Buy article online - an online subscription or single-article purchase is required to access this article.
The title compound, [Ag(AsC
18H
15)
4]PF
6, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry
. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag—As distances are 2.6381 (6) and 2.6499 (9) Å, and the As—Ag—As angles are 108.91 (1) and 110.03 (1)°.
Supporting information
CCDC reference: 624722
Key indicators
- Single-crystal X-ray study
- T = 100 K
- Mean (C-C) = 0.004 Å
- R factor = 0.032
- wR factor = 0.072
- Data-to-parameter ratio = 20.2
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.56 Ratio
Alert level G
REFLT03_ALERT_1_G ALERT: Expected hkl max differ from CIF values
From the CIF: _diffrn_reflns_theta_max 28.25
From the CIF: _reflns_number_total 4969
From the CIF: _diffrn_reflns_limit_ max hkl 10. 17. 67.
From the CIF: _diffrn_reflns_limit_ min hkl -17. -8. -67.
TEST1: Expected hkl limits for theta max
Calculated maximum hkl 19. 19. 68.
Calculated minimum hkl -19. -19. -68.
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
1 ALERT level C = Check and explain
1 ALERT level G = General alerts; check
1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
1 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
0 ALERT type 5 Informative message, check
Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT-Plus (Bruker, 2004); data reduction: SAINT-Plus and XPREP (Bruker 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: SHELXL97.
Tetrakis(triphenylarsine)silver(I) hexafluorophosphate
top
Crystal data top
[Ag(C18H15As)4]PF6 | Dx = 1.622 Mg m−3 |
Mr = 1477.72 | Mo Kα radiation, λ = 0.71073 Å |
Trigonal, R3 | Cell parameters from 6298 reflections |
Hall symbol: -R 3 | θ = 2.6–28.3° |
a = 14.276 (5) Å | µ = 2.59 mm−1 |
c = 51.421 (5) Å | T = 100 K |
V = 9076 (5) Å3 | Cuboid, colourless |
Z = 6 | 0.43 × 0.32 × 0.22 mm |
F(000) = 4440 | |
Data collection top
Bruker X8 APEX-II 4K KappaCCD diffractometer | 4969 independent reflections |
Graphite monochromator | 4358 reflections with I > 2σ(I) |
Detector resolution: 512 pixels mm-1 | Rint = 0.021 |
ω and φ scans | θmax = 28.3°, θmin = 1.2° |
Absorption correction: multi-scan (SADABS; Bruker, 2004) | h = −17→10 |
Tmin = 0.379, Tmax = 0.565 | k = −8→17 |
12694 measured reflections | l = −67→67 |
Refinement top
