Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229616009384/ku3179sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S2053229616009384/ku3179Isup2.hkl |
CCDC reference: 1484497
Data collection: CrysAlis CCD (Oxford Diffraction, 2008); cell refinement: CrysAlis CCD (Oxford Diffraction, 2008); data reduction: CrysAlis RED (Oxford Diffraction, 2008); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015b); molecular graphics: DIAMOND (Brandenburg, 2006); software used to prepare material for publication: SHELXL2014 (Sheldrick, 2015b).
Li4Ge2B | Dx = 2.901 Mg m−3 Dm = 2.88 (2) Mg m−3 Dm measured by volumetric |
Mr = 183.79 | Mo Kα radiation, λ = 0.71073 Å |
Trigonal, R3m:H | Cell parameters from 287 reflections |
a = 4.4603 (3) Å | θ = 3.3–25.2° |
c = 18.3197 (11) Å | µ = 13.95 mm−1 |
V = 315.63 (5) Å3 | T = 293 K |
Z = 3 | Plate, metallic dark grey |
F(000) = 243 | 0.06 × 0.05 × 0.01 mm |
Oxford Diffraction Xcalibur3 CCD diffractometer | 269 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.022 |
ω scans | θmax = 29.9°, θmin = 3.3° |
Absorption correction: analytical (CrysAlis RED; Oxford Diffraction, 2008) | h = −5→5 |
Tmin = 0.441, Tmax = 0.859 | k = −6→6 |
1160 measured reflections | l = −25→25 |
287 independent reflections |
Refinement on F2 | 1 restraint |
Least-squares matrix: full | w = 1/[σ2(Fo2) + 0.009P] where P = (Fo2 + 2Fc2)/3 |
R[F2 > 2σ(F2)] = 0.022 | (Δ/σ)max < 0.001 |
wR(F2) = 0.047 | Δρmax = 0.52 e Å−3 |
S = 1.04 | Δρmin = −0.53 e Å−3 |
287 reflections | Absolute structure: Refined as an inversion twin |
16 parameters | Absolute structure parameter: 0.45 (11) |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
Refinement. Refined as a 2-component inversion twin |
x | y | z | Uiso*/Ueq | ||
Ge1 | 0.0000 | 0.0000 | 0.40695 (9) | 0.0121 (9) | |
Ge2 | 0.0000 | 0.0000 | 0.26645 (4) | 0.0107 (8) | |
B3 | 0.0000 | 0.0000 | 0.1244 (12) | 0.008 (3) | |
Li4 | 0.0000 | 0.0000 | 0.836 (4) | 0.018 (2)* | |
