38.00 Perc. PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 8 PLAT420_ALERT_2_C D-H Without Acceptor N2 - H2A ... ? PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 2 Cl O4
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 8 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Siemens, 1996); cell refinement: SMART; data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.
[Co(C20H25N2O)2]ClO4 | Z = 1 |
Mr = 777.22 | F(000) = 410 |
Triclinic, P1 | Dx = 1.326 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 9.061 (2) Å | Cell parameters from 2138 reflections |
b = 10.378 (2) Å | θ = 2.8–25.6° |
c = 11.464 (2) Å | µ = 0.56 mm−1 |
α = 78.01 (3)° | T = 293 K |
β = 67.79 (3)° | Block, brown |
γ = 81.41 (3)° | 0.27 × 0.22 × 0.10 mm |
V = 973.3 (3) Å3 |
Bruker SMART CCD diffractometer | 3849 independent reflections |
Radiation source: fine-focus sealed tube | 2551 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.031 |
φ and ω scans | θmax = 26.5°, θmin = 2.0° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −11→10 |
Tmin = 0.863, Tmax = 0.946 | k = −13→11 |
4553 measured reflections | l = −14→11 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.075 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.213 | H-atom parameters constrained |
S = 1.04 | w = 1/[σ2(Fo2) + (0.1068P)2] where P = (Fo2 + 2Fc2)/3 |
3849 reflections | (Δ/σ)max < 0.001 |
250 parameters | Δρmax = 0.79 e Å−3 |
0 restraints | Δρmin = −0.30 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Co1 | 0.0000 | 0.0000 | 0.0000 | 0.0354 (3) | |
Cl1 | −0.1065 (7) | −0.4967 (5) | 0.5145 (4) | 0.1154 (16) | 0.50 |
O1 | −0.1410 (4) | 0.1332 (3) | 0.0814 (3) | 0.0417 (8) | |
O2 | −0.218 (2) | −0.5225 (13) | 0.6350 (11) | 0.196 (8) | 0.50 |
O3 | −0.2237 (19) | −0.4347 (13) | 0.4360 (11) | 0.159 (6) | 0.50 |
O4 | −0.0010 (13) | −0.6075 (8) | 0.4867 (8) | 0.197 (4) | |
N1 | −0.0675 (4) | −0.1236 (4) | 0.1558 (3) | 0.0383 (9) | |
N2 | 0.1705 (4) | 0.0483 (4) | 0.0503 (4) | 0.0433 (10) | |
H2A | 0.2604 | 0.0270 | −0.0134 | 0.080* | |
C1 | −0.3264 (5) | −0.0066 (5) | 0.2438 (4) | 0.0407 (11) | |
C2 | −0.2795 (5) | 0.1151 (5) | 0.1734 (4) | 0.0414 (11) | |
