Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229621004071/ky3203sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S2053229621004071/ky3203Isup2.hkl | |
Portable Document Format (PDF) file https://doi.org/10.1107/S2053229621004071/ky3203sup3.pdf |
CCDC reference: 1877829
Data collection: APEX2 (Bruker, 2013); cell refinement: SAINT (Bruker, 2013); data reduction: SAINT (Bruker, 2013); program(s) used to solve structure: SHELXS2013 (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2015b); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL2013 (Sheldrick, 2015b) and PLATON (Spek, 2020).
Na3EuB8O15 | Z = 2 |
Mr = 547.41 | F(000) = 512 |
Triclinic, P1 | Dx = 3.168 Mg m−3 |
a = 6.2861 (5) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 7.5366 (6) Å | Cell parameters from 724 reflections |
c = 13.4963 (11) Å | θ = 2.9–24.0° |
α = 90.547 (1)° | µ = 5.68 mm−1 |
β = 100.667 (1)° | T = 296 K |
γ = 113.489 (1)° | Prism, colorless |
V = 573.81 (8) Å3 | 0.20 × 0.10 × 0.10 mm |
Bruker SMART APEXII CCD area detector diffractometer | 2807 independent reflections |
Radiation source: fine-focus sealed tube | 2599 reflections with I > 2σ(I) |
Detector resolution: 83.33 pixels mm-1 | Rint = 0.032 |
ω scans | θmax = 28.3°, θmin = 3.0° |
Absorption correction: multi-scan (SADABS; Sheldrick, 2003) | h = −8→8 |
Tmin = 0.307, Tmax = 0.748 | k = −10→10 |
7261 measured reflections | l = −17→17 |
Refinement on F2 | 0 restraints |
Least-squares matrix: full | w = 1/[σ2(Fo2) + (0.0189P)2 + 1.0032P] where P = (Fo2 + 2Fc2)/3 |
R[F2 > 2σ(F2)] = 0.023 | (Δ/σ)max = 0.001 |
wR(F2) = 0.055 | Δρmax = 1.17 e Å−3 |
S = 1.07 | Δρmin = −0.92 e Å−3 |
2807 reflections | Extinction correction: SHELXL2013 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
245 parameters | Extinction coefficient: 0.0079 (6) |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
Refinement. A suitable single crystal with dimensions of 0.20 × 0.10 × 0.10 mm was selected for single-crystal X-ray diffraction experiments. It was mounted on a Bruker SMART APEXII CCD diffractometer equipped with graphite-monochromatic Mo Kα radiation (λ = 0.71073 Å) with a tube power of 50 kV and 30 mA. Intensity data were collected by the narrow frame method at 296 (2) K with a scan width of 0.5° in an ω-scan method. The unit cells were determined and refined by least-squares upon the refinement of XYZ-centroids of reflections above 2.0σ(I). Then the data were scaled for absorption using the APEX2 package (Bruker, 2013). The intensities of all measured reflections were corrected for Lp and crystal absorption effects. The crystal structure of the title compound was solved by direct methods and refined by full-matrix least squares fitting on F2 by SHELX2013 (Sheldrick, 2015). The final refined solution was checked with the program PLATON (Spek, 2020). |
