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The solid-state structure of star-shaped 2,4,6-tris{(E)-2-[4-(dimethylamino)-phenyl]ethenyl}-1,3,5-triazine is determined from a powder sample by exploiting the respective strengths of single-crystal three-dimensional electron diffraction and powder X-ray diffraction data. The unit-cell parameters were determined from single crystal electron diffraction data. Using this information, the powder X-ray diffraction data were indexed, and the crystal structure was determined from the powder diffraction profile. The compound crystallizes in a noncentrosymmetric space group, P212121. The molecular conformation in the crystal structure was used to calculate the molecular dipole moment of 3.22 Debye, which enables the material to show nonlinear optical effects.
Supporting information
CCDC reference: 1492552
Data collection: WINXPOW (Stoe & Cie, 2004); cell refinement: TOPAS-Academic (Coelho, 2012); data reduction: DASH 3.3 (David et al., 2006); program(s) used to solve structure: DASH 3.3 (David et al., 2006); program(s) used to refine structure: TOPAS-Academic (Coelho, 2012); molecular graphics: Mercury (Macrae et al., 2008).
2,4,6-tris((E)-2-(4-(dimethylamino)phenyl)ethenyl)-1,3,5-triazine
top
Crystal data top
C33H36N6 | Z = 4 |
Mr = 516.69 | F(000) = 1104 |
Orthorhombic, P212121 | Dx = 1.194 Mg m−3 |
a = 54.631 (3) Å | Cu Kα1 radiation, λ = 1.54056 Å |
b = 8.0040 (2) Å | T = 298 K |
c = 6.5754 (3) Å | Particle morphology: powder |
V = 2875.2 (2) Å3 | dark violet |
Data collection top
STOE-Stadi-P diffractometer | Scan method: continuous |
Ge(111) monochromator | 2θmin = 4.000°, 2θmax = 39.980°, 2θstep = 0.02° |
Refinement top
Least-squares matrix: full with fixed elements per cycle | 258 parameters |
Rp = 6.269 | 213 restraints |
Rwp = 6.168 | 0 constraints |
Rexp = 5.101 | H-atom parameters not refined |
RBragg = 0.966 | Weighting scheme based on measured s.u.'s w = 1/σ[Yobs]2 |
1800 data points | (Δ/σ)max = 0.001 |
Excluded region(s): none | Background function: Chebyshev function with 15 terms |
Profile function: fundamental parameters | Preferred orientation correction: none |
Special details top
Geometry. H atoms added with Mercury. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
C1 | 0.13318 (13) | 0.0101 (10) | 0.4203 (11) | 0.050 (2) | |
C2 | 0.15500 (12) | −0.0564 (13) | 0.5044 (11) | 0.050 (2) | |
N1 | 0.13479 (15) | 0.1003 (10) | 0.2479 (12) | 0.050 (2) | |
N3 | 0.11336 (14) | −0.0291 (11) | 0.5273 (13) | 0.050 (2) | |
C3 | 0.17680 (11) | −0.0298 (13) | 0.4164 (12) | 0.050 (2) | |
C12 | 0.11340 (12) | 0.1530 (10) | 0.1844 (11) | 0.050 (2) | |
C23 | 0.09301 (12) | 0.0303 (10) | 0.4475 (11) | 0.050 (2) | |
C4 | 0.20034 (12) | −0.0877 (12) | 0.4886 (11) | 0.050 (2) | |
N2 | 0.09232 (14) | 0.1218 (11) | 0.2758 (13) | 0.050 (2) | |