Li5 | 0.0000 | 0.0000 | 0.7006 (12) | 0.018 (2)* | |
Li6 | 0.0000 | 0.0000 | 0.9967 (13) | 0.018 (2)* | |
Li7 | 0.0000 | 0.0000 | 0.541 (3) | 0.018 (2)* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Ge1 | 0.0112 (9) | 0.0112 (9) | 0.0141 (17) | 0.0056 (5) | 0.000 | 0.000 |
Ge2 | 0.0121 (9) | 0.0121 (9) | 0.0080 (13) | 0.0060 (5) | 0.000 | 0.000 |
B3 | 0.011 (3) | 0.011 (3) | 0.001 (8) | 0.0054 (13) | 0.000 | 0.000 |
Ge1—Li7 | 2.45 (5) | Li4—Ge1ix | 3.11 (4) |
Ge1—Ge2 | 2.5738 (16) | Li4—Ge1viii | 3.11 (4) |
Ge1—Li5i | 2.676 (6) | Li4—Ge1x | 3.11 (4) |
Ge1—Li5ii | 2.676 (6) | Li4—Ge2xii | 3.13 (4) |
Ge1—Li5iii | 2.676 (6) | Li5—Li6i | 2.664 (9) |
Ge1—Li6iv | 2.935 (12) | Li5—Li6ii | 2.664 (10) |
Ge1—Li6v | 2.935 (12) | Li5—Li6iii | 2.664 (9) |
Ge1—Li6vi | 2.935 (12) | Li5—Ge1viii | 2.676 (6) |
Ge1—Li4ii | 3.11 (4) | Li5—Ge1ix | 2.676 (6) |
Ge1—Li4i | 3.11 (4) | Li5—Ge1x | 2.676 (6) |
Ge1—Li4iii | 3.11 (4) | Li5—Li7 | 2.93 (6) |
Ge2—Li7i | 2.79 (2) | Li5—Ge2ix | 3.169 (13) |
Ge2—Li7ii | 2.79 (2) | Li5—Ge2viii | 3.169 (13) |
Ge2—Li7iii | 2.79 (2) | Li5—Ge2x | 3.170 (13) |
Ge2—Li6v | 2.826 (10) | Li6—B3xiv | 2.34 (4) |
Ge2—Li6iv | 2.826 (10) | Li6—Li5viii | 2.664 (10) |
Ge2—Li6vi | 2.826 (10) | Li6—Li5ix | 2.664 (10) |
Ge2—Li4iv | 3.13 (4) | Li6—Li5x | 2.664 (9) |
Ge2—Li4v | 3.13 (4) | Li6—Ge2xi | 2.826 (10) |
Ge2—Li4vi | 3.13 (4) | Li6—Ge2xii | 2.826 (10) |
Ge2—Li5ii | 3.169 (13) | Li6—Ge2xiii | 2.826 (10) |
Ge2—Li5i | 3.169 (13) | Li6—Ge1xii | 2.935 (12) |
B3—Li6vii | 2.34 (4) | Li6—Ge1xi | 2.935 (12) |
B3—Li4v | 2.70 (3) | Li6—Ge1xiii | 2.935 (12) |
B3—Li4iv | 2.70 (3) | Li6—Li7ix | 3.42 (4) |
B3—Li4vi | 2.70 (3) | Li7—Li4i | 2.67 (3) |
Li4—Li5 | 2.48 (7) | Li7—Li4ii | 2.67 (3) |
Li4—Li7viii | 2.67 (3) | Li7—Li4iii | 2.67 (3) |
Li4—Li7ix | 2.67 (3) | Li7—Ge2viii | 2.79 (2) |
Li4—Li7x | 2.67 (3) | Li7—Ge2ix | 2.79 (2) |
Li4—B3xi | 2.70 (3) | Li7—Ge2x | 2.79 (2) |