x | y | z | Uiso*/Ueq | ||
Eu1 | 0.91847 (3) | 0.24942 (3) | 0.33266 (2) | 0.00535 (8) | |
Na1 | 0.3659 (3) | 0.6134 (2) | 0.27070 (15) | 0.0243 (4) | |
Na2 | 0.9079 (3) | 0.6895 (2) | 0.39134 (13) | 0.0216 (4) | |
Na3 | 0.7492 (3) | 0.2624 (3) | 0.02310 (13) | 0.0209 (4) | |
B1 | 0.6186 (7) | 0.3639 (6) | 0.5004 (3) | 0.0083 (8) | |
B2 | 0.2727 (7) | 0.0580 (6) | 0.4860 (3) | 0.0072 (8) | |
B3 | 0.3876 (7) | 0.2020 (6) | 0.3268 (3) | 0.0062 (8) | |
B4 | 0.3718 (7) | −0.0175 (6) | 0.1854 (3) | 0.0078 (8) | |
B5 | 0.1056 (7) | 0.1530 (6) | 0.1589 (3) | 0.0066 (8) | |
B6 | 0.3158 (7) | 0.1298 (6) | −0.1428 (3) | 0.0057 (7) | |
B7 | 0.2053 (7) | 0.2816 (6) | −0.0105 (3) | 0.0069 (8) | |
B8 | 0.1645 (7) | 0.3893 (6) | −0.1803 (3) | 0.0069 (8) | |
O1 | 0.8030 (5) | 0.5062 (4) | 0.5592 (2) | 0.0135 (6) | |
O2 | 0.5907 (4) | 0.3550 (3) | 0.39506 (18) | 0.0065 (5) | |
O3 | 0.4513 (5) | 0.2229 (4) | 0.54500 (19) | 0.0108 (5) | |
O4 | 0.1594 (5) | −0.1015 (4) | 0.5276 (2) | 0.0107 (5) | |
O5 | 0.2177 (4) | 0.0700 (4) | 0.38304 (19) | 0.0092 (5) | |
O6 | 0.2550 (4) | 0.2788 (3) | 0.25274 (18) | 0.0056 (5) | |
O7 | 0.4978 (4) | 0.0948 (4) | 0.27470 (19) | 0.0081 (5) | |
O8 | 0.1686 (4) | −0.0077 (4) | 0.13785 (19) | 0.0070 (5) | |
O9 | 0.1260 (4) | 0.2790 (4) | 0.07619 (19) | 0.0078 (5) | |
O10 | 0.1452 (4) | −0.0744 (3) | −0.17355 (19) | 0.0068 (5) | |
O11 | 0.5575 (4) | 0.1478 (4) | −0.14699 (19) | 0.0078 (5) | |
O12 | 0.3258 (4) | 0.1795 (4) | −0.03558 (18) | 0.0065 (5) | |
O13 | 0.1628 (5) | 0.4132 (4) | −0.07694 (19) | 0.0092 (5) | |
O14 | 0.0749 (5) | 0.4854 (4) | −0.2456 (2) | 0.0111 (5) | |
O15 | 0.2621 (4) | 0.2666 (4) | −0.21007 (19) | 0.0074 (5) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Eu1 | 0.00544 (10) | 0.00627 (11) | 0.00421 (10) | 0.00227 (7) | 0.00098 (6) | 0.00042 (6) |
Na1 | 0.0221 (9) | 0.0150 (9) | 0.0406 (11) | 0.0077 (7) | 0.0173 (8) | 0.0109 (8) |
Na2 | 0.0284 (10) | 0.0191 (9) | 0.0138 (8) | 0.0076 (8) | 0.0013 (7) | −0.0041 (7) |
Na3 | 0.0159 (8) | 0.0253 (9) | 0.0217 (9) | 0.0128 (7) | −0.0052 (7) | −0.0074 (7) |
B1 | 0.0101 (19) | 0.0083 (19) | 0.009 (2) | 0.0059 (16) | 0.0034 (15) | 0.0015 (15) |
B2 | 0.0069 (18) | 0.0100 (19) | 0.0076 (19) | 0.0061 (15) | 0.0021 (15) | 0.0004 (15) |
B3 | 0.0045 (18) | 0.0054 (18) | 0.0081 (19) | 0.0023 (15) | −0.0009 (15) | −0.0028 (15) |
B4 | 0.0081 (19) | 0.0060 (18) | 0.010 (2) | 0.0030 (15) | 0.0043 (15) | 0.0029 (15) |
B5 | 0.0083 (19) | 0.0091 (19) | 0.0049 (18) | 0.0059 (15) | 0.0018 (15) | −0.0003 (15) |
B6 | 0.0056 (18) | 0.0047 (18) | 0.0069 (19) | 0.0030 (15) | −0.0003 (14) | −0.0014 (14) |
B7 | 0.0059 (18) | 0.0067 (19) | 0.0069 (19) | 0.0013 (15) | 0.0015 (15) | −0.0005 (15) |