C13 | 0.11146 (13) | 0.2286 (13) | −0.0021 (10) | 0.050 (2) | |
C24 | 0.06929 (12) | 0.0017 (17) | 0.5374 (10) | 0.050 (2) | |
C5 | 0.20402 (12) | −0.1650 (11) | 0.6795 (11) | 0.050 (2) | |
C9 | 0.22047 (12) | −0.0864 (12) | 0.3512 (10) | 0.050 (2) | |
C14 | 0.13150 (12) | 0.2596 (13) | −0.1004 (11) | 0.050 (2) | |
C25 | 0.06509 (11) | −0.0616 (16) | 0.7230 (11) | 0.050 (2) | |
C6 | 0.22574 (12) | −0.2412 (10) | 0.7286 (10) | 0.050 (2) | |
C8 | 0.24262 (12) | −0.1583 (11) | 0.3980 (11) | 0.050 (2) | |
C15 | 0.13279 (12) | 0.3738 (10) | −0.2655 (11) | 0.050 (2) | |
C26 | 0.04179 (12) | −0.0835 (12) | 0.8167 (11) | 0.050 (2) | |
C7 | 0.24565 (10) | −0.2330 (7) | 0.5893 (10) | 0.050 (2) | |
C16 | 0.15518 (12) | 0.4070 (11) | −0.3617 (11) | 0.050 (2) | |
C20 | 0.11183 (12) | 0.4399 (11) | −0.3622 (11) | 0.050 (2) | |
C27 | 0.01977 (11) | −0.0192 (12) | 0.7414 (11) | 0.050 (2) | |
C31 | 0.04096 (12) | −0.1664 (11) | 1.0020 (11) | 0.050 (2) | |
N4 | 0.26655 (10) | −0.2928 (8) | 0.6419 (10) | 0.050 (2) | |
C17 | 0.15662 (12) | 0.4950 (11) | −0.5371 (11) | 0.050 (2) | |
C19 | 0.11285 (11) | 0.5276 (11) | −0.5363 (11) | 0.050 (2) | |
C28 | −0.00159 (12) | −0.0366 (12) | 0.8441 (11) | 0.050 (2) | |
C30 | 0.01974 (12) | −0.1854 (12) | 1.1103 (11) | 0.050 (2) | |
C10 | 0.27305 (10) | −0.3594 (7) | 0.8412 (10) | 0.050 (2) | |
C11 | 0.28863 (9) | −0.3096 (7) | 0.5102 (9) | 0.050 (2) | |
C18 | 0.13524 (12) | 0.5555 (7) | −0.6284 (10) | 0.050 (2) | |
C29 | −0.00237 (12) | −0.1192 (12) | 1.0343 (11) | 0.050 (2) | |
N5 | 0.13561 (12) | 0.6352 (8) | −0.7985 (9) | 0.050 (2) | |
N6 | −0.02454 (12) | −0.1461 (12) | 1.1279 (10) | 0.050 (2) | |
C22 | 0.11470 (11) | 0.7117 (7) | −0.9035 (8) | 0.050 (2) | |
C21 | 0.15573 (11) | 0.6782 (7) | −0.9382 (8) | 0.050 (2) | |
C32 | −0.04517 (11) | −0.0555 (8) | 1.0442 (10) | 0.050 (2) | |
C33 | −0.02750 (13) | −0.2042 (8) | 1.3402 (9) | 0.050 (2) | |
H2 | 0.15404 | −0.130483 | 0.643084 | 0.060 (2) | |
H3 | 0.176785 | 0.042778 | 0.276314 | 0.060 (2) | |
H13 | 0.093678 | 0.261444 | −0.065379 | 0.060 (2) | |
H24 | 0.05335 | 0.034479 | 0.446307 | 0.060 (2) | |
H5 | 0.18923 | −0.164063 | 0.790536 | 0.060 (2) | |
H9 | 0.218248 | −0.026317 | 0.203757 | 0.060 (2) | |
H14 | 0.14815 | 0.195073 | −0.054317 | 0.060 (2) | |
H25 | 0.081041 | −0.100006 | 0.81064 | 0.060 (2) | |
H6 | 0.227718 | −0.307184 | 0.872502 | 0.060 (2) | |
H8 | 0.257561 | −0.157268 | 0.288377 | 0.060 (2) | |
H16 | 0.17198 | 0.360395 | −0.292947 | 0.060 (2) | |
H20 | 0.094017 | 0.418818 | −0.292439 | 0.060 (2) | |
H27 | 0.019792 | 0.046578 | 0.596424 | 0.060 (2) | |
H31 | 0.057831 | −0.218298 | 1.06356 | 0.060 (2) | |
H17 | 0.174358 | 0.518651 | −0.606957 | 0.060 (2) | |
H19 | 0.096147 | 0.576398 | −0.604438 | 0.060 (2) | |
H28 | −0.018392 | 0.013696 | 0.779338 | 0.060 (2) | |
H30 | 0.019930 | −0.251569 | 1.255 | 0.060 (2) | |
H10a | 0.288443 | −0.285724 | 0.89624 | 0.060 (2) | |
