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Using the least-squares refinement procedure, high-performance Brown-Wu bond-valence parameters, r0 and n, reported for the Sn2+/O2-, Sb3+/O2-, Te4+/O2- and I5+/O2- ion pairs have been converted into the commonly used bond-valence parameters, r0 and b. The r0 and b values obtained can be recommended as a replacement for the conventional bond-valence parameters based on the `universal constant' b = 0.37 Å.

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