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The crystal structures of 222- and 221-polybasite [(Ag,Cu)16(Sb,As)2S11] crystals have been solved and refined by means of X-ray diffraction data (collected at 100 and 120 K, respectively) from twinned crystals. Both structures consist of the stacking of [(Ag,Cu)6Sb2S7]2− and [Ag9CuS4]2+ module layers in which Sb forms isolated SbS3 pyramids typically occurring in sulfosalts; copper links two S atoms in a linear coordination and silver occupies sites with coordination ranging from quasi-linear to almost tetrahedral. An Ag → Cu substitution in the [(Ag,Cu)6Sb2S7]2− module layer is observed in both structures, the substitution amount being larger in the 221- than in the 222-polybasite. A pattern of the possible mechanism regulating the type of unit cell that is stabilized is proposed: starting from the hypothetical stoichiometric and fully ordered Ag15CuSb2S11 222-polybasite structure, with a low C2/c monoclinic symmetry and a large 222 supercell, the disorder introduced by the substitution of Cu for Ag increases the symmetry with a cell reduction along the c axis yielding the 221 supercell and a trigonal crystal system. A further increase of the substitution gives rise to a folding of the cell along the a and b axes and the 111-pearceite structure, space group P\bar3m1.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S010876810600975X/lc5045sup1.cif
Contains datablocks global, polybasite221, polybasite222

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010876810600975X/lc5045polybasite221sup2.hkl
Contains datablock polybasite221

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010876810600975X/lc5045polybasite222sup3.hkl
Contains datablock polybasite222

Computing details top

For both compounds, program(s) used to refine structure: (Jana2000; Petricek and Dusek, 2000); software used to prepare material for publication: (Jana2000; Petricek and Dusek, 2000).

Figures top
[Figure 1]
[Figure 2]
[Figure 3]
[Figure 4]
[Figure 5]
[Figure 6]
(polybasite221) top
Crystal data top
Ag14.52Cu1.48S11Sb2Dx = 6.390 Mg m3
Mr = 2256.5Mo Kα radiation, λ = 0.71069 Å
Trigonal, P321Cell parameters from 162 reflections
Hall symbol: P 3;2"θ = 6.4–35°
a = 15.0954 (12) ŵ = 16.32 mm1
c = 11.8825 (8) ÅT = 120 K
V = 2344.9 (3) Å3Block, black
Z = 40.14 × 0.08 × 0.06 mm
F(000) = 4013
Data collection top
Nonius CCD
diffractometer
Rint = 0.063
ω, ϕ scansθmax = 35.0°, θmin = 6.4°
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
h = 2424
Tmin = 0.196, Tmax = 0.417k = 2424
6847 independent reflectionsl = 1919
6224 reflections with I > 2σ(I)
Refinement top
Refinement on FWeighting scheme based on measured s.u.'s w = 1/(σ2(F) + 0.000484F2)
R[F2 > 2σ(F2)] = 0.036(Δ/σ)max = 0.001
wR(F2) = 0.046Δρmax = 1.05 e Å3
S = 1.41Δρmin = 0.81 e Å3
6847 reflectionsExtinction correction: B-C type 1 Lorentzian isotropic (Becker & Coppens, 1974)
224 parametersExtinction coefficient: 0.108 (16)
Crystal data top
Ag14.52Cu1.48S11Sb2Z = 4
Mr = 2256.5Mo Kα radiation
Trigonal, P321µ = 16.32 mm1
a = 15.0954 (12) ÅT = 120 K
c = 11.8825 (8) Å0.14 × 0.08 × 0.06 mm
V = 2344.9 (3) Å3
Data collection top
Nonius CCD
diffractometer
6847 independent reflections
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
6224 reflections with I > 2σ(I)
Tmin = 0.196, Tmax = 0.417Rint = 0.063
Refinement top
R[F2 > 2σ(F2)] = 0.036224 parameters
wR(F2) = 0.046Δρmax = 1.05 e Å3
S = 1.41Δρmin = 0.81 e Å3
6847 reflections
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Sb10.3333330.6666670.08748 (6)0.01292 (16)
Sb20.33285 (3)0.15587 (3)0.08778 (3)0.01123 (13)
Ag10.36661 (4)0.42990 (4)0.10137 (5)0.01845 (18)
Ag20.09007 (5)0.42358 (5)0.14418 (6)0.0247 (3)0.785 (10)
Ag2cu0.0900660.4235810.1441760.0247 (3)0.215 (10)
Ag30.07708 (13)0.14671 (14)0.12156 (13)0.0403 (4)0.895 (11)
Ag3cu0.0770830.1467060.1215580.0403 (4)0.105 (11)
Ag40.56682 (5)0.41741 (4)0.11845 (5)0.02131 (19)
Ag50.34923 (5)0.55037 (5)0.39194 (5)0.0234 (2)
Ag60.27335 (11)0.07446 (10)0.39259 (10)0.0244 (2)
Ag70.13137 (5)0.17613 (4)0.37640 (5)0.0260 (2)
Ag80.52806 (15)0.16567 (11)0.37649 (11)0.0393 (3)
Ag90.09891 (5)0.41993 (4)0.39861 (5)0.0215 (2)
Ag100.37973 (15)0.30736 (10)0.36194 (11)0.0400 (3)
Cu100.51322 (7)0.50.0121 (3)
Cu2000.50.0153 (5)
S10.26964 (13)0.50882 (12)0.19090 (13)0.0137 (5)
S20.00297 (12)0.24192 (14)0.20453 (13)0.0166 (5)
S30.26011 (14)0.24957 (14)0.17635 (13)0.0149 (6)
S40.48834 (13)0.24179 (13)0.19616 (14)0.0150 (5)
S50.49297 (11)0.50299 (11)0.31858 (11)0.0110 (5)
S6000.3189 (2)0.0101 (5)
S70.20146 (12)0.34647 (12)0.46132 (12)0.0121 (5)
S80.3333330.6666670.5400 (2)0.0102 (5)
S90.53714 (18)0.53714 (18)00.0335 (8)
S100.0323 (6)0.0323 (6)00.050 (3)0.3333
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sb10.0137 (2)0.0137 (2)0.0113 (3)0.00687 (10)00
Sb20.01299 (19)0.01127 (15)0.01014 (14)0.00659 (14)0.00027 (12)0.00019 (11)
Ag10.0181 (2)0.0194 (2)0.0193 (2)0.0105 (2)0.00089 (16)0.00345 (18)
Ag20.0138 (3)0.0230 (4)0.0316 (3)0.0048 (2)0.0045 (2)0.0058 (2)
Ag2cu0.0138 (3)0.0230 (4)0.0316 (3)0.0048 (2)0.0045 (2)0.0058 (2)
Ag30.0288 (4)0.0515 (6)0.0477 (5)0.0255 (4)0.0144 (3)0.0267 (4)
Ag3cu0.0288 (4)0.0515 (6)0.0477 (5)0.0255 (4)0.0144 (3)0.0267 (4)
Ag40.0193 (3)0.0160 (2)0.0216 (2)0.0035 (2)0.00119 (19)0.00045 (18)
Ag50.0232 (3)0.0263 (3)0.0216 (2)0.0131 (2)0.00162 (19)0.0077 (2)
Ag60.0368 (3)0.0220 (3)0.0172 (2)0.0168 (3)0.0034 (2)0.00234 (18)
Ag70.0350 (3)0.0117 (2)0.0220 (2)0.0046 (2)0.0083 (2)0.00048 (19)
Ag80.0769 (6)0.0152 (3)0.0165 (3)0.0160 (3)0.0053 (3)0.0005 (2)
Ag90.0273 (3)0.0215 (3)0.0245 (2)0.0187 (2)0.0080 (2)0.00499 (19)
Ag100.0683 (6)0.0127 (2)0.0174 (2)0.0040 (3)0.0015 (3)0.00146 (19)
Cu10.0155 (5)0.0136 (3)0.0077 (4)0.0078 (3)0.0011 (3)0.00057 (17)
Cu20.0185 (6)0.0185 (6)0.0088 (7)0.0092 (3)00
S10.0146 (7)0.0115 (7)0.0160 (6)0.0073 (6)0.0001 (5)0.0009 (5)
S20.0110 (6)0.0227 (8)0.0160 (6)0.0084 (6)0.0006 (5)0.0013 (6)
S30.0191 (8)0.0170 (8)0.0138 (6)0.0130 (6)0.0022 (5)0.0018 (5)
S40.0111 (6)0.0114 (6)0.0218 (7)0.0050 (5)0.0013 (5)0.0008 (5)
S50.0135 (6)0.0109 (6)0.0086 (5)0.0061 (5)0.0007 (4)0.0012 (4)
S60.0108 (6)0.0108 (6)0.0087 (9)0.0054 (3)00
S70.0162 (6)0.0118 (6)0.0102 (5)0.0085 (5)0.0030 (4)0.0014 (5)
S80.0099 (6)0.0099 (6)0.0107 (9)0.0050 (3)00
S90.0265 (9)0.0265 (9)0.0219 (12)0.0058 (11)0.0102 (6)0.0102 (6)
S100.039 (4)0.039 (4)0.027 (4)0.014 (4)0.020 (3)0.020 (3)
Geometric parameters (Å, º) top
Sb1—S12.4127 (17)Ag4—S4vi2.609 (2)
Sb1—S1i2.4127 (16)Ag4—S92.502 (3)
Sb1—S1ii2.413 (3)Ag5—Cu1i2.9790 (14)
Sb2—S2iii2.4392 (15)Ag5—S12.6058 (17)
Sb2—S32.422 (3)Ag5—S52.744 (2)
Sb2—S42.4095 (16)Ag5—S72.8747 (14)
Ag1—Ag1iv2.9227 (9)Ag5—S82.5800 (18)
Ag1—S12.537 (2)Ag6—S2iii2.425 (2)
Ag1—S32.5324 (18)Ag6—S7vii2.4065 (18)
Ag1—S92.556 (2)Ag7—Cu22.8083 (5)
Ag2—Ag2cu0Ag7—S32.9156 (17)
Ag2—S12.4133 (18)Ag7—S62.4891 (8)
Ag2—S22.4810 (19)Ag7—S72.4552 (17)
Ag2—S5ii2.977 (2)Ag8—Cu1vii2.8103 (18)
Ag2—S9ii2.437 (3)Ag8—S42.638 (3)
Ag2cu—S12.4133 (17)Ag8—S5viii2.546 (3)
Ag2cu—S22.4810 (18)Ag8—S8vii2.5442 (16)
Ag2cu—S5ii2.977 (2)Ag9—Cu12.7868 (11)
Ag2cu—S9ii2.437 (3)Ag9—S5ii2.490 (3)
Ag3—Ag3cu0Ag9—S72.429 (2)
Ag3—S22.497 (3)Ag10—Cu1i2.8743 (15)
Ag3—S32.486 (2)Ag10—S32.704 (2)
Ag3—S102.088 (6)Ag10—S52.6192 (18)
Ag3—S10v2.462 (8)Ag10—S7vii2.533 (2)
Ag3—S10iii2.756 (7)Cu1—S5ii2.1663 (13)
Ag3cu—S22.497 (2)Cu1—S5ix2.1663 (13)
Ag3cu—S32.4855 (17)Cu2—S62.152 (2)
Ag3cu—S102.088 (6)Cu2—S6vii2.152 (2)
Ag3cu—S10v2.462 (8)S10—S10v0.844 (11)
Ag3cu—S10iii2.756 (7)S10—S10iii0.844 (11)
Ag4—S42.4786 (18)
S1—Sb1—S1i96.37 (7)Ag1—S3—Ag3cu119.29 (9)
S1—Sb1—S1ii96.37 (7)Ag1—S3—Ag7129.77 (9)
S1i—Sb1—S196.37 (7)Ag1—S3—Ag1088.71 (5)
S1i—Sb1—S1ii96.37 (8)Ag3—S3—Ag3cu0
S1ii—Sb1—S196.37 (7)Ag3—S3—Ag769.80 (6)
S1ii—Sb1—S1i96.37 (8)Ag3—S3—Ag10140.33 (8)
S2iii—Sb2—S396.56 (7)Ag3cu—S3—Ag769.80 (4)
S2iii—Sb2—S497.37 (7)Ag3cu—S3—Ag10140.33 (7)
S3—Sb2—S493.30 (7)Ag7—S3—Ag1070.63 (5)
Ag1iv—Ag1—S1149.18 (5)Sb2—S4—Ag4101.11 (7)
Ag1iv—Ag1—S394.25 (5)Sb2—S4—Ag4viii99.67 (6)
Ag1iv—Ag1—S955.12 (5)Sb2—S4—Ag8124.89 (7)
S1—Ag1—S398.74 (6)Ag4—S4—Ag4viii110.07 (6)
S1—Ag1—S9122.35 (8)Ag4—S4—Ag8132.63 (7)
S3—Ag1—S9138.06 (10)Ag4viii—S4—Ag4110.07 (6)
Ag2cu—Ag2—S10Ag4viii—S4—Ag875.59 (8)
Ag2cu—Ag2—S20Ag2i—S5—Ag2cui0
Ag2cu—Ag2—S5ii0Ag2i—S5—Ag593.84 (6)
Ag2cu—Ag2—S9ii0Ag2i—S5—Ag8vi107.12 (6)
S1—Ag2—S2112.77 (7)Ag2i—S5—Ag9i66.58 (4)
S1—Ag2—S5ii101.51 (6)Ag2i—S5—Ag10147.00 (6)
S1—Ag2—S9ii130.28 (7)Ag2i—S5—Cu1i139.71 (6)
S2—Ag2—S5ii98.12 (6)Ag2cui—S5—Ag593.84 (6)
S2—Ag2—S9ii113.31 (7)Ag2cui—S5—Ag8vi107.12 (6)
S5ii—Ag2—S9ii89.57 (8)Ag2cui—S5—Ag9i66.58 (4)
Ag2—Ag2cu—S10Ag2cui—S5—Ag10147.00 (6)
Ag2—Ag2cu—S20Ag2cui—S5—Cu1i139.71 (6)
Ag2—Ag2cu—S5ii0Ag5—S5—Ag8vi145.55 (6)
Ag2—Ag2cu—S9ii0Ag5—S5—Ag9i70.43 (5)
S1—Ag2cu—S2112.77 (6)Ag5—S5—Ag1094.36 (7)
S1—Ag2cu—S5ii101.51 (6)Ag5—S5—Cu1i73.64 (6)
S1—Ag2cu—S9ii130.28 (7)Ag8vi—S5—Ag9i92.82 (6)
S2—Ag2cu—S5ii98.12 (5)Ag8vi—S5—Ag1082.85 (8)
S2—Ag2cu—S9ii113.31 (7)Ag8vi—S5—Cu1i72.71 (7)
S5ii—Ag2cu—S9ii89.57 (8)Ag9i—S5—Ag10145.76 (6)
Ag3cu—Ag3—S20Ag9i—S5—Cu1i73.16 (5)
Ag3cu—Ag3—S30Ag10—S5—Cu1i73.14 (5)
Ag3cu—Ag3—S100Ag7—S6—Ag7v112.77 (5)
Ag3cu—Ag3—S10v0Ag7—S6—Ag7iii112.77 (5)
Ag3cu—Ag3—S10iii0Ag7—S6—Cu274.08 (5)
S2—Ag3—S3104.11 (9)Ag7v—S6—Ag7112.77 (5)
S2—Ag3—S10134.4 (3)Ag7v—S6—Ag7iii112.77 (5)
S2—Ag3—S10v116.7 (3)Ag7v—S6—Cu274.08 (5)