Refinement on F2 | 0 restraints |
Least-squares matrix: full | H-atom parameters constrained |
R[F2 > 2σ(F2)] = 0.032 | w = 1/[σ2(Fo2) + (0.0232P)2 + 59.264P] where P = (Fo2 + 2Fc2)/3 |
wR(F2) = 0.072 | (Δ/σ)max = 0.002 |
S = 1.05 | Δρmax = 2.53 e Å−3 |
4969 reflections | Δρmin = −1.9 e Å−3 |
246 parameters | |
Special details top
Experimental. The intensity data was collected on a Bruker X8 Apex II 4 K Kappa CCD
diffractometer using an exposure time of xx s/frame. A total of xxxx frames
were collected with a frame width of 0.5° covering up to θ = 28.25° with
99.5% completeness accomplished. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
P1 | 0 | 0 | 0 | 0.0155 (3) | |
F1 | 0.04155 (14) | 0.10501 (13) | 0.01799 (3) | 0.0279 (4) | |
P2 | 0.3333 | 0.6667 | 0.1667 | 0.0193 (3) | |
F2 | 0.32187 (16) | 0.56998 (15) | 0.14871 (3) | 0.0347 (4) | |
Ag | 0.6667 | 0.3333 | 0.086232 (6) | 0.01314 (6) | |
As1 | 0.52854 (2) | 0.39282 (2) | 0.102934 (4) | 0.01314 (6) | |
As2 | 0.6667 | 0.3333 | 0.034928 (8) | 0.01314 (6) | |
C11 | 0.5317 (2) | 0.5225 (2) | 0.08997 (5) | 0.0159 (5) | |
C12 | 0.4911 (2) | 0.5775 (2) | 0.10415 (5) | 0.0202 (5) | |
H12 | 0.4642 | 0.5544 | 0.1212 | 0.024* | |
C13 | 0.4899 (2) | 0.6660 (2) | 0.09339 (5) | 0.0236 (6) | |
H13 | 0.4623 | 0.7034 | 0.1032 | 0.028* | |
C14 | 0.5288 (2) | 0.6999 (2) | 0.06844 (5) | 0.0231 (6) | |
H14 | 0.5263 | 0.7594 | 0.061 | 0.028* | |
C15 | 0.5712 (2) | 0.6469 (2) | 0.05441 (5) | 0.0239 (6) | |
H15 | 0.5997 | 0.6712 | 0.0375 | 0.029* | |
C16 | 0.5722 (2) | 0.5584 (2) | 0.06511 (5) | 0.0204 (5) | |
H16 | 0.6008 | 0.5219 | 0.0554 | 0.024* | |
C21 | 0.5203 (2) | 0.4091 (2) | 0.14013 (5) | 0.0181 (5) | |
C22 | 0.4239 (2) | 0.3861 (2) | 0.15219 (5) | 0.0274 (6) | |
H22 | 0.3587 | 0.3565 | 0.1424 | 0.033* | |
C23 | 0.4236 (3) | 0.4068 (3) | 0.17855 (6) | 0.0402 (8) | |
H23 | 0.3582 | 0.3925 | 0.1868 | 0.048* | |
C24 | 0.5179 (3) | 0.4480 (3) | 0.19283 (6) | 0.0398 (9) | |
H24 | 0.5171 | 0.4625 | 0.2108 | 0.048* | |
C25 | 0.6132 (3) | 0.4683 (3) | 0.18118 (6) | 0.0331 (7) | |
H25 | 0.6775 | 0.495 | 0.1912 | 0.04* | |
C26 | 0.6147 (2) | 0.4495 (2) | 0.15466 (5) | 0.0243 (6) | |
H26 | 0.6804 | 0.4644 | 0.1465 | 0.029* | |
C31 | 0.3813 (2) | 0.2836 (2) | 0.09391 (5) | 0.0162 (5) | |
C32 | 0.3502 (2) | 0.1758 (2) | 0.09796 (5) | 0.0223 (5) | |
H32 | 0.3972 | 0.1578 | 0.1069 | 0.027* | |