Li4—B3xii | 2.70 (3) | Li7—Li6ii | 3.42 (4) |
Li4—B3xiii | 2.70 (3) | Li7—Li6i | 3.42 (4) |
Li4—Li6 | 2.95 (9) | Li7—Li6iii | 3.42 (4) |
Li7—Ge1—Ge2 | 180.0 | Li7x—Li4—Ge2xii | 56.9 (10) |
Li7—Ge1—Li5i | 105.7 (5) | B3xi—Li4—Ge2xii | 124.4 (9) |
Ge2—Ge1—Li5i | 74.3 (5) | B3xii—Li4—Ge2xii | 52.4 (7) |
Li7—Ge1—Li5ii | 105.7 (5) | B3xiii—Li4—Ge2xii | 124.4 (9) |
Ge2—Ge1—Li5ii | 74.3 (5) | Li6—Li4—Ge2xii | 55.3 (11) |
Li5i—Ge1—Li5ii | 112.9 (4) | Ge1ix—Li4—Ge2xii | 180 (2) |
Li7—Ge1—Li5iii | 105.7 (5) | Ge1viii—Li4—Ge2xii | 88.85 (3) |
Ge2—Ge1—Li5iii | 74.3 (5) | Ge1x—Li4—Ge2xii | 88.85 (3) |
Li5i—Ge1—Li5iii | 112.9 (4) | Li4—Li5—Li6i | 104.9 (8) |
Li5ii—Ge1—Li5iii | 112.9 (4) | Li4—Li5—Li6ii | 104.9 (8) |
Li7—Ge1—Li6iv | 118.7 (4) | Li6i—Li5—Li6ii | 113.7 (6) |
Ge2—Ge1—Li6iv | 61.3 (4) | Li4—Li5—Li6iii | 104.9 (8) |
Li5i—Ge1—Li6iv | 56.46 (19) | Li6i—Li5—Li6iii | 113.7 (6) |
Li5ii—Ge1—Li6iv | 135.6 (5) | Li6ii—Li5—Li6iii | 113.7 (6) |
Li5iii—Ge1—Li6iv | 56.47 (19) | Li4—Li5—Ge1viii | 74.3 (5) |
Li7—Ge1—Li6v | 118.7 (4) | Li6i—Li5—Ge1viii | 179.1 (12) |
Ge2—Ge1—Li6v | 61.3 (4) | Li6ii—Li5—Ge1viii | 66.7 (2) |
Li5i—Ge1—Li6v | 135.6 (5) | Li6iii—Li5—Ge1viii | 66.7 (2) |
Li5ii—Ge1—Li6v | 56.46 (19) | Li4—Li5—Ge1ix | 74.3 (5) |
Li5iii—Ge1—Li6v | 56.47 (19) | Li6i—Li5—Ge1ix | 66.7 (2) |
Li6iv—Ge1—Li6v | 98.9 (5) | Li6ii—Li5—Ge1ix | 179.1 (12) |
Li7—Ge1—Li6vi | 118.7 (4) | Li6iii—Li5—Ge1ix | 66.7 (2) |
Ge2—Ge1—Li6vi | 61.3 (4) | Ge1viii—Li5—Ge1ix | 112.9 (4) |
Li5i—Ge1—Li6vi | 56.47 (19) | Li4—Li5—Ge1x | 74.3 (5) |
Li5ii—Ge1—Li6vi | 56.47 (19) | Li6i—Li5—Ge1x | 66.7 (2) |
Li5iii—Ge1—Li6vi | 135.6 (5) | Li6ii—Li5—Ge1x | 66.7 (2) |
Li6iv—Ge1—Li6vi | 98.9 (5) | Li6iii—Li5—Ge1x | 179.1 (12) |
Li6v—Ge1—Li6vi | 98.9 (5) | Ge1viii—Li5—Ge1x | 112.9 (4) |
Li7—Ge1—Li4ii | 55.8 (12) | Ge1ix—Li5—Ge1x | 112.9 (4) |
Ge2—Ge1—Li4ii | 124.2 (12) | Li4—Li5—Li7 | 180.000 (13) |
Li5i—Ge1—Li4ii | 123.4 (3) | Li6i—Li5—Li7 | 75.1 (8) |