B8 | 0.0051 (18) | 0.0062 (18) | 0.0076 (19) | 0.0006 (15) | 0.0008 (14) | 0.0025 (15) |
O1 | 0.0109 (13) | 0.0132 (14) | 0.0112 (14) | 0.0012 (11) | −0.0011 (11) | −0.0036 (11) |
O2 | 0.0060 (12) | 0.0071 (12) | 0.0045 (12) | 0.0011 (10) | 0.0005 (9) | −0.0004 (9) |
O3 | 0.0111 (13) | 0.0105 (13) | 0.0049 (12) | −0.0014 (11) | 0.0012 (10) | 0.0002 (10) |
O4 | 0.0110 (13) | 0.0105 (13) | 0.0096 (13) | 0.0025 (11) | 0.0035 (10) | 0.0041 (10) |
O5 | 0.0087 (12) | 0.0104 (13) | 0.0058 (12) | 0.0017 (10) | 0.0007 (10) | 0.0013 (10) |
O6 | 0.0063 (12) | 0.0070 (12) | 0.0041 (12) | 0.0035 (10) | 0.0007 (9) | −0.0008 (9) |
O7 | 0.0056 (12) | 0.0123 (13) | 0.0077 (13) | 0.0061 (10) | −0.0008 (10) | −0.0035 (10) |
O8 | 0.0055 (12) | 0.0104 (13) | 0.0075 (12) | 0.0064 (10) | 0.0000 (9) | −0.0010 (10) |
O9 | 0.0116 (13) | 0.0105 (13) | 0.0040 (12) | 0.0071 (10) | 0.0021 (10) | 0.0017 (10) |
O10 | 0.0045 (11) | 0.0060 (12) | 0.0092 (12) | 0.0010 (10) | 0.0026 (9) | −0.0005 (10) |
O11 | 0.0039 (12) | 0.0080 (12) | 0.0118 (13) | 0.0027 (10) | 0.0018 (10) | −0.0026 (10) |
O12 | 0.0066 (12) | 0.0097 (12) | 0.0050 (12) | 0.0060 (10) | −0.0003 (9) | 0.0001 (10) |
O13 | 0.0157 (13) | 0.0105 (13) | 0.0062 (12) | 0.0098 (11) | 0.0030 (10) | 0.0020 (10) |
O14 | 0.0154 (13) | 0.0140 (13) | 0.0104 (13) | 0.0111 (11) | 0.0057 (11) | 0.0063 (11) |
O15 | 0.0097 (12) | 0.0099 (13) | 0.0064 (12) | 0.0068 (10) | 0.0039 (10) | 0.0032 (10) |
Eu1—O4i | 2.232 (3) | B2—Na2xii | 2.894 (4) |
Eu1—O1ii | 2.241 (3) | B2—Na2vii | 3.164 (4) |
Eu1—O14iii | 2.319 (3) | B3—O6 | 1.455 (5) |
Eu1—O10iv | 2.391 (2) | B3—O5 | 1.475 (5) |
Eu1—O7 | 2.392 (2) | B3—O2 | 1.476 (4) |
Eu1—O6v | 2.483 (2) | B3—O7 | 1.497 (4) |
Eu1—O5v | 2.720 (3) | B3—Eu1ix | 3.123 (4) |
Eu1—O2 | 2.743 (2) | B4—O8 | 1.349 (5) |
Eu1—B5v | 3.013 (4) | B4—O11iv | 1.362 (5) |
Eu1—B3v | 3.123 (4) | B4—O7 | 1.375 (5) |
Eu1—B3 | 3.197 (4) | B4—Na1xiii | 3.010 (4) |
Eu1—Na1v | 3.3014 (17) | B4—Na3iv | 3.145 (5) |
Na1—O6 | 2.330 (3) | B5—O8 | 1.457 (5) |
Na1—O11iii | 2.434 (3) | B5—O9 | 1.464 (5) |
Na1—O15iii | 2.448 (3) | B5—O6 | 1.487 (5) |
Na1—O14vi | 2.520 (3) | B5—O10xiv | 1.500 (5) |
Na1—O3vii | 2.604 (3) | B5—Na3ix | 3.007 (4) |
Na1—O1vii | 2.718 (3) | B5—Eu1ix | 3.013 (4) |
Na1—B6iii | 2.998 (4) | B6—O12 | 1.475 (5) |
Na1—B4viii | 3.010 (4) | B6—O15 | 1.478 (5) |
Na1—B1vii | 3.073 (5) | B6—O10 | 1.483 (4) |
Na1—Eu1ix | 3.3013 (17) | B6—O11 | 1.483 (5) |
Na1—Na2 | 3.311 (3) | B6—Na1iii | 2.998 (4) |
Na1—Na2ix | 3.781 (3) | B7—O9 | 1.352 (5) |
Na2—O4x | 2.291 (3) | B7—O12 | 1.354 (5) |
Na2—O14iii | 2.400 (3) | B7—O13 | 1.414 (5) |
Na2—O2 | 2.523 (3) | B7—Na3ix | 2.933 (4) |
Na2—O15iii | 2.563 (3) | B8—O14 | 1.331 (5) |
Na2—O1 | 2.713 (3) | B8—O15 | 1.389 (5) |
Na2—O1ii | 2.762 (3) | B8—O13 | 1.407 (5) |