C33 | 0.2510 (2) | 0.0941 (2) | 0.08906 (6) | 0.0268 (6) | |
H33 | 0.2305 | 0.0206 | 0.0919 | 0.032* | |
C34 | 0.1819 (2) | 0.1200 (2) | 0.07606 (6) | 0.0256 (6) | |
H34 | 0.1147 | 0.064 | 0.0696 | 0.031* | |
C35 | 0.2107 (2) | 0.2271 (2) | 0.07246 (5) | 0.0243 (6) | |
H35 | 0.1626 | 0.2447 | 0.0639 | 0.029* | |
C36 | 0.3104 (2) | 0.3091 (2) | 0.08140 (5) | 0.0204 (5) | |
H36 | 0.33 | 0.3827 | 0.079 | 0.025* | |
C41 | 0.5338 (2) | 0.2294 (2) | 0.01776 (5) | 0.0156 (5) | |
C42 | 0.4363 (2) | 0.2159 (2) | 0.02718 (5) | 0.0189 (5) | |
H42 | 0.4363 | 0.2578 | 0.0415 | 0.023* | |
C43 | 0.3394 (2) | 0.1415 (2) | 0.01568 (5) | 0.0229 (6) | |
H43 | 0.2729 | 0.1318 | 0.0223 | 0.027* | |
C44 | 0.3398 (2) | 0.0814 (2) | −0.00543 (6) | 0.0253 (6) | |
H44 | 0.2736 | 0.0315 | −0.0136 | 0.03* | |
C45 | 0.4361 (2) | 0.0937 (2) | −0.01469 (6) | 0.0269 (6) | |
H45 | 0.4358 | 0.0514 | −0.029 | 0.032* | |
C46 | 0.5335 (2) | 0.1676 (2) | −0.00318 (5) | 0.0215 (5) | |
H46 | 0.5997 | 0.176 | −0.0096 | 0.026* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
P1 | 0.0137 (5) | 0.0137 (5) | 0.0191 (7) | 0.0068 (2) | 0 | 0 |
F1 | 0.0300 (9) | 0.0197 (8) | 0.0320 (9) | 0.0108 (7) | −0.0035 (7) | −0.0084 (7) |
P2 | 0.0224 (5) | 0.0224 (5) | 0.0131 (7) | 0.0112 (3) | 0 | 0 |
F2 | 0.0430 (11) | 0.0333 (10) | 0.0293 (9) | 0.0202 (9) | −0.0011 (8) | −0.0105 (7) |
Ag | 0.01311 (7) | 0.01311 (7) | 0.01319 (9) | 0.00656 (3) | 0 | 0 |
As1 | 0.01311 (7) | 0.01311 (7) | 0.01319 (9) | 0.00656 (3) | 0 | 0 |
As2 | 0.01311 (7) | 0.01311 (7) | 0.01319 (9) | 0.00656 (3) | 0 | 0 |
C11 | 0.0129 (11) | 0.0169 (12) | 0.0178 (11) | 0.0074 (10) | −0.0014 (9) | −0.0025 (9) |
C12 | 0.0222 (13) | 0.0236 (14) | 0.0174 (11) | 0.0134 (12) | 0.0007 (10) | −0.0021 (10) |
C13 | 0.0285 (15) | 0.0215 (14) | 0.0263 (13) | 0.0165 (12) | −0.0021 (11) | −0.0046 (11) |
C14 | 0.0239 (14) | 0.0170 (13) | 0.0277 (13) | 0.0097 (11) | −0.0060 (11) | 0.0002 (10) |
C15 | 0.0224 (14) | 0.0246 (14) | 0.0215 (12) | 0.0093 (12) | 0.0023 (10) | 0.0030 (10) |
C16 | 0.0204 (13) | 0.0230 (14) | 0.0204 (12) | 0.0128 (11) | 0.0024 (10) | −0.0015 (10) |
C21 | 0.0232 (13) | 0.0150 (12) | 0.0170 (11) | 0.0102 (11) | −0.0013 (10) | −0.0001 (9) |
C22 | 0.0255 (15) | 0.0300 (16) | 0.0219 (13) | 0.0104 (13) | 0.0036 (11) | −0.0019 (11) |