H10b | 0.278885 | −0.488042 | 0.817581 | 0.060 (2) | |
H10c | 0.257626 | −0.352906 | 0.94582 | 0.060 (2) | |
H11a | 0.303201 | −0.238653 | 0.583104 | 0.060 (2) | |
H11b | 0.285065 | −0.263714 | 0.357125 | 0.060 (2) | |
H11c | 0.293451 | −0.441612 | 0.50863 | 0.060 (2) | |
H22a | 0.118912 | 0.843968 | −0.920295 | 0.060 (2) | |
H22b | 0.097807 | 0.693423 | −0.818436 | 0.060 (2) | |
H22c | 0.113639 | 0.653801 | −1.05311 | 0.060 (2) | |
H21a | 0.173197 | 0.631831 | −0.881778 | 0.060 (2) | |
H21b | 0.155861 | 0.813799 | −0.951729 | 0.060 (2) | |
H21c | 0.151221 | 0.623021 | −1.08488 | 0.060 (2) | |
H32a | −0.052662 | 0.020080 | 1.16704 | 0.060 (2) | |
H32b | −0.058614 | −0.148489 | 0.997942 | 0.060 (2) | |
H32c | −0.039607 | 0.022019 | 0.916181 | 0.060 (2) | |
H33a | −0.038175 | −0.109321 | 1.4191 | 0.060 (2) | |
H33b | −0.009816 | −0.223004 | 1.41312 | 0.060 (2) | |
H33c | −0.037896 | −0.320171 | 1.33386 | 0.060 (2) | |
Geometric parameters (Å, º) top
C1—C2 | 1.42 (1) | C20—H20 | 1.0890 |
C1—N1 | 1.35 (1) | C27—C28 | 1.355 (9) |
C1—N3 | 1.33 (1) | C27—H27 | 1.0890 |
C2—C3 | 1.341 (9) | C31—C30 | 1.37 (1) |
C2—H2 | 1.0890 | C31—H31 | 1.0890 |
N1—C12 | 1.31 (1) | N4—C10 | 1.459 (9) |
N3—C23 | 1.32 (1) | N4—C11 | 1.491 (8) |
C3—C4 | 1.45 (1) | C17—C18 | 1.40 (1) |
C3—H3 | 1.0890 | C17—H17 | 1.0890 |
C12—N2 | 1.32 (1) | C19—C18 | 1.383 (9) |
C12—C13 | 1.37 (1) | C19—H19 | 1.0890 |
C23—N2 | 1.35 (1) | C28—C29 | 1.42 (1) |
C23—C24 | 1.44 (1) | C28—H28 | 1.0890 |
C4—C5 | 1.41 (1) | C30—C29 | 1.41 (1) |
C4—C9 | 1.423 (9) | C30—H30 | 1.0890 |
C13—C14 | 1.30 (1) | C10—H10a | 1.0890 |
C13—H13 | 1.0890 | C10—H10b | 1.0890 |
C24—C25 | 1.34 (1) | C10—H10c | 1.0890 |
C24—H24 | 1.0890 | C11—H11a | 1.0890 |
C5—C6 | 1.37 (1) | C11—H11b | 1.0890 |
C5—H5 | 1.0890 | C11—H11c | 1.0890 |
C9—C8 | 1.37 (1) | C18—N5 | 1.288 (9) |
C9—H9 | 1.0890 | C29—N6 | 1.38 (1) |
C14—C15 | 1.42 (1) | N5—C22 | 1.469 (9) |
C14—H14 | 1.0890 | N5—C21 | 1.473 (9) |
C25—C26 | 1.425 (9) | N6—C32 | 1.45 (1) |
C25—H25 | 1.0890 | N6—C33 | 1.480 (9) |
C6—C7 | 1.424 (9) | C22—H22a | 1.0890 |
C6—H6 | 1.0890 | C22—H22b | 1.0890 |
C8—C7 | 1.40 (1) | C22—H22c | 1.0890 |
C8—H8 | 1.0890 | C21—H21a | 1.0890 |
C15—C16 | 1.40 (1) | C21—H21b | 1.0890 |
C15—C20 | 1.41 (1) | C21—H21c | 1.0890 |
C26—C27 | 1.40 (1) | C32—H32a | 1.0890 |
C26—C31 | 1.39 (1) | C32—H32b | 1.0890 |
C7—N4 | 1.285 (8) | C32—H32c | 1.0890 |
C16—C17 | 1.35 (1) | C33—H33a | 1.0890 |
C16—H16 | 1.0890 | C33—H33b | 1.0890 |
C20—C19 | 1.34 (1) | C33—H33c | 1.0890 |
| | | |
C2—C1—N1 | 118.3 (7) | C30—C31—H31 | 118.75 |
C2—C1—N3 | 113.0 (7) | C7—N4—C10 | 126.4 (6) |
N1—C1—N3 | 128.7 (8) | C7—N4—C11 | 126.6 (6) |
C1—C2—C3 | 121.2 (7) | C10—N4—C11 | 107.0 (5) |
C1—C2—H2 | 119.376 | C16—C17—C18 | 119.8 (7) |
C3—C2—H2 | 119.374 | C16—C17—H17 | 120.102 |
C1—N1—C12 | 112.5 (7) | C18—C17—H17 | 120.1 |