S2—Ag3—S10iii133.0 (3)Ag7iii—S6—Ag7112.77 (5)
S3—Ag3—S10119.8 (3)Ag7iii—S6—Ag7v112.77 (5)
S3—Ag3—S10v138.7 (3)Ag7iii—S6—Cu274.08 (6)
S3—Ag3—S10iii122.8 (3)Ag5—S7—Ag6vii135.37 (8)
S10—Ag3—S10v19.2 (3)Ag5—S7—Ag7134.50 (6)
S10—Ag3—S10iii12.33 (17)Ag5—S7—Ag975.74 (5)
S10v—Ag3—S1019.2 (3)Ag5—S7—Ag10vii87.16 (5)
S10v—Ag3—S10iii17.5 (4)Ag6vii—S7—Ag789.36 (6)
S10iii—Ag3—S1012.33 (17)Ag6vii—S7—Ag983.53 (8)
S10iii—Ag3—S10v17.5 (4)Ag6vii—S7—Ag10vii76.82 (6)
Ag3—Ag3cu—S20Ag7—S7—Ag9108.23 (6)
Ag3—Ag3cu—S30Ag7—S7—Ag10vii116.56 (9)
Ag3—Ag3cu—S100Ag9—S7—Ag10vii130.32 (9)
Ag3—Ag3cu—S10v0Ag5—S8—Ag5i78.60 (7)
Ag3—Ag3cu—S10iii0Ag5—S8—Ag5ii78.60 (7)
S2—Ag3cu—S3104.11 (6)Ag5—S8—Ag8vii95.68 (5)
S2—Ag3cu—S10134.4 (3)Ag5—S8—Ag8xii77.54 (5)
S2—Ag3cu—S10v116.7 (3)Ag5—S8—Ag8ix156.13 (8)
S2—Ag3cu—S10iii133.0 (3)Ag5i—S8—Ag578.60 (7)
S3—Ag3cu—S10119.8 (3)Ag5i—S8—Ag5ii78.61 (6)
S3—Ag3cu—S10v138.7 (3)Ag5i—S8—Ag8vii156.13 (8)
S3—Ag3cu—S10iii122.8 (3)Ag5i—S8—Ag8xii95.68 (4)
S10—Ag3cu—S10v19.2 (3)Ag5i—S8—Ag8ix77.54 (4)
S10—Ag3cu—S10iii12.33 (17)Ag5ii—S8—Ag578.60 (7)
S10v—Ag3cu—S1019.2 (3)Ag5ii—S8—Ag5i78.61 (6)
S10v—Ag3cu—S10iii17.5 (4)Ag5ii—S8—Ag8vii77.54 (4)
S10iii—Ag3cu—S1012.33 (17)Ag5ii—S8—Ag8xii156.13 (9)
S10iii—Ag3cu—S10v17.5 (4)Ag5ii—S8—Ag8ix95.68 (6)
S4—Ag4—S4vi105.05 (7)Ag8vii—S8—Ag8xii105.78 (8)
S4—Ag4—S9145.08 (7)Ag8vii—S8—Ag8ix105.78 (9)
S4vi—Ag4—S4105.05 (7)Ag8xii—S8—Ag8vii105.78 (8)
S4vi—Ag4—S9109.86 (7)Ag8xii—S8—Ag8ix105.78 (10)
Cu1i—Ag5—S1129.00 (6)Ag8ix—S8—Ag8vii105.78 (9)
Cu1i—Ag5—S544.25 (3)Ag8ix—S8—Ag8xii105.78 (10)
Cu1i—Ag5—S779.87 (5)Ag1—S9—Ag1iv69.75 (5)
Cu1i—Ag5—S8104.02 (4)Ag1—S9—Ag2i86.60 (6)
S1—Ag5—S588.60 (6)Ag1—S9—Ag2xiii156.35 (9)
S1—Ag5—S789.29 (4)Ag1—S9—Ag2cui86.60 (6)
S1—Ag5—S8126.90 (7)Ag1—S9—Ag2cuxiii156.35 (9)
S5—Ag5—S795.93 (5)Ag1—S9—Ag476.39 (5)
S5—Ag5—S8138.47 (4)Ag1—S9—Ag4iv77.85 (8)
S7—Ag5—S8104.28 (5)Ag1iv—S9—Ag169.75 (5)
S2iii—Ag6—S7vii158.12 (7)Ag1iv—S9—Ag2i156.35 (9)
Cu2—Ag7—S3143.83 (5)Ag1iv—S9—Ag2xiii86.60 (6)
Cu2—Ag7—S647.46 (5)Ag1iv—S9—Ag2cui156.35 (9)
Cu2—Ag7—S7120.47 (4)Ag1iv—S9—Ag2cuxiii86.60 (6)
S3—Ag7—S6101.89 (6)Ag1iv—S9—Ag477.85 (8)
S3—Ag7—S794.62 (5)Ag1iv—S9—Ag4iv76.39 (5)
S6—Ag7—S7158.03 (6)Ag2i—S9—Ag2xiii117.05 (8)
Cu1vii—Ag8—S4151.33 (6)Ag2i—S9—Ag2cui0
Cu1vii—Ag8—S5viii47.39 (5)Ag2i—S9—Ag2cuxiii117.05 (8)
Cu1vii—Ag8—S8vii109.97 (7)Ag2i—S9—Ag497.10 (4)
S4—Ag8—S5viii105.70 (7)Ag2i—S9—Ag4iv99.22 (12)
S4—Ag8—S8vii97.84 (7)Ag2xiii—S9—Ag2i117.05 (8)
S5viii—Ag8—S8vii140.63 (11)Ag2xiii—S9—Ag2cui117.05 (8)
Cu1—Ag9—S5ii48.07 (4)Ag2xiii—S9—Ag2cuxiii0
Cu1—Ag9—S7136.30 (4)Ag2xiii—S9—Ag499.22 (12)
S5ii—Ag9—S7173.36 (5)Ag2xiii—S9—Ag4iv97.10 (4)
Cu1i—Ag10—S3137.70 (9)Ag2cui—S9—Ag2cuxiii117.05 (8)
Cu1i—Ag10—S546.16 (4)Ag2cui—S9—Ag497.10 (3)
Cu1i—Ag10—S7vii87.83 (5)Ag2cui—S9—Ag4iv99.22 (12)
S3—Ag10—S599.06 (7)Ag2cuxiii—S9—Ag2cui117.05 (8)
S3—Ag10—S7vii125.66 (7)Ag2cuxiii—S9—Ag499.22 (12)
S5—Ag10—S7vii133.35 (7)Ag2cuxiii—S9—Ag4iv97.10 (3)
Ag5ii—Cu1—Ag5ix158.40 (5)Ag4—S9—Ag4iv148.46 (9)
Ag5ii—Cu1—Ag8v121.57 (3)Ag4iv—S9—Ag4148.46 (9)
Ag5ii—Cu1—Ag8vii67.25 (3)Ag3—S10—Ag3v85.5 (2)
Ag5ii—Cu1—Ag963.19 (2)Ag3—S10—Ag3iv109.7 (3)
Ag5ii—Cu1—Ag9x137.80 (4)Ag3—S10—Ag3iii93.49 (16)
Ag5ii—Cu1—Ag10ii84.47 (5)Ag3—S10—Ag3xiv101.1 (4)
Ag5ii—Cu1—Ag10ix79.31 (5)Ag3—S10—Ag3xv164.7 (3)
Ag5ii—Cu1—S5ii62.12 (5)Ag3—S10—Ag3cu0
Ag5ii—Cu1—S5ix119.79 (5)Ag3—S10—Ag3cuv85.5 (2)
Ag5ix—Cu1—Ag5ii158.40 (5)Ag3—S10—Ag3cuiv109.7 (3)
Ag5ix—Cu1—Ag8v67.25 (4)Ag3—S10—Ag3cuiii93.49 (15)
Ag5ix—Cu1—Ag8vii121.57 (3)Ag3—S10—Ag3cuxiv101.1 (4)
Ag5ix—Cu1—Ag9137.80 (4)Ag3—S10—Ag3cuxv164.7 (3)
Ag5ix—Cu1—Ag9x63.19 (2)Ag3—S10—S10v106.3 (9)
Ag5ix—Cu1—Ag10ii79.31 (5)Ag3—S10—S10iii135.77 (19)
Ag5ix—Cu1—Ag10ix84.47 (5)Ag3v—S10—Ag385.5 (2)
Ag5ix—Cu1—S5ii119.79 (6)Ag3v—S10—Ag3iv164.7 (3)
Ag5ix—Cu1—S5ix62.12 (6)Ag3v—S10—Ag3iii78.91 (16)
Ag8v—Cu1—Ag8vii137.15 (8)Ag3v—S10—Ag3xiv81.5 (3)
Ag8v—Cu1—Ag981.34 (6)Ag3v—S10—Ag3xv79.44 (19)
Ag8v—Cu1—Ag9x65.53 (5)Ag3v—S10—Ag3cu85.5 (2)
Ag8v—Cu1—Ag10ii73.92 (6)Ag3v—S10—Ag3cuv0
Ag8v—Cu1—Ag10ix145.74 (8)Ag3v—S10—Ag3cuiv164.7 (3)
Ag8v—Cu1—S5ii59.90 (5)Ag3v—S10—Ag3cuiii78.91 (15)
Ag8v—Cu1—S5ix116.40 (5)Ag3v—S10—Ag3cuxiv81.5 (3)
Ag8vii—Cu1—Ag8v137.15 (8)Ag3v—S10—Ag3cuxv79.44 (18)
Ag8vii—Cu1—Ag965.53 (4)Ag3v—S10—S10v31.90 (15)
Ag8vii—Cu1—Ag9x81.34 (4)Ag3v—S10—S10iii61.1 (9)
Ag8vii—Cu1—Ag10ii145.74 (6)Ag3iv—S10—Ag3109.7 (3)
Ag8vii—Cu1—Ag10ix73.92 (7)Ag3iv—S10—Ag3v164.7 (3)
Ag8vii—Cu1—S5ii116.40 (7)Ag3iv—S10—Ag3iii101.1 (4)
Ag8vii—Cu1—S5ix59.90 (7)Ag3iv—S10—Ag3xiv93.49 (16)
Ag9—Cu1—Ag9x78.72 (3)Ag3iv—S10—Ag3xv85.5 (2)
Ag9—Cu1—Ag10ii119.19 (4)Ag3iv—S10—Ag3cu109.7 (3)
Ag9—Cu1—Ag10ix132.50 (5)Ag3iv—S10—Ag3cuv164.7 (3)
Ag9—Cu1—S5ii58.76 (7)Ag3iv—S10—Ag3cuiv0
Ag9—Cu1—S5ix113.45 (7)Ag3iv—S10—Ag3cuiii101.1 (4)
Ag9x—Cu1—Ag978.72 (3)Ag3iv—S10—Ag3cuxiv93.49 (15)
Ag9x—Cu1—Ag10ii132.50 (4)Ag3iv—S10—Ag3cuxv85.5 (2)
Ag9x—Cu1—Ag10ix119.19 (3)Ag3iv—S10—S10v135.77 (19)
Ag9x—Cu1—S5ii113.45 (5)Ag3iv—S10—S10iii106.3 (9)
Ag9x—Cu1—S5ix58.76 (4)Ag3iii—S10—Ag393.49 (16)
Ag10ii—Cu1—Ag10ix82.43 (6)Ag3iii—S10—Ag3v78.91 (16)
Ag10ii—Cu1—S5ii60.70 (8)Ag3iii—S10—Ag3iv101.1 (4)
Ag10ii—Cu1—S5ix127.35 (8)Ag3iii—S10—Ag3xiv154.5 (3)
Ag10ix—Cu1—Ag10ii82.43 (6)Ag3iii—S10—Ag3xv81.5 (3)
Ag10ix—Cu1—S5ii127.35 (6)Ag3iii—S10—Ag3cu93.49 (15)
Ag10ix—Cu1—S5ix60.70 (5)Ag3iii—S10—Ag3cuv78.91 (15)
S5ii—Cu1—S5ix171.05 (9)Ag3iii—S10—Ag3cuiv101.1 (4)
S5ix—Cu1—S5ii171.05 (9)Ag3iii—S10—Ag3cuiii0
Ag7—Cu2—Ag7v95.15 (2)Ag3iii—S10—Ag3cuxiv154.5 (3)
Ag7—Cu2—Ag7vii68.524 (18)Ag3iii—S10—Ag3cuxv81.5 (3)
Ag7—Cu2—Ag7iii95.15 (2)Ag3iii—S10—S10v101.4 (9)
Ag7—Cu2—Ag7x107.16 (2)Ag3iii—S10—S10iii54.5 (8)
Ag7—Cu2—Ag7xi153.08 (3)Ag3xiv—S10—Ag3101.1 (4)
Ag7—Cu2—S658.467 (12)Ag3xiv—S10—Ag3v81.5 (3)
Ag7—Cu2—S6vii121.533 (12)Ag3xiv—S10—Ag3iv93.49 (16)
Ag7v—Cu2—Ag795.15 (2)Ag3xiv—S10—Ag3iii154.5 (3)
Ag7v—Cu2—Ag7vii153.08 (3)Ag3xiv—S10—Ag3xv78.91 (16)
Ag7v—Cu2—Ag7iii95.15 (3)Ag3xiv—S10—Ag3cu101.1 (4)
Ag7v—Cu2—Ag7x68.52 (2)Ag3xiv—S10—Ag3cuv81.5 (3)
Ag7v—Cu2—Ag7xi107.16 (2)Ag3xiv—S10—Ag3cuiv93.49 (15)
Ag7v—Cu2—S658.467 (13)Ag3xiv—S10—Ag3cuiii154.5 (3)
Ag7v—Cu2—S6vii121.533 (13)Ag3xiv—S10—Ag3cuxiv0
Ag7vii—Cu2—Ag768.524 (18)Ag3xiv—S10—Ag3cuxv78.91 (15)
Ag7vii—Cu2—Ag7v153.08 (3)Ag3xiv—S10—S10v54.5 (8)
Ag7vii—Cu2—Ag7iii107.16 (2)Ag3xiv—S10—S10iii101.4 (9)
Ag7vii—Cu2—Ag7x95.15 (2)Ag3xv—S10—Ag3164.7 (3)
Ag7vii—Cu2—Ag7xi95.15 (2)Ag3xv—S10—Ag3v79.44 (19)
Ag7vii—Cu2—S6121.533 (12)Ag3xv—S10—Ag3iv85.5 (2)
Ag7vii—Cu2—S6vii58.467 (12)Ag3xv—S10—Ag3iii81.5 (3)
Ag7iii—Cu2—Ag795.15 (2)Ag3xv—S10—Ag3xiv78.91 (16)
Ag7iii—Cu2—Ag7v95.15 (3)Ag3xv—S10—Ag3cu164.7 (3)
Ag7iii—Cu2—Ag7vii107.16 (2)Ag3xv—S10—Ag3cuv79.44 (18)
Ag7iii—Cu2—Ag7x153.08 (2)Ag3xv—S10—Ag3cuiv85.5 (2)
Ag7iii—Cu2—Ag7xi68.52 (2)Ag3xv—S10—Ag3cuiii81.5 (3)
Ag7iii—Cu2—S658.467 (15)Ag3xv—S10—Ag3cuxiv78.91 (15)
Ag7iii—Cu2—S6vii121.533 (15)Ag3xv—S10—Ag3cuxv0
Ag7x—Cu2—Ag7107.16 (2)Ag3xv—S10—S10v61.1 (9)
Ag7x—Cu2—Ag7v68.52 (2)Ag3xv—S10—S10iii31.90 (15)
Ag7x—Cu2—Ag7vii95.15 (2)Ag3cu—S10—Ag3cuv85.5 (2)
Ag7x—Cu2—Ag7iii153.08 (2)Ag3cu—S10—Ag3cuiv109.7 (3)
Ag7x—Cu2—Ag7xi95.15 (3)Ag3cu—S10—Ag3cuiii93.49 (14)
Ag7x—Cu2—S6121.533 (15)Ag3cu—S10—Ag3cuxiv101.1 (4)
Ag7x—Cu2—S6vii58.467 (15)Ag3cu—S10—Ag3cuxv164.7 (3)
Ag7xi—Cu2—Ag7153.08 (3)Ag3cu—S10—S10v106.3 (9)
Ag7xi—Cu2—Ag7v107.16 (2)Ag3cu—S10—S10iii135.77 (19)
Ag7xi—Cu2—Ag7vii95.15 (2)Ag3cuv—S10—Ag3cu85.5 (2)
Ag7xi—Cu2—Ag7iii68.52 (2)Ag3cuv—S10—Ag3cuiv164.7 (3)
Ag7xi—Cu2—Ag7x95.15 (3)Ag3cuv—S10—Ag3cuiii78.91 (14)
Ag7xi—Cu2—S6121.533 (13)Ag3cuv—S10—Ag3cuxiv81.5 (3)
Ag7xi—Cu2—S6vii58.467 (13)Ag3cuv—S10—Ag3cuxv79.44 (17)
S6—Cu2—S6vii180Ag3cuv—S10—S10v31.90 (15)
S6vii—Cu2—S6180Ag3cuv—S10—S10iii61.1 (9)
Sb1—S1—Ag1102.21 (6)Ag3cuiv—S10—Ag3cu109.7 (3)
Sb1—S1—Ag2101.31 (8)Ag3cuiv—S10—Ag3cuv164.7 (3)
Sb1—S1—Ag2cu101.31 (8)Ag3cuiv—S10—Ag3cuiii101.1 (4)
Sb1—S1—Ag5108.73 (6)Ag3cuiv—S10—Ag3cuxiv93.49 (14)
Ag1—S1—Ag2114.28 (7)Ag3cuiv—S10—Ag3cuxv85.5 (2)
Ag1—S1—Ag2cu114.28 (6)Ag3cuiv—S10—S10v135.77 (19)
Ag1—S1—Ag5101.10 (8)Ag3cuiv—S10—S10iii106.3 (9)
Ag2—S1—Ag2cu0Ag3cuiii—S10—Ag3cu93.49 (14)
Ag2—S1—Ag5126.80 (7)Ag3cuiii—S10—Ag3cuv78.91 (14)
Ag2cu—S1—Ag5126.80 (7)Ag3cuiii—S10—Ag3cuiv101.1 (4)
Sb2v—S2—Ag2100.30 (8)Ag3cuiii—S10—Ag3cuxiv154.5 (3)
Sb2v—S2—Ag2cu100.30 (8)Ag3cuiii—S10—Ag3cuxv81.5 (3)
Sb2v—S2—Ag3100.21 (7)Ag3cuiii—S10—S10v101.4 (9)
Sb2v—S2—Ag3cu100.21 (6)Ag3cuiii—S10—S10iii54.5 (8)
Sb2v—S2—Ag6v102.21 (7)Ag3cuxiv—S10—Ag3cu101.1 (4)
Ag2—S2—Ag2cu0Ag3cuxiv—S10—Ag3cuv81.5 (3)
Ag2—S2—Ag3110.65 (7)Ag3cuxiv—S10—Ag3cuiv93.49 (14)
Ag2—S2—Ag3cu110.65 (6)Ag3cuxiv—S10—Ag3cuiii154.5 (3)
Ag2—S2—Ag6v119.51 (10)Ag3cuxiv—S10—Ag3cuxv78.91 (14)
Ag2cu—S2—Ag3110.65 (7)Ag3cuxiv—S10—S10v54.5 (8)
Ag2cu—S2—Ag3cu110.65 (6)Ag3cuxiv—S10—S10iii101.4 (9)
Ag2cu—S2—Ag6v119.51 (9)Ag3cuxv—S10—Ag3cu164.7 (3)
Ag3—S2—Ag3cu0Ag3cuxv—S10—Ag3cuv79.44 (17)
Ag3—S2—Ag6v119.23 (11)Ag3cuxv—S10—Ag3cuiv85.5 (2)
Ag3cu—S2—Ag6v119.23 (10)Ag3cuxv—S10—Ag3cuiii81.5 (3)
Sb2—S3—Ag1104.20 (7)Ag3cuxv—S10—Ag3cuxiv78.91 (14)
Sb2—S3—Ag3102.02 (8)Ag3cuxv—S10—S10v61.1 (9)
Sb2—S3—Ag3cu102.02 (6)Ag3cuxv—S10—S10iii31.90 (15)
Sb2—S3—Ag7122.88 (8)S10v—S10—S10iii60.0 (14)
Sb2—S3—Ag1096.78 (9)S10iii—S10—S10v60.0 (14)
Ag1—S3—Ag3119.29 (10)
Symmetry codes: (i) y+1, xy+1, z; (ii) x+y, x+1, z; (iii) x+y, x, z; (iv) y, x, z; (v) y, xy, z; (vi) x+y+1, x+1, z; (vii) y, x, z+1; (viii) y+1, xy, z; (ix) xy, y+1, z+1; (x) x, x+y, z+1; (xi) xy, y, z+1; (xii) x+1, x+y+1, z+1; (xiii) xy+1, y+1, z; (xiv) x, x+y, z; (xv) xy, y, z.
