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The title compound, {[Ag(C
6H
7AsNO
3)(C
18H
15P)]·H
2O}
n, has been synthesized from the reaction of 4-aminophenylarsonic acid with silver nitrate, in aqueous ammonia, with the addition of triphenylphosphane (PPh
3). The Ag
I centre is four-coordinated by one amino N atom, one PPh
3 P atom and two arsonate O atoms, forming a severely distorted [AgNPO
2] tetrahedron. Two Ag
I-centred tetrahedra are held together to produce a dinuclear [Ag
2O
2N
2P
2] unit by sharing an O–O edge. 4-Aminophenylarsonate (Hapa
−) adopts a μ
3-κ
3N:
O:
O-tridentate coordination mode connecting two dinuclear units, resulting in a neutral [Ag(Hapa)(PPh
3)]
n layer lying parallel to the (10
) plane. The PPh
3 ligands are suspended on both sides of the [Ag(Hapa)(PPh
3)]
n layer, displaying up and down orientations. There is an
R22(8) hydrogen-bonded dimer involving two arsonate groups from two Hapa
− ligands related by a centre of inversion. Additionally, there are hydrogen-bonding interactions involving the solvent water molecules and the arsonate and amine groups of the Hapa
− ligands, and weak π–π stacking interactions within the [Ag(Hapa)(PPh
3)]
n layer. These two-dimensional layers are further assembled by weak van der Waals interactions to form the final architecture.
Supporting information
CCDC reference: 1051130
Data collection: CrystalClear (Rigaku, 2007); cell refinement: CrystalClear (Rigaku, 2007); data reduction: CrystalClear (Rigaku, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).
Poly[[(µ
3-4-aminophenylarsonato-
κ3N:
O:
O)(triphenylphosphane-
κP)silver(I)]
monohydrate]
top
Crystal data top
[Ag(C6H7AsNO3)(C18H15P)]·H2O | F(000) = 1208 |
Mr = 604.20 | Dx = 1.723 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 7233 reflections |
a = 14.751 (3) Å | θ = 3.3–27.5° |
b = 10.014 (2) Å | µ = 2.38 mm−1 |
c = 16.418 (4) Å | T = 293 K |
β = 106.13 (3)° | Block, colourless |
V = 2329.8 (9) Å3 | 0.31 × 0.15 × 0.10 mm |
Z = 4 | |
Data collection top
Rigaku Mercury CCD area-detector diffractometer | 5331 independent reflections |
Radiation source: fine-focus sealed tube | 4947 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.042 |
Detector resolution: 28.5714 pixels mm-1 | θmax = 27.5°, θmin = 3.3° |
ω scans | h = −19→19 |
Absorption correction: multi-scan (RAPID-AUTO; Rigaku, 1998) | k = −12→12 |
Tmin = 0.746, Tmax = 1.000 | l = −18→21 |
18980 measured reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.043 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.079 | H-atom parameters constrained |
