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The title compound, beryllium tetrahydrogenhexaoxoiodate(VII) tetrahydate, is built up from slightly deformed Be(OH2)4 tetrahedra (a,b) and IO2(OH)4 octahedra (A,B) with cis configuration of the oxo ligands. They are arranged along [001] forming layers with stacking aBAbABaBAbAB. The [H4IO6] and Be(OH2)42+ ions are held together by a network of eight independent hydrogen bonds of different strength. Two of the H atoms of [H4IO6] are disordered over O—H↔H—O split positions.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks BeH4IO6, default

fcf

Structure factor file (CIF format)
Contains datablock Be(H4IO6)2*4H2O

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