C3 | −0.3837 (6) | 0.2289 (5) | 0.2039 (5) | 0.0539 (13) | |
H3A | −0.3478 | 0.3141 | 0.1593 | 0.080* | |
C4 | −0.5337 (7) | 0.2200 (6) | 0.2943 (5) | 0.0595 (15) | |
H4A | −0.6020 | 0.2984 | 0.3154 | 0.080* | |
C5 | −0.7496 (7) | 0.0841 (8) | 0.4457 (5) | 0.0700 (18) | |
H5A | −0.8201 | 0.1625 | 0.4614 | 0.080* | |
C6 | −0.8003 (7) | −0.0390 (9) | 0.5061 (6) | 0.077 (2) | |
H6A | −0.9081 | −0.0466 | 0.5653 | 0.080* | |
C7 | −0.7019 (8) | −0.1483 (8) | 0.4832 (6) | 0.0743 (19) | |
H7A | −0.7403 | −0.2327 | 0.5281 | 0.080* | |
C8 | −0.5477 (6) | −0.1409 (6) | 0.3983 (5) | 0.0612 (15) | |
H8A | −0.4787 | −0.2198 | 0.3812 | 0.080* | |
C9 | −0.4877 (6) | −0.0186 (5) | 0.3351 (4) | 0.0469 (12) | |
C10 | −0.5887 (6) | 0.0943 (6) | 0.3584 (5) | 0.0548 (14) | |
C11 | −0.2076 (5) | −0.1150 (5) | 0.2424 (4) | 0.0417 (11) | |
H11A | −0.2347 | −0.1876 | 0.3119 | 0.080* | |
C12 | 0.0467 (6) | −0.2293 (5) | 0.1802 (5) | 0.0491 (13) | |
H12A | 0.0664 | −0.2903 | 0.1224 | 0.080* | |
H12B | 0.0014 | −0.2760 | 0.2657 | 0.080* | |
C13 | 0.2009 (6) | −0.1782 (5) | 0.1653 (6) | 0.0584 (15) | |
H13A | 0.2793 | −0.1966 | 0.0853 | 0.080* | |
H13B | 0.2371 | −0.2259 | 0.2321 | 0.080* | |
C14 | 0.1936 (7) | −0.0355 (5) | 0.1642 (5) | 0.0547 (14) | |
H14A | 0.1054 | −0.0149 | 0.2386 | 0.080* | |
H14B | 0.2895 | −0.0144 | 0.1708 | 0.080* | |
C15 | 0.1791 (5) | 0.1940 (5) | 0.0406 (5) | 0.0429 (11) | |
H15A | 0.1232 | 0.2388 | −0.0146 | 0.080* | |
C16 | 0.3513 (6) | 0.2299 (5) | −0.0240 (5) | 0.0576 (14) | |
H16A | 0.4005 | 0.1952 | −0.1025 | 0.080* | |
H16B | 0.4106 | 0.1926 | 0.0306 | 0.080* | |
C17 | 0.3551 (7) | 0.3781 (6) | −0.0497 (6) | 0.0704 (17) | |
H17A | 0.3014 | 0.4135 | −0.1087 | 0.080* | |
H17B | 0.4637 | 0.4018 | −0.0894 | 0.080* | |
C18 | 0.2716 (8) | 0.4373 (6) | 0.0702 (7) | 0.0739 (18) | |
H18A | 0.2687 | 0.5318 | 0.0478 | 0.080* | |
H18B | 0.3315 | 0.4101 | 0.1258 | 0.080* | |
C19 | 0.1050 (8) | 0.3951 (6) | 0.1384 (6) | 0.0701 (17) | |
H19A | 0.0417 | 0.4311 | 0.0866 | 0.080* | |
H19B | 0.0575 | 0.4290 | 0.2174 | 0.080* | |
C20 | 0.1003 (6) | 0.2460 (5) | 0.1658 (5) | 0.0551 (14) | |
H20A | 0.1586 | 0.2098 | 0.2213 | 0.080* | |