S = 1.20 | w = 1/[σ2(Fo2) + (0.0166P)2 + 2.698P] where P = (Fo2 + 2Fc2)/3 |
5331 reflections | (Δ/σ)max = 0.001 |
289 parameters | Δρmax = 0.45 e Å−3 |
0 restraints | Δρmin = −0.46 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R-factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Ag1 | 0.373989 (18) | 0.00080 (3) | 0.454968 (17) | 0.03820 (9) | |
As1 | 0.46537 (2) | 0.29970 (3) | 0.44930 (2) | 0.02964 (9) | |
P1 | 0.22421 (6) | 0.00973 (9) | 0.48273 (6) | 0.03131 (19) | |
N1 | 0.1050 (2) | 0.3627 (3) | 0.15862 (18) | 0.0405 (7) | |
H1A | 0.0589 | 0.3931 | 0.1758 | 0.049* | |
H1B | 0.0896 | 0.2872 | 0.1337 | 0.049* | |
C1 | 0.3503 (2) | 0.3171 (3) | 0.3599 (2) | 0.0300 (7) | |
C2 | 0.3391 (3) | 0.2455 (3) | 0.2851 (2) | 0.0369 (8) | |
H2A | 0.3868 | 0.1886 | 0.2793 | 0.044* | |
C3 | 0.2577 (3) | 0.2585 (3) | 0.2197 (2) | 0.0392 (8) | |
H3A | 0.2506 | 0.2103 | 0.1698 | 0.047* | |
C4 | 0.1860 (2) | 0.3434 (3) | 0.2279 (2) | 0.0318 (7) | |
C5 | 0.1970 (2) | 0.4132 (4) | 0.3025 (2) | 0.0364 (8) | |
H5A | 0.1492 | 0.4693 | 0.3088 | 0.044* | |
C6 | 0.2790 (2) | 0.3997 (3) | 0.3679 (2) | 0.0355 (8) | |
H6A | 0.2859 | 0.4472 | 0.4179 | 0.043* | |
C7 | 0.1304 (2) | 0.0923 (3) | 0.4025 (2) | 0.0335 (7) | |
C8 | 0.1194 (3) | 0.0571 (4) | 0.3185 (2) | 0.0467 (9) | |
H8A | 0.1613 | −0.0025 | 0.3048 | 0.056* | |
C9 | 0.0463 (3) | 0.1106 (4) | 0.2553 (3) | 0.0574 (12) | |
H9A | 0.0371 | 0.0836 | 0.1994 | 0.069* | |
C10 | −0.0129 (3) | 0.2033 (5) | 0.2745 (3) | 0.0595 (12) | |
H10A | −0.0608 | 0.2411 | 0.2314 | 0.071* | |
C11 | −0.0018 (3) | 0.2406 (4) | 0.3570 (3) | 0.0555 (11) | |
H11A | −0.0421 | 0.3037 | 0.3698 | 0.067* | |
C12 | 0.0694 (3) | 0.1842 (4) | 0.4217 (3) | 0.0436 (9) | |
H12A | 0.0761 | 0.2082 | 0.4778 | 0.052* | |
C13 | 0.2162 (2) | 0.0887 (3) | 0.5805 (2) | 0.0333 (7) | |
C14 | 0.1638 (3) | 0.0357 (4) | 0.6310 (2) | 0.0440 (9) | |
H14A | 0.1359 | −0.0478 | 0.6184 | 0.053* | |
C15 | 0.1529 (3) | 0.1064 (5) | 0.7000 (3) | 0.0562 (11) | |
H15A | 0.1185 | 0.0697 | 0.7341 | 0.067* | |
C16 | 0.1930 (3) | 0.2315 (5) | 0.7184 (3) | 0.0623 (12) | |
H16A | 0.1844 | 0.2800 | 0.7639 | 0.075* | |
C17 | 0.2458 (3) | 0.2837 (4) | 0.6689 (3) | 0.0572 (11) | |
H17A | 0.2733 | 0.3675 | 0.6817 | 0.069* | |
C18 | 0.2587 (3) | 0.2135 (4) | 0.6007 (2) | 0.0450 (9) | |
H18A | 0.2954 | 0.2492 | 0.5683 | 0.054* | |
C19 | 0.1802 (2) | −0.1601 (3) | 0.4856 (2) | 0.0332 (7) | |
C20 | 0.0901 (3) | −0.2005 (4) | 0.4401 (3) | 0.0452 (9) | |
H20A | 0.0473 | −0.1383 | 0.4092 | 0.054* | |