Na2—O5x | 2.768 (3) | B8—Na2iii | 2.819 (4) |
Na2—B8iii | 2.819 (4) | B8—Na3iii | 3.165 (4) |
Na2—O3vii | 2.858 (3) | O1—Eu1ii | 2.241 (3) |
Na2—B2x | 2.894 (5) | O1—Na1vii | 2.718 (3) |
Na2—B1 | 3.000 (5) | O1—Na2ii | 2.762 (3) |
Na2—B2vii | 3.164 (4) | O3—Na1vii | 2.604 (3) |
Na3—O9v | 2.296 (3) | O3—Na2vii | 2.858 (3) |
Na3—O13iii | 2.356 (3) | O4—Eu1i | 2.232 (3) |
Na3—O11 | 2.361 (3) | O4—Na2xii | 2.291 (3) |
Na3—O12 | 2.447 (3) | O5—Eu1ix | 2.720 (3) |
Na3—O10iv | 2.623 (3) | O5—Na2xii | 2.768 (3) |
Na3—B7v | 2.933 (4) | O6—Eu1ix | 2.483 (2) |
Na3—O13v | 2.975 (3) | O9—Na3ix | 2.296 (3) |
Na3—B6 | 2.993 (4) | O10—B5xiv | 1.500 (5) |
Na3—B5v | 3.007 (4) | O10—Eu1iv | 2.391 (2) |
Na3—B4iv | 3.145 (5) | O10—Na3iv | 2.623 (3) |
Na3—B8iii | 3.165 (4) | O11—B4iv | 1.362 (5) |
Na3—Na3xi | 3.863 (4) | O11—Na1iii | 2.434 (3) |
B1—O1 | 1.333 (5) | O13—Na3iii | 2.356 (3) |
B1—O3 | 1.397 (5) | O13—Na3ix | 2.975 (3) |
B1—O2 | 1.398 (5) | O14—Eu1iii | 2.318 (3) |
B1—Na1vii | 3.073 (5) | O14—Na2iii | 2.400 (3) |
B2—O4 | 1.322 (5) | O14—Na1vi | 2.520 (3) |
B2—O5 | 1.381 (5) | O15—Na1iii | 2.448 (3) |
B2—O3 | 1.406 (5) | O15—Na2iii | 2.563 (3) |
O4i—Eu1—O1ii | 84.47 (10) | O12—Na3—O13v | 133.31 (10) |
O4i—Eu1—O14iii | 144.72 (10) | O10iv—Na3—O13v | 107.21 (9) |
O1ii—Eu1—O14iii | 79.17 (10) | B7v—Na3—O13v | 27.67 (9) |
O4i—Eu1—O10iv | 122.54 (9) | O9v—Na3—B6 | 146.77 (12) |
O1ii—Eu1—O10iv | 141.44 (9) | O13iii—Na3—B6 | 106.88 (11) |
O14iii—Eu1—O10iv | 88.27 (9) | O11—Na3—B6 | 29.22 (10) |
O4i—Eu1—O7 | 83.76 (9) | O12—Na3—B6 | 29.32 (10) |
O1ii—Eu1—O7 | 141.00 (9) | O10iv—Na3—B6 | 128.85 (11) |
O14iii—Eu1—O7 | 89.60 (9) | B7v—Na3—B6 | 122.23 (13) |
O10iv—Eu1—O7 | 74.22 (8) | O13v—Na3—B6 | 106.43 (11) |
O4i—Eu1—O6v | 125.07 (9) | O9v—Na3—B5v | 28.18 (10) |
O1ii—Eu1—O6v | 83.56 (9) | O13iii—Na3—B5v | 106.16 (11) |
O14iii—Eu1—O6v | 84.00 (9) | O11—Na3—B5v | 128.92 (12) |
O10iv—Eu1—O6v | 58.78 (8) | O12—Na3—B5v | 144.37 (12) |
O7—Eu1—O6v | 132.65 (8) | O10iv—Na3—B5v | 29.91 (9) |
O4i—Eu1—O5v | 72.00 (9) | B7v—Na3—B5v | 51.45 (12) |
O1ii—Eu1—O5v | 84.01 (9) | O13v—Na3—B5v | 77.73 (10) |
O14iii—Eu1—O5v | 135.83 (8) | B6—Na3—B5v | 146.81 (12) |
O10iv—Eu1—O5v | 80.06 (8) | O9v—Na3—B4iv | 97.29 (11) |
O7—Eu1—O5v | 126.59 (8) | O13iii—Na3—B4iv | 136.36 (12) |
O6v—Eu1—O5v | 53.53 (8) | O11—Na3—B4iv | 23.57 (10) |
O4i—Eu1—O2 | 73.49 (8) | O12—Na3—B4iv | 77.01 (10) |
O1ii—Eu1—O2 | 87.18 (9) | O10iv—Na3—B4iv | 110.68 (11) |
O14iii—Eu1—O2 | 74.67 (8) | B7v—Na3—B4iv | 74.86 (11) |
O10iv—Eu1—O2 | 124.55 (8) | O13v—Na3—B4iv | 70.31 (10) |
O7—Eu1—O2 | 53.82 (8) | B6—Na3—B4iv | 49.56 (11) |
O6v—Eu1—O2 | 158.02 (8) | B5v—Na3—B4iv | 105.35 (12) |
O5v—Eu1—O2 | 145.02 (7) | O9v—Na3—B8iii | 93.10 (11) |
O4i—Eu1—B5v | 131.31 (10) | O13iii—Na3—B8iii | 24.34 (9) |
