Tetracarbonyl(tetraphosphorus hexaoxide)iron

Jansen, M.; Clade, J.

doi:10.1107/S0108270196004398

Tetracarbonyl(tetraphosphorus hexaoxide)iron

The title [Fe(CO)₄(P₄O₆) molecule consists of a trigonal-bipyramidally coordinated Fe atom, with the adamantane-like P₄O₆ cage in an axial position. As a consequence of the electronic effects of the iron–carbonyl group on the P₄O₆ cage, the P—O bond lengths show distortions similar to those observed within the series P₄O₇→P₄O₆S→P₄O₆Se, but the effects are slightly less pronounced.

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Tetracarbonyl(tetraphosphorus hexaoxide)iron

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