C21 | 0.0642 (3) | −0.3331 (4) | 0.4408 (3) | 0.0553 (11) | |
H21A | 0.0043 | −0.3601 | 0.4097 | 0.066* | |
C22 | 0.1266 (3) | −0.4254 (4) | 0.4874 (3) | 0.0557 (11) | |
H22A | 0.1086 | −0.5144 | 0.4877 | 0.067* | |
C23 | 0.2147 (3) | −0.3865 (4) | 0.5330 (3) | 0.0540 (11) | |
H23A | 0.2563 | −0.4487 | 0.5653 | 0.065* | |
C24 | 0.2423 (3) | −0.2552 (4) | 0.5314 (2) | 0.0418 (8) | |
H24A | 0.3031 | −0.2301 | 0.5613 | 0.050* | |
O1 | 0.50011 (16) | 0.1400 (2) | 0.44945 (15) | 0.0355 (5) | |
O2 | 0.45402 (19) | 0.3537 (2) | 0.54106 (15) | 0.0424 (6) | |
O3 | 0.55121 (16) | 0.3912 (2) | 0.42135 (16) | 0.0425 (6) | |
H3 | 0.5471 | 0.4699 | 0.4338 | 0.064* | |
OW1 | 0.5529 (2) | 0.0356 (3) | 0.3137 (2) | 0.0753 (10) | |
H1W | 0.5494 | 0.0759 | 0.3562 | 0.113* | |
H2W | 0.5954 | 0.0495 | 0.2915 | 0.113* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Ag1 | 0.02939 (14) | 0.04202 (16) | 0.04215 (16) | −0.00168 (12) | 0.00822 (11) | −0.00161 (12) |
As1 | 0.03008 (17) | 0.02429 (16) | 0.02937 (17) | −0.00141 (14) | −0.00035 (13) | 0.00190 (13) |
P1 | 0.0277 (4) | 0.0309 (4) | 0.0337 (4) | −0.0002 (4) | 0.0057 (4) | 0.0021 (4) |
N1 | 0.0350 (16) | 0.0440 (17) | 0.0357 (16) | −0.0002 (14) | −0.0013 (13) | 0.0074 (13) |
C1 | 0.0316 (17) | 0.0241 (15) | 0.0304 (16) | −0.0008 (13) | 0.0022 (13) | 0.0031 (13) |
C2 | 0.0391 (19) | 0.0317 (17) | 0.0351 (18) | 0.0085 (15) | 0.0022 (15) | −0.0015 (14) |
C3 | 0.045 (2) | 0.0328 (18) | 0.0333 (18) | 0.0010 (16) | 0.0002 (16) | −0.0033 (15) |
C4 | 0.0291 (17) | 0.0295 (17) | 0.0325 (17) | −0.0026 (13) | 0.0013 (14) | 0.0070 (14) |
C5 | 0.0311 (17) | 0.0360 (19) | 0.0409 (19) | 0.0077 (15) | 0.0077 (15) | 0.0055 (16) |
C6 | 0.0361 (18) | 0.0343 (18) | 0.0330 (17) | 0.0029 (15) | 0.0045 (14) | −0.0006 (15) |
C7 | 0.0303 (17) | 0.0313 (17) | 0.0363 (18) | −0.0018 (14) | 0.0049 (14) | 0.0041 (15) |
C8 | 0.059 (3) | 0.038 (2) | 0.040 (2) | 0.0005 (19) | 0.0086 (19) | 0.0025 (17) |
C9 | 0.073 (3) | 0.052 (3) | 0.037 (2) | −0.017 (2) | −0.002 (2) | 0.0092 (19) |
C10 | 0.039 (2) | 0.064 (3) | 0.062 (3) | −0.011 (2) | −0.009 (2) | 0.028 (2) |
C11 | 0.039 (2) | 0.054 (3) | 0.073 (3) | 0.0117 (19) | 0.015 (2) | 0.021 (2) |
C12 | 0.036 (2) | 0.047 (2) | 0.047 (2) | 0.0041 (17) | 0.0098 (17) | 0.0072 (18) |
C13 | 0.0297 (17) | 0.0346 (18) | 0.0330 (17) | 0.0022 (14) | 0.0045 (14) | 0.0004 (14) |
C14 | 0.046 (2) | 0.044 (2) | 0.042 (2) | −0.0048 (18) | 0.0122 (17) | 0.0003 (17) |
C15 | 0.061 (3) | 0.070 (3) | 0.042 (2) | 0.000 (2) | 0.022 (2) | 0.003 (2) |