(polybasite222) top
Crystal data top
Ag14.814Cu1.186S11Sb2F(000) = 16139
Mr = 2269.5Dx = 6.401 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71069 Å
Hall symbol: -C 2ycCell parameters from 228 reflections
a = 26.188 (3) Åθ = 6.4–36°
b = 15.1199 (18) ŵ = 16.25 mm1
c = 23.784 (3) ÅT = 100 K
β = 90°Block, black
V = 9418 (2) Å30.15 × 0.12 × 0.09 mm
Z = 16
Data collection top
Nonius CCD
diffractometer
Rint = 0.073
ω, ϕ scansθmax = 36.0°, θmin = 6.5°
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
h = 4339
Tmin = 0.186, Tmax = 0.268k = 2524
43813 independent reflectionsl = 3839
38767 reflections with I > 2σ(I)
Refinement top
Refinement on FWeighting scheme based on measured s.u.'s w = 1/(σ2(F) + 0.000484F2)
R[F2 > 2σ(F2)] = 0.050(Δ/σ)max = 0.002
wR(F2) = 0.057Δρmax = 1.15 e Å3
S = 1.48Δρmin = 1.10 e Å3
43813 reflectionsExtinction correction: B-C type 1 Gaussian isotropic (Becker & Coppens, 1974)
592 parametersExtinction coefficient: 0.058449
Crystal data top
Ag14.814Cu1.186S11Sb2V = 9418 (2) Å3
Mr = 2269.5Z = 16
Monoclinic, C2/cMo Kα radiation
a = 26.188 (3) ŵ = 16.25 mm1
b = 15.1199 (18) ÅT = 100 K
c = 23.784 (3) Å0.15 × 0.12 × 0.09 mm
β = 90°
Data collection top
Nonius CCD
diffractometer
43813 independent reflections
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
38767 reflections with I > 2σ(I)
Tmin = 0.186, Tmax = 0.268Rint = 0.073
Refinement top
R[F2 > 2σ(F2)] = 0.050592 parameters
wR(F2) = 0.057Δρmax = 1.15 e Å3
S = 1.48Δρmin = 1.10 e Å3
43813 reflections
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Sb10.16691 (2)0.24468 (4)0.043172 (19)0.00956 (11)
Sb20.16495 (2)0.75956 (3)0.04531 (2)0.00994 (11)
Sb30.42279 (2)0.00463 (3)0.04458 (2)0.00930 (11)
Sb40.41010 (2)0.50144 (3)0.04556 (2)0.00909 (11)
Ag10.03265 (3)0.15019 (4)0.05067 (3)0.01525 (15)
Ag20.04411 (3)0.35807 (5)0.06687 (3)0.02130 (18)
Ag30.04367 (7)0.62582 (12)0.07179 (7)0.0183 (2)0.629 (10)
Ag3cu0.0436710.6258230.0717910.0183 (2)0.371 (10)
Ag40.02949 (3)0.86029 (5)0.05571 (3)0.01601 (15)
Ag50.16341 (3)0.00236 (4)0.07795 (3)0.01789 (15)
Ag60.18568 (3)0.50214 (4)0.04781 (3)0.01345 (14)
Ag70.28893 (3)0.10133 (4)0.05286 (3)0.01352 (14)
Ag80.28366 (3)0.37619 (4)0.06492 (3)0.01808 (16)
Ag90.28776 (6)0.62742 (10)0.06453 (6)0.02113 (18)
Ag100.28782 (3)0.90120 (4)0.05781 (3)0.01542 (15)
Ag110.43191 (3)0.25277 (4)0.05661 (3)0.01649 (16)
Ag120.41473 (8)0.74569 (10)0.06274 (7)0.0292 (3)
Ag130.16136 (2)0.00334 (5)0.20404 (3)0.01731 (15)
Ag140.34606 (6)0.02735 (14)0.17942 (7)0.0278 (2)
Ag150.46076 (3)0.00332 (5)0.19763 (3)0.01657 (15)
Ag160.09979 (3)0.19379 (5)0.19995 (3)0.01964 (17)
Ag170.22299 (3)0.17223 (4)0.19582 (3)0.01814 (16)
Ag180.41209 (3)0.20694 (5)0.18710 (3)0.01792 (16)
Ag190.05294 (3)0.37623 (4)0.19771 (3)0.01483 (14)
Ag200.17400 (3)0.37194 (5)0.19025 (3)0.01810 (16)
Ag210.29031 (3)0.36252 (4)0.19557 (3)0.01846 (16)
Ag220.40081 (3)0.42196 (5)0.19368 (3)0.01853 (16)
Ag230.06107 (3)0.63423 (4)0.19347 (3)0.01860 (16)
Ag240.18582 (7)0.63050 (10)0.18493 (6)0.02220 (18)
Ag250.30915 (3)0.60887 (5)0.18989 (3)0.02353 (19)
Ag260.46596 (4)0.59302 (5)0.18331 (3)0.0265 (2)
Ag270.01979 (3)0.90541 (4)0.18484 (3)0.02073 (17)
Ag280.13309 (7)0.80839 (10)0.19781 (6)0.02180 (19)
Ag290.25624 (6)0.84547 (6)0.19081 (4)0.0504 (4)
Ag300.41597 (3)0.80262 (5)0.18696 (3)0.02007 (17)
Cu100.23886 (9)0.250.0097 (3)
Cu200.75503 (10)0.250.0127 (3)
Cu30.24135 (4)0.50395 (7)0.24890 (4)0.0107 (2)
S10.11844 (8)0.14076 (13)0.09828 (8)0.0124 (4)
S20.13520 (8)0.37545 (13)0.08965 (8)0.0117 (4)
S30.24561 (8)0.23559 (12)0.09666 (8)0.0096 (4)
S40.13478 (8)0.62719 (13)0.09082 (8)0.0125 (5)
S50.11857 (8)0.86442 (13)0.10367 (9)0.0135 (5)
S60.24456 (8)0.76115 (13)0.09706 (9)0.0123 (5)
S70.49861 (8)0.00273 (13)0.10515 (8)0.0128 (4)
S80.37890 (8)0.11781 (13)0.08808 (8)0.0102 (4)
S90.37867 (8)0.37455 (13)0.09860 (8)0.0113 (4)
S100.49477 (7)0.50546 (12)0.08729 (8)0.0099 (4)
S110.37878 (8)0.61442 (13)0.10859 (9)0.0133 (5)
S120.37553 (8)0.88766 (13)0.09824 (9)0.0127 (5)
S130.22726 (8)0.00277 (16)0.00135 (9)0.0155 (5)
S140.48778 (12)0.77813 (18)0.00040 (10)0.0278 (7)
S150.07259 (7)0.01881 (13)0.23137 (8)0.0097 (4)
S160.24775 (8)0.00902 (13)0.16066 (8)0.0097 (4)
S170.00440 (8)0.24792 (13)0.15961 (7)0.0095 (4)
S180.32644 (7)0.22384 (12)0.22820 (7)0.0090 (4)
S190.10304 (7)0.50215 (12)0.22999 (8)0.0088 (4)
S200.24470 (7)0.49395 (12)0.15820 (7)0.0088 (4)
S210.00012 (8)0.74821 (13)0.15950 (7)0.0086 (4)
S220.33157 (7)0.75747 (11)0.23146 (6)0.0070 (4)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sb10.0107 (2)0.0090 (2)0.00900 (17)0.00039 (17)0.00115 (18)0.00059 (16)
Sb20.0117 (2)0.00890 (19)0.00920 (18)0.00008 (16)0.00150 (18)0.00023 (15)
Sb30.01021 (19)0.0092 (2)0.00850 (19)0.00040 (16)0.00135 (15)0.00093 (16)
Sb40.01014 (19)0.00880 (19)0.00834 (18)0.00010 (16)0.00106 (15)0.00067 (16)
Ag10.0145 (3)0.0157 (3)0.0156 (3)0.0025 (2)0.0003 (2)0.0005 (2)
Ag20.0128 (3)0.0251 (3)0.0261 (3)0.0018 (2)0.0000 (2)0.0072 (3)
Ag30.0155 (4)0.0192 (4)0.0201 (4)0.0052 (3)0.0004 (3)0.0038 (3)
Ag3cu0.0155 (4)0.0192 (4)0.0201 (4)0.0052 (3)0.0004 (3)0.0038 (3)
Ag40.0137 (3)0.0173 (3)0.0170 (3)0.0017 (2)0.0003 (2)0.0006 (2)
Ag50.0214 (3)0.0120 (2)0.0202 (3)0.0008 (2)0.0061 (2)0.0007 (2)
Ag60.0141 (2)0.0140 (2)0.0122 (2)0.0004 (2)0.00375 (19)0.0001 (2)
Ag70.0133 (3)0.0123 (2)0.0149 (3)0.00038 (19)0.0027 (2)0.00264 (19)
Ag80.0170 (3)0.0135 (3)0.0237 (3)0.0031 (2)0.0055 (2)0.0001 (2)
Ag90.0226 (3)0.0198 (3)0.0209 (3)0.0098 (3)0.0012 (3)0.0030 (2)
Ag100.0144 (3)0.0143 (3)0.0175 (3)0.0001 (2)0.0011 (2)0.0032 (2)
Ag110.0183 (3)0.0121 (3)0.0191 (3)0.0023 (2)0.0008 (2)0.0016 (2)
Ag120.0542 (6)0.0129 (3)0.0204 (3)0.0067 (3)0.0004 (4)0.0032 (2)
Ag130.0103 (2)0.0233 (3)0.0183 (3)0.0039 (2)0.0046 (2)0.0056 (2)
Ag140.0102 (3)0.0612 (6)0.0119 (3)0.0024 (3)0.0004 (2)0.0029 (3)
Ag150.0142 (2)0.0236 (3)0.0119 (2)0.0034 (2)0.00292 (19)0.0011 (2)
Ag160.0208 (3)0.0207 (3)0.0174 (3)0.0053 (2)0.0049 (2)0.0065 (2)
Ag170.0226 (3)0.0187 (3)0.0131 (2)0.0005 (2)0.0079 (2)0.0004 (2)
Ag180.0098 (2)0.0293 (3)0.0147 (3)0.0016 (2)0.0009 (2)0.0046 (2)
Ag190.0185 (3)0.0090 (2)0.0170 (3)0.00400 (19)0.0035 (2)0.0010 (2)
Ag200.0190 (3)0.0192 (3)0.0161 (3)0.0003 (2)0.0042 (2)0.0047 (2)
Ag210.0186 (3)0.0140 (3)0.0228 (3)0.0071 (2)0.0050 (2)0.0052 (2)
Ag220.0195 (3)0.0232 (3)0.0129 (3)0.0053 (2)0.0028 (2)0.0033 (2)
Ag230.0239 (3)0.0135 (3)0.0184 (3)0.0080 (2)0.0062 (2)0.0031 (2)
Ag240.0319 (4)0.0202 (3)0.0145 (3)0.0156 (3)0.0016 (3)0.0033 (2)
Ag250.0374 (4)0.0211 (3)0.0121 (3)0.0170 (3)0.0048 (3)0.0019 (2)
Ag260.0467 (5)0.0204 (3)0.0125 (3)0.0202 (3)0.0029 (3)0.0038 (2)
Ag270.0315 (4)0.0144 (3)0.0163 (3)0.0115 (2)0.0074 (3)0.0036 (2)
Ag280.0377 (4)0.0153 (3)0.0124 (3)0.0037 (3)0.0027 (3)0.0013 (2)
Ag290.1043 (10)0.0296 (4)0.0174 (3)0.0423 (5)0.0133 (5)0.0080 (3)
Ag300.0112 (3)0.0371 (4)0.0119 (3)0.0036 (2)0.0000 (2)0.0022 (2)
Cu10.0121 (5)0.0108 (6)0.0063 (5)00.0023 (5)0
Cu20.0159 (6)0.0147 (6)0.0075 (5)00.0017 (5)0
Cu30.0126 (4)0.0125 (4)0.0070 (3)0.0019 (3)0.0012 (3)0.0015 (3)
S10.0121 (8)0.0121 (8)0.0130 (8)0.0022 (6)0.0003 (6)0.0010 (6)
S20.0123 (8)0.0078 (7)0.0149 (8)0.0001 (6)0.0019 (6)0.0006 (6)
S30.0095 (7)0.0097 (7)0.0095 (7)0.0004 (6)0.0009 (6)0.0013 (6)
S40.0176 (9)0.0083 (7)0.0115 (7)0.0006 (6)0.0021 (7)0.0002 (6)
S50.0123 (8)0.0132 (8)0.0151 (8)0.0035 (6)0.0014 (7)0.0002 (6)
S60.0096 (8)0.0118 (7)0.0155 (9)0.0003 (6)0.0015 (6)0.0029 (6)
S70.0078 (7)0.0185 (8)0.0122 (7)0.0013 (6)0.0009 (6)0.0023 (6)
S80.0129 (8)0.0086 (7)0.0092 (7)0.0009 (6)0.0015 (6)0.0002 (6)
S90.0132 (8)0.0104 (7)0.0101 (7)0.0032 (6)0.0013 (6)0.0010 (6)
S100.0071 (7)0.0096 (7)0.0129 (7)0.0002 (6)0.0009 (6)0.0031 (6)
S110.0146 (8)0.0100 (7)0.0154 (8)0.0019 (6)0.0018 (7)0.0016 (6)
S120.0145 (8)0.0103 (7)0.0134 (8)0.0022 (6)0.0006 (7)0.0032 (6)
S130.0127 (7)0.0219 (9)0.0120 (8)0.0009 (8)0.0004 (6)0.0008 (7)
S140.0401 (15)0.0262 (12)0.0172 (10)0.0170 (10)0.0002 (10)0.0101 (9)
S150.0082 (7)0.0121 (7)0.0088 (7)0.0017 (5)0.0014 (6)0.0029 (6)
S160.0081 (7)0.0132 (8)0.0078 (7)0.0005 (6)0.0022 (6)0.0013 (6)
S170.0118 (8)0.0097 (7)0.0070 (6)0.0022 (6)0.0027 (6)0.0010 (6)
S180.0089 (7)0.0101 (7)0.0080 (6)0.0013 (6)0.0005 (6)0.0014 (5)
S190.0080 (7)0.0091 (7)0.0094 (7)0.0010 (6)0.0005 (5)0.0003 (6)
S200.0107 (7)0.0090 (7)0.0067 (6)0.0021 (6)0.0007 (6)0.0007 (6)
S210.0103 (7)0.0089 (7)0.0065 (6)0.0001 (6)0.0007 (6)0.0005 (6)
S220.0079 (7)0.0061 (6)0.0070 (6)0.0031 (5)0.0012 (6)0.0009 (5)
Geometric parameters (Å, º) top
Sb1—S12.408 (2)Ag14—S19viii2.562 (2)
Sb1—S22.413 (2)Ag15—S72.414 (2)
Sb1—S32.426 (2)Ag15—S19viii2.3992 (19)
Sb2—S42.409 (2)Ag16—Cu12.9514 (8)
Sb2—S52.432 (2)Ag16—S12.594 (2)
Sb2—S62.421 (2)Ag16—S152.840 (2)
Sb3—S72.453 (2)Ag16—S172.798 (2)
Sb3—S82.412 (2)Ag16—S22viii2.6115 (19)
Sb3—S12i2.411 (2)Ag17—S32.614 (2)
Sb4—S92.439 (2)Ag17—S162.685 (2)
Sb4—S102.430 (2)Ag17—S182.923 (2)
Sb4—S112.416 (2)Ag17—S22viii2.5872 (18)
Ag1—S12.520 (2)Ag18—Cu2ix2.8402 (8)
Ag1—S10ii2.556 (2)Ag18—S82.849 (2)
Ag1—S14ii2.569 (3)Ag18—S182.460 (2)
Ag2—S22.461 (2)Ag18—S21ix2.477 (2)
Ag2—S7iii2.584 (2)Ag19—Cu12.7899 (12)
Ag2—S14ii2.489 (3)Ag19—S172.490 (2)
Ag2—S172.953 (2)Ag19—S192.4363 (19)
Ag3—Ag3cu0Ag20—S22.600 (2)
Ag3—Ag232.9324 (18)Ag20—S192.8674 (19)
Ag3—S42.429 (3)Ag20—S202.723 (2)
Ag3—S7iii2.408 (3)Ag20—S22viii2.5463 (17)