O1ii—Eu1—B5v | 112.31 (11) | O11—Na3—B8iii | 138.14 (12) |
O14iii—Eu1—B5v | 83.94 (10) | O12—Na3—B8iii | 95.10 (11) |
O10iv—Eu1—B5v | 29.45 (9) | O10iv—Na3—B8iii | 89.49 (10) |
O7—Eu1—B5v | 103.30 (10) | B7v—Na3—B8iii | 109.71 (12) |
O6v—Eu1—B5v | 29.41 (9) | O13v—Na3—B8iii | 104.21 (10) |
O5v—Eu1—B5v | 65.32 (9) | B6—Na3—B8iii | 117.77 (12) |
O2—Eu1—B5v | 147.89 (9) | B5v—Na3—B8iii | 91.92 (11) |
O4i—Eu1—B3v | 98.12 (10) | B4iv—Na3—B8iii | 159.83 (12) |
O1ii—Eu1—B3v | 75.86 (10) | O9v—Na3—Na3xi | 64.89 (8) |
O14iii—Eu1—B3v | 107.70 (10) | O13iii—Na3—Na3xi | 50.31 (7) |
O10iv—Eu1—B3v | 73.56 (9) | O11—Na3—Na3xi | 98.71 (10) |
O7—Eu1—B3v | 142.67 (10) | O12—Na3—Na3xi | 124.66 (10) |
O6v—Eu1—B3v | 27.12 (9) | O10iv—Na3—Na3xi | 117.00 (9) |
O5v—Eu1—B3v | 28.16 (9) | B7v—Na3—Na3xi | 56.94 (9) |
O2—Eu1—B3v | 161.87 (9) | O13v—Na3—Na3xi | 37.54 (6) |
B5v—Eu1—B3v | 48.59 (11) | B6—Na3—Na3xi | 113.26 (11) |
O4i—Eu1—B3 | 77.92 (10) | B5v—Na3—Na3xi | 90.35 (10) |
O1ii—Eu1—B3 | 114.62 (10) | B4iv—Na3—Na3xi | 100.47 (10) |
O14iii—Eu1—B3 | 80.87 (10) | B8iii—Na3—Na3xi | 68.50 (9) |
O10iv—Eu1—B3 | 98.84 (9) | O1—B1—O3 | 119.4 (4) |
O7—Eu1—B3 | 26.39 (9) | O1—B1—O2 | 120.7 (3) |
O6v—Eu1—B3 | 153.38 (9) | O3—B1—O2 | 119.9 (3) |
O5v—Eu1—B3 | 142.82 (9) | O1—B1—Na2 | 64.7 (2) |
O2—Eu1—B3 | 27.44 (8) | O3—B1—Na2 | 169.8 (3) |
B5v—Eu1—B3 | 126.42 (10) | O2—B1—Na2 | 56.84 (18) |
B3v—Eu1—B3 | 168.01 (14) | O1—B1—Na1vii | 62.1 (2) |
O4i—Eu1—Na1v | 136.46 (8) | O3—B1—Na1vii | 57.49 (19) |
O1ii—Eu1—Na1v | 54.78 (8) | O2—B1—Na1vii | 174.5 (3) |
O14iii—Eu1—Na1v | 49.58 (7) | Na2—B1—Na1vii | 124.73 (15) |
O10iv—Eu1—Na1v | 89.50 (7) | O4—B2—O5 | 121.2 (3) |
O7—Eu1—Na1v | 136.96 (7) | O4—B2—O3 | 121.3 (3) |
O6v—Eu1—Na1v | 44.79 (6) | O5—B2—O3 | 117.5 (3) |
O5v—Eu1—Na1v | 87.58 (6) | O4—B2—Na2xii | 50.41 (19) |
O2—Eu1—Na1v | 114.31 (6) | O5—B2—Na2xii | 70.9 (2) |
B5v—Eu1—Na1v | 64.63 (9) | O3—B2—Na2xii | 171.6 (3) |
B3v—Eu1—Na1v | 60.67 (8) | O4—B2—Na2vii | 92.9 (2) |
B3—Eu1—Na1v | 129.59 (8) | O5—B2—Na2vii | 111.4 (2) |
O6—Na1—O11iii | 130.94 (12) | O3—B2—Na2vii | 64.61 (19) |
O6—Na1—O15iii | 101.40 (11) | Na2xii—B2—Na2vii | 114.61 (13) |
O11iii—Na1—O15iii | 58.73 (9) | O6—B3—O5 | 106.9 (3) |
O6—Na1—O14vi | 82.95 (10) | O6—B3—O2 | 113.2 (3) |
O11iii—Na1—O14vi | 97.59 (10) | O5—B3—O2 | 111.9 (3) |
O15iii—Na1—O14vi | 152.24 (12) | O6—B3—O7 | 110.3 (3) |
O6—Na1—O3vii | 115.18 (11) | O5—B3—O7 | 110.6 (3) |
O11iii—Na1—O3vii | 111.57 (10) | O2—B3—O7 | 104.1 (3) |
O15iii—Na1—O3vii | 96.41 (10) | O6—B3—Eu1ix | 51.08 (15) |
O14vi—Na1—O3vii | 106.58 (11) | O5—B3—Eu1ix | 60.53 (17) |
O6—Na1—O1vii | 76.85 (10) | O2—B3—Eu1ix | 110.7 (2) |
O11iii—Na1—O1vii | 148.14 (11) | O7—B3—Eu1ix | 144.9 (2) |
O15iii—Na1—O1vii | 140.49 (11) | O6—B3—Eu1 | 125.1 (2) |