C1—N3—C23 | 113.0 (8) | C20—C19—C18 | 119.6 (7) |
C2—C3—C4 | 126.6 (8) | C20—C19—H19 | 120.199 |
C2—C3—H3 | 116.678 | C18—C19—H19 | 120.199 |
C4—C3—H3 | 116.68 | C27—C28—C29 | 120.9 (7) |
N1—C12—N2 | 124.8 (8) | C27—C28—H28 | 119.528 |
N1—C12—C13 | 119.7 (7) | C29—C28—H28 | 119.528 |
N2—C12—C13 | 115.0 (7) | C31—C30—C29 | 119.9 (7) |
N3—C23—N2 | 123.6 (7) | C31—C30—H30 | 120.028 |
N3—C23—C24 | 122.5 (7) | C29—C30—H30 | 120.028 |
N2—C23—C24 | 113.9 (7) | N4—C10—H10a | 106.779 |
C3—C4—C5 | 123.9 (7) | N4—C10—H10b | 106.779 |
C3—C4—C9 | 118.4 (7) | N4—C10—H10c | 111.206 |
C5—C4—C9 | 117.2 (7) | H10a—C10—H10b | 109.473 |
C12—N2—C23 | 117.3 (8) | H10a—C10—H10c | 111.206 |
C12—C13—C14 | 117.7 (8) | H10b—C10—H10c | 111.205 |
C12—C13—H13 | 121.134 | N4—C11—H11a | 106.779 |
C14—C13—H13 | 121.134 | N4—C11—H11b | 111.206 |
C23—C24—C25 | 125.9 (8) | N4—C11—H11c | 106.779 |
C23—C24—H24 | 117.045 | H11a—C11—H11b | 111.206 |
C25—C24—H24 | 117.046 | H11a—C11—H11c | 109.471 |
C4—C5—C6 | 121.7 (7) | H11b—C11—H11c | 111.206 |
C4—C5—H5 | 119.125 | C17—C18—C19 | 119.6 (6) |
C6—C5—H5 | 119.127 | C17—C18—N5 | 122.1 (6) |
C4—C9—C8 | 122.3 (7) | C19—C18—N5 | 118.3 (6) |
C4—C9—H9 | 118.83 | C28—C29—C30 | 117.6 (7) |
C8—C9—H9 | 118.831 | C28—C29—N6 | 119.7 (7) |
C13—C14—C15 | 123.1 (8) | C30—C29—N6 | 122.5 (7) |
C13—C14—H14 | 118.441 | C18—N5—C22 | 127.1 (6) |
C15—C14—H14 | 118.44 | C18—N5—C21 | 132.0 (6) |
C24—C25—C26 | 126.4 (8) | C22—N5—C21 | 100.9 (5) |
C24—C25—H25 | 116.825 | C29—N6—C32 | 115.9 (7) |
C26—C25—H25 | 116.825 | C29—N6—C33 | 124.6 (7) |
C5—C6—C7 | 119.3 (6) | C32—N6—C33 | 115.5 (6) |
C5—C6—H6 | 120.373 | N5—C22—H22a | 106.777 |
C7—C6—H6 | 120.372 | N5—C22—H22b | 111.206 |
C9—C8—C7 | 118.9 (7) | N5—C22—H22c | 106.779 |
C9—C8—H8 | 120.556 | H22a—C22—H22b | 111.207 |
C7—C8—H8 | 120.558 | H22a—C22—H22c | 109.472 |
C14—C15—C16 | 120.6 (7) | H22b—C22—H22c | 111.205 |
C14—C15—C20 | 123.0 (7) | N5—C21—H21a | 111.206 |
C16—C15—C20 | 115.7 (7) | N5—C21—H21b | 106.778 |
C25—C26—C27 | 124.7 (7) | N5—C21—H21c | 106.78 |
C25—C26—C31 | 117.9 (7) | H21a—C21—H21b | 111.206 |
C27—C26—C31 | 117.3 (7) | H21a—C21—H21c | 111.205 |
C6—C7—C8 | 120.4 (6) | H21b—C21—H21c | 109.471 |
C6—C7—N4 | 119.2 (6) | N6—C32—H32a | 106.779 |
C8—C7—N4 | 120.3 (6) | N6—C32—H32b | 106.779 |
C15—C16—C17 | 122.2 (7) | N6—C32—H32c | 111.206 |
C15—C16—H16 | 118.877 | H32a—C32—H32b | 109.471 |
C17—C16—H16 | 118.878 | H32a—C32—H32c | 111.206 |
C15—C20—C19 | 123.1 (7) | H32b—C32—H32c | 111.206 |
C15—C20—H20 | 118.474 | N6—C33—H33a | 106.78 |
C19—C20—H20 | 118.474 | N6—C33—H33b | 111.206 |
C26—C27—C28 | 121.7 (7) | N6—C33—H33c | 106.777 |
C26—C27—H27 | 119.126 | H33a—C33—H33b | 111.205 |
C28—C27—H27 | 119.126 | H33a—C33—H33c | 109.472 |
C26—C31—C30 | 122.5 (7) | H33b—C33—H33c | 111.207 |
C26—C31—H31 | 118.747 | | |
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