Ag3—S14iv2.381 (3)Ag21—Ag29viii2.9757 (12)
Ag3cu—Ag232.9324 (7)Ag21—Cu32.7976 (12)
Ag3cu—S42.429 (2)Ag21—S182.4277 (19)
Ag3cu—S7iii2.408 (2)Ag21—S202.483 (2)
Ag3cu—S14iv2.381 (3)Ag22—S92.442 (2)
Ag4—S52.598 (2)Ag22—S15x2.410 (2)
Ag4—S10iii2.492 (2)Ag23—Cu22.7752 (12)
Ag4—S14iv2.513 (3)Ag23—S192.4395 (19)
Ag5—Ag132.9994 (10)Ag23—S212.484 (2)
Ag5—S12.450 (2)Ag24—Cu32.8444 (19)
Ag5—S5i2.470 (2)Ag24—S42.607 (3)
Ag5—S132.474 (2)Ag24—S18x2.523 (2)
Ag5—S162.959 (2)Ag24—S202.654 (3)
Ag6—Ag7v2.9364 (9)Ag25—Cu32.7639 (13)
Ag6—Ag10iv2.9879 (9)Ag25—S112.659 (2)
Ag6—S22.531 (2)Ag25—S202.537 (2)
Ag6—S42.530 (2)Ag25—S222.5240 (18)
Ag6—S13v2.562 (2)Ag26—Cu1xi2.8588 (13)
Ag7—S32.548 (2)Ag26—S102.745 (2)
Ag7—S82.513 (2)Ag26—S112.911 (2)
Ag7—S132.566 (2)Ag26—S15x2.529 (2)
Ag8—S32.466 (2)Ag26—S17xi2.611 (2)
Ag8—S92.614 (2)Ag27—Cu22.7999 (14)
Ag8—S13v2.496 (2)Ag27—S10iii2.846 (2)
Ag9—S62.443 (3)Ag27—S15vi2.465 (2)
Ag9—S112.611 (3)Ag27—S212.506 (2)
Ag9—S13v2.482 (3)Ag28—S52.424 (3)
Ag10—S62.577 (2)Ag28—S18x2.420 (2)
Ag10—S122.499 (2)Ag29—Cu3x2.7932 (14)
Ag10—S13vi2.535 (2)Ag29—S62.587 (2)
Ag11—S82.579 (2)Ag29—S16vi2.584 (2)
Ag11—S92.516 (2)Ag29—S222.568 (2)
Ag11—S14vii2.536 (3)Ag30—Cu1xi2.8319 (8)
Ag12—S112.453 (3)Ag30—S122.688 (2)
Ag12—S122.525 (3)Ag30—S17xi2.544 (2)
Ag12—S142.481 (3)Ag30—S222.544 (2)
Ag13—Cu3viii2.7829 (12)Cu1—S172.1572 (17)
Ag13—S152.425 (2)Cu1—S17xii2.1572 (17)
Ag13—S162.488 (2)Cu2—S212.1549 (16)
Ag14—Cu3viii2.8760 (19)Cu2—S21xii2.1549 (16)
Ag14—S82.707 (3)Cu3—S16x2.171 (2)
Ag14—S12i2.964 (3)Cu3—S202.164 (2)
Ag14—S162.628 (3)
S1—Sb1—S295.96 (7)Ag23—Cu2—S21xii116.95 (7)
S1—Sb1—S397.20 (7)Ag23xii—Cu2—Ag2397.68 (5)
S2—Sb1—S395.66 (7)Ag23xii—Cu2—Ag27155.40 (3)
S4—Sb2—S596.97 (7)Ag23xii—Cu2—Ag27xii99.18 (2)
S4—Sb2—S693.57 (7)Ag23xii—Cu2—S21116.95 (7)
S5—Sb2—S697.67 (7)Ag23xii—Cu2—S21xii58.91 (6)
S7—Sb3—S897.18 (7)Ag27—Cu2—Ag27xii71.41 (4)
S7—Sb3—S12i96.46 (7)Ag27—Cu2—S2159.05 (6)
S8—Sb3—S12i92.68 (7)Ag27—Cu2—S21xii126.30 (8)
S9—Sb4—S1096.68 (7)Ag27xii—Cu2—Ag2771.41 (4)
S9—Sb4—S1196.93 (7)Ag27xii—Cu2—S21126.30 (8)
S10—Sb4—S1192.21 (7)Ag27xii—Cu2—S21xii59.05 (6)
S1—Ag1—S10ii98.31 (7)S21—Cu2—S21xii174.51 (11)
S1—Ag1—S14ii131.52 (8)S21xii—Cu2—S21174.51 (11)
S10ii—Ag1—S14ii128.93 (8)Ag13x—Cu3—Ag14x119.38 (5)
S2—Ag2—S7iii106.41 (7)Ag13x—Cu3—Ag2176.12 (3)
S2—Ag2—S14ii140.17 (9)Ag13x—Cu3—Ag24133.27 (5)
S2—Ag2—S17103.71 (7)Ag13x—Cu3—Ag2567.54 (3)
S7iii—Ag2—S14ii110.41 (8)Ag13x—Cu3—Ag29viii76.70 (4)
S7iii—Ag2—S1791.94 (6)Ag13x—Cu3—S16x58.75 (6)
S14ii—Ag2—S1789.86 (7)Ag13x—Cu3—S20111.31 (7)
Ag3cu—Ag3—Ag230Ag14x—Cu3—Ag21136.69 (6)
Ag3cu—Ag3—S40Ag14x—Cu3—Ag2480.07 (6)
Ag3cu—Ag3—S7iii0Ag14x—Cu3—Ag25137.88 (6)
Ag3cu—Ag3—S14iv0Ag14x—Cu3—Ag29viii79.58 (5)
Ag23—Ag3—S470.31 (6)Ag14x—Cu3—S16x60.86 (7)
Ag23—Ag3—S7iii77.65 (7)Ag14x—Cu3—S20129.18 (7)
Ag23—Ag3—S14iv136.97 (10)Ag21—Cu3—Ag24120.40 (5)
S4—Ag3—S7iii115.27 (10)Ag21—Cu3—Ag2585.07 (3)
S4—Ag3—S14iv117.87 (11)Ag21—Cu3—Ag29viii64.32 (3)
S7iii—Ag3—S14iv123.89 (11)Ag21—Cu3—S16x114.57 (7)
Ag3—Ag3cu—Ag230Ag21—Cu3—S2058.40 (6)
Ag3—Ag3cu—S40Ag24—Cu3—Ag2570.78 (4)
Ag3—Ag3cu—S7iii0Ag24—Cu3—Ag29viii149.68 (6)
Ag3—Ag3cu—S14iv0Ag24—Cu3—S16x124.99 (7)
Ag23—Ag3cu—S470.31 (5)Ag24—Cu3—S2062.26 (6)
Ag23—Ag3cu—S7iii77.65 (5)Ag25—Cu3—Ag29viii137.60 (5)
Ag23—Ag3cu—S14iv136.97 (6)Ag25—Cu3—S16x113.47 (7)
S4—Ag3cu—S7iii115.27 (7)Ag25—Cu3—S2060.52 (6)
S4—Ag3cu—S14iv117.87 (8)Ag29viii—Cu3—S16x61.23 (6)
S7iii—Ag3cu—S14iv123.89 (8)Ag29viii—Cu3—S20116.80 (7)
S5—Ag4—S10iii100.03 (7)S16x—Cu3—S20169.92 (9)
S5—Ag4—S14iv114.30 (8)Sb1—S1—Ag1100.87 (7)
S10iii—Ag4—S14iv145.66 (9)Sb1—S1—Ag5101.34 (8)
Ag13—Ag5—S177.87 (5)Sb1—S1—Ag16113.89 (8)
Ag13—Ag5—S5i75.41 (5)Ag1—S1—Ag5112.85 (8)
Ag13—Ag5—S13138.46 (6)Ag1—S1—Ag16103.50 (7)
Ag13—Ag5—S1649.35 (4)Ag5—S1—Ag16122.59 (8)
S1—Ag5—S5i116.34 (7)Sb1—S2—Ag298.35 (7)
S1—Ag5—S13119.81 (8)Sb1—S2—Ag6105.09 (8)
S1—Ag5—S16101.45 (6)Sb1—S2—Ag20105.69 (7)
S5i—Ag5—S13118.50 (8)Ag2—S2—Ag6120.04 (8)
S5i—Ag5—S16102.65 (6)Ag2—S2—Ag20125.41 (8)
S13—Ag5—S1689.21 (6)Ag6—S2—Ag2099.97 (7)
Ag7v—Ag6—Ag10iv61.48 (2)Sb1—S3—Ag7102.06 (7)
Ag7v—Ag6—S292.04 (5)Sb1—S3—Ag897.70 (7)
Ag7v—Ag6—S4147.92 (5)Sb1—S3—Ag17107.54 (7)
Ag7v—Ag6—S13v55.14 (5)Ag7—S3—Ag8112.44 (8)
Ag10iv—Ag6—S2145.28 (5)Ag7—S3—Ag17100.25 (7)
Ag10iv—Ag6—S495.55 (5)Ag8—S3—Ag17133.13 (8)
Ag10iv—Ag6—S13v53.69 (5)Sb2—S4—Ag3104.22 (9)
S2—Ag6—S497.55 (7)Sb2—S4—Ag3cu104.22 (8)
S2—Ag6—S13v130.31 (7)Sb2—S4—Ag6105.45 (8)
S4—Ag6—S13v130.60 (7)Sb2—S4—Ag24101.63 (8)
Ag6v—Ag7—S3149.16 (5)Ag3—S4—Ag3cu0
Ag6v—Ag7—S896.45 (5)Ag3—S4—Ag6115.85 (9)
Ag6v—Ag7—S1355.00 (5)Ag3—S4—Ag24131.59 (10)
S3—Ag7—S8101.66 (7)Ag3cu—S4—Ag6115.85 (8)
S3—Ag7—S13113.80 (7)Ag3cu—S4—Ag24131.59 (9)
S8—Ag7—S13144.09 (7)Ag6—S4—Ag2495.24 (8)
S3—Ag8—S9106.42 (7)Sb2—S5—Ag4100.50 (7)
S3—Ag8—S13v143.90 (7)Sb2—S5—Ag5vi99.88 (8)
S9—Ag8—S13v108.06 (7)Sb2—S5—Ag28102.76 (8)
S6—Ag9—S11110.98 (9)Ag4—S5—Ag5vi109.79 (8)
S6—Ag9—S13v139.03 (10)Ag4—S5—Ag28122.56 (9)
S11—Ag9—S13v109.92 (9)Ag5vi—S5—Ag28116.69 (9)
Ag6iv—Ag10—S6143.97 (5)Sb2—S6—Ag9103.27 (8)
Ag6iv—Ag10—S1298.64 (5)Sb2—S6—Ag10101.68 (7)
Ag6iv—Ag10—S13vi54.54 (5)Sb2—S6—Ag29123.01 (9)
S6—Ag10—S12101.38 (7)Ag9—S6—Ag10111.22 (9)
S6—Ag10—S13vi112.81 (7)Ag9—S6—Ag29128.78 (10)
S12—Ag10—S13vi145.68 (7)Ag10—S6—Ag2981.68 (6)
S8—Ag11—S999.53 (7)Sb3—S7—Ag2ix99.02 (7)
S8—Ag11—S14vii116.98 (8)Sb3—S7—Ag3ix102.27 (8)
S9—Ag11—S14vii143.48 (8)Sb3—S7—Ag3cuix102.27 (7)
S11—Ag12—S12112.53 (10)Sb3—S7—Ag15101.72 (8)
S11—Ag12—S14136.48 (11)Ag2ix—S7—Ag3ix108.38 (9)
S12—Ag12—S14110.36 (10)Ag2ix—S7—Ag3cuix108.38 (8)
Ag5—Ag13—Cu3viii112.69 (3)Ag2ix—S7—Ag15122.76 (8)
Ag5—Ag13—S15106.60 (5)Ag3ix—S7—Ag3cuix0
Ag5—Ag13—S1664.49 (5)Ag3ix—S7—Ag15118.08 (9)
Cu3viii—Ag13—S15140.31 (6)Ag3cuix—S7—Ag15118.08 (8)
Cu3viii—Ag13—S1648.25 (5)Sb3—S8—Ag7103.17 (7)
S15—Ag13—S16168.37 (7)Sb3—S8—Ag11103.08 (7)
Cu3viii—Ag14—S8142.24 (8)Sb3—S8—Ag1496.19 (8)
Cu3viii—Ag14—S12i120.38 (8)Sb3—S8—Ag18124.90 (8)
Cu3viii—Ag14—S1646.20 (5)Ag7—S8—Ag11119.10 (8)
Cu3viii—Ag14—S19viii84.10 (7)Ag7—S8—Ag1485.39 (7)
S8—Ag14—S12i75.79 (7)Ag7—S8—Ag18127.48 (8)
S8—Ag14—S16103.20 (8)Ag11—S8—Ag14143.47 (9)
S8—Ag14—S19viii125.78 (9)Ag11—S8—Ag1872.63 (5)
S12i—Ag14—S1693.98 (8)Ag14—S8—Ag1870.89 (6)
S12i—Ag14—S19viii107.84 (9)Sb4—S9—Ag898.93 (7)
S16—Ag14—S19viii129.56 (9)Sb4—S9—Ag11100.57 (7)
S7—Ag15—S19viii159.95 (7)Sb4—S9—Ag2299.67 (7)
Cu1—Ag16—S1127.89 (5)Ag8—S9—Ag11114.37 (8)
Cu1—Ag16—S1583.50 (5)Ag8—S9—Ag22120.46 (8)
Cu1—Ag16—S1743.97 (4)Ag11—S9—Ag22116.79 (8)
Cu1—Ag16—S22viii105.81 (5)Sb4—S10—Ag1xi103.68 (7)
S1—Ag16—S1590.26 (6)Sb4—S10—Ag4ix100.82 (7)
S1—Ag16—S1786.50 (6)Sb4—S10—Ag2695.80 (7)
S1—Ag16—S22viii124.52 (6)Sb4—S10—Ag27ix121.98 (8)
S15—Ag16—S1797.98 (6)Ag1xi—S10—Ag4ix120.65 (8)
S15—Ag16—S22viii110.59 (6)Ag1xi—S10—Ag2688.70 (6)
S17—Ag16—S22viii136.12 (6)Ag1xi—S10—Ag27ix130.06 (8)
S3—Ag17—S1690.06 (6)Ag4ix—S10—Ag26140.88 (8)
S3—Ag17—S1885.98 (6)Ag4ix—S10—Ag27ix72.15 (5)
S3—Ag17—S22viii123.08 (6)Ag26—S10—Ag27ix68.99 (5)
S16—Ag17—S1895.94 (6)Sb4—S11—Ag996.55 (8)
S16—Ag17—S22viii143.07 (6)Sb4—S11—Ag1299.55 (9)
S18—Ag17—S22viii101.70 (6)Sb4—S11—Ag25131.42 (8)
Cu2ix—Ag18—S8143.49 (5)Sb4—S11—Ag2691.95 (7)
Cu2ix—Ag18—S18120.22 (5)Ag9—S11—Ag1296.38 (9)
Cu2ix—Ag18—S21ix47.21 (4)Ag9—S11—Ag2570.62 (6)
S8—Ag18—S1895.70 (6)Ag9—S11—Ag26165.75 (9)
S8—Ag18—S21ix100.60 (6)Ag12—S11—Ag25127.75 (9)
S18—Ag18—S21ix158.10 (7)Ag12—S11—Ag2693.46 (8)
Cu1—Ag19—S1747.81 (4)Ag25—S11—Ag2695.19 (7)
Cu1—Ag19—S19135.15 (5)Sb3vi—S12—Ag10102.29 (8)
S17—Ag19—S19176.77 (7)Sb3vi—S12—Ag12100.87 (9)
S2—Ag20—S1992.07 (6)Sb3vi—S12—Ag14vi89.83 (7)
S2—Ag20—S2089.67 (6)Sb3vi—S12—Ag30122.43 (9)
S2—Ag20—S22viii131.64 (6)Ag10—S12—Ag12108.35 (9)
S19—Ag20—S2093.89 (6)Ag10—S12—Ag14vi87.30 (7)
S19—Ag20—S22viii100.87 (6)Ag10—S12—Ag30134.70 (9)
S20—Ag20—S22viii134.77 (6)Ag12—S12—Ag14vi158.37 (10)
Ag29viii—Ag21—Cu357.77 (3)Ag12—S12—Ag3072.28 (7)
Ag29viii—Ag21—S1878.15 (5)Ag14vi—S12—Ag3086.11 (7)
Ag29viii—Ag21—S20101.38 (5)Ag5—S13—Ag6v159.60 (10)
Cu3—Ag21—S18133.94 (5)Ag5—S13—Ag793.13 (7)
Cu3—Ag21—S2047.94 (5)Ag5—S13—Ag8v111.32 (9)
S18—Ag21—S20173.26 (7)Ag5—S13—Ag9v112.43 (9)
S9—Ag22—S15x158.74 (7)Ag5—S13—Ag10i92.91 (7)
Ag3—Ag23—Ag3cu0Ag6v—S13—Ag769.86 (6)
Ag3—Ag23—Cu2114.65 (4)Ag6v—S13—Ag8v79.10 (7)
Ag3—Ag23—S19112.70 (6)Ag6v—S13—Ag9v81.70 (7)
Ag3—Ag23—S2167.00 (5)Ag6v—S13—Ag10i71.77 (6)
Ag3cu—Ag23—Cu2114.65 (2)Ag7—S13—Ag8v84.45 (7)
Ag3cu—Ag23—S19112.70 (5)Ag7—S13—Ag9v150.08 (10)
Ag3cu—Ag23—S2167.00 (4)Ag7—S13—Ag10i72.83 (6)
Cu2—Ag23—S19128.75 (5)Ag8v—S13—Ag9v99.52 (8)
Cu2—Ag23—S2147.98 (4)Ag8v—S13—Ag10i147.72 (9)
S19—Ag23—S21166.73 (7)Ag9v—S13—Ag10i89.92 (8)
Cu3—Ag24—S4135.10 (8)Ag1xi—S14—Ag2xi77.92 (8)
Cu3—Ag24—S18x90.18 (6)Ag1xi—S14—Ag3iv162.68 (13)
Cu3—Ag24—S2046.20 (5)Ag1xi—S14—Ag3cuiv162.68 (12)
S4—Ag24—S18x130.43 (9)Ag1xi—S14—Ag4iv72.70 (8)
S4—Ag24—S2094.44 (8)Ag1xi—S14—Ag11vii74.40 (8)
S18x—Ag24—S20134.85 (9)Ag1xi—S14—Ag1285.27 (9)
Cu3—Ag25—S11145.89 (6)Ag2xi—S14—Ag3iv111.54 (12)
Cu3—Ag25—S2047.96 (5)Ag2xi—S14—Ag3cuiv111.54 (11)
Cu3—Ag25—S22117.48 (5)Ag2xi—S14—Ag4iv147.94 (13)
S11—Ag25—S20105.18 (6)Ag2xi—S14—Ag11vii86.38 (10)
S11—Ag25—S2295.58 (6)Ag2xi—S14—Ag1299.43 (10)
S20—Ag25—S22151.74 (7)Ag3iv—S14—Ag3cuiv0
Cu1xi—Ag26—S10138.40 (5)Ag3iv—S14—Ag4iv94.15 (10)
Cu1xi—Ag26—S11119.84 (5)Ag3iv—S14—Ag11vii91.33 (10)
Cu1xi—Ag26—S15x91.23 (5)Ag3iv—S14—Ag12106.59 (13)