Li5ii—Ge1—Li4ii | 49.9 (11) | Li6ii—Li5—Li7 | 75.1 (8) |
Li5iii—Ge1—Li4ii | 123.4 (3) | Li6iii—Li5—Li7 | 75.1 (8) |
Li6iv—Ge1—Li4ii | 174.5 (11) | Ge1viii—Li5—Li7 | 105.7 (5) |
Li6v—Ge1—Li4ii | 84.7 (9) | Ge1ix—Li5—Li7 | 105.7 (5) |
Li6vi—Ge1—Li4ii | 84.7 (9) | Ge1x—Li5—Li7 | 105.7 (5) |
Li7—Ge1—Li4i | 55.8 (12) | Li4—Li5—Ge2ix | 125.7 (3) |
Ge2—Ge1—Li4i | 124.2 (12) | Li6i—Li5—Ge2ix | 57.2 (4) |
Li5i—Ge1—Li4i | 49.9 (11) | Li6ii—Li5—Ge2ix | 129.5 (10) |
Li5ii—Ge1—Li4i | 123.4 (3) | Li6iii—Li5—Ge2ix | 57.2 (4) |
Li5iii—Ge1—Li4i | 123.4 (3) | Ge1viii—Li5—Ge2ix | 123.3 (3) |
Li6iv—Ge1—Li4i | 84.7 (9) | Ge1ix—Li5—Ge2ix | 51.41 (14) |
Li6v—Ge1—Li4i | 174.5 (11) | Ge1x—Li5—Ge2ix | 123.3 (3) |
Li6vi—Ge1—Li4i | 84.7 (9) | Li7—Li5—Ge2ix | 54.3 (3) |
Li4ii—Ge1—Li4i | 91.5 (16) | Li4—Li5—Ge2viii | 125.7 (3) |
Li7—Ge1—Li4iii | 55.8 (12) | Li6i—Li5—Ge2viii | 129.5 (10) |
Ge2—Ge1—Li4iii | 124.2 (12) | Li6ii—Li5—Ge2viii | 57.2 (4) |
Li5i—Ge1—Li4iii | 123.4 (3) | Li6iii—Li5—Ge2viii | 57.2 (4) |
Li5ii—Ge1—Li4iii | 123.4 (3) | Ge1viii—Li5—Ge2viii | 51.41 (14) |
Li5iii—Ge1—Li4iii | 49.9 (11) | Ge1ix—Li5—Ge2viii | 123.3 (3) |
Li6iv—Ge1—Li4iii | 84.7 (9) | Ge1x—Li5—Ge2viii | 123.3 (3) |
Li6v—Ge1—Li4iii | 84.7 (9) | Li7—Li5—Ge2viii | 54.3 (3) |
Li6vi—Ge1—Li4iii | 174.5 (11) | Ge2ix—Li5—Ge2viii | 89.4 (5) |
Li4ii—Ge1—Li4iii | 91.5 (16) | Li4—Li5—Ge2x | 125.7 (3) |
Li4i—Ge1—Li4iii | 91.5 (16) | Li6i—Li5—Ge2x | 57.2 (4) |
Ge1—Ge2—Li7i | 112.8 (10) | Li6ii—Li5—Ge2x | 57.2 (4) |
Ge1—Ge2—Li7ii | 112.8 (10) | Li6iii—Li5—Ge2x | 129.5 (10) |
Li7i—Ge2—Li7ii | 105.9 (11) | Ge1viii—Li5—Ge2x | 123.3 (3) |
Ge1—Ge2—Li7iii | 112.8 (10) | Ge1ix—Li5—Ge2x | 123.3 (3) |
Li7i—Ge2—Li7iii | 105.9 (11) | Ge1x—Li5—Ge2x | 51.41 (14) |
Li7ii—Ge2—Li7iii | 105.9 (11) | Li7—Li5—Ge2x | 54.3 (3) |
Ge1—Ge2—Li6v | 65.7 (4) | Ge2ix—Li5—Ge2x | 89.4 (5) |
Li7i—Ge2—Li6v | 178.5 (10) | Ge2viii—Li5—Ge2x | 89.4 (5) |
Li7ii—Ge2—Li6v | 74.9 (7) | B3xiv—Li6—Li5viii | 75.1 (8) |