H20B | −0.0073 | 0.2203 | 0.2073 | 0.080* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Co1 | 0.0288 (5) | 0.0368 (6) | 0.0386 (5) | −0.0063 (4) | −0.0112 (4) | −0.0010 (4) |
Cl1 | 0.185 (4) | 0.064 (2) | 0.075 (3) | −0.012 (3) | −0.026 (3) | −0.003 (2) |
O1 | 0.0342 (18) | 0.0397 (19) | 0.0458 (19) | −0.0033 (14) | −0.0101 (15) | −0.0033 (14) |
O2 | 0.32 (2) | 0.128 (11) | 0.060 (7) | 0.030 (12) | −0.007 (10) | 0.001 (7) |
O3 | 0.219 (15) | 0.129 (10) | 0.092 (8) | −0.052 (10) | −0.037 (9) | 0.057 (7) |
O4 | 0.262 (10) | 0.132 (7) | 0.171 (7) | −0.004 (7) | −0.054 (7) | −0.024 (6) |
N1 | 0.035 (2) | 0.035 (2) | 0.043 (2) | −0.0072 (17) | −0.0137 (18) | 0.0012 (17) |
N2 | 0.039 (2) | 0.041 (2) | 0.051 (2) | −0.0075 (18) | −0.0181 (19) | −0.0034 (18) |
C1 | 0.037 (3) | 0.047 (3) | 0.036 (3) | −0.005 (2) | −0.011 (2) | −0.007 (2) |
C2 | 0.036 (3) | 0.051 (3) | 0.038 (3) | 0.002 (2) | −0.016 (2) | −0.009 (2) |
C3 | 0.056 (3) | 0.055 (3) | 0.047 (3) | 0.007 (3) | −0.018 (3) | −0.008 (2) |
C4 | 0.051 (3) | 0.076 (4) | 0.046 (3) | 0.020 (3) | −0.016 (3) | −0.019 (3) |
C5 | 0.044 (3) | 0.120 (6) | 0.042 (3) | 0.012 (4) | −0.012 (3) | −0.024 (3) |
C6 | 0.043 (4) | 0.133 (7) | 0.045 (3) | −0.014 (4) | −0.005 (3) | −0.012 (4) |
C7 | 0.052 (4) | 0.105 (6) | 0.057 (4) | −0.024 (4) | −0.006 (3) | −0.007 (4) |
C8 | 0.045 (3) | 0.077 (4) | 0.055 (3) | −0.013 (3) | −0.011 (3) | −0.007 (3) |
C9 | 0.039 (3) | 0.065 (4) | 0.037 (3) | −0.002 (3) | −0.014 (2) | −0.009 (2) |
C10 | 0.043 (3) | 0.086 (4) | 0.033 (3) | 0.004 (3) | −0.013 (2) | −0.013 (3) |
C11 | 0.040 (3) | 0.046 (3) | 0.037 (3) | −0.014 (2) | −0.011 (2) | −0.001 (2) |
C12 | 0.041 (3) | 0.044 (3) | 0.054 (3) | −0.003 (2) | −0.015 (2) | 0.006 (2) |
C13 | 0.052 (3) | 0.052 (3) | 0.074 (4) | −0.004 (3) | −0.036 (3) | 0.009 (3) |
C14 | 0.060 (3) | 0.053 (3) | 0.059 (3) | −0.004 (3) | −0.035 (3) | 0.000 (3) |
C15 | 0.034 (3) | 0.044 (3) | 0.049 (3) | −0.007 (2) | −0.012 (2) | −0.008 (2) |
C16 | 0.039 (3) | 0.060 (4) | 0.070 (4) | −0.014 (3) | −0.007 (3) | −0.019 (3) |
C17 | 0.057 (4) | 0.057 (4) | 0.089 (5) | −0.023 (3) | −0.013 (3) | −0.004 (3) |
