Bis(triethylsulfonium) Tetraiodocadmate(II)

Bengtsson-Kloo, L.; Berglund, J.; Stegemann, H.; Svensson, C.; Svensson, P.H.

doi:10.1107/S0108270196006956

Bis(triethylsulfonium) Tetraiodocadmate(II)

L. Bengtsson-Kloo, J. Berglund, H. Stegemann, C. Svensson and P. H. Svensson

The reaction of CdI₂ with an acetone solution of (Et₃S)I (molar ratio 1:2) gives the title compound. The structure of [(C₂H₅)₃S]₂CdI₄ contains discrete pyramidal Et₃S⁺ and tetrahedral CdI₄^2- ions. The bond distances of the two independent anions (Cd1-I1 and Cd2-I2) are 2.772 (1) and 2.784 (1) Å, respectively. The cation with approximate threefold symmetry is disordered such that each of the middle methylene groups takes two positions with a ratio of ca 2:1.

Read article Similar articles

Subscribe to Acta Crystallographica Section C: Structural Chemistry

The full text of this article is available to subscribers to the journal.

Information on subscribing
Sample issue
Purchase subscription
Reduced-price subscriptions
If you have already subscribed, you may need to register

If you have already registered and are using a computer listed in your registration details, please email support@iucr.org for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.

E-mail address*
Repeat e-mail address* (for error checking)

Format*	PDF (US $40)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number (non-UK EC countries only)
Country*

Terms and conditions of use
Contact us

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page

Bis(triethylsulfonium) Tetraiodocadmate(II)

Supporting information

Subscribe to Acta Crystallographica Section C: Structural Chemistry

Buy online

	Crystallographic Information File (CIF) Contains datablock CdI4
	Structure factor file (SHELXL table format) Supplementary material