C16 | 0.075 (3) | 0.070 (3) | 0.041 (2) | 0.006 (3) | 0.015 (2) | −0.014 (2) |
C17 | 0.066 (3) | 0.049 (3) | 0.050 (2) | −0.005 (2) | 0.004 (2) | −0.014 (2) |
C18 | 0.044 (2) | 0.042 (2) | 0.048 (2) | −0.0116 (18) | 0.0107 (18) | −0.0058 (18) |
C19 | 0.0349 (18) | 0.0292 (17) | 0.0373 (18) | −0.0015 (14) | 0.0132 (15) | −0.0014 (14) |
C20 | 0.0358 (19) | 0.042 (2) | 0.055 (2) | −0.0024 (17) | 0.0080 (18) | 0.0047 (18) |
C21 | 0.046 (2) | 0.048 (2) | 0.070 (3) | −0.013 (2) | 0.013 (2) | −0.006 (2) |
C22 | 0.066 (3) | 0.033 (2) | 0.075 (3) | −0.010 (2) | 0.032 (2) | −0.007 (2) |
C23 | 0.063 (3) | 0.035 (2) | 0.065 (3) | 0.005 (2) | 0.020 (2) | 0.009 (2) |
C24 | 0.040 (2) | 0.0366 (19) | 0.046 (2) | 0.0006 (16) | 0.0078 (17) | 0.0019 (16) |
O1 | 0.0316 (12) | 0.0250 (11) | 0.0429 (14) | 0.0018 (10) | −0.0011 (10) | 0.0036 (10) |
O2 | 0.0590 (17) | 0.0334 (13) | 0.0316 (13) | −0.0089 (12) | 0.0073 (12) | −0.0019 (10) |
O3 | 0.0348 (13) | 0.0334 (13) | 0.0583 (16) | −0.0052 (11) | 0.0110 (12) | 0.0014 (12) |
OW1 | 0.069 (2) | 0.083 (2) | 0.077 (2) | −0.0036 (19) | 0.0252 (19) | −0.0138 (19) |
Geometric parameters (Å, º) top
Ag1—O1 | 2.346 (2) | C10—C11 | 1.371 (6) |
Ag1—P1 | 2.3783 (10) | C10—H10A | 0.9300 |
Ag1—N1i | 2.410 (3) | C11—C12 | 1.389 (5) |
Ag1—O1ii | 2.506 (2) | C11—H11A | 0.9300 |
As1—O2 | 1.653 (2) | C12—H12A | 0.9300 |
As1—O1 | 1.679 (2) | C13—C14 | 1.387 (5) |
As1—O3 | 1.725 (2) | C13—C18 | 1.396 (5) |
As1—C1 | 1.919 (3) | C14—C15 | 1.382 (5) |
P1—C7 | 1.822 (3) | C14—H14A | 0.9300 |
P1—C13 | 1.823 (3) | C15—C16 | 1.382 (6) |
P1—C19 | 1.826 (3) | C15—H15A | 0.9300 |
N1—C4 | 1.416 (4) | C16—C17 | 1.374 (6) |
N1—Ag1iii | 2.410 (3) | C16—H16A | 0.9300 |
N1—H1A | 0.8600 | C17—C18 | 1.380 (5) |
N1—H1B | 0.8600 | C17—H17A | 0.9300 |
C1—C6 | 1.374 (5) | C18—H18A | 0.9300 |
C1—C2 | 1.391 (5) | C19—C24 | 1.389 (5) |
C2—C3 | 1.377 (5) | C19—C20 | 1.392 (5) |
C2—H2A | 0.9300 | C20—C21 | 1.383 (5) |
C3—C4 | 1.392 (5) | C20—H20A | 0.9300 |
C3—H3A | 0.9300 | C21—C22 | 1.376 (6) |
C4—C5 | 1.380 (5) | C21—H21A | 0.9300 |
C5—C6 | 1.383 (4) | C22—C23 | 1.365 (6) |
C5—H5A | 0.9300 | C22—H22A | 0.9300 |
C6—H6A | 0.9300 | C23—C24 | 1.378 (5) |
C7—C12 | 1.383 (5) | C23—H23A | 0.9300 |
C7—C8 | 1.389 (5) | C24—H24A | 0.9300 |
C8—C9 | 1.380 (5) | O1—Ag1ii | 2.506 (2) |
C8—H8A | 0.9300 | O3—H3 | 0.8200 |
C9—C10 | 1.370 (6) | OW1—H1W | 0.8199 |
C9—H9A | 0.9300 | OW1—H2W | 0.8199 |
| | | |
O1—Ag1—P1 | 140.70 (6) | C9—C10—C11 | 120.2 (4) |
O1—Ag1—N1i | 92.11 (10) | C9—C10—H10A | 119.9 |
P1—Ag1—N1i | 119.75 (8) | C11—C10—H10A | 119.9 |