C18 | 0.096 (5) | 0.043 (3) | 0.100 (5) | −0.011 (3) | −0.055 (4) | −0.008 (3) |
C19 | 0.089 (5) | 0.055 (4) | 0.069 (4) | 0.010 (3) | −0.030 (4) | −0.024 (3) |
C20 | 0.055 (3) | 0.059 (4) | 0.050 (3) | −0.005 (3) | −0.016 (3) | −0.013 (3) |
Co1—O1 | 1.876 (3) | C7—C8 | 1.371 (7) |
Co1—O1i | 1.876 (3) | C7—H7A | 0.9600 |
Co1—N1 | 1.915 (4) | C8—C9 | 1.399 (7) |
Co1—N1i | 1.915 (4) | C8—H8A | 0.9600 |
Co1—N2i | 1.999 (4) | C9—C10 | 1.380 (7) |
Co1—N2 | 1.999 (4) | C11—H11A | 0.9600 |
Cl1—O2 | 1.369 (13) | C12—C13 | 1.506 (7) |
Cl1—O4 | 1.389 (9) | C12—H12A | 0.9600 |
Cl1—O4ii | 1.555 (10) | C12—H12B | 0.9599 |
Cl1—O3 | 1.622 (15) | C13—C14 | 1.470 (7) |
Cl1—Cl1ii | 1.824 (12) | C13—H13A | 0.9600 |
O1—C2 | 1.308 (5) | C13—H13B | 0.9600 |
O4—Cl1ii | 1.555 (10) | C14—H14A | 0.9600 |
N1—C11 | 1.286 (5) | C14—H14B | 0.9600 |
N1—C12 | 1.450 (6) | C15—C20 | 1.514 (7) |
N2—C14 | 1.479 (6) | C15—C16 | 1.519 (6) |
N2—C15 | 1.505 (6) | C15—H15A | 0.9601 |
N2—H2A | 0.9000 | C16—C17 | 1.508 (8) |
C1—C2 | 1.379 (7) | C16—H16A | 0.9600 |
C1—C11 | 1.434 (7) | C16—H16B | 0.9600 |
C1—C9 | 1.446 (6) | C17—C18 | 1.505 (9) |
C2—C3 | 1.414 (7) | C17—H17A | 0.9601 |
C3—C4 | 1.365 (7) | C17—H17B | 0.9600 |
C3—H3A | 0.9600 | C18—C19 | 1.498 (8) |
C4—C10 | 1.418 (8) | C18—H18A | 0.9600 |
C4—H4A | 0.9601 | C18—H18B | 0.9600 |
C5—C6 | 1.375 (9) | C19—C20 | 1.517 (7) |
C5—C10 | 1.428 (7) | C19—H19A | 0.9600 |
C5—H5A | 0.9600 | C19—H19B | 0.9600 |
C6—C7 | 1.339 (9) | C20—H20A | 0.9600 |
C6—H6A | 0.9599 | C20—H20B | 0.9600 |
O1—Co1—O1i | 180.0 | C8—C9—C1 | 122.5 (5) |
O1—Co1—N1 | 90.34 (15) | C9—C10—C4 | 120.1 (5) |
O1i—Co1—N1 | 89.66 (15) | C9—C10—C5 | 119.9 (6) |
O1—Co1—N1i | 89.66 (15) | C4—C10—C5 | 120.0 (6) |
O1i—Co1—N1i | 90.34 (15) | N1—C11—C1 | 125.7 (4) |
N1—Co1—N1i | 180.0 | N1—C11—H11A | 117.0 |
O1—Co1—N2i | 90.13 (15) | C1—C11—H11A | 117.4 |
O1i—Co1—N2i | 89.87 (15) | N1—C12—C13 | 112.0 (4) |
N1—Co1—N2i | 90.66 (15) | N1—C12—H12A | 108.5 |
N1i—Co1—N2i | 89.34 (15) | C13—C12—H12A | 110.3 |
O1—Co1—N2 | 89.87 (15) | N1—C12—H12B | 109.4 |
O1i—Co1—N2 | 90.13 (15) | C13—C12—H12B | 108.6 |
N1—Co1—N2 | 89.34 (15) | H12A—C12—H12B | 107.9 |
N1i—Co1—N2 | 90.66 (15) | C14—C13—C12 | 115.2 (5) |