C23 | 0.045 (2) | 0.042 (2) | 0.0239 (15) | 0.0150 (17) | 0.0137 (14) | −0.0015 (13) |
C24 | 0.061 (2) | 0.0285 (17) | 0.0162 (13) | 0.0117 (17) | 0.0014 (14) | −0.0016 (11) |
C25 | 0.0431 (19) | 0.0239 (15) | 0.0240 (14) | 0.0105 (14) | −0.0133 (13) | −0.0027 (11) |
C26 | 0.0271 (15) | 0.0216 (14) | 0.0244 (13) | 0.0123 (12) | −0.0060 (11) | −0.0013 (10) |
C31 | 0.0146 (12) | 0.0187 (12) | 0.0142 (10) | 0.0075 (10) | 0.0009 (9) | −0.0032 (9) |
C32 | 0.0191 (13) | 0.0208 (14) | 0.0277 (13) | 0.0105 (11) | −0.0003 (10) | 0.0017 (10) |
C33 | 0.0239 (15) | 0.0169 (13) | 0.0353 (15) | 0.0070 (12) | 0.0006 (12) | −0.0016 (11) |
C34 | 0.0150 (13) | 0.0238 (15) | 0.0291 (14) | 0.0031 (11) | −0.0017 (10) | −0.0054 (11) |
C35 | 0.0162 (13) | 0.0288 (15) | 0.0267 (13) | 0.0104 (12) | −0.0038 (10) | −0.0007 (11) |
C36 | 0.0175 (13) | 0.0182 (13) | 0.0249 (13) | 0.0084 (11) | −0.0015 (10) | −0.0010 (10) |
C41 | 0.0162 (12) | 0.0149 (12) | 0.0154 (11) | 0.0076 (10) | 0.0005 (9) | 0.0028 (9) |
C42 | 0.0201 (13) | 0.0200 (13) | 0.0186 (11) | 0.0116 (11) | 0.0012 (10) | 0.0016 (9) |
C43 | 0.0178 (13) | 0.0232 (14) | 0.0294 (14) | 0.0116 (12) | 0.0019 (10) | 0.0045 (11) |
C44 | 0.0191 (14) | 0.0191 (14) | 0.0328 (15) | 0.0058 (11) | −0.0076 (11) | −0.0024 (11) |
C45 | 0.0265 (15) | 0.0262 (15) | 0.0275 (14) | 0.0127 (13) | −0.0059 (11) | −0.0103 (11) |
C46 | 0.0185 (13) | 0.0236 (14) | 0.0210 (12) | 0.0095 (11) | 0.0005 (10) | −0.0045 (10) |
Geometric parameters (Å, º) top
P1—F1i | 1.6018 (16) | C21—C26 | 1.389 (4) |
P1—F1ii | 1.6018 (16) | C21—C22 | 1.391 (4) |
P1—F1 | 1.6018 (16) | C22—C23 | 1.388 (4) |
P1—F1iii | 1.6018 (16) | C22—H22 | 0.95 |
P1—F1iv | 1.6018 (16) | C23—C24 | 1.381 (5) |
P1—F1v | 1.6018 (16) | C23—H23 | 0.95 |
P2—F2vi | 1.5995 (17) | C24—C25 | 1.379 (5) |
P2—F2vii | 1.5995 (18) | C24—H24 | 0.95 |
P2—F2 | 1.5995 (17) | C25—C26 | 1.392 (4) |
P2—F2viii | 1.5995 (17) | C25—H25 | 0.95 |
P2—F2ix | 1.5996 (18) | C26—H26 | 0.95 |
P2—F2x | 1.5996 (17) | C31—C32 | 1.387 (4) |
Ag—As2 | 2.6381 (6) | C31—C36 | 1.394 (4) |
Ag—As1xi | 2.6499 (9) | C32—C33 | 1.386 (4) |
Ag—As1xii | 2.6499 (9) | C32—H32 | 0.95 |
Ag—As1 | 2.6499 (9) | C33—C34 | 1.386 (4) |
As1—C21 | 1.937 (2) | C33—H33 | 0.95 |
As1—C31 | 1.946 (3) | C34—C35 | 1.383 (4) |
As1—C11 | 1.947 (3) | C34—H34 | 0.95 |
As2—C41xi | 1.941 (3) | C35—C36 | 1.393 (4) |