O1—Ag1—O1ii | 84.30 (8) | C10—C11—C12 | 120.1 (4) |
P1—Ag1—O1ii | 117.87 (6) | C10—C11—H11A | 120.0 |
N1i—Ag1—O1ii | 85.95 (9) | C12—C11—H11A | 120.0 |
O2—As1—O1 | 114.75 (12) | C7—C12—C11 | 119.9 (4) |
O2—As1—O3 | 109.65 (13) | C7—C12—H12A | 120.0 |
O1—As1—O3 | 105.09 (12) | C11—C12—H12A | 120.0 |
O2—As1—C1 | 112.09 (14) | C14—C13—C18 | 119.2 (3) |
O1—As1—C1 | 106.98 (12) | C14—C13—P1 | 122.9 (3) |
O3—As1—C1 | 107.85 (13) | C18—C13—P1 | 117.6 (3) |
C7—P1—C13 | 102.59 (16) | C15—C14—C13 | 120.3 (4) |
C7—P1—C19 | 103.74 (16) | C15—C14—H14A | 119.8 |
C13—P1—C19 | 105.71 (16) | C13—C14—H14A | 119.8 |
C7—P1—Ag1 | 115.96 (12) | C16—C15—C14 | 120.2 (4) |
C13—P1—Ag1 | 118.42 (11) | C16—C15—H15A | 119.9 |
C19—P1—Ag1 | 109.02 (11) | C14—C15—H15A | 119.9 |
C4—N1—Ag1iii | 116.0 (2) | C17—C16—C15 | 119.6 (4) |
C4—N1—H1A | 110.7 | C17—C16—H16A | 120.2 |
Ag1iii—N1—H1A | 109.5 | C15—C16—H16A | 120.2 |
C4—N1—H1B | 108.2 | C16—C17—C18 | 120.9 (4) |
Ag1iii—N1—H1B | 102.1 | C16—C17—H17A | 119.5 |
H1A—N1—H1B | 109.8 | C18—C17—H17A | 119.5 |
C6—C1—C2 | 119.2 (3) | C17—C18—C13 | 119.7 (4) |
C6—C1—As1 | 121.3 (2) | C17—C18—H18A | 120.2 |
C2—C1—As1 | 119.5 (2) | C13—C18—H18A | 120.2 |
C3—C2—C1 | 120.3 (3) | C24—C19—C20 | 118.6 (3) |
C3—C2—H2A | 119.9 | C24—C19—P1 | 117.9 (3) |
C1—C2—H2A | 119.9 | C20—C19—P1 | 123.4 (3) |
C2—C3—C4 | 120.2 (3) | C21—C20—C19 | 119.9 (4) |
C2—C3—H3A | 119.9 | C21—C20—H20A | 120.0 |
C4—C3—H3A | 119.9 | C19—C20—H20A | 120.0 |
C5—C4—C3 | 119.4 (3) | C22—C21—C20 | 120.5 (4) |
C5—C4—N1 | 120.5 (3) | C22—C21—H21A | 119.8 |
C3—C4—N1 | 120.1 (3) | C20—C21—H21A | 119.8 |
C4—C5—C6 | 120.1 (3) | C23—C22—C21 | 120.0 (4) |
C4—C5—H5A | 120.0 | C23—C22—H22A | 120.0 |
C6—C5—H5A | 120.0 | C21—C22—H22A | 120.0 |
C1—C6—C5 | 120.8 (3) | C22—C23—C24 | 120.2 (4) |
C1—C6—H6A | 119.6 | C22—C23—H23A | 119.9 |
C5—C6—H6A | 119.6 | C24—C23—H23A | 119.9 |
C12—C7—C8 | 119.4 (3) | C23—C24—C19 | 120.7 (4) |
C12—C7—P1 | 123.3 (3) | C23—C24—H24A | 119.6 |
C8—C7—P1 | 117.3 (3) | C19—C24—H24A | 119.6 |
C9—C8—C7 | 120.0 (4) | As1—O1—Ag1 | 108.72 (11) |
C9—C8—H8A | 120.0 | As1—O1—Ag1ii | 135.19 (12) |
C7—C8—H8A | 120.0 | Ag1—O1—Ag1ii | 95.70 (8) |
C10—C9—C8 | 120.3 (4) | As1—O3—H3 | 109.5 |
C10—C9—H9A | 119.8 | H1W—OW1—H2W | 122.0 |
C8—C9—H9A | 119.8 | | |
| | | |
O1—Ag1—P1—C7 | 71.03 (16) | C7—P1—C13—C14 | 93.5 (3) |
N1i—Ag1—P1—C7 | −68.89 (16) | C19—P1—C13—C14 | −14.9 (3) |
O1ii—Ag1—P1—C7 | −171.03 (14) | Ag1—P1—C13—C14 | −137.4 (3) |
O1—Ag1—P1—C13 | −51.59 (16) | C7—P1—C13—C18 | −81.0 (3) |