Cu1xi—Ag26—S17xi46.18 (4)Ag3cuiv—S14—Ag4iv94.15 (9)
S10—Ag26—S1176.19 (6)Ag3cuiv—S14—Ag11vii91.33 (9)
S10—Ag26—S15x124.28 (6)Ag3cuiv—S14—Ag12106.59 (12)
S10—Ag26—S17xi98.45 (6)Ag4iv—S14—Ag11vii73.73 (8)
S11—Ag26—S15x103.07 (7)Ag4iv—S14—Ag1290.77 (10)
S11—Ag26—S17xi94.07 (6)Ag11vii—S14—Ag12157.27 (13)
S15x—Ag26—S17xi136.48 (6)Ag13—S15—Ag1677.22 (6)
Cu2—Ag27—S10iii147.16 (5)Ag13—S15—Ag22viii82.09 (6)
Cu2—Ag27—S15vi114.84 (5)Ag13—S15—Ag26viii129.83 (8)
Cu2—Ag27—S2147.53 (4)Ag13—S15—Ag27i110.50 (8)
S10iii—Ag27—S15vi97.20 (6)Ag16—S15—Ag22viii133.49 (8)
S10iii—Ag27—S21105.12 (6)Ag16—S15—Ag26viii84.15 (6)
S15vi—Ag27—S21152.02 (7)Ag16—S15—Ag27i132.11 (8)
S5—Ag28—S18x157.70 (10)Ag22viii—S15—Ag26viii77.97 (6)
Ag21x—Ag29—Cu3x57.91 (3)Ag22viii—S15—Ag27i94.10 (7)
Ag21x—Ag29—S6140.99 (7)Ag26viii—S15—Ag27i116.42 (8)
Ag21x—Ag29—S16vi97.69 (5)Ag5—S16—Ag1366.16 (5)
Ag21x—Ag29—S2291.01 (5)Ag5—S16—Ag14147.96 (8)
Cu3x—Ag29—S6150.23 (6)Ag5—S16—Ag1793.33 (6)
Cu3x—Ag29—S16vi47.43 (5)Ag5—S16—Ag29i102.48 (7)
Cu3x—Ag29—S22103.52 (6)Ag5—S16—Cu3viii139.07 (9)
S6—Ag29—S16vi102.84 (7)Ag13—S16—Ag14145.51 (9)
S6—Ag29—S2299.20 (7)Ag13—S16—Ag1771.52 (5)
S16vi—Ag29—S22131.78 (8)Ag13—S16—Ag29i85.99 (7)
Cu1xi—Ag30—S12152.18 (5)Ag13—S16—Cu3viii73.00 (6)
Cu1xi—Ag30—S17xi46.94 (4)Ag14—S16—Ag1794.98 (8)
Cu1xi—Ag30—S22111.32 (5)Ag14—S16—Ag29i88.25 (8)
S12—Ag30—S17xi108.26 (6)Ag14—S16—Cu3viii72.94 (7)
S12—Ag30—S2296.47 (6)Ag17—S16—Ag29i144.47 (8)
S17xi—Ag30—S22144.12 (7)Ag17—S16—Cu3viii75.86 (6)
Ag16—Cu1—Ag16xii153.31 (5)Ag29i—S16—Cu3viii71.34 (6)
Ag16—Cu1—Ag1963.39 (2)Ag2—S17—Ag1696.13 (6)
Ag16—Cu1—Ag19xii142.34 (4)Ag2—S17—Ag1969.68 (5)
Ag16—Cu1—Ag26ii82.78 (3)Ag2—S17—Ag26ii143.41 (7)
Ag16—Cu1—Ag26viii76.68 (3)Ag2—S17—Ag30ii109.16 (7)
Ag16—Cu1—Ag30ii123.58 (2)Ag2—S17—Cu1143.04 (9)
Ag16—Cu1—Ag30viii66.68 (2)Ag16—S17—Ag1969.36 (5)
Ag16—Cu1—S1764.24 (6)Ag16—S17—Ag26ii90.45 (6)
Ag16—Cu1—S17xii117.64 (6)Ag16—S17—Ag30ii145.10 (7)
Ag16xii—Cu1—Ag16153.31 (5)Ag16—S17—Cu171.79 (6)
Ag16xii—Cu1—Ag19142.34 (4)Ag19—S17—Ag26ii144.81 (8)
Ag16xii—Cu1—Ag19xii63.39 (2)Ag19—S17—Ag30ii96.80 (7)
Ag16xii—Cu1—Ag26ii76.68 (3)Ag19—S17—Cu173.39 (6)
Ag16xii—Cu1—Ag26viii82.78 (3)Ag26ii—S17—Ag30ii83.41 (7)
Ag16xii—Cu1—Ag30ii66.68 (2)Ag26ii—S17—Cu172.98 (6)
Ag16xii—Cu1—Ag30viii123.58 (2)Ag30ii—S17—Cu173.57 (6)
Ag16xii—Cu1—S17117.64 (6)Ag17—S18—Ag18135.46 (7)
Ag16xii—Cu1—S17xii64.24 (6)Ag17—S18—Ag2177.59 (5)
Ag19—Cu1—Ag19xii83.76 (4)Ag17—S18—Ag24viii87.05 (7)
Ag19—Cu1—Ag26ii118.81 (2)Ag17—S18—Ag28viii137.63 (8)
Ag19—Cu1—Ag26viii131.81 (2)Ag18—S18—Ag21108.54 (7)
Ag19—Cu1—Ag30ii84.07 (3)Ag18—S18—Ag24viii112.54 (8)
Ag19—Cu1—Ag30viii66.20 (3)Ag18—S18—Ag28viii86.81 (7)
Ag19—Cu1—S1758.79 (6)Ag21—S18—Ag24viii134.06 (9)
Ag19—Cu1—S17xii115.06 (7)Ag21—S18—Ag28viii86.95 (7)
Ag19xii—Cu1—Ag1983.76 (4)Ag24viii—S18—Ag28viii75.85 (7)
Ag19xii—Cu1—Ag26ii131.81 (2)Ag14x—S19—Ag15x75.98 (6)
Ag19xii—Cu1—Ag26viii118.81 (2)Ag14x—S19—Ag19131.41 (9)
Ag19xii—Cu1—Ag30ii66.20 (3)Ag14x—S19—Ag2092.41 (7)
Ag19xii—Cu1—Ag30viii84.07 (3)Ag14x—S19—Ag23114.34 (8)
Ag19xii—Cu1—S17115.06 (7)Ag15x—S19—Ag1981.76 (6)
Ag19xii—Cu1—S17xii58.79 (6)Ag15x—S19—Ag20133.86 (7)
Ag26ii—Cu1—Ag26viii79.06 (4)Ag15x—S19—Ag2386.31 (6)
Ag26ii—Cu1—Ag30ii74.13 (3)Ag19—S19—Ag2073.06 (5)
Ag26ii—Cu1—Ag30viii143.00 (4)Ag19—S19—Ag23106.55 (7)
Ag26ii—Cu1—S1760.84 (6)Ag20—S19—Ag23137.45 (8)
Ag26ii—Cu1—S17xii125.82 (7)Ag20—S20—Ag2171.62 (5)
Ag26viii—Cu1—Ag26ii79.06 (4)Ag20—S20—Ag2493.72 (7)
Ag26viii—Cu1—Ag30ii143.00 (4)Ag20—S20—Ag25146.44 (8)
Ag26viii—Cu1—Ag30viii74.13 (3)Ag20—S20—Cu374.97 (6)
Ag26viii—Cu1—S17125.82 (7)Ag21—S20—Ag24144.71 (8)
Ag26viii—Cu1—S17xii60.84 (6)Ag21—S20—Ag2596.99 (7)
Ag30ii—Cu1—Ag30viii140.19 (6)Ag21—S20—Cu373.66 (6)
Ag30ii—Cu1—S1759.49 (6)Ag24—S20—Ag2577.45 (6)
Ag30ii—Cu1—S17xii117.67 (6)Ag24—S20—Cu371.54 (7)
Ag30viii—Cu1—Ag30ii140.19 (6)Ag25—S20—Cu371.52 (6)
Ag30viii—Cu1—S17117.67 (6)Ag18iii—S21—Ag23109.70 (7)
Ag30viii—Cu1—S17xii59.49 (6)Ag18iii—S21—Ag27111.50 (8)
S17—Cu1—S17xii172.71 (10)Ag18iii—S21—Cu275.28 (6)
S17xii—Cu1—S17172.71 (10)Ag23—S21—Ag27116.61 (8)
Ag18iii—Cu2—Ag18x150.33 (6)Ag23—S21—Cu273.10 (6)
Ag18iii—Cu2—Ag2392.49 (4)Ag27—S21—Cu273.42 (7)
Ag18iii—Cu2—Ag23xii67.64 (3)Ag16x—S22—Ag17x77.22 (5)
Ag18iii—Cu2—Ag2793.80 (3)Ag16x—S22—Ag20x80.40 (5)
Ag18iii—Cu2—Ag27xii110.45 (3)Ag16x—S22—Ag2594.39 (6)
Ag18iii—Cu2—S2157.51 (6)Ag16x—S22—Ag29162.72 (7)
Ag18iii—Cu2—S21xii120.84 (6)Ag16x—S22—Ag3076.15 (6)
Ag18x—Cu2—Ag18iii150.33 (6)Ag17x—S22—Ag20x79.52 (5)
Ag18x—Cu2—Ag2367.64 (3)Ag17x—S22—Ag2571.94 (5)
Ag18x—Cu2—Ag23xii92.49 (4)Ag17x—S22—Ag2994.91 (7)
Ag18x—Cu2—Ag27110.45 (3)Ag17x—S22—Ag30153.07 (8)
Ag18x—Cu2—Ag27xii93.80 (3)Ag20x—S22—Ag25151.43 (8)
Ag18x—Cu2—S21120.84 (6)Ag20x—S22—Ag2983.06 (6)
Ag18x—Cu2—S21xii57.51 (6)Ag20x—S22—Ag3099.88 (7)
Ag23—Cu2—Ag23xii97.68 (5)Ag25—S22—Ag2997.76 (7)
Ag23—Cu2—Ag2799.18 (2)Ag25—S22—Ag30106.14 (7)
Ag23—Cu2—Ag27xii155.40 (3)Ag29—S22—Ag30111.82 (7)
Ag23—Cu2—S2158.91 (6)
Symmetry codes: (i) x, y1, z; (ii) x1/2, y1/2, z; (iii) x1/2, y+1/2, z; (iv) x+1/2, y+3/2, z; (v) x+1/2, y+1/2, z; (vi) x, y+1, z; (vii) x+1, y+1, z; (viii) x+1/2, y1/2, z+1/2; (ix) x+1/2, y1/2, z; (x) x+1/2, y+1/2, z+1/2; (xi) x+1/2, y+1/2, z; (xii) x, y, z+1/2.

Experimental details

(polybasite221)(polybasite222)
Crystal data
Chemical formulaAg14.52Cu1.48S11Sb2Ag14.814Cu1.186S11Sb2
Mr2256.52269.5
Crystal system, space groupTrigonal, P321Monoclinic, C2/c
Temperature (K)120100
a, b, c (Å)15.0954 (12), 15.0954 (12), 11.8825 (8)26.188 (3), 15.1199 (18), 23.784 (3)
α, β, γ (°)90, 90, 12090, 90, 90
V3)2344.9 (3)9418 (2)
Z416
Radiation typeMo KαMo Kα
µ (mm1)16.3216.25
Crystal size (mm)0.14 × 0.08 × 0.060.15 × 0.12 × 0.09
Data collection
DiffractometerNonius CCD
diffractometer
Nonius CCD
diffractometer
Absorption correctionGaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
Gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
Tmin, Tmax0.196, 0.4170.186, 0.268
No. of measured, independent and
observed [I > 2σ(I)] reflections
?, 6847, 6224 ?, 43813, 38767
Rint0.0630.073
(sin θ/λ)max1)0.8070.827
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.036, 0.046, 1.41 0.050, 0.057, 1.48
No. of reflections684743813
No. of parameters224592
No. of restraints??
Δρmax, Δρmin (e Å3)1.05, 0.811.15, 1.10

Computer programs: (Jana2000; Petricek and Dusek, 2000).

Selected geometric parameters (Å, º) for (polybasite221) top
Sb1—S12.4127 (17)Ag4—S4vi2.609 (2)
Sb1—S1i2.4127 (16)Ag4—S92.502 (3)
Sb1—S1ii2.413 (3)Ag5—Cu1i2.9790 (14)
Sb2—S2iii2.4392 (15)Ag5—S12.6058 (17)
Sb2—S32.422 (3)Ag5—S52.744 (2)
Sb2—S42.4095 (16)Ag5—S72.8747 (14)
Ag1—Ag1iv2.9227 (9)Ag5—S82.5800 (18)
Ag1—S12.537 (2)Ag6—S2iii2.425 (2)
Ag1—S32.5324 (18)Ag6—S7vii2.4065 (18)
Ag1—S92.556 (2)Ag7—Cu22.8083 (5)
Ag2—Ag2cu0Ag7—S32.9156 (17)
Ag2—S12.4133 (18)Ag7—S62.4891 (8)
Ag2—S22.4810 (19)Ag7—S72.4552 (17)
Ag2—S5ii2.977 (2)Ag8—Cu1vii2.8103 (18)
Ag2—S9ii2.437 (3)Ag8—S42.638 (3)
Ag2cu—S12.4133 (17)Ag8—S5viii2.546 (3)
Ag2cu—S22.4810 (18)Ag8—S8vii2.5442 (16)
Ag2cu—S5ii2.977 (2)Ag9—Cu12.7868 (11)
Ag2cu—S9ii2.437 (3)Ag9—S5ii2.490 (3)
Ag3—Ag3cu0Ag9—S72.429 (2)
Ag3—S22.497 (3)Ag10—Cu1i2.8743 (15)
Ag3—S32.486 (2)Ag10—S32.704 (2)
Ag3—S102.088 (6)Ag10—S52.6192 (18)
Ag3—S10v2.462 (8)Ag10—S7vii2.533 (2)
Ag3—S10iii2.756 (7)Cu1—S5ii2.1663 (13)
Ag3cu—S22.497 (2)Cu1—S5ix2.1663 (13)
Ag3cu—S32.4855 (17)Cu2—S62.152 (2)
Ag3cu—S102.088 (6)Cu2—S6vii2.152 (2)
Ag3cu—S10v2.462 (8)S10—S10v0.844 (11)
Ag3cu—S10iii2.756 (7)S10—S10iii0.844 (11)
Ag4—S42.4786 (18)
S1—Sb1—S1i96.37 (7)Ag1—S3—Ag3cu119.29 (9)
S1—Sb1—S1ii96.37 (7)Ag1—S3—Ag7129.77 (9)
S1i—Sb1—S196.37 (7)Ag1—S3—Ag1088.71 (5)
S1i—Sb1—S1ii96.37 (8)Ag3—S3—Ag3cu0
S1ii—Sb1—S196.37 (7)Ag3—S3—Ag769.80 (6)
S1ii—Sb1—S1i96.37 (8)Ag3—S3—Ag10140.33 (8)
S2iii—Sb2—S396.56 (7)Ag3cu—S3—Ag769.80 (4)
S2iii—Sb2—S497.37 (7)Ag3cu—S3—Ag10140.33 (7)
S3—Sb2—S493.30 (7)Ag7—S3—Ag1070.63 (5)
Ag1iv—Ag1—S1149.18 (5)Sb2—S4—Ag4101.11 (7)
Ag1iv—Ag1—S394.25 (5)Sb2—S4—Ag4viii99.67 (6)
Ag1iv—Ag1—S955.12 (5)Sb2—S4—Ag8124.89 (7)
S1—Ag1—S398.74 (6)Ag4—S4—Ag4viii110.07 (6)
S1—Ag1—S9122.35 (8)Ag4—S4—Ag8132.63 (7)
S3—Ag1—S9138.06 (10)Ag4viii—S4—Ag4110.07 (6)
Ag2cu—Ag2—S10Ag4viii—S4—Ag875.59 (8)
Ag2cu—Ag2—S20Ag2i—S5—Ag2cui0
Ag2cu—Ag2—S5ii0Ag2i—S5—Ag593.84 (6)
Ag2cu—Ag2—S9ii0Ag2i—S5—Ag8vi107.12 (6)
S1—Ag2—S2112.77 (7)Ag2i—S5—Ag9i66.58 (4)
S1—Ag2—S5ii101.51 (6)Ag2i—S5—Ag10147.00 (6)
S1—Ag2—S9ii130.28 (7)Ag2i—S5—Cu1i139.71 (6)
S2—Ag2—S5ii98.12 (6)Ag2cui—S5—Ag593.84 (6)
S2—Ag2—S9ii113.31 (7)Ag2cui—S5—Ag8vi107.12 (6)
S5ii—Ag2—S9ii89.57 (8)Ag2cui—S5—Ag9i66.58 (4)
Ag2—Ag2cu—S10Ag2cui—S5—Ag10147.00 (6)
Ag2—Ag2cu—S20Ag2cui—S5—Cu1i139.71 (6)
Ag2—Ag2cu—S5ii0Ag5—S5—Ag8vi145.55 (6)
Ag2—Ag2cu—S9ii0Ag5—S5—Ag9i70.43 (5)
S1—Ag2cu—S2112.77 (6)Ag5—S5—Ag1094.36 (7)
S1—Ag2cu—S5ii101.51 (6)Ag5—S5—Cu1i73.64 (6)
S1—Ag2cu—S9ii130.28 (7)Ag8vi—S5—Ag9i92.82 (6)
S2—Ag2cu—S5ii98.12 (5)Ag8vi—S5—Ag1082.85 (8)
S2—Ag2cu—S9ii113.31 (7)Ag8vi—S5—Cu1i72.71 (7)
S5ii—Ag2cu—S9ii89.57 (8)Ag9i—S5—Ag10145.76 (6)
Ag3cu—Ag3—S20Ag9i—S5—Cu1i73.16 (5)
Ag3cu—Ag3—S30Ag10—S5—Cu1i73.14 (5)
Ag3cu—Ag3—S100Ag7—S6—Ag7v112.77 (5)
Ag3cu—Ag3—S10v0Ag7—S6—Ag7iii112.77 (5)
Ag3cu—Ag3—S10iii0Ag7—S6—Cu274.08 (5)
S2—Ag3—S3104.11 (9)Ag7v—S6—Ag7112.77 (5)
S2—Ag3—S10134.4 (3)Ag7v—S6—Ag7iii112.77 (5)
S2—Ag3—S10v116.7 (3)Ag7v—S6—Cu274.08 (5)
S2—Ag3—S10iii133.0 (3)Ag7iii—S6—Ag7112.77 (5)
S3—Ag3—S10119.8 (3)Ag7iii—S6—Ag7v112.77 (5)