N2i—Co1—N2 | 180.0 | C14—C13—H13A | 107.4 |
O2—Cl1—O4 | 110.2 (8) | C12—C13—H13A | 107.7 |
O2—Cl1—O4ii | 108.4 (9) | C14—C13—H13B | 109.5 |
O4—Cl1—O4ii | 103.7 (6) | C12—C13—H13B | 109.1 |
O2—Cl1—O3 | 99.6 (10) | H13A—C13—H13B | 107.7 |
O4—Cl1—O3 | 122.8 (8) | C13—C14—N2 | 114.2 (4) |
O4ii—Cl1—O3 | 111.7 (7) | C13—C14—H14A | 107.5 |
O2—Cl1—Cl1ii | 122.1 (10) | N2—C14—H14A | 108.4 |
O4—Cl1—Cl1ii | 55.9 (5) | C13—C14—H14B | 109.6 |
O4ii—Cl1—Cl1ii | 47.8 (4) | N2—C14—H14B | 109.1 |
O3—Cl1—Cl1ii | 136.7 (6) | H14A—C14—H14B | 107.8 |
C2—O1—Co1 | 125.3 (3) | N2—C15—C20 | 114.8 (4) |
Cl1—O4—Cl1ii | 76.3 (6) | N2—C15—C16 | 110.4 (4) |
C11—N1—C12 | 118.1 (4) | C20—C15—C16 | 110.8 (4) |
C11—N1—Co1 | 123.2 (3) | N2—C15—H15A | 106.8 |
C12—N1—Co1 | 118.6 (3) | C20—C15—H15A | 106.8 |
C14—N2—C15 | 115.2 (4) | C16—C15—H15A | 106.8 |
C14—N2—Co1 | 116.0 (3) | C17—C16—C15 | 109.4 (5) |
C15—N2—Co1 | 115.4 (3) | C17—C16—H16A | 110.2 |
C14—N2—H2A | 102.5 | C15—C16—H16A | 110.0 |
C15—N2—H2A | 102.2 | C17—C16—H16B | 108.9 |
Co1—N2—H2A | 102.3 | C15—C16—H16B | 109.9 |
C2—C1—C11 | 119.2 (4) | H16A—C16—H16B | 108.4 |
C2—C1—C9 | 120.0 (5) | C18—C17—C16 | 111.9 (5) |
C11—C1—C9 | 119.9 (4) | C18—C17—H17A | 108.7 |
O1—C2—C1 | 124.1 (4) | C16—C17—H17A | 107.9 |
O1—C2—C3 | 117.0 (4) | C18—C17—H17B | 110.4 |
C1—C2—C3 | 118.9 (4) | C16—C17—H17B | 110.1 |
C4—C3—C2 | 121.5 (5) | H17A—C17—H17B | 107.8 |
C4—C3—H3A | 119.6 | C19—C18—C17 | 111.5 (5) |
C2—C3—H3A | 118.9 | C19—C18—H18A | 109.9 |
C3—C4—C10 | 119.8 (5) | C17—C18—H18A | 108.7 |
C3—C4—H4A | 120.5 | C19—C18—H18B | 109.4 |
C10—C4—H4A | 119.7 | C17—C18—H18B | 109.2 |
C6—C5—C10 | 118.8 (6) | H18A—C18—H18B | 108.2 |
C6—C5—H5A | 121.3 | C18—C19—C20 | 112.4 (5) |
C10—C5—H5A | 119.9 | C18—C19—H19A | 109.3 |
C7—C6—C5 | 121.1 (6) | C20—C19—H19A | 108.1 |
C7—C6—H6A | 119.6 | C18—C19—H19B | 109.6 |
C5—C6—H6A | 119.3 | C20—C19—H19B | 109.2 |
C6—C7—C8 | 121.0 (7) | H19A—C19—H19B | 108.1 |
C6—C7—H7A | 119.1 | C15—C20—C19 | 108.4 (4) |
C8—C7—H7A | 119.9 | C15—C20—H20A | 109.7 |
C7—C8—C9 | 120.8 (6) | C19—C20—H20A | 108.5 |
C7—C8—H8A | 120.5 | C15—C20—H20B | 110.2 |
C9—C8—H8A | 118.7 | C19—C20—H20B | 111.6 |