As2—C41 | 1.941 (3) | C35—H35 | 0.95 |
As2—C41xii | 1.941 (3) | C36—H36 | 0.95 |
C11—C16 | 1.391 (3) | C41—C46 | 1.390 (3) |
C11—C12 | 1.393 (4) | C41—C42 | 1.393 (4) |
C12—C13 | 1.387 (4) | C42—C43 | 1.387 (4) |
C12—H12 | 0.95 | C42—H42 | 0.95 |
C13—C14 | 1.386 (4) | C43—C44 | 1.386 (4) |
C13—H13 | 0.95 | C43—H43 | 0.95 |
C14—C15 | 1.385 (4) | C44—C45 | 1.381 (4) |
C14—H14 | 0.95 | C44—H44 | 0.95 |
C15—C16 | 1.384 (4) | C45—C46 | 1.389 (4) |
C15—H15 | 0.95 | C45—H45 | 0.95 |
C16—H16 | 0.95 | C46—H46 | 0.95 |
| | | |
F1i—P1—F1ii | 89.99 (9) | C16—C15—C14 | 119.9 (3) |
F1i—P1—F1 | 180.00 (16) | C16—C15—H15 | 120.1 |
F1ii—P1—F1 | 90.01 (9) | C14—C15—H15 | 120.1 |
F1i—P1—F1iii | 89.99 (9) | C15—C16—C11 | 120.7 (2) |
F1ii—P1—F1iii | 89.99 (9) | C15—C16—H16 | 119.7 |
F1—P1—F1iii | 90.01 (9) | C11—C16—H16 | 119.7 |
F1i—P1—F1iv | 90.01 (9) | C26—C21—C22 | 119.9 (2) |
F1ii—P1—F1iv | 180.00 (14) | C26—C21—As1 | 118.4 (2) |
F1—P1—F1iv | 89.99 (9) | C22—C21—As1 | 121.6 (2) |
F1iii—P1—F1iv | 90.01 (9) | C23—C22—C21 | 119.6 (3) |
F1i—P1—F1v | 90.01 (9) | C23—C22—H22 | 120.2 |
F1ii—P1—F1v | 90.01 (9) | C21—C22—H22 | 120.2 |
F1—P1—F1v | 89.99 (9) | C24—C23—C22 | 120.3 (3) |
F1iii—P1—F1v | 180.0 (2) | C24—C23—H23 | 119.9 |
F1iv—P1—F1v | 89.99 (9) | C22—C23—H23 | 119.9 |
F2vi—P2—F2vii | 90.02 (10) | C25—C24—C23 | 120.5 (3) |
F2vi—P2—F2 | 90.02 (10) | C25—C24—H24 | 119.7 |
F2vii—P2—F2 | 90.02 (10) | C23—C24—H24 | 119.7 |
F2vi—P2—F2viii | 179.9950 (10) | C24—C25—C26 | 119.6 (3) |
F2vii—P2—F2viii | 89.99 (10) | C24—C25—H25 | 120.2 |
F2—P2—F2viii | 89.99 (10) | C26—C25—H25 | 120.2 |
F2vi—P2—F2ix | 89.99 (10) | C21—C26—C25 | 120.1 (3) |
F2vii—P2—F2ix | 180.00 (13) | C21—C26—H26 | 119.9 |
F2—P2—F2ix | 89.99 (10) | C25—C26—H26 | 119.9 |
F2viii—P2—F2ix | 90.01 (10) | C32—C31—C36 | 119.2 (2) |
F2vi—P2—F2x | 89.99 (10) | C32—C31—As1 | 118.2 (2) |
F2vii—P2—F2x | 89.99 (10) | C36—C31—As1 | 122.4 (2) |
F2—P2—F2x | 180.00 (15) | C33—C32—C31 | 120.6 (3) |
F2viii—P2—F2x | 90.01 (10) | C33—C32—H32 | 119.7 |
F2ix—P2—F2x | 90.01 (10) | C31—C32—H32 | 119.7 |
As2—Ag—As1xi | 108.911 (10) | C34—C33—C32 | 119.9 (3) |
As2—Ag—As1xii | 108.911 (10) | C34—C33—H33 | 120 |
As1xi—Ag—As1xii | 110.026 (10) | C32—C33—H33 | 120 |
As2—Ag—As1 | 108.911 (10) | C35—C34—C33 | 120.1 (3) |
As1xi—Ag—As1 | 110.026 (10) | C35—C34—H34 | 120 |