S3—Ag3—S10v138.7 (3)Ag7iii—S6—Cu274.08 (6)
S3—Ag3—S10iii122.8 (3)Ag5—S7—Ag6vii135.37 (8)
S10—Ag3—S10v19.2 (3)Ag5—S7—Ag7134.50 (6)
S10—Ag3—S10iii12.33 (17)Ag5—S7—Ag975.74 (5)
S10v—Ag3—S1019.2 (3)Ag5—S7—Ag10vii87.16 (5)
S10v—Ag3—S10iii17.5 (4)Ag6vii—S7—Ag789.36 (6)
S10iii—Ag3—S1012.33 (17)Ag6vii—S7—Ag983.53 (8)
S10iii—Ag3—S10v17.5 (4)Ag6vii—S7—Ag10vii76.82 (6)
Ag3—Ag3cu—S20Ag7—S7—Ag9108.23 (6)
Ag3—Ag3cu—S30Ag7—S7—Ag10vii116.56 (9)
Ag3—Ag3cu—S100Ag9—S7—Ag10vii130.32 (9)
Ag3—Ag3cu—S10v0Ag5—S8—Ag5i78.60 (7)
Ag3—Ag3cu—S10iii0Ag5—S8—Ag5ii78.60 (7)
S2—Ag3cu—S3104.11 (6)Ag5—S8—Ag8vii95.68 (5)
S2—Ag3cu—S10134.4 (3)Ag5—S8—Ag8xii77.54 (5)
S2—Ag3cu—S10v116.7 (3)Ag5—S8—Ag8ix156.13 (8)
S2—Ag3cu—S10iii133.0 (3)Ag5i—S8—Ag578.60 (7)
S3—Ag3cu—S10119.8 (3)Ag5i—S8—Ag5ii78.61 (6)
S3—Ag3cu—S10v138.7 (3)Ag5i—S8—Ag8vii156.13 (8)
S3—Ag3cu—S10iii122.8 (3)Ag5i—S8—Ag8xii95.68 (4)
S10—Ag3cu—S10v19.2 (3)Ag5i—S8—Ag8ix77.54 (4)
S10—Ag3cu—S10iii12.33 (17)Ag5ii—S8—Ag578.60 (7)
S10v—Ag3cu—S1019.2 (3)Ag5ii—S8—Ag5i78.61 (6)
S10v—Ag3cu—S10iii17.5 (4)Ag5ii—S8—Ag8vii77.54 (4)
S10iii—Ag3cu—S1012.33 (17)Ag5ii—S8—Ag8xii156.13 (9)
S10iii—Ag3cu—S10v17.5 (4)Ag5ii—S8—Ag8ix95.68 (6)
S4—Ag4—S4vi105.05 (7)Ag8vii—S8—Ag8xii105.78 (8)
S4—Ag4—S9145.08 (7)Ag8vii—S8—Ag8ix105.78 (9)
S4vi—Ag4—S4105.05 (7)Ag8xii—S8—Ag8vii105.78 (8)
S4vi—Ag4—S9109.86 (7)Ag8xii—S8—Ag8ix105.78 (10)
Cu1i—Ag5—S1129.00 (6)Ag8ix—S8—Ag8vii105.78 (9)
Cu1i—Ag5—S544.25 (3)Ag8ix—S8—Ag8xii105.78 (10)
Cu1i—Ag5—S779.87 (5)Ag1—S9—Ag1iv69.75 (5)
Cu1i—Ag5—S8104.02 (4)Ag1—S9—Ag2i86.60 (6)
S1—Ag5—S588.60 (6)Ag1—S9—Ag2xiii156.35 (9)
S1—Ag5—S789.29 (4)Ag1—S9—Ag2cui86.60 (6)
S1—Ag5—S8126.90 (7)Ag1—S9—Ag2cuxiii156.35 (9)
S5—Ag5—S795.93 (5)Ag1—S9—Ag476.39 (5)
S5—Ag5—S8138.47 (4)Ag1—S9—Ag4iv77.85 (8)
S7—Ag5—S8104.28 (5)Ag1iv—S9—Ag169.75 (5)
S2iii—Ag6—S7vii158.12 (7)Ag1iv—S9—Ag2i156.35 (9)
Cu2—Ag7—S3143.83 (5)Ag1iv—S9—Ag2xiii86.60 (6)
Cu2—Ag7—S647.46 (5)Ag1iv—S9—Ag2cui156.35 (9)
Cu2—Ag7—S7120.47 (4)Ag1iv—S9—Ag2cuxiii86.60 (6)
S3—Ag7—S6101.89 (6)Ag1iv—S9—Ag477.85 (8)
S3—Ag7—S794.62 (5)Ag1iv—S9—Ag4iv76.39 (5)
S6—Ag7—S7158.03 (6)Ag2i—S9—Ag2xiii117.05 (8)
Cu1vii—Ag8—S4151.33 (6)Ag2i—S9—Ag2cui0
Cu1vii—Ag8—S5viii47.39 (5)Ag2i—S9—Ag2cuxiii117.05 (8)
Cu1vii—Ag8—S8vii109.97 (7)Ag2i—S9—Ag497.10 (4)
S4—Ag8—S5viii105.70 (7)Ag2i—S9—Ag4iv99.22 (12)
S4—Ag8—S8vii97.84 (7)Ag2xiii—S9—Ag2i117.05 (8)
S5viii—Ag8—S8vii140.63 (11)Ag2xiii—S9—Ag2cui117.05 (8)
Cu1—Ag9—S5ii48.07 (4)Ag2xiii—S9—Ag2cuxiii0
Cu1—Ag9—S7136.30 (4)Ag2xiii—S9—Ag499.22 (12)
S5ii—Ag9—S7173.36 (5)Ag2xiii—S9—Ag4iv97.10 (4)
Cu1i—Ag10—S3137.70 (9)Ag2cui—S9—Ag2cuxiii117.05 (8)
Cu1i—Ag10—S546.16 (4)Ag2cui—S9—Ag497.10 (3)
Cu1i—Ag10—S7vii87.83 (5)Ag2cui—S9—Ag4iv99.22 (12)
S3—Ag10—S599.06 (7)Ag2cuxiii—S9—Ag2cui117.05 (8)
S3—Ag10—S7vii125.66 (7)Ag2cuxiii—S9—Ag499.22 (12)
S5—Ag10—S7vii133.35 (7)Ag2cuxiii—S9—Ag4iv97.10 (3)
Ag5ii—Cu1—Ag5ix158.40 (5)Ag4—S9—Ag4iv148.46 (9)
Ag5ii—Cu1—Ag8v121.57 (3)Ag4iv—S9—Ag4148.46 (9)
Ag5ii—Cu1—Ag8vii67.25 (3)Ag3—S10—Ag3v85.5 (2)
Ag5ii—Cu1—Ag963.19 (2)Ag3—S10—Ag3iv109.7 (3)
Ag5ii—Cu1—Ag9x137.80 (4)Ag3—S10—Ag3iii93.49 (16)
Ag5ii—Cu1—Ag10ii84.47 (5)Ag3—S10—Ag3xiv101.1 (4)
Ag5ii—Cu1—Ag10ix79.31 (5)Ag3—S10—Ag3xv164.7 (3)
Ag5ii—Cu1—S5ii62.12 (5)Ag3—S10—Ag3cu0
Ag5ii—Cu1—S5ix119.79 (5)Ag3—S10—Ag3cuv85.5 (2)
Ag5ix—Cu1—Ag5ii158.40 (5)Ag3—S10—Ag3cuiv109.7 (3)
Ag5ix—Cu1—Ag8v67.25 (4)Ag3—S10—Ag3cuiii93.49 (15)
Ag5ix—Cu1—Ag8vii121.57 (3)Ag3—S10—Ag3cuxiv101.1 (4)
Ag5ix—Cu1—Ag9137.80 (4)Ag3—S10—Ag3cuxv164.7 (3)
Ag5ix—Cu1—Ag9x63.19 (2)Ag3—S10—S10v106.3 (9)
Ag5ix—Cu1—Ag10ii79.31 (5)Ag3—S10—S10iii135.77 (19)
Ag5ix—Cu1—Ag10ix84.47 (5)Ag3v—S10—Ag385.5 (2)
Ag5ix—Cu1—S5ii119.79 (6)Ag3v—S10—Ag3iv164.7 (3)
Ag5ix—Cu1—S5ix62.12 (6)Ag3v—S10—Ag3iii78.91 (16)
Ag8v—Cu1—Ag8vii137.15 (8)Ag3v—S10—Ag3xiv81.5 (3)
Ag8v—Cu1—Ag981.34 (6)Ag3v—S10—Ag3xv79.44 (19)
Ag8v—Cu1—Ag9x65.53 (5)Ag3v—S10—Ag3cu85.5 (2)
Ag8v—Cu1—Ag10ii73.92 (6)Ag3v—S10—Ag3cuv0
Ag8v—Cu1—Ag10ix145.74 (8)Ag3v—S10—Ag3cuiv164.7 (3)
Ag8v—Cu1—S5ii59.90 (5)Ag3v—S10—Ag3cuiii78.91 (15)
Ag8v—Cu1—S5ix116.40 (5)Ag3v—S10—Ag3cuxiv81.5 (3)
Ag8vii—Cu1—Ag8v137.15 (8)Ag3v—S10—Ag3cuxv79.44 (18)
Ag8vii—Cu1—Ag965.53 (4)Ag3v—S10—S10v31.90 (15)
Ag8vii—Cu1—Ag9x81.34 (4)Ag3v—S10—S10iii61.1 (9)
Ag8vii—Cu1—Ag10ii145.74 (6)Ag3iv—S10—Ag3109.7 (3)
Ag8vii—Cu1—Ag10ix73.92 (7)Ag3iv—S10—Ag3v164.7 (3)
Ag8vii—Cu1—S5ii116.40 (7)Ag3iv—S10—Ag3iii101.1 (4)
Ag8vii—Cu1—S5ix59.90 (7)Ag3iv—S10—Ag3xiv93.49 (16)
Ag9—Cu1—Ag9x78.72 (3)Ag3iv—S10—Ag3xv85.5 (2)
Ag9—Cu1—Ag10ii119.19 (4)Ag3iv—S10—Ag3cu109.7 (3)
Ag9—Cu1—Ag10ix132.50 (5)Ag3iv—S10—Ag3cuv164.7 (3)
Ag9—Cu1—S5ii58.76 (7)Ag3iv—S10—Ag3cuiv0
Ag9—Cu1—S5ix113.45 (7)Ag3iv—S10—Ag3cuiii101.1 (4)
Ag9x—Cu1—Ag978.72 (3)Ag3iv—S10—Ag3cuxiv93.49 (15)
Ag9x—Cu1—Ag10ii132.50 (4)Ag3iv—S10—Ag3cuxv85.5 (2)
Ag9x—Cu1—Ag10ix119.19 (3)Ag3iv—S10—S10v135.77 (19)
Ag9x—Cu1—S5ii113.45 (5)Ag3iv—S10—S10iii106.3 (9)
Ag9x—Cu1—S5ix58.76 (4)Ag3iii—S10—Ag393.49 (16)
Ag10ii—Cu1—Ag10ix82.43 (6)Ag3iii—S10—Ag3v78.91 (16)
Ag10ii—Cu1—S5ii60.70 (8)Ag3iii—S10—Ag3iv101.1 (4)
Ag10ii—Cu1—S5ix127.35 (8)Ag3iii—S10—Ag3xiv154.5 (3)
Ag10ix—Cu1—Ag10ii82.43 (6)Ag3iii—S10—Ag3xv81.5 (3)
Ag10ix—Cu1—S5ii127.35 (6)Ag3iii—S10—Ag3cu93.49 (15)
Ag10ix—Cu1—S5ix60.70 (5)Ag3iii—S10—Ag3cuv78.91 (15)
S5ii—Cu1—S5ix171.05 (9)Ag3iii—S10—Ag3cuiv101.1 (4)
S5ix—Cu1—S5ii171.05 (9)Ag3iii—S10—Ag3cuiii0
Ag7—Cu2—Ag7v95.15 (2)Ag3iii—S10—Ag3cuxiv154.5 (3)
Ag7—Cu2—Ag7vii68.524 (18)Ag3iii—S10—Ag3cuxv81.5 (3)
Ag7—Cu2—Ag7iii95.15 (2)Ag3iii—S10—S10v101.4 (9)
Ag7—Cu2—Ag7x107.16 (2)Ag3iii—S10—S10iii54.5 (8)
Ag7—Cu2—Ag7xi153.08 (3)Ag3xiv—S10—Ag3101.1 (4)
Ag7—Cu2—S658.467 (12)Ag3xiv—S10—Ag3v81.5 (3)
Ag7—Cu2—S6vii121.533 (12)Ag3xiv—S10—Ag3iv93.49 (16)
Ag7v—Cu2—Ag795.15 (2)Ag3xiv—S10—Ag3iii154.5 (3)
Ag7v—Cu2—Ag7vii153.08 (3)Ag3xiv—S10—Ag3xv78.91 (16)
Ag7v—Cu2—Ag7iii95.15 (3)Ag3xiv—S10—Ag3cu101.1 (4)
Ag7v—Cu2—Ag7x68.52 (2)Ag3xiv—S10—Ag3cuv81.5 (3)
Ag7v—Cu2—Ag7xi107.16 (2)Ag3xiv—S10—Ag3cuiv93.49 (15)
Ag7v—Cu2—S658.467 (13)Ag3xiv—S10—Ag3cuiii154.5 (3)
Ag7v—Cu2—S6vii121.533 (13)Ag3xiv—S10—Ag3cuxiv0
Ag7vii—Cu2—Ag768.524 (18)Ag3xiv—S10—Ag3cuxv78.91 (15)
Ag7vii—Cu2—Ag7v153.08 (3)Ag3xiv—S10—S10v54.5 (8)
Ag7vii—Cu2—Ag7iii107.16 (2)Ag3xiv—S10—S10iii101.4 (9)
Ag7vii—Cu2—Ag7x95.15 (2)Ag3xv—S10—Ag3164.7 (3)
Ag7vii—Cu2—Ag7xi95.15 (2)Ag3xv—S10—Ag3v79.44 (19)
Ag7vii—Cu2—S6121.533 (12)Ag3xv—S10—Ag3iv85.5 (2)
Ag7vii—Cu2—S6vii58.467 (12)Ag3xv—S10—Ag3iii81.5 (3)
Ag7iii—Cu2—Ag795.15 (2)Ag3xv—S10—Ag3xiv78.91 (16)
Ag7iii—Cu2—Ag7v95.15 (3)Ag3xv—S10—Ag3cu164.7 (3)
Ag7iii—Cu2—Ag7vii107.16 (2)Ag3xv—S10—Ag3cuv79.44 (18)
Ag7iii—Cu2—Ag7x153.08 (2)Ag3xv—S10—Ag3cuiv85.5 (2)
Ag7iii—Cu2—Ag7xi68.52 (2)Ag3xv—S10—Ag3cuiii81.5 (3)
Ag7iii—Cu2—S658.467 (15)Ag3xv—S10—Ag3cuxiv78.91 (15)
Ag7iii—Cu2—S6vii121.533 (15)Ag3xv—S10—Ag3cuxv0
Ag7x—Cu2—Ag7107.16 (2)Ag3xv—S10—S10v61.1 (9)
Ag7x—Cu2—Ag7v68.52 (2)Ag3xv—S10—S10iii31.90 (15)
Ag7x—Cu2—Ag7vii95.15 (2)Ag3cu—S10—Ag3cuv85.5 (2)
Ag7x—Cu2—Ag7iii153.08 (2)Ag3cu—S10—Ag3cuiv109.7 (3)
Ag7x—Cu2—Ag7xi95.15 (3)Ag3cu—S10—Ag3cuiii93.49 (14)
Ag7x—Cu2—S6121.533 (15)Ag3cu—S10—Ag3cuxiv101.1 (4)
Ag7x—Cu2—S6vii58.467 (15)Ag3cu—S10—Ag3cuxv164.7 (3)
Ag7xi—Cu2—Ag7153.08 (3)Ag3cu—S10—S10v106.3 (9)
Ag7xi—Cu2—Ag7v107.16 (2)Ag3cu—S10—S10iii135.77 (19)
Ag7xi—Cu2—Ag7vii95.15 (2)Ag3cuv—S10—Ag3cu85.5 (2)
Ag7xi—Cu2—Ag7iii68.52 (2)Ag3cuv—S10—Ag3cuiv164.7 (3)
Ag7xi—Cu2—Ag7x95.15 (3)Ag3cuv—S10—Ag3cuiii78.91 (14)
Ag7xi—Cu2—S6121.533 (13)Ag3cuv—S10—Ag3cuxiv81.5 (3)
Ag7xi—Cu2—S6vii58.467 (13)Ag3cuv—S10—Ag3cuxv79.44 (17)
S6—Cu2—S6vii180Ag3cuv—S10—S10v31.90 (15)
S6vii—Cu2—S6180Ag3cuv—S10—S10iii61.1 (9)
Sb1—S1—Ag1102.21 (6)Ag3cuiv—S10—Ag3cu109.7 (3)
Sb1—S1—Ag2101.31 (8)Ag3cuiv—S10—Ag3cuv164.7 (3)
Sb1—S1—Ag2cu101.31 (8)Ag3cuiv—S10—Ag3cuiii101.1 (4)
Sb1—S1—Ag5108.73 (6)Ag3cuiv—S10—Ag3cuxiv93.49 (14)
Ag1—S1—Ag2114.28 (7)Ag3cuiv—S10—Ag3cuxv85.5 (2)
Ag1—S1—Ag2cu114.28 (6)Ag3cuiv—S10—S10v135.77 (19)
Ag1—S1—Ag5101.10 (8)Ag3cuiv—S10—S10iii106.3 (9)
Ag2—S1—Ag2cu0Ag3cuiii—S10—Ag3cu93.49 (14)
Ag2—S1—Ag5126.80 (7)Ag3cuiii—S10—Ag3cuv78.91 (14)
Ag2cu—S1—Ag5126.80 (7)Ag3cuiii—S10—Ag3cuiv101.1 (4)
Sb2v—S2—Ag2100.30 (8)Ag3cuiii—S10—Ag3cuxiv154.5 (3)
Sb2v—S2—Ag2cu100.30 (8)Ag3cuiii—S10—Ag3cuxv81.5 (3)
Sb2v—S2—Ag3100.21 (7)Ag3cuiii—S10—S10v101.4 (9)
Sb2v—S2—Ag3cu100.21 (6)Ag3cuiii—S10—S10iii54.5 (8)
Sb2v—S2—Ag6v102.21 (7)Ag3cuxiv—S10—Ag3cu101.1 (4)
Ag2—S2—Ag2cu0Ag3cuxiv—S10—Ag3cuv81.5 (3)
Ag2—S2—Ag3110.65 (7)Ag3cuxiv—S10—Ag3cuiv93.49 (14)
Ag2—S2—Ag3cu110.65 (6)Ag3cuxiv—S10—Ag3cuiii154.5 (3)
Ag2—S2—Ag6v119.51 (10)Ag3cuxiv—S10—Ag3cuxv78.91 (14)
Ag2cu—S2—Ag3110.65 (7)Ag3cuxiv—S10—S10v54.5 (8)
Ag2cu—S2—Ag3cu110.65 (6)Ag3cuxiv—S10—S10iii101.4 (9)
Ag2cu—S2—Ag6v119.51 (9)Ag3cuxv—S10—Ag3cu164.7 (3)
Ag3—S2—Ag3cu0Ag3cuxv—S10—Ag3cuv79.44 (17)
Ag3—S2—Ag6v119.23 (11)Ag3cuxv—S10—Ag3cuiv85.5 (2)
Ag3cu—S2—Ag6v119.23 (10)Ag3cuxv—S10—Ag3cuiii81.5 (3)
Sb2—S3—Ag1104.20 (7)Ag3cuxv—S10—Ag3cuxiv78.91 (14)
Sb2—S3—Ag3102.02 (8)Ag3cuxv—S10—S10v61.1 (9)
Sb2—S3—Ag3cu102.02 (6)Ag3cuxv—S10—S10iii31.90 (15)
Sb2—S3—Ag7122.88 (8)S10v—S10—S10iii60.0 (14)
Sb2—S3—Ag1096.78 (9)S10iii—S10—S10v60.0 (14)
Ag1—S3—Ag3119.29 (10)
Symmetry codes: (i) y+1, xy+1, z; (ii) x+y, x+1, z; (iii) x+y, x, z; (iv) y, x, z; (v) y, xy, z; (vi) x+y+1, x+1, z; (vii) y, x, z+1; (viii) y+1, xy, z; (ix) xy, y+1, z+1; (x) x, x+y, z+1; (xi) xy, y, z+1; (xii) x+1, x+y+1, z+1; (xiii) xy+1, y+1, z; (xiv) x, x+y, z; (xv) xy, y, z.