O14vi—Na1—O1vii | 67.27 (9) | O5—B3—Eu1 | 127.0 (2) |
O3vii—Na1—O1vii | 52.51 (9) | O2—B3—Eu1 | 58.88 (16) |
O6—Na1—B6iii | 119.86 (12) | O7—B3—Eu1 | 45.24 (14) |
O11iii—Na1—B6iii | 29.41 (9) | Eu1ix—B3—Eu1 | 168.01 (14) |
O15iii—Na1—B6iii | 29.34 (9) | O8—B4—O11iv | 119.2 (3) |
O14vi—Na1—B6iii | 125.95 (12) | O8—B4—O7 | 120.2 (3) |
O3vii—Na1—B6iii | 105.28 (11) | O11iv—B4—O7 | 120.5 (3) |
O1vii—Na1—B6iii | 157.74 (12) | O8—B4—Na1xiii | 120.5 (2) |
O6—Na1—B4viii | 150.77 (13) | O11iv—B4—Na1xiii | 52.48 (18) |
O11iii—Na1—B4viii | 26.34 (10) | O7—B4—Na1xiii | 93.3 (2) |
O15iii—Na1—B4viii | 78.47 (11) | O8—B4—Na3iv | 77.0 (2) |
O14vi—Na1—B4viii | 84.61 (11) | O11iv—B4—Na3iv | 43.91 (17) |
O3vii—Na1—B4viii | 93.71 (11) | O7—B4—Na3iv | 161.1 (3) |
O1vii—Na1—B4viii | 121.82 (12) | Na1xiii—B4—Na3iv | 83.07 (11) |
B6iii—Na1—B4viii | 50.79 (11) | O8—B5—O9 | 111.8 (3) |
O6—Na1—B1vii | 95.01 (11) | O8—B5—O6 | 113.4 (3) |
O11iii—Na1—B1vii | 134.06 (12) | O9—B5—O6 | 106.9 (3) |
O15iii—Na1—B1vii | 119.34 (12) | O8—B5—O10xiv | 109.5 (3) |
O14vi—Na1—B1vii | 87.15 (11) | O9—B5—O10xiv | 108.5 (3) |
O3vii—Na1—B1vii | 26.90 (10) | O6—B5—O10xiv | 106.5 (3) |
O1vii—Na1—B1vii | 25.67 (9) | O8—B5—Na3ix | 126.1 (2) |
B6iii—Na1—B1vii | 132.17 (13) | O9—B5—Na3ix | 47.80 (16) |
B4viii—Na1—B1vii | 110.70 (12) | O6—B5—Na3ix | 120.3 (2) |
O6—Na1—Eu1ix | 48.64 (7) | O10xiv—B5—Na3ix | 60.70 (17) |
O11iii—Na1—Eu1ix | 139.90 (9) | O8—B5—Eu1ix | 131.4 (2) |
O15iii—Na1—Eu1ix | 149.83 (9) | O9—B5—Eu1ix | 116.7 (2) |
O14vi—Na1—Eu1ix | 44.47 (6) | O6—B5—Eu1ix | 55.09 (16) |
O3vii—Na1—Eu1ix | 94.83 (8) | O10xiv—B5—Eu1ix | 51.63 (15) |
O1vii—Na1—Eu1ix | 42.34 (6) | Na3ix—B5—Eu1ix | 86.58 (11) |
B6iii—Na1—Eu1ix | 159.88 (11) | O12—B6—O15 | 112.5 (3) |
B4viii—Na1—Eu1ix | 128.59 (10) | O12—B6—O10 | 109.5 (3) |
B1vii—Na1—Eu1ix | 67.95 (9) | O15—B6—O10 | 112.2 (3) |
O6—Na1—Na2 | 91.69 (9) | O12—B6—O11 | 105.2 (3) |
O11iii—Na1—Na2 | 102.26 (8) | O15—B6—O11 | 107.9 (3) |
O15iii—Na1—Na2 | 50.15 (7) | O10—B6—O11 | 109.1 (3) |
O14vi—Na1—Na2 | 157.61 (10) | O12—B6—Na3 | 54.32 (16) |
O3vii—Na1—Na2 | 56.28 (8) | O15—B6—Na3 | 121.7 (2) |
O1vii—Na1—Na2 | 90.35 (8) | O10—B6—Na3 | 125.9 (2) |
B6iii—Na1—Na2 | 75.43 (9) | O11—B6—Na3 | 51.02 (16) |
B4viii—Na1—Na2 | 109.11 (10) | O12—B6—Na1iii | 124.9 (2) |
B1vii—Na1—Na2 | 71.61 (9) | O15—B6—Na1iii | 54.25 (16) |
Eu1ix—Na1—Na2 | 117.62 (6) | O10—B6—Na1iii | 125.2 (2) |
O6—Na1—Na2ix | 106.12 (9) | O11—B6—Na1iii | 53.71 (17) |
O11iii—Na1—Na2ix | 103.65 (8) | Na3—B6—Na1iii | 85.92 (12) |
O15iii—Na1—Na2ix | 152.27 (9) | O9—B7—O12 | 126.6 (3) |
O14vi—Na1—Na2ix | 38.63 (7) | O9—B7—O13 | 114.0 (3) |
O3vii—Na1—Na2ix | 68.88 (8) | O12—B7—O13 | 119.3 (3) |
O1vii—Na1—Na2ix | 46.85 (7) | O9—B7—Na3ix | 49.44 (18) |
B6iii—Na1—Na2ix | 129.71 (10) | O12—B7—Na3ix | 145.9 (3) |