As1xii—Ag—As1 | 110.026 (10) | C33—C34—H34 | 120 |
C21—As1—C31 | 103.03 (11) | C34—C35—C36 | 120.0 (3) |
C21—As1—C11 | 101.42 (10) | C34—C35—H35 | 120 |
C31—As1—C11 | 100.55 (11) | C36—C35—H35 | 120 |
C21—As1—Ag | 117.25 (8) | C35—C36—C31 | 120.2 (3) |
C31—As1—Ag | 110.14 (7) | C35—C36—H36 | 119.9 |
C11—As1—Ag | 121.77 (7) | C31—C36—H36 | 119.9 |
C41xi—As2—C41 | 100.93 (9) | C46—C41—C42 | 119.7 (2) |
C41xi—As2—C41xii | 100.93 (9) | C46—C41—As2 | 121.94 (19) |
C41—As2—C41xii | 100.93 (9) | C42—C41—As2 | 118.33 (19) |
C41xi—As2—Ag | 117.06 (7) | C43—C42—C41 | 120.2 (2) |
C41—As2—Ag | 117.06 (7) | C43—C42—H42 | 119.9 |
C41xii—As2—Ag | 117.06 (7) | C41—C42—H42 | 119.9 |
C16—C11—C12 | 119.1 (2) | C44—C43—C42 | 119.8 (3) |
C16—C11—As1 | 118.24 (19) | C44—C43—H43 | 120.1 |
C12—C11—As1 | 122.59 (19) | C42—C43—H43 | 120.1 |
C13—C12—C11 | 120.2 (2) | C45—C44—C43 | 120.3 (3) |
C13—C12—H12 | 119.9 | C45—C44—H44 | 119.9 |
C11—C12—H12 | 119.9 | C43—C44—H44 | 119.9 |
C14—C13—C12 | 120.1 (3) | C44—C45—C46 | 120.3 (3) |
C14—C13—H13 | 119.9 | C44—C45—H45 | 119.9 |
C12—C13—H13 | 119.9 | C46—C45—H45 | 119.9 |
C15—C14—C13 | 120.0 (3) | C45—C46—C41 | 119.8 (3) |
C15—C14—H14 | 120 | C45—C46—H46 | 120.1 |
C13—C14—H14 | 120 | C41—C46—H46 | 120.1 |
| | | |
As2—Ag—As1—C21 | −175.89 (9) | Ag—As1—C21—C22 | −147.1 (2) |
As1xi—Ag—As1—C21 | 64.80 (9) | C26—C21—C22—C23 | 1.8 (4) |
As1xii—Ag—As1—C21 | −56.58 (9) | As1—C21—C22—C23 | −175.1 (2) |
As2—Ag—As1—C31 | 66.79 (8) | C21—C22—C23—C24 | −1.2 (5) |
As1xi—Ag—As1—C31 | −52.52 (8) | C22—C23—C24—C25 | −0.5 (5) |
As1xii—Ag—As1—C31 | −173.90 (8) | C23—C24—C25—C26 | 1.5 (5) |
As2—Ag—As1—C11 | −50.37 (9) | C22—C21—C26—C25 | −0.8 (4) |
As1xi—Ag—As1—C11 | −169.68 (8) | As1—C21—C26—C25 | 176.2 (2) |
As1xii—Ag—As1—C11 | 68.94 (9) | C24—C25—C26—C21 | −0.9 (5) |
As1xi—Ag—As2—C41xi | −65.12 (8) | C21—As1—C31—C32 | −81.5 (2) |
As1xii—Ag—As2—C41xi | 54.88 (8) | C11—As1—C31—C32 | 174.0 (2) |
As1—Ag—As2—C41xi | 174.88 (8) | Ag—As1—C31—C32 | 44.3 (2) |
As1xi—Ag—As2—C41 | 54.88 (8) | C21—As1—C31—C36 | 104.6 (2) |
As1xii—Ag—As2—C41 | 174.88 (8) | C11—As1—C31—C36 | 0.2 (2) |
As1—Ag—As2—C41 | −65.12 (8) | Ag—As1—C31—C36 | −129.51 (19) |
As1xi—Ag—As2—C41xii | 174.88 (8) | C36—C31—C32—C33 | 1.8 (4) |
As1xii—Ag—As2—C41xii | −65.12 (8) | As1—C31—C32—C33 | −172.2 (2) |
As1—Ag—As2—C41xii | 54.88 (8) | C31—C32—C33—C34 | −0.2 (4) |