Selected geometric parameters (Å, º) for (polybasite222) top
Sb1—S12.408 (2)Ag14—S19viii2.562 (2)
Sb1—S22.413 (2)Ag15—S72.414 (2)
Sb1—S32.426 (2)Ag15—S19viii2.3992 (19)
Sb2—S42.409 (2)Ag16—Cu12.9514 (8)
Sb2—S52.432 (2)Ag16—S12.594 (2)
Sb2—S62.421 (2)Ag16—S152.840 (2)
Sb3—S72.453 (2)Ag16—S172.798 (2)
Sb3—S82.412 (2)Ag16—S22viii2.6115 (19)
Sb3—S12i2.411 (2)Ag17—S32.614 (2)
Sb4—S92.439 (2)Ag17—S162.685 (2)
Sb4—S102.430 (2)Ag17—S182.923 (2)
Sb4—S112.416 (2)Ag17—S22viii2.5872 (18)
Ag1—S12.520 (2)Ag18—Cu2ix2.8402 (8)
Ag1—S10ii2.556 (2)Ag18—S82.849 (2)
Ag1—S14ii2.569 (3)Ag18—S182.460 (2)
Ag2—S22.461 (2)Ag18—S21ix2.477 (2)
Ag2—S7iii2.584 (2)Ag19—Cu12.7899 (12)
Ag2—S14ii2.489 (3)Ag19—S172.490 (2)
Ag2—S172.953 (2)Ag19—S192.4363 (19)
Ag3—Ag3cu0Ag20—S22.600 (2)
Ag3—Ag232.9324 (18)Ag20—S192.8674 (19)
Ag3—S42.429 (3)Ag20—S202.723 (2)
Ag3—S7iii2.408 (3)Ag20—S22viii2.5463 (17)
Ag3—S14iv2.381 (3)Ag21—Ag29viii2.9757 (12)
Ag3cu—Ag232.9324 (7)Ag21—Cu32.7976 (12)
Ag3cu—S42.429 (2)Ag21—S182.4277 (19)
Ag3cu—S7iii2.408 (2)Ag21—S202.483 (2)
Ag3cu—S14iv2.381 (3)Ag22—S92.442 (2)
Ag4—S52.598 (2)Ag22—S15x2.410 (2)
Ag4—S10iii2.492 (2)Ag23—Cu22.7752 (12)
Ag4—S14iv2.513 (3)Ag23—S192.4395 (19)
Ag5—Ag132.9994 (10)Ag23—S212.484 (2)
Ag5—S12.450 (2)Ag24—Cu32.8444 (19)
Ag5—S5i2.470 (2)Ag24—S42.607 (3)
Ag5—S132.474 (2)Ag24—S18x2.523 (2)
Ag5—S162.959 (2)Ag24—S202.654 (3)
Ag6—Ag7v2.9364 (9)Ag25—Cu32.7639 (13)
Ag6—Ag10iv2.9879 (9)Ag25—S112.659 (2)
Ag6—S22.531 (2)Ag25—S202.537 (2)
Ag6—S42.530 (2)Ag25—S222.5240 (18)
Ag6—S13v2.562 (2)Ag26—Cu1xi2.8588 (13)
Ag7—S32.548 (2)Ag26—S102.745 (2)
Ag7—S82.513 (2)Ag26—S112.911 (2)
Ag7—S132.566 (2)Ag26—S15x2.529 (2)
Ag8—S32.466 (2)Ag26—S17xi2.611 (2)
Ag8—S92.614 (2)Ag27—Cu22.7999 (14)
Ag8—S13v2.496 (2)Ag27—S10iii2.846 (2)
Ag9—S62.443 (3)Ag27—S15vi2.465 (2)
Ag9—S112.611 (3)Ag27—S212.506 (2)
Ag9—S13v2.482 (3)Ag28—S52.424 (3)
Ag10—S62.577 (2)Ag28—S18x2.420 (2)
Ag10—S122.499 (2)Ag29—Cu3x2.7932 (14)
Ag10—S13vi2.535 (2)Ag29—S62.587 (2)
Ag11—S82.579 (2)Ag29—S16vi2.584 (2)
Ag11—S92.516 (2)Ag29—S222.568 (2)
Ag11—S14vii2.536 (3)Ag30—Cu1xi2.8319 (8)
Ag12—S112.453 (3)Ag30—S122.688 (2)
Ag12—S122.525 (3)Ag30—S17xi2.544 (2)
Ag12—S142.481 (3)Ag30—S222.544 (2)
Ag13—Cu3viii2.7829 (12)Cu1—S172.1572 (17)
Ag13—S152.425 (2)Cu1—S17xii2.1572 (17)
Ag13—S162.488 (2)Cu2—S212.1549 (16)
Ag14—Cu3viii2.8760 (19)Cu2—S21xii2.1549 (16)
Ag14—S82.707 (3)Cu3—S16x2.171 (2)
Ag14—S12i2.964 (3)Cu3—S202.164 (2)
Ag14—S162.628 (3)
S1—Sb1—S295.96 (7)Ag23—Cu2—S21xii116.95 (7)
S1—Sb1—S397.20 (7)Ag23xii—Cu2—Ag2397.68 (5)
S2—Sb1—S395.66 (7)Ag23xii—Cu2—Ag27155.40 (3)
S4—Sb2—S596.97 (7)Ag23xii—Cu2—Ag27xii99.18 (2)
S4—Sb2—S693.57 (7)Ag23xii—Cu2—S21116.95 (7)
S5—Sb2—S697.67 (7)Ag23xii—Cu2—S21xii58.91 (6)
S7—Sb3—S897.18 (7)Ag27—Cu2—Ag27xii71.41 (4)
S7—Sb3—S12i96.46 (7)Ag27—Cu2—S2159.05 (6)
S8—Sb3—S12i92.68 (7)Ag27—Cu2—S21xii126.30 (8)
S9—Sb4—S1096.68 (7)Ag27xii—Cu2—Ag2771.41 (4)
S9—Sb4—S1196.93 (7)Ag27xii—Cu2—S21126.30 (8)
S10—Sb4—S1192.21 (7)Ag27xii—Cu2—S21xii59.05 (6)
S1—Ag1—S10ii98.31 (7)S21—Cu2—S21xii174.51 (11)
S1—Ag1—S14ii131.52 (8)S21xii—Cu2—S21174.51 (11)
S10ii—Ag1—S14ii128.93 (8)Ag13x—Cu3—Ag14x119.38 (5)
S2—Ag2—S7iii106.41 (7)Ag13x—Cu3—Ag2176.12 (3)
S2—Ag2—S14ii140.17 (9)Ag13x—Cu3—Ag24133.27 (5)
S2—Ag2—S17103.71 (7)Ag13x—Cu3—Ag2567.54 (3)
S7iii—Ag2—S14ii110.41 (8)Ag13x—Cu3—Ag29viii76.70 (4)
S7iii—Ag2—S1791.94 (6)Ag13x—Cu3—S16x58.75 (6)
S14ii—Ag2—S1789.86 (7)Ag13x—Cu3—S20111.31 (7)
Ag3cu—Ag3—Ag230Ag14x—Cu3—Ag21136.69 (6)
Ag3cu—Ag3—S40Ag14x—Cu3—Ag2480.07 (6)
Ag3cu—Ag3—S7iii0Ag14x—Cu3—Ag25137.88 (6)
Ag3cu—Ag3—S14iv0Ag14x—Cu3—Ag29viii79.58 (5)
Ag23—Ag3—S470.31 (6)Ag14x—Cu3—S16x60.86 (7)
Ag23—Ag3—S7iii77.65 (7)Ag14x—Cu3—S20129.18 (7)
Ag23—Ag3—S14iv136.97 (10)Ag21—Cu3—Ag24120.40 (5)
S4—Ag3—S7iii115.27 (10)Ag21—Cu3—Ag2585.07 (3)
S4—Ag3—S14iv117.87 (11)Ag21—Cu3—Ag29viii64.32 (3)
S7iii—Ag3—S14iv123.89 (11)Ag21—Cu3—S16x114.57 (7)
Ag3—Ag3cu—Ag230Ag21—Cu3—S2058.40 (6)
Ag3—Ag3cu—S40Ag24—Cu3—Ag2570.78 (4)
Ag3—Ag3cu—S7iii0Ag24—Cu3—Ag29viii149.68 (6)
Ag3—Ag3cu—S14iv0Ag24—Cu3—S16x124.99 (7)
Ag23—Ag3cu—S470.31 (5)Ag24—Cu3—S2062.26 (6)
Ag23—Ag3cu—S7iii77.65 (5)Ag25—Cu3—Ag29viii137.60 (5)
Ag23—Ag3cu—S14iv136.97 (6)Ag25—Cu3—S16x113.47 (7)
S4—Ag3cu—S7iii115.27 (7)Ag25—Cu3—S2060.52 (6)
S4—Ag3cu—S14iv117.87 (8)Ag29viii—Cu3—S16x61.23 (6)
S7iii—Ag3cu—S14iv123.89 (8)Ag29viii—Cu3—S20116.80 (7)
S5—Ag4—S10iii100.03 (7)S16x—Cu3—S20169.92 (9)
S5—Ag4—S14iv114.30 (8)Sb1—S1—Ag1100.87 (7)
S10iii—Ag4—S14iv145.66 (9)Sb1—S1—Ag5101.34 (8)
Ag13—Ag5—S177.87 (5)Sb1—S1—Ag16113.89 (8)
Ag13—Ag5—S5i75.41 (5)Ag1—S1—Ag5112.85 (8)
Ag13—Ag5—S13138.46 (6)Ag1—S1—Ag16103.50 (7)
Ag13—Ag5—S1649.35 (4)Ag5—S1—Ag16122.59 (8)
S1—Ag5—S5i116.34 (7)Sb1—S2—Ag298.35 (7)
S1—Ag5—S13119.81 (8)Sb1—S2—Ag6105.09 (8)
S1—Ag5—S16101.45 (6)Sb1—S2—Ag20105.69 (7)
S5i—Ag5—S13118.50 (8)Ag2—S2—Ag6120.04 (8)
S5i—Ag5—S16102.65 (6)Ag2—S2—Ag20125.41 (8)
S13—Ag5—S1689.21 (6)Ag6—S2—Ag2099.97 (7)
Ag7v—Ag6—Ag10iv61.48 (2)Sb1—S3—Ag7102.06 (7)
Ag7v—Ag6—S292.04 (5)Sb1—S3—Ag897.70 (7)
Ag7v—Ag6—S4147.92 (5)Sb1—S3—Ag17107.54 (7)
Ag7v—Ag6—S13v55.14 (5)Ag7—S3—Ag8112.44 (8)
Ag10iv—Ag6—S2145.28 (5)Ag7—S3—Ag17100.25 (7)
Ag10iv—Ag6—S495.55 (5)Ag8—S3—Ag17133.13 (8)
Ag10iv—Ag6—S13v53.69 (5)Sb2—S4—Ag3104.22 (9)
S2—Ag6—S497.55 (7)Sb2—S4—Ag3cu104.22 (8)
S2—Ag6—S13v130.31 (7)Sb2—S4—Ag6105.45 (8)
S4—Ag6—S13v130.60 (7)Sb2—S4—Ag24101.63 (8)
Ag6v—Ag7—S3149.16 (5)Ag3—S4—Ag3cu0
Ag6v—Ag7—S896.45 (5)Ag3—S4—Ag6115.85 (9)
Ag6v—Ag7—S1355.00 (5)Ag3—S4—Ag24131.59 (10)
S3—Ag7—S8101.66 (7)Ag3cu—S4—Ag6115.85 (8)
S3—Ag7—S13113.80 (7)Ag3cu—S4—Ag24131.59 (9)
S8—Ag7—S13144.09 (7)Ag6—S4—Ag2495.24 (8)
S3—Ag8—S9106.42 (7)Sb2—S5—Ag4100.50 (7)
S3—Ag8—S13v143.90 (7)Sb2—S5—Ag5vi99.88 (8)
S9—Ag8—S13v108.06 (7)Sb2—S5—Ag28102.76 (8)
S6—Ag9—S11110.98 (9)Ag4—S5—Ag5vi109.79 (8)
S6—Ag9—S13v139.03 (10)Ag4—S5—Ag28122.56 (9)
S11—Ag9—S13v109.92 (9)Ag5vi—S5—Ag28116.69 (9)
Ag6iv—Ag10—S6143.97 (5)Sb2—S6—Ag9103.27 (8)
Ag6iv—Ag10—S1298.64 (5)Sb2—S6—Ag10101.68 (7)
Ag6iv—Ag10—S13vi54.54 (5)Sb2—S6—Ag29123.01 (9)
S6—Ag10—S12101.38 (7)Ag9—S6—Ag10111.22 (9)
S6—Ag10—S13vi112.81 (7)Ag9—S6—Ag29128.78 (10)
S12—Ag10—S13vi145.68 (7)Ag10—S6—Ag2981.68 (6)
S8—Ag11—S999.53 (7)Sb3—S7—Ag2ix99.02 (7)
S8—Ag11—S14vii116.98 (8)Sb3—S7—Ag3ix102.27 (8)
S9—Ag11—S14vii143.48 (8)Sb3—S7—Ag3cuix102.27 (7)
S11—Ag12—S12112.53 (10)Sb3—S7—Ag15101.72 (8)
S11—Ag12—S14136.48 (11)Ag2ix—S7—Ag3ix108.38 (9)
S12—Ag12—S14110.36 (10)Ag2ix—S7—Ag3cuix108.38 (8)
Ag5—Ag13—Cu3viii112.69 (3)Ag2ix—S7—Ag15122.76 (8)
Ag5—Ag13—S15106.60 (5)Ag3ix—S7—Ag3cuix0
Ag5—Ag13—S1664.49 (5)Ag3ix—S7—Ag15118.08 (9)
Cu3viii—Ag13—S15140.31 (6)Ag3cuix—S7—Ag15118.08 (8)
Cu3viii—Ag13—S1648.25 (5)Sb3—S8—Ag7103.17 (7)
S15—Ag13—S16168.37 (7)Sb3—S8—Ag11103.08 (7)
Cu3viii—Ag14—S8142.24 (8)Sb3—S8—Ag1496.19 (8)
Cu3viii—Ag14—S12i120.38 (8)Sb3—S8—Ag18124.90 (8)
Cu3viii—Ag14—S1646.20 (5)Ag7—S8—Ag11119.10 (8)
Cu3viii—Ag14—S19viii84.10 (7)Ag7—S8—Ag1485.39 (7)
S8—Ag14—S12i75.79 (7)Ag7—S8—Ag18127.48 (8)
S8—Ag14—S16103.20 (8)Ag11—S8—Ag14143.47 (9)
S8—Ag14—S19viii125.78 (9)Ag11—S8—Ag1872.63 (5)
S12i—Ag14—S1693.98 (8)Ag14—S8—Ag1870.89 (6)
S12i—Ag14—S19viii107.84 (9)Sb4—S9—Ag898.93 (7)
S16—Ag14—S19viii129.56 (9)Sb4—S9—Ag11100.57 (7)
S7—Ag15—S19viii159.95 (7)Sb4—S9—Ag2299.67 (7)
Cu1—Ag16—S1127.89 (5)Ag8—S9—Ag11114.37 (8)
Cu1—Ag16—S1583.50 (5)Ag8—S9—Ag22120.46 (8)
Cu1—Ag16—S1743.97 (4)Ag11—S9—Ag22116.79 (8)
Cu1—Ag16—S22viii105.81 (5)Sb4—S10—Ag1xi103.68 (7)
S1—Ag16—S1590.26 (6)Sb4—S10—Ag4ix100.82 (7)
S1—Ag16—S1786.50 (6)Sb4—S10—Ag2695.80 (7)
S1—Ag16—S22viii124.52 (6)Sb4—S10—Ag27ix121.98 (8)
S15—Ag16—S1797.98 (6)Ag1xi—S10—Ag4ix120.65 (8)
S15—Ag16—S22viii110.59 (6)Ag1xi—S10—Ag2688.70 (6)
S17—Ag16—S22viii136.12 (6)Ag1xi—S10—Ag27ix130.06 (8)
S3—Ag17—S1690.06 (6)Ag4ix—S10—Ag26140.88 (8)