C10—C9—C8 | 118.3 (5) | H20A—C20—H20B | 108.3 |
C10—C9—C1 | 119.1 (5) | ||
N1—Co1—O1—C2 | −32.8 (3) | C7—C8—C9—C1 | −179.3 (5) |
N1i—Co1—O1—C2 | 147.2 (3) | C2—C1—C9—C10 | −5.5 (7) |
N2i—Co1—O1—C2 | 57.9 (3) | C11—C1—C9—C10 | 163.4 (4) |
N2—Co1—O1—C2 | −122.1 (3) | C2—C1—C9—C8 | 172.4 (5) |
O2—Cl1—O4—Cl1ii | −115.8 (10) | C11—C1—C9—C8 | −18.8 (7) |
O4ii—Cl1—O4—Cl1ii | 0.0 | C8—C9—C10—C4 | −178.6 (5) |
O3—Cl1—O4—Cl1ii | 127.6 (7) | C1—C9—C10—C4 | −0.7 (7) |
O1—Co1—N1—C11 | 28.4 (4) | C8—C9—C10—C5 | 0.4 (7) |
O1i—Co1—N1—C11 | −151.6 (4) | C1—C9—C10—C5 | 178.3 (4) |
N2i—Co1—N1—C11 | −61.8 (4) | C3—C4—C10—C9 | 3.9 (8) |
N2—Co1—N1—C11 | 118.2 (4) | C3—C4—C10—C5 | −175.1 (5) |
O1—Co1—N1—C12 | −149.1 (3) | C6—C5—C10—C9 | 0.7 (8) |
O1i—Co1—N1—C12 | 30.9 (3) | C6—C5—C10—C4 | 179.7 (5) |
N2i—Co1—N1—C12 | 120.8 (3) | C12—N1—C11—C1 | 169.8 (4) |
N2—Co1—N1—C12 | −59.2 (3) | Co1—N1—C11—C1 | −7.6 (6) |
O1—Co1—N2—C14 | 99.1 (4) | C2—C1—C11—N1 | −21.2 (7) |
O1i—Co1—N2—C14 | −80.9 (4) | C9—C1—C11—N1 | 169.9 (4) |
N1—Co1—N2—C14 | 8.8 (4) | C11—N1—C12—C13 | −125.6 (5) |
N1i—Co1—N2—C14 | −171.2 (4) | Co1—N1—C12—C13 | 51.9 (5) |
O1—Co1—N2—C15 | −40.0 (3) | N1—C12—C13—C14 | 15.8 (7) |
O1i—Co1—N2—C15 | 140.0 (3) | C12—C13—C14—N2 | −68.1 (6) |
N1—Co1—N2—C15 | −130.4 (3) | C15—N2—C14—C13 | −174.1 (4) |
N1i—Co1—N2—C15 | 49.6 (3) | Co1—N2—C14—C13 | 46.6 (6) |
Co1—O1—C2—C1 | 15.4 (6) | C14—N2—C15—C20 | −39.8 (6) |
Co1—O1—C2—C3 | −166.7 (3) | Co1—N2—C15—C20 | 99.7 (4) |
C11—C1—C2—O1 | 17.2 (7) | C14—N2—C15—C16 | 86.2 (5) |
C9—C1—C2—O1 | −173.9 (4) | Co1—N2—C15—C16 | −134.3 (4) |
C11—C1—C2—C3 | −160.6 (4) | N2—C15—C16—C17 | 172.0 (4) |
C9—C1—C2—C3 | 8.3 (7) | C20—C15—C16—C17 | −59.7 (6) |
O1—C2—C3—C4 | 176.9 (4) | C15—C16—C17—C18 | 56.0 (7) |
C1—C2—C3—C4 | −5.1 (7) | C16—C17—C18—C19 | −53.6 (7) |
C2—C3—C4—C10 | −1.0 (8) | C17—C18—C19—C20 | 54.2 (7) |
C10—C5—C6—C7 | −0.7 (9) | N2—C15—C20—C19 | −174.6 (4) |
C5—C6—C7—C8 | −0.3 (10) | C16—C15—C20—C19 | 59.5 (6) |
C6—C7—C8—C9 | 1.4 (9) | C18—C19—C20—C15 | −56.8 (6) |
C7—C8—C9—C10 | −1.4 (8) |
Symmetry codes: (i) −x, −y, −z; (ii) −x, −y−1, −z+1. |
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