Li7iii—Ge2—Li6v | 74.9 (7) | B3xiv—Li6—Li5ix | 75.1 (8) |
Ge1—Ge2—Li6iv | 65.7 (4) | Li5viii—Li6—Li5ix | 113.7 (6) |
Li7i—Ge2—Li6iv | 74.9 (7) | B3xiv—Li6—Li5x | 75.1 (8) |
Li7ii—Ge2—Li6iv | 178.5 (10) | Li5viii—Li6—Li5x | 113.7 (6) |
Li7iii—Ge2—Li6iv | 74.9 (7) | Li5ix—Li6—Li5x | 113.7 (6) |
Li6v—Ge2—Li6iv | 104.2 (5) | B3xiv—Li6—Ge2xi | 114.3 (4) |
Ge1—Ge2—Li6vi | 65.7 (4) | Li5viii—Li6—Ge2xi | 170.5 (11) |
Li7i—Ge2—Li6vi | 74.9 (7) | Li5ix—Li6—Ge2xi | 70.4 (3) |
Li7ii—Ge2—Li6vi | 74.9 (7) | Li5x—Li6—Ge2xi | 70.4 (3) |
Li7iii—Ge2—Li6vi | 178.5 (10) | B3xiv—Li6—Ge2xii | 114.3 (4) |
Li6v—Ge2—Li6vi | 104.2 (5) | Li5viii—Li6—Ge2xii | 70.4 (3) |
Li6iv—Ge2—Li6vi | 104.2 (5) | Li5ix—Li6—Ge2xii | 170.5 (11) |
Ge1—Ge2—Li4iv | 124.7 (11) | Li5x—Li6—Ge2xii | 70.4 (3) |
Li7i—Ge2—Li4iv | 53.1 (5) | Ge2xi—Li6—Ge2xii | 104.2 (5) |
Li7ii—Ge2—Li4iv | 122.5 (13) | B3xiv—Li6—Ge2xiii | 114.3 (4) |
Li7iii—Ge2—Li4iv | 53.1 (5) | Li5viii—Li6—Ge2xiii | 70.4 (3) |
Li6v—Ge2—Li4iv | 127.5 (3) | Li5ix—Li6—Ge2xiii | 70.4 (3) |
Li6iv—Ge2—Li4iv | 59.0 (14) | Li5x—Li6—Ge2xiii | 170.5 (11) |
Li6vi—Ge2—Li4iv | 127.5 (3) | Ge2xi—Li6—Ge2xiii | 104.2 (5) |
Ge1—Ge2—Li4v | 124.7 (11) | Ge2xii—Li6—Ge2xiii | 104.2 (5) |
Li7i—Ge2—Li4v | 122.5 (13) | B3xiv—Li6—Ge1xii | 61.3 (4) |
Li7ii—Ge2—Li4v | 53.1 (4) | Li5viii—Li6—Ge1xii | 56.8 (3) |
Li7iii—Ge2—Li4v | 53.1 (5) | Li5ix—Li6—Ge1xii | 136.5 (11) |
Li6v—Ge2—Li4v | 59.0 (14) | Li5x—Li6—Ge1xii | 56.8 (3) |
Li6iv—Ge2—Li4v | 127.5 (3) | Ge2xi—Li6—Ge1xii | 126.69 (7) |
Li6vi—Ge2—Li4v | 127.5 (3) | Ge2xii—Li6—Ge1xii | 53.02 (4) |
Li4iv—Ge2—Li4v | 90.8 (16) | Ge2xiii—Li6—Ge1xii | 126.69 (7) |
Ge1—Ge2—Li4vi | 124.7 (11) | B3xiv—Li6—Ge1xi | 61.3 (4) |
Li7i—Ge2—Li4vi | 53.1 (4) | Li5viii—Li6—Ge1xi | 136.5 (11) |
Li7ii—Ge2—Li4vi | 53.1 (5) | Li5ix—Li6—Ge1xi | 56.8 (3) |
Li7iii—Ge2—Li4vi | 122.5 (13) | Li5x—Li6—Ge1xi | 56.8 (3) |
Li6v—Ge2—Li4vi | 127.5 (3) | Ge2xi—Li6—Ge1xi | 53.02 (4) |
Li6iv—Ge2—Li4vi | 127.5 (3) | Ge2xii—Li6—Ge1xi | 126.69 (7) |