S3—Ag17—S1885.98 (6)Ag4ix—S10—Ag27ix72.15 (5)
S3—Ag17—S22viii123.08 (6)Ag26—S10—Ag27ix68.99 (5)
S16—Ag17—S1895.94 (6)Sb4—S11—Ag996.55 (8)
S16—Ag17—S22viii143.07 (6)Sb4—S11—Ag1299.55 (9)
S18—Ag17—S22viii101.70 (6)Sb4—S11—Ag25131.42 (8)
Cu2ix—Ag18—S8143.49 (5)Sb4—S11—Ag2691.95 (7)
Cu2ix—Ag18—S18120.22 (5)Ag9—S11—Ag1296.38 (9)
Cu2ix—Ag18—S21ix47.21 (4)Ag9—S11—Ag2570.62 (6)
S8—Ag18—S1895.70 (6)Ag9—S11—Ag26165.75 (9)
S8—Ag18—S21ix100.60 (6)Ag12—S11—Ag25127.75 (9)
S18—Ag18—S21ix158.10 (7)Ag12—S11—Ag2693.46 (8)
Cu1—Ag19—S1747.81 (4)Ag25—S11—Ag2695.19 (7)
Cu1—Ag19—S19135.15 (5)Sb3vi—S12—Ag10102.29 (8)
S17—Ag19—S19176.77 (7)Sb3vi—S12—Ag12100.87 (9)
S2—Ag20—S1992.07 (6)Sb3vi—S12—Ag14vi89.83 (7)
S2—Ag20—S2089.67 (6)Sb3vi—S12—Ag30122.43 (9)
S2—Ag20—S22viii131.64 (6)Ag10—S12—Ag12108.35 (9)
S19—Ag20—S2093.89 (6)Ag10—S12—Ag14vi87.30 (7)
S19—Ag20—S22viii100.87 (6)Ag10—S12—Ag30134.70 (9)
S20—Ag20—S22viii134.77 (6)Ag12—S12—Ag14vi158.37 (10)
Ag29viii—Ag21—Cu357.77 (3)Ag12—S12—Ag3072.28 (7)
Ag29viii—Ag21—S1878.15 (5)Ag14vi—S12—Ag3086.11 (7)
Ag29viii—Ag21—S20101.38 (5)Ag5—S13—Ag6v159.60 (10)
Cu3—Ag21—S18133.94 (5)Ag5—S13—Ag793.13 (7)
Cu3—Ag21—S2047.94 (5)Ag5—S13—Ag8v111.32 (9)
S18—Ag21—S20173.26 (7)Ag5—S13—Ag9v112.43 (9)
S9—Ag22—S15x158.74 (7)Ag5—S13—Ag10i92.91 (7)
Ag3—Ag23—Ag3cu0Ag6v—S13—Ag769.86 (6)
Ag3—Ag23—Cu2114.65 (4)Ag6v—S13—Ag8v79.10 (7)
Ag3—Ag23—S19112.70 (6)Ag6v—S13—Ag9v81.70 (7)
Ag3—Ag23—S2167.00 (5)Ag6v—S13—Ag10i71.77 (6)
Ag3cu—Ag23—Cu2114.65 (2)Ag7—S13—Ag8v84.45 (7)
Ag3cu—Ag23—S19112.70 (5)Ag7—S13—Ag9v150.08 (10)
Ag3cu—Ag23—S2167.00 (4)Ag7—S13—Ag10i72.83 (6)
Cu2—Ag23—S19128.75 (5)Ag8v—S13—Ag9v99.52 (8)
Cu2—Ag23—S2147.98 (4)Ag8v—S13—Ag10i147.72 (9)
S19—Ag23—S21166.73 (7)Ag9v—S13—Ag10i89.92 (8)
Cu3—Ag24—S4135.10 (8)Ag1xi—S14—Ag2xi77.92 (8)
Cu3—Ag24—S18x90.18 (6)Ag1xi—S14—Ag3iv162.68 (13)
Cu3—Ag24—S2046.20 (5)Ag1xi—S14—Ag3cuiv162.68 (12)
S4—Ag24—S18x130.43 (9)Ag1xi—S14—Ag4iv72.70 (8)
S4—Ag24—S2094.44 (8)Ag1xi—S14—Ag11vii74.40 (8)
S18x—Ag24—S20134.85 (9)Ag1xi—S14—Ag1285.27 (9)
Cu3—Ag25—S11145.89 (6)Ag2xi—S14—Ag3iv111.54 (12)
Cu3—Ag25—S2047.96 (5)Ag2xi—S14—Ag3cuiv111.54 (11)
Cu3—Ag25—S22117.48 (5)Ag2xi—S14—Ag4iv147.94 (13)
S11—Ag25—S20105.18 (6)Ag2xi—S14—Ag11vii86.38 (10)
S11—Ag25—S2295.58 (6)Ag2xi—S14—Ag1299.43 (10)
S20—Ag25—S22151.74 (7)Ag3iv—S14—Ag3cuiv0
Cu1xi—Ag26—S10138.40 (5)Ag3iv—S14—Ag4iv94.15 (10)
Cu1xi—Ag26—S11119.84 (5)Ag3iv—S14—Ag11vii91.33 (10)
Cu1xi—Ag26—S15x91.23 (5)Ag3iv—S14—Ag12106.59 (13)
Cu1xi—Ag26—S17xi46.18 (4)Ag3cuiv—S14—Ag4iv94.15 (9)
S10—Ag26—S1176.19 (6)Ag3cuiv—S14—Ag11vii91.33 (9)
S10—Ag26—S15x124.28 (6)Ag3cuiv—S14—Ag12106.59 (12)
S10—Ag26—S17xi98.45 (6)Ag4iv—S14—Ag11vii73.73 (8)
S11—Ag26—S15x103.07 (7)Ag4iv—S14—Ag1290.77 (10)
S11—Ag26—S17xi94.07 (6)Ag11vii—S14—Ag12157.27 (13)
S15x—Ag26—S17xi136.48 (6)Ag13—S15—Ag1677.22 (6)
Cu2—Ag27—S10iii147.16 (5)Ag13—S15—Ag22viii82.09 (6)
Cu2—Ag27—S15vi114.84 (5)Ag13—S15—Ag26viii129.83 (8)
Cu2—Ag27—S2147.53 (4)Ag13—S15—Ag27i110.50 (8)
S10iii—Ag27—S15vi97.20 (6)Ag16—S15—Ag22viii133.49 (8)
S10iii—Ag27—S21105.12 (6)Ag16—S15—Ag26viii84.15 (6)
S15vi—Ag27—S21152.02 (7)Ag16—S15—Ag27i132.11 (8)
S5—Ag28—S18x157.70 (10)Ag22viii—S15—Ag26viii77.97 (6)
Ag21x—Ag29—Cu3x57.91 (3)Ag22viii—S15—Ag27i94.10 (7)
Ag21x—Ag29—S6140.99 (7)Ag26viii—S15—Ag27i116.42 (8)
Ag21x—Ag29—S16vi97.69 (5)Ag5—S16—Ag1366.16 (5)
Ag21x—Ag29—S2291.01 (5)Ag5—S16—Ag14147.96 (8)
Cu3x—Ag29—S6150.23 (6)Ag5—S16—Ag1793.33 (6)
Cu3x—Ag29—S16vi47.43 (5)Ag5—S16—Ag29i102.48 (7)
Cu3x—Ag29—S22103.52 (6)Ag5—S16—Cu3viii139.07 (9)
S6—Ag29—S16vi102.84 (7)Ag13—S16—Ag14145.51 (9)
S6—Ag29—S2299.20 (7)Ag13—S16—Ag1771.52 (5)
S16vi—Ag29—S22131.78 (8)Ag13—S16—Ag29i85.99 (7)
Cu1xi—Ag30—S12152.18 (5)Ag13—S16—Cu3viii73.00 (6)
Cu1xi—Ag30—S17xi46.94 (4)Ag14—S16—Ag1794.98 (8)
Cu1xi—Ag30—S22111.32 (5)Ag14—S16—Ag29i88.25 (8)
S12—Ag30—S17xi108.26 (6)Ag14—S16—Cu3viii72.94 (7)
S12—Ag30—S2296.47 (6)Ag17—S16—Ag29i144.47 (8)
S17xi—Ag30—S22144.12 (7)Ag17—S16—Cu3viii75.86 (6)
Ag16—Cu1—Ag16xii153.31 (5)Ag29i—S16—Cu3viii71.34 (6)
Ag16—Cu1—Ag1963.39 (2)Ag2—S17—Ag1696.13 (6)
Ag16—Cu1—Ag19xii142.34 (4)Ag2—S17—Ag1969.68 (5)
Ag16—Cu1—Ag26ii82.78 (3)Ag2—S17—Ag26ii143.41 (7)
Ag16—Cu1—Ag26viii76.68 (3)Ag2—S17—Ag30ii109.16 (7)
Ag16—Cu1—Ag30ii123.58 (2)Ag2—S17—Cu1143.04 (9)
Ag16—Cu1—Ag30viii66.68 (2)Ag16—S17—Ag1969.36 (5)
Ag16—Cu1—S1764.24 (6)Ag16—S17—Ag26ii90.45 (6)
Ag16—Cu1—S17xii117.64 (6)Ag16—S17—Ag30ii145.10 (7)
Ag16xii—Cu1—Ag16153.31 (5)Ag16—S17—Cu171.79 (6)
Ag16xii—Cu1—Ag19142.34 (4)Ag19—S17—Ag26ii144.81 (8)
Ag16xii—Cu1—Ag19xii63.39 (2)Ag19—S17—Ag30ii96.80 (7)
Ag16xii—Cu1—Ag26ii76.68 (3)Ag19—S17—Cu173.39 (6)
Ag16xii—Cu1—Ag26viii82.78 (3)Ag26ii—S17—Ag30ii83.41 (7)
Ag16xii—Cu1—Ag30ii66.68 (2)Ag26ii—S17—Cu172.98 (6)
Ag16xii—Cu1—Ag30viii123.58 (2)Ag30ii—S17—Cu173.57 (6)
Ag16xii—Cu1—S17117.64 (6)Ag17—S18—Ag18135.46 (7)
Ag16xii—Cu1—S17xii64.24 (6)Ag17—S18—Ag2177.59 (5)
Ag19—Cu1—Ag19xii83.76 (4)Ag17—S18—Ag24viii87.05 (7)
Ag19—Cu1—Ag26ii118.81 (2)Ag17—S18—Ag28viii137.63 (8)
Ag19—Cu1—Ag26viii131.81 (2)Ag18—S18—Ag21108.54 (7)
Ag19—Cu1—Ag30ii84.07 (3)Ag18—S18—Ag24viii112.54 (8)
Ag19—Cu1—Ag30viii66.20 (3)Ag18—S18—Ag28viii86.81 (7)
Ag19—Cu1—S1758.79 (6)Ag21—S18—Ag24viii134.06 (9)
Ag19—Cu1—S17xii115.06 (7)Ag21—S18—Ag28viii86.95 (7)
Ag19xii—Cu1—Ag1983.76 (4)Ag24viii—S18—Ag28viii75.85 (7)
Ag19xii—Cu1—Ag26ii131.81 (2)Ag14x—S19—Ag15x75.98 (6)
Ag19xii—Cu1—Ag26viii118.81 (2)Ag14x—S19—Ag19131.41 (9)
Ag19xii—Cu1—Ag30ii66.20 (3)Ag14x—S19—Ag2092.41 (7)
Ag19xii—Cu1—Ag30viii84.07 (3)Ag14x—S19—Ag23114.34 (8)
Ag19xii—Cu1—S17115.06 (7)Ag15x—S19—Ag1981.76 (6)
Ag19xii—Cu1—S17xii58.79 (6)Ag15x—S19—Ag20133.86 (7)
Ag26ii—Cu1—Ag26viii79.06 (4)Ag15x—S19—Ag2386.31 (6)
Ag26ii—Cu1—Ag30ii74.13 (3)Ag19—S19—Ag2073.06 (5)
Ag26ii—Cu1—Ag30viii143.00 (4)Ag19—S19—Ag23106.55 (7)
Ag26ii—Cu1—S1760.84 (6)Ag20—S19—Ag23137.45 (8)
Ag26ii—Cu1—S17xii125.82 (7)Ag20—S20—Ag2171.62 (5)
Ag26viii—Cu1—Ag26ii79.06 (4)Ag20—S20—Ag2493.72 (7)
Ag26viii—Cu1—Ag30ii143.00 (4)Ag20—S20—Ag25146.44 (8)
Ag26viii—Cu1—Ag30viii74.13 (3)Ag20—S20—Cu374.97 (6)
Ag26viii—Cu1—S17125.82 (7)Ag21—S20—Ag24144.71 (8)
Ag26viii—Cu1—S17xii60.84 (6)Ag21—S20—Ag2596.99 (7)
Ag30ii—Cu1—Ag30viii140.19 (6)Ag21—S20—Cu373.66 (6)
Ag30ii—Cu1—S1759.49 (6)Ag24—S20—Ag2577.45 (6)
Ag30ii—Cu1—S17xii117.67 (6)Ag24—S20—Cu371.54 (7)
Ag30viii—Cu1—Ag30ii140.19 (6)Ag25—S20—Cu371.52 (6)
Ag30viii—Cu1—S17117.67 (6)Ag18iii—S21—Ag23109.70 (7)
Ag30viii—Cu1—S17xii59.49 (6)Ag18iii—S21—Ag27111.50 (8)
S17—Cu1—S17xii172.71 (10)Ag18iii—S21—Cu275.28 (6)
S17xii—Cu1—S17172.71 (10)Ag23—S21—Ag27116.61 (8)
Ag18iii—Cu2—Ag18x150.33 (6)Ag23—S21—Cu273.10 (6)
Ag18iii—Cu2—Ag2392.49 (4)Ag27—S21—Cu273.42 (7)
Ag18iii—Cu2—Ag23xii67.64 (3)Ag16x—S22—Ag17x77.22 (5)
Ag18iii—Cu2—Ag2793.80 (3)Ag16x—S22—Ag20x80.40 (5)
Ag18iii—Cu2—Ag27xii110.45 (3)Ag16x—S22—Ag2594.39 (6)
Ag18iii—Cu2—S2157.51 (6)Ag16x—S22—Ag29162.72 (7)
Ag18iii—Cu2—S21xii120.84 (6)Ag16x—S22—Ag3076.15 (6)
Ag18x—Cu2—Ag18iii150.33 (6)Ag17x—S22—Ag20x79.52 (5)
Ag18x—Cu2—Ag2367.64 (3)Ag17x—S22—Ag2571.94 (5)
Ag18x—Cu2—Ag23xii92.49 (4)Ag17x—S22—Ag2994.91 (7)
Ag18x—Cu2—Ag27110.45 (3)Ag17x—S22—Ag30153.07 (8)
Ag18x—Cu2—Ag27xii93.80 (3)Ag20x—S22—Ag25151.43 (8)
Ag18x—Cu2—S21120.84 (6)Ag20x—S22—Ag2983.06 (6)
Ag18x—Cu2—S21xii57.51 (6)Ag20x—S22—Ag3099.88 (7)
Ag23—Cu2—Ag23xii97.68 (5)Ag25—S22—Ag2997.76 (7)
Ag23—Cu2—Ag2799.18 (2)Ag25—S22—Ag30106.14 (7)
Ag23—Cu2—Ag27xii155.40 (3)Ag29—S22—Ag30111.82 (7)
Ag23—Cu2—S2158.91 (6)
Symmetry codes: (i) x, y1, z; (ii) x1/2, y1/2, z; (iii) x1/2, y+1/2, z; (iv) x+1/2, y+3/2, z; (v) x+1/2, y+1/2, z; (vi) x, y+1, z; (vii) x+1, y+1, z; (viii) x+1/2, y1/2, z+1/2; (ix) x+1/2, y1/2, z; (x) x+1/2, y+1/2, z+1/2; (xi) x+1/2, y+1/2, z; (xii) x, y, z+1/2.
 

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