B4viii—Na1—Na2ix | 79.19 (9) | O13—B7—Na3ix | 77.8 (2) |
B1vii—Na1—Na2ix | 55.29 (9) | O14—B8—O15 | 122.5 (3) |
Eu1ix—Na1—Na2ix | 57.48 (4) | O14—B8—O13 | 119.2 (3) |
Na2—Na1—Na2ix | 124.70 (8) | O15—B8—O13 | 118.3 (3) |
O4x—Na2—O14iii | 139.32 (13) | O14—B8—Na2iii | 58.18 (19) |
O4x—Na2—O2 | 127.05 (11) | O15—B8—Na2iii | 65.00 (19) |
O14iii—Na2—O2 | 77.65 (10) | O13—B8—Na2iii | 171.2 (3) |
O4x—Na2—O15iii | 134.25 (11) | O14—B8—Na3iii | 83.5 (2) |
O14iii—Na2—O15iii | 57.32 (9) | O15—B8—Na3iii | 144.1 (2) |
O2—Na2—O15iii | 95.22 (10) | O13—B8—Na3iii | 43.63 (16) |
O4x—Na2—O1 | 73.31 (10) | Na2iii—B8—Na3iii | 138.64 (15) |
O14iii—Na2—O1 | 120.22 (11) | B1—O1—Eu1ii | 173.2 (3) |
O2—Na2—O1 | 53.75 (9) | B1—O1—Na2 | 88.9 (2) |
O15iii—Na2—O1 | 144.86 (11) | Eu1ii—O1—Na2 | 94.51 (10) |
O4x—Na2—O1ii | 83.02 (10) | B1—O1—Na1vii | 92.2 (2) |
O14iii—Na2—O1ii | 68.09 (9) | Eu1ii—O1—Na1vii | 82.88 (9) |
O2—Na2—O1ii | 81.52 (9) | Na2—O1—Na1vii | 164.30 (13) |
O15iii—Na2—O1ii | 124.53 (10) | B1—O1—Na2ii | 98.6 (2) |
O1—Na2—O1ii | 71.94 (10) | Eu1ii—O1—Na2ii | 85.96 (9) |
O4x—Na2—O5x | 54.52 (9) | Na2—O1—Na2ii | 108.06 (10) |
O14iii—Na2—O5x | 104.69 (10) | Na1vii—O1—Na2ii | 87.26 (10) |
O2—Na2—O5x | 173.93 (11) | B1—O2—B3 | 122.7 (3) |
O15iii—Na2—O5x | 81.62 (9) | B1—O2—Na2 | 95.5 (2) |
O1—Na2—O5x | 127.45 (10) | B3—O2—Na2 | 140.1 (2) |
O1ii—Na2—O5x | 104.55 (10) | B1—O2—Eu1 | 111.3 (2) |
O4x—Na2—B8iii | 143.54 (13) | B3—O2—Eu1 | 93.68 (19) |
O14iii—Na2—B8iii | 28.11 (10) | Na2—O2—Eu1 | 81.22 (8) |
O2—Na2—B8iii | 88.25 (11) | B1—O3—B2 | 120.4 (3) |
O15iii—Na2—B8iii | 29.43 (10) | B1—O3—Na1vii | 95.6 (2) |
O1—Na2—B8iii | 140.72 (12) | B2—O3—Na1vii | 143.9 (2) |
O1ii—Na2—B8iii | 95.25 (11) | B1—O3—Na2vii | 118.9 (2) |
O5x—Na2—B8iii | 91.43 (11) | B2—O3—Na2vii | 89.0 (2) |
O4x—Na2—O3vii | 85.23 (10) | Na1vii—O3—Na2vii | 74.45 (9) |
O14iii—Na2—O3vii | 134.81 (11) | B2—O4—Eu1i | 148.8 (3) |
O2—Na2—O3vii | 78.04 (9) | B2—O4—Na2xii | 103.2 (2) |
O15iii—Na2—O3vii | 87.89 (9) | Eu1i—O4—Na2xii | 107.70 (11) |
O1—Na2—O3vii | 71.17 (9) | B2—O5—B3 | 123.2 (3) |
O1ii—Na2—O3vii | 143.09 (10) | B2—O5—Eu1ix | 112.9 (2) |
O5x—Na2—O3vii | 96.60 (9) | B3—O5—Eu1ix | 91.30 (19) |
B8iii—Na2—O3vii | 114.35 (11) | B2—O5—Na2xii | 81.0 (2) |
O4x—Na2—B2x | 26.41 (11) | B3—O5—Na2xii | 145.0 (2) |
O14iii—Na2—B2x | 124.78 (12) | Eu1ix—O5—Na2xii | 102.41 (9) |
O2—Na2—B2x | 153.23 (12) | B3—O6—B5 | 118.4 (3) |
O15iii—Na2—B2x | 109.09 (12) | B3—O6—Na1 | 116.3 (2) |
O1—Na2—B2x | 99.61 (11) | B5—O6—Na1 | 123.4 (2) |
O1ii—Na2—B2x | 93.25 (11) | B3—O6—Eu1ix | 101.8 (2) |
O5x—Na2—B2x | 28.13 (10) | B5—O6—Eu1ix | 95.49 (19) |
B8iii—Na2—B2x | 118.45 (13) | Na1—O6—Eu1ix | 86.56 (9) |
O3vii—Na2—B2x | 91.47 (11) | B4—O7—B3 | 119.0 (3) |