Li6vi—Ge2—Li4vi | 59.0 (14) | Ge2xiii—Li6—Ge1xi | 126.69 (7) |
Li4iv—Ge2—Li4vi | 90.8 (16) | Ge1xii—Li6—Ge1xi | 98.9 (5) |
Li4v—Ge2—Li4vi | 90.8 (16) | B3xiv—Li6—Ge1xiii | 61.3 (4) |
Ge1—Ge2—Li5ii | 54.3 (3) | Li5viii—Li6—Ge1xiii | 56.8 (3) |
Li7i—Ge2—Li5ii | 126.9 (5) | Li5ix—Li6—Ge1xiii | 56.8 (3) |
Li7ii—Ge2—Li5ii | 58.5 (11) | Li5x—Li6—Ge1xiii | 136.5 (11) |
Li7iii—Ge2—Li5ii | 126.9 (5) | Ge2xi—Li6—Ge1xiii | 126.69 (7) |
Li6v—Ge2—Li5ii | 52.4 (2) | Ge2xii—Li6—Ge1xiii | 126.69 (7) |
Li6iv—Ge2—Li5ii | 120.0 (5) | Ge2xiii—Li6—Ge1xiii | 53.02 (4) |
Li6vi—Ge2—Li5ii | 52.4 (2) | Ge1xii—Li6—Ge1xiii | 98.9 (5) |
Li4iv—Ge2—Li5ii | 179.0 (13) | Ge1xi—Li6—Ge1xiii | 98.9 (5) |
Li4v—Ge2—Li5ii | 89.9 (8) | B3xiv—Li6—Li4 | 180.00 (2) |
Li4vi—Ge2—Li5ii | 89.9 (8) | Li5viii—Li6—Li4 | 104.9 (8) |
Ge1—Ge2—Li5i | 54.3 (3) | Li5ix—Li6—Li4 | 104.9 (8) |
Li7i—Ge2—Li5i | 58.5 (11) | Li5x—Li6—Li4 | 104.9 (8) |
Li7ii—Ge2—Li5i | 126.9 (5) | Ge2xi—Li6—Li4 | 65.7 (4) |
Li7iii—Ge2—Li5i | 126.9 (5) | Ge2xii—Li6—Li4 | 65.7 (4) |
Li6v—Ge2—Li5i | 120.0 (5) | Ge2xiii—Li6—Li4 | 65.7 (4) |
Li6iv—Ge2—Li5i | 52.4 (2) | Ge1xii—Li6—Li4 | 118.7 (4) |
Li6vi—Ge2—Li5i | 52.4 (2) | Ge1xi—Li6—Li4 | 118.7 (4) |
Li4iv—Ge2—Li5i | 89.9 (8) | Ge1xiii—Li6—Li4 | 118.7 (4) |
Li4v—Ge2—Li5i | 179.0 (13) | B3xiv—Li6—Li7ix | 131.1 (8) |
Li4vi—Ge2—Li5i | 89.9 (8) | Li5viii—Li6—Li7ix | 122.2 (5) |
Li5ii—Ge2—Li5i | 89.4 (5) | Li5ix—Li6—Li7ix | 56.0 (9) |
Li6vii—B3—Li4v | 107.7 (17) | Li5x—Li6—Li7ix | 122.2 (6) |
Li6vii—B3—Li4iv | 107.7 (17) | Ge2xi—Li6—Li7ix | 52.1 (3) |
Li4v—B3—Li4iv | 111.2 (16) | Ge2xii—Li6—Li7ix | 114.5 (11) |
Li6vii—B3—Li4vi | 107.7 (17) | Ge2xiii—Li6—Li7ix | 52.1 (3) |
Li4v—B3—Li4vi | 111.2 (16) | Ge1xii—Li6—Li7ix | 167.5 (11) |
Li4iv—B3—Li4vi | 111.2 (16) | Ge1xi—Li6—Li7ix | 89.2 (4) |
Li5—Li4—Li7viii | 105 (2) | Ge1xiii—Li6—Li7ix | 89.2 (4) |
Li5—Li4—Li7ix | 105 (2) | Li4—Li6—Li7ix | 48.9 (8) |