N1i—Ag1—P1—C13 | 168.49 (15) | C19—P1—C13—C18 | 170.6 (3) |
O1ii—Ag1—P1—C13 | 66.35 (14) | Ag1—P1—C13—C18 | 48.1 (3) |
O1—Ag1—P1—C19 | −172.41 (14) | C18—C13—C14—C15 | 0.7 (6) |
N1i—Ag1—P1—C19 | 47.67 (15) | P1—C13—C14—C15 | −173.7 (3) |
O1ii—Ag1—P1—C19 | −54.46 (13) | C13—C14—C15—C16 | 1.0 (6) |
O2—As1—C1—C6 | 17.7 (3) | C14—C15—C16—C17 | −1.6 (7) |
O1—As1—C1—C6 | 144.3 (3) | C15—C16—C17—C18 | 0.6 (7) |
O3—As1—C1—C6 | −103.1 (3) | C16—C17—C18—C13 | 1.1 (6) |
O2—As1—C1—C2 | −162.8 (3) | C14—C13—C18—C17 | −1.8 (6) |
O1—As1—C1—C2 | −36.2 (3) | P1—C13—C18—C17 | 173.0 (3) |
O3—As1—C1—C2 | 76.4 (3) | C7—P1—C19—C24 | 170.0 (3) |
C6—C1—C2—C3 | 0.6 (5) | C13—P1—C19—C24 | −82.5 (3) |
As1—C1—C2—C3 | −178.9 (3) | Ag1—P1—C19—C24 | 45.8 (3) |
C1—C2—C3—C4 | 0.0 (5) | C7—P1—C19—C20 | −5.7 (3) |
C2—C3—C4—C5 | −0.7 (5) | C13—P1—C19—C20 | 101.8 (3) |
C2—C3—C4—N1 | 176.1 (3) | Ag1—P1—C19—C20 | −129.9 (3) |
Ag1iii—N1—C4—C5 | 102.3 (3) | C24—C19—C20—C21 | −0.3 (6) |
Ag1iii—N1—C4—C3 | −74.5 (4) | P1—C19—C20—C21 | 175.4 (3) |
C3—C4—C5—C6 | 0.7 (5) | C19—C20—C21—C22 | 1.0 (7) |
N1—C4—C5—C6 | −176.1 (3) | C20—C21—C22—C23 | −0.2 (7) |
C2—C1—C6—C5 | −0.6 (5) | C21—C22—C23—C24 | −1.2 (7) |
As1—C1—C6—C5 | 178.9 (3) | C22—C23—C24—C19 | 1.9 (6) |
C4—C5—C6—C1 | −0.1 (5) | C20—C19—C24—C23 | −1.2 (6) |
C13—P1—C7—C12 | −3.8 (3) | P1—C19—C24—C23 | −177.1 (3) |
C19—P1—C7—C12 | 106.1 (3) | O2—As1—O1—Ag1 | 72.59 (14) |
Ag1—P1—C7—C12 | −134.4 (3) | O3—As1—O1—Ag1 | −166.90 (11) |
C13—P1—C7—C8 | 177.9 (3) | C1—As1—O1—Ag1 | −52.42 (15) |
C19—P1—C7—C8 | −72.2 (3) | O2—As1—O1—Ag1ii | −46.7 (2) |
Ag1—P1—C7—C8 | 47.3 (3) | O3—As1—O1—Ag1ii | 73.77 (19) |
C12—C7—C8—C9 | −2.0 (6) | C1—As1—O1—Ag1ii | −171.75 (17) |
P1—C7—C8—C9 | 176.4 (3) | P1—Ag1—O1—As1 | −13.57 (17) |
C7—C8—C9—C10 | 3.2 (6) | N1i—Ag1—O1—As1 | 132.41 (12) |
C8—C9—C10—C11 | −2.1 (6) | O1ii—Ag1—O1—As1 | −141.87 (16) |
C9—C10—C11—C12 | −0.1 (6) | P1—Ag1—O1—Ag1ii | 128.29 (7) |
C8—C7—C12—C11 | −0.2 (6) | N1i—Ag1—O1—Ag1ii | −85.72 (10) |
P1—C7—C12—C11 | −178.5 (3) | O1ii—Ag1—O1—Ag1ii | 0.0 |
C10—C11—C12—C7 | 1.3 (6) | | |
Symmetry codes: (i) −x+1/2, y−1/2, −z+1/2; (ii) −x+1, −y, −z+1; (iii) −x+1/2, y+1/2, −z+1/2. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
N1—H1A···OW1iii | 0.86 | 2.22 | 3.035 (5) | 157 |
N1—H1B···O2iv | 0.86 | 2.57 | 3.316 (4) | 145 |
O3—H3···O2v | 0.82 | 1.82 | 2.634 (4) | 176 |
OW1—H1W···O1 | 0.82 | 1.98 | 2.763 (4) | 161 |
Symmetry codes: (iii) −x+1/2, y+1/2, −z+1/2; (iv) x−1/2, −y+1/2, z−1/2; (v) −x+1, −y+1, −z+1. |
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