C21—As1—C11—C16 | 159.4 (2) | C32—C33—C34—C35 | −1.4 (4) |
C31—As1—C11—C16 | −94.8 (2) | C33—C34—C35—C36 | 1.5 (4) |
Ag—As1—C11—C16 | 27.0 (2) | C34—C35—C36—C31 | 0.2 (4) |
C21—As1—C11—C12 | −23.3 (2) | C32—C31—C36—C35 | −1.8 (4) |
C31—As1—C11—C12 | 82.4 (2) | As1—C31—C36—C35 | 172.0 (2) |
Ag—As1—C11—C12 | −155.75 (18) | C41xi—As2—C41—C46 | −6.7 (2) |
C16—C11—C12—C13 | 0.8 (4) | C41xii—As2—C41—C46 | 96.81 (17) |
As1—C11—C12—C13 | −176.4 (2) | Ag—As2—C41—C46 | −134.95 (19) |
C11—C12—C13—C14 | 0.2 (4) | C41xi—As2—C41—C42 | 172.3 (2) |
C12—C13—C14—C15 | −1.5 (4) | C41xii—As2—C41—C42 | −84.2 (3) |
C13—C14—C15—C16 | 1.7 (4) | Ag—As2—C41—C42 | 44.0 (2) |
C14—C15—C16—C11 | −0.6 (4) | C46—C41—C42—C43 | −0.2 (4) |
C12—C11—C16—C15 | −0.7 (4) | As2—C41—C42—C43 | −179.2 (2) |
As1—C11—C16—C15 | 176.7 (2) | C41—C42—C43—C44 | −0.7 (4) |
C31—As1—C21—C26 | 157.0 (2) | C42—C43—C44—C45 | 1.4 (4) |
C11—As1—C21—C26 | −99.2 (2) | C43—C44—C45—C46 | −1.0 (5) |
Ag—As1—C21—C26 | 35.9 (2) | C44—C45—C46—C41 | 0.1 (4) |
C31—As1—C21—C22 | −26.0 (3) | C42—C41—C46—C45 | 0.5 (4) |
C11—As1—C21—C22 | 77.8 (2) | As2—C41—C46—C45 | 179.5 (2) |
Symmetry codes: (i) −x, −y, −z; (ii) x−y, x, −z; (iii) y, −x+y, −z; (iv) −x+y, −x, z; (v) −y, x−y, z; (vi) −x+y, −x+1, z; (vii) −y+1, x−y+1, z; (viii) x−y+2/3, x+1/3, −z+1/3; (ix) y−1/3, −x+y+1/3, −z+1/3; (x) −x+2/3, −y+4/3, −z+1/3; (xi) −y+1, x−y, z; (xii) −x+y+1, −x+1, z. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
C13—H13···F2vii | 0.95 | 2.55 | 3.373 (3) | 145 |
Symmetry code: (vii) −y+1, x−y+1, z. |
Comparative geometrical parameters for selected [Ag(AsPh3)4]X
complexes. topX | Ag—As (Å) | Ag—As (Å) | Ag—As (Å) | Ag—As (Å) | Notes |
NO3 | 2.650 | 2.649 | - | - | (i) |
ClO4 | 2.680 | 2.652 | - | - | (i) |
PF6 | 2.6381 (6) | 2.6499 (9) | - | - | TW |
BF4 | 2.6451 (10) | 2.6578 (5) | - | - | (ii) |
BrO3 | 2.655 (1) | 2.637 (1) | 2.659 (1) | 2.644 (1) | (iii) |
Notes: TW is this work; (i) Bowmaker et al. (1997), extracted
from CSD; (ii)
Tripathi et al. (1997); (iii) Cingolani et al.
(2003). |
Subscribe to Acta Crystallographica Section E: Crystallographic Communications
The full text of this article is available to subscribers to the journal.
If you have already registered and are using a computer listed in your registration details, please email
support@iucr.org for assistance.