Li7viii—Li4—Li7ix | 113.4 (17) | Ge1—Li7—Li4i | 75 (2) |
Li5—Li4—Li7x | 105 (2) | Ge1—Li7—Li4ii | 75 (2) |
Li7viii—Li4—Li7x | 113.4 (18) | Li4i—Li7—Li4ii | 113.4 (17) |
Li7ix—Li4—Li7x | 113.4 (18) | Ge1—Li7—Li4iii | 75 (2) |
Li5—Li4—B3xi | 72.3 (17) | Li4i—Li7—Li4iii | 113.4 (18) |
Li7viii—Li4—B3xi | 178 (4) | Li4ii—Li7—Li4iii | 113.4 (18) |
Li7ix—Li4—B3xi | 67.6 (4) | Ge1—Li7—Ge2viii | 112.8 (10) |
Li7x—Li4—B3xi | 67.6 (4) | Li4i—Li7—Ge2viii | 172 (3) |
Li5—Li4—B3xii | 72.3 (17) | Li4ii—Li7—Ge2viii | 69.9 (9) |
Li7viii—Li4—B3xii | 67.6 (4) | Li4iii—Li7—Ge2viii | 69.9 (9) |
Li7ix—Li4—B3xii | 178 (4) | Ge1—Li7—Ge2ix | 112.8 (10) |
Li7x—Li4—B3xii | 67.6 (4) | Li4i—Li7—Ge2ix | 69.9 (9) |
B3xi—Li4—B3xii | 111.2 (16) | Li4ii—Li7—Ge2ix | 172 (3) |
Li5—Li4—B3xiii | 72.3 (17) | Li4iii—Li7—Ge2ix | 69.9 (9) |
Li7viii—Li4—B3xiii | 67.6 (4) | Ge2viii—Li7—Ge2ix | 105.9 (11) |
Li7ix—Li4—B3xiii | 67.6 (4) | Ge1—Li7—Ge2x | 112.8 (10) |
Li7x—Li4—B3xiii | 178 (4) | Li4i—Li7—Ge2x | 69.9 (9) |
B3xi—Li4—B3xiii | 111.2 (16) | Li4ii—Li7—Ge2x | 69.9 (9) |
B3xii—Li4—B3xiii | 111.2 (16) | Li4iii—Li7—Ge2x | 172 (3) |
Li5—Li4—Li6 | 180.0 | Ge2viii—Li7—Ge2x | 105.9 (11) |
Li7viii—Li4—Li6 | 75 (2) | Ge2ix—Li7—Ge2x | 105.9 (11) |
Li7ix—Li4—Li6 | 75 (2) | Ge1—Li7—Li5 | 180.0 |
Li7x—Li4—Li6 | 75 (2) | Li4i—Li7—Li5 | 105 (2) |
B3xi—Li4—Li6 | 107.7 (17) | Li4ii—Li7—Li5 | 105 (2) |
B3xii—Li4—Li6 | 107.7 (17) | Li4iii—Li7—Li5 | 105 (2) |
B3xiii—Li4—Li6 | 107.7 (17) | Ge2viii—Li7—Li5 | 67.2 (10) |
Li5—Li4—Ge1ix | 55.8 (12) | Ge2ix—Li7—Li5 | 67.2 (10) |
Li7viii—Li4—Ge1ix | 123.1 (12) | Ge2x—Li7—Li5 | 67.2 (10) |
Li7ix—Li4—Ge1ix | 49.4 (13) | Ge1—Li7—Li6ii | 131.1 (8) |
Li7x—Li4—Ge1ix | 123.1 (12) | Li4i—Li7—Li6ii | 122.4 (14) |
B3xi—Li4—Ge1ix | 55.6 (8) | Li4ii—Li7—Li6ii | 56.3 (18) |
B3xii—Li4—Ge1ix | 128 (3) | Li4iii—Li7—Li6ii | 122.4 (14) |
B3xiii—Li4—Ge1ix | 55.6 (8) | Ge2viii—Li7—Li6ii | 53.0 (6) |
Li6—Li4—Ge1ix | 124.2 (12) | Ge2ix—Li7—Li6ii | 116.0 (18) |