O4x—Na2—B1 | 99.51 (12) | B4—O7—Eu1 | 128.3 (2) |
O14iii—Na2—B1 | 101.44 (12) | B3—O7—Eu1 | 108.37 (19) |
O2—Na2—B1 | 27.63 (10) | B4—O8—B5 | 122.9 (3) |
O15iii—Na2—B1 | 120.22 (12) | B7—O9—B5 | 132.7 (3) |
O1—Na2—B1 | 26.37 (10) | B7—O9—Na3ix | 104.0 (2) |
O1ii—Na2—B1 | 77.66 (11) | B5—O9—Na3ix | 104.0 (2) |
O5x—Na2—B1 | 152.58 (12) | B6—O10—B5xiv | 123.3 (3) |
B8iii—Na2—B1 | 115.77 (13) | B6—O10—Eu1iv | 125.3 (2) |
O3vii—Na2—B1 | 69.97 (10) | B5xiv—O10—Eu1iv | 98.92 (19) |
B2x—Na2—B1 | 125.60 (13) | B6—O10—Na3iv | 103.5 (2) |
O4x—Na2—B2vii | 60.17 (11) | B5xiv—O10—Na3iv | 89.40 (19) |
O14iii—Na2—B2vii | 156.34 (12) | Eu1iv—O10—Na3iv | 110.76 (10) |
O2—Na2—B2vii | 100.24 (11) | B4iv—O11—B6 | 129.8 (3) |
O15iii—Na2—B2vii | 99.90 (11) | B4iv—O11—Na3 | 112.5 (2) |
O1—Na2—B2vii | 73.73 (10) | B6—O11—Na3 | 99.8 (2) |
O1ii—Na2—B2vii | 135.34 (11) | B4iv—O11—Na1iii | 101.2 (2) |
O5x—Na2—B2vii | 75.33 (10) | B6—O11—Na1iii | 96.9 (2) |
B8iii—Na2—B2vii | 129.32 (13) | Na3—O11—Na1iii | 116.74 (12) |
O3vii—Na2—B2vii | 26.38 (9) | B7—O12—B6 | 120.4 (3) |
B2x—Na2—B2vii | 65.39 (13) | B7—O12—Na3 | 126.2 (2) |
B1—Na2—B2vii | 84.07 (12) | B6—O12—Na3 | 96.36 (19) |
O9v—Na3—O13iii | 96.45 (11) | B8—O13—B7 | 119.8 (3) |
O9v—Na3—O11 | 118.12 (11) | B8—O13—Na3iii | 112.0 (2) |
O13iii—Na3—O11 | 118.17 (11) | B7—O13—Na3iii | 122.9 (2) |
O9v—Na3—O12 | 169.36 (12) | B8—O13—Na3ix | 128.0 (2) |
O13iii—Na3—O12 | 93.81 (10) | B7—O13—Na3ix | 74.51 (19) |
O11—Na3—O12 | 58.49 (9) | Na3iii—O13—Na3ix | 92.15 (10) |
O9v—Na3—O10iv | 58.08 (9) | B8—O14—Eu1iii | 155.4 (2) |
O13iii—Na3—O10iv | 111.76 (10) | B8—O14—Na2iii | 93.7 (2) |
O11—Na3—O10iv | 129.84 (11) | Eu1iii—O14—Na2iii | 93.30 (10) |
O12—Na3—O10iv | 115.17 (11) | B8—O14—Na1vi | 115.8 (2) |
O9v—Na3—B7v | 26.57 (10) | Eu1iii—O14—Na1vi | 85.95 (9) |
O13iii—Na3—B7v | 102.93 (12) | Na2iii—O14—Na1vi | 100.43 (12) |
O11—Na3—B7v | 93.01 (11) | B8—O15—B6 | 122.3 (3) |
O12—Na3—B7v | 151.40 (12) | B8—O15—Na1iii | 122.6 (2) |
O10iv—Na3—B7v | 80.05 (11) | B6—O15—Na1iii | 96.41 (19) |
O9v—Na3—O13v | 50.20 (8) | B8—O15—Na2iii | 85.6 (2) |
O13iii—Na3—O13v | 87.85 (10) | B6—O15—Na2iii | 145.0 (2) |
O11—Na3—O13v | 79.80 (9) | Na1iii—O15—Na2iii | 82.68 (10) |
Symmetry codes: (i) −x+1, −y, −z+1; (ii) −x+2, −y+1, −z+1; (iii) −x+1, −y+1, −z; (iv) −x+1, −y, −z; (v) x+1, y, z; (vi) −x, −y+1, −z; (vii) −x+1, −y+1, −z+1; (viii) x, y+1, z; (ix) x−1, y, z; (x) x+1, y+1, z; (xi) −x+2, −y+1, −z; (xii) x−1, y−1, z; (xiii) x, y−1, z; (xiv) −x, −y, −z. |
Subscribe to Acta Crystallographica Section C: Structural Chemistry
The full text of this article is available to subscribers to the journal.
- Information on subscribing
- Sample issue
- Purchase subscription
- Reduced-price subscriptions
- If you have already subscribed, you may need to register