Li5—Li4—Ge1viii | 55.8 (12) | Ge2x—Li7—Li6ii | 53.0 (6) |
Li7viii—Li4—Ge1viii | 49.4 (13) | Li5—Li7—Li6ii | 48.9 (8) |
Li7ix—Li4—Ge1viii | 123.1 (12) | Ge1—Li7—Li6i | 131.1 (8) |
Li7x—Li4—Ge1viii | 123.1 (12) | Li4i—Li7—Li6i | 56.3 (18) |
B3xi—Li4—Ge1viii | 128 (3) | Li4ii—Li7—Li6i | 122.4 (14) |
B3xii—Li4—Ge1viii | 55.6 (8) | Li4iii—Li7—Li6i | 122.4 (14) |
B3xiii—Li4—Ge1viii | 55.6 (8) | Ge2viii—Li7—Li6i | 116.0 (18) |
Li6—Li4—Ge1viii | 124.2 (12) | Ge2ix—Li7—Li6i | 53.0 (6) |
Ge1ix—Li4—Ge1viii | 91.5 (16) | Ge2x—Li7—Li6i | 53.0 (6) |
Li5—Li4—Ge1x | 55.8 (12) | Li5—Li7—Li6i | 48.9 (8) |
Li7viii—Li4—Ge1x | 123.1 (12) | Li6ii—Li7—Li6i | 81.4 (12) |
Li7ix—Li4—Ge1x | 123.1 (12) | Ge1—Li7—Li6iii | 131.1 (8) |
Li7x—Li4—Ge1x | 49.4 (13) | Li4i—Li7—Li6iii | 122.4 (14) |
B3xi—Li4—Ge1x | 55.6 (8) | Li4ii—Li7—Li6iii | 122.4 (14) |
B3xii—Li4—Ge1x | 55.6 (8) | Li4iii—Li7—Li6iii | 56.3 (18) |
B3xiii—Li4—Ge1x | 128 (3) | Ge2viii—Li7—Li6iii | 53.0 (6) |
Li6—Li4—Ge1x | 124.2 (12) | Ge2ix—Li7—Li6iii | 53.0 (6) |
Ge1ix—Li4—Ge1x | 91.5 (16) | Ge2x—Li7—Li6iii | 116.0 (18) |
Ge1viii—Li4—Ge1x | 91.5 (16) | Li5—Li7—Li6iii | 48.9 (8) |
Li5—Li4—Ge2xii | 124.7 (11) | Li6ii—Li7—Li6iii | 81.4 (12) |
Li7viii—Li4—Ge2xii | 56.9 (10) | Li6i—Li7—Li6iii | 81.4 (12) |
Li7ix—Li4—Ge2xii | 130 (3) |
Symmetry codes: (i) x−2/3, y−1/3, z−1/3; (ii) x+1/3, y+2/3, z−1/3; (iii) x+1/3, y−1/3, z−1/3; (iv) x−1/3, y−2/3, z−2/3; (v) x+2/3, y+1/3, z−2/3; (vi) x−1/3, y+1/3, z−2/3; (vii) x, y, z−1; (viii) x+2/3, y+1/3, z+1/3; (ix) x−1/3, y−2/3, z+1/3; (x) x−1/3, y+1/3, z+1/3; (xi) x−2/3, y−1/3, z+2/3; (xii) x+1/3, y+2/3, z+2/3; (xiii) x+1/3, y−1/3, z+2/3; (xiv) x, y, z+1. |
Subscribe to Acta Crystallographica Section C: Structural Chemistry
The full text of this article is available to subscribers to the journal.
- Information on subscribing
- Sample issue
- Purchase subscription
- Reduced-price subscriptions
- If you have already subscribed, you may need to register