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The title compound, (C
16H
20N
4)
3[AgCl
4]
2, exists as discrete 3,3′-(1,4-phenyldimethylene)bis(1-methylimidazolium) cations and tetrachloroargentate(I) anions, which are linked by C—H
Cl hydrogen bonds [C
Cl = 3.453 (5)–3.711 (7) Å] and π–π interactions. The asymmetric unit contains one anion, one cation in a general position, and half of a cation which lies on an inversion centre.
Supporting information
CCDC reference: 263573
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.007 Å
- R factor = 0.051
- wR factor = 0.132
- Data-to-parameter ratio = 18.2
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
PLAT061_ALERT_3_C Tmax/Tmin Range Test RR' too Large ............. 0.90
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 2.42
PLAT199_ALERT_1_C Check the Reported cell_measurement_temperature 293
PLAT200_ALERT_1_C Check the Reported cell_ambient_temperature .... 293
PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C4
PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C12
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor .... 2.08
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
8 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
4 ALERT type 2 Indicator that the structure model may be wrong or deficient
1 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1999); software used to prepare material for publication: SHELXTL.
3,3'-(
p-phenylenedimethylene)bis(1-methylimiadzolium)–tetrachloroargentate(I) (3/2)
top
Crystal data top
(C16H20N4)3[AgCl4]2 | F(000) = 1324 |
Mr = 1304.42 | Dx = 1.521 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 962 reflections |
a = 9.111 (3) Å | θ = 3.3–24.0° |
b = 18.921 (7) Å | µ = 1.11 mm−1 |
c = 16.536 (5) Å | T = 293 K |
β = 92.368 (6)° | Block, colourless |
V = 2848.2 (17) Å3 | 0.24 × 0.20 × 0.16 mm |
Z = 2 | |
Data collection top
Bruker SMART 1000 CCD area-detector diffractometer | 5799 independent reflections |
Radiation source: fine-focus sealed tube | 3614 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.043 |
φ and ω scans | θmax = 26.4°, θmin = 1.6° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −11→10 |
Tmin = 0.689, Tmax = 0.838 | k = −22→23 |
13029 measured reflections | l = −20→11 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.051 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.132 | H-atom parameters constrained |
S = 1.07 | w = 1/[σ2(Fo2) + (0.048P)2 + 2.3376P] where P = (Fo2 + 2Fc2)/3 |
5799 reflections | (Δ/σ)max < 0.001 |
319 parameters | Δρmax = 0.97 e Å−3 |
0 restraints | Δρmin = −0.40 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Ag1 | 0.77042 (4) | 0.19654 (3) | 0.20540 (3) | 0.07001 (18) | |
Cl1 | 0.99882 (13) | 0.15684 (8) | 0.28615 (8) | 0.0618 (3) | |
Cl2 | 0.5975 (2) | 0.25556 (13) | 0.30595 (9) | 0.1188 (8) | |
Cl3 | 0.81265 (15) | 0.29222 (8) | 0.09801 (9) | 0.0735 (4) | |
Cl4 | 0.66917 (16) | 0.08514 (9) | 0.13128 (10) | 0.0830 (5) | |
N1 | 0.9620 (4) | −0.1050 (2) | 0.9995 (2) | 0.0519 (10) | |
N2 | 0.7947 (4) | −0.0797 (2) | 0.9076 (2) | 0.0517 (10) | |
N3 | 0.7871 (4) | 0.22876 (19) | 0.6280 (2) | 0.0452 (9) | |
N4 | 0.9034 (4) | 0.2563 (2) | 0.5216 (2) | 0.0507 (9) | |
N5 | 0.4477 (5) | 0.0685 (3) | 0.3880 (2) | 0.0670 (13) | |
N6 | 0.6511 (4) | 0.0124 (2) | 0.3714 (2) | 0.0472 (9) | |
C1 | 1.0988 (6) | −0.1325 (3) | 1.0392 (3) | 0.0741 (16) | |
H1A | 1.0813 | −0.1788 | 1.0603 | 0.111* | |
H1B | 1.1296 | −0.1015 | 1.0827 | 0.111* | |
H1C | 1.1742 | −0.1348 | 1.0004 | 0.111* | |
C2 | 0.9276 (5) | −0.1071 (2) | 0.9212 (3) | 0.0489 (11) | |
H2 | 0.9872 | −0.1249 | 0.8817 | 0.059* | |
C3 | 0.8478 (7) | −0.0740 (3) | 1.0372 (3) | 0.0768 (17) | |
H3 | 0.8432 | −0.0650 | 1.0923 | 0.092* | |
C4 | 0.7435 (7) | −0.0589 (3) | 0.9801 (4) | 0.0804 (19) | |
H4 | 0.6530 | −0.0380 | 0.9885 | 0.096* | |
C5 | 0.7167 (5) | −0.0716 (3) | 0.8278 (3) | 0.0572 (13) | |
H5A | 0.6148 | −0.0853 | 0.8324 | 0.069* | |
H5B | 0.7603 | −0.1030 | 0.7892 | 0.069* | |
C6 | 0.7232 (5) | 0.0035 (2) | 0.7966 (3) | 0.0476 (11) | |
C7 | 0.8502 (5) | 0.0279 (3) | 0.7609 (3) | 0.0518 (12) | |
H7 | 0.9296 | −0.0024 | 0.7554 | 0.062* | |
C8 | 0.8585 (5) | 0.0969 (3) | 0.7338 (3) | 0.0516 (12) | |
H8 | 0.9444 | 0.1130 | 0.7114 | 0.062* | |
C9 | 0.7399 (5) | 0.1424 (2) | 0.7396 (3) | 0.0457 (11) | |
C10 | 0.6135 (5) | 0.1183 (3) | 0.7740 (3) | 0.0513 (12) | |
H10 | 0.5333 | 0.1483 | 0.7777 | 0.062* | |
C11 | 0.6053 (5) | 0.0498 (3) | 0.8029 (3) | 0.0510 (12) | |
H11 | 0.5202 | 0.0346 | 0.8268 | 0.061* | |
C12 | 0.7508 (6) | 0.2186 (3) | 0.7134 (3) | 0.0634 (14) | |
H12A | 0.6579 | 0.2418 | 0.7223 | 0.076* | |
H12B | 0.8254 | 0.2419 | 0.7475 | 0.076* | |
C13 | 0.9154 (5) | 0.2500 (3) | 0.6009 (3) | 0.0493 (11) | |
H13 | 0.9998 | 0.2590 | 0.6329 | 0.059* | |
C14 | 0.6907 (5) | 0.2219 (3) | 0.5623 (4) | 0.0623 (14) | |
H14 | 0.5929 | 0.2080 | 0.5635 | 0.075* | |
C15 | 0.7626 (6) | 0.2386 (3) | 0.4967 (3) | 0.0638 (14) | |
H15 | 0.7245 | 0.2384 | 0.4436 | 0.077* | |
C16 | 1.0185 (7) | 0.2804 (4) | 0.4689 (3) | 0.0834 (18) | |
H16A | 1.0224 | 0.3311 | 0.4694 | 0.125* | |
H16B | 0.9971 | 0.2642 | 0.4147 | 0.125* | |
H16C | 1.1115 | 0.2617 | 0.4881 | 0.125* | |
C17 | 0.3399 (7) | 0.1272 (4) | 0.3932 (4) | 0.103 (3) | |
H17A | 0.3272 | 0.1388 | 0.4490 | 0.155* | |
H17B | 0.2474 | 0.1127 | 0.3686 | 0.155* | |
H17C | 0.3756 | 0.1678 | 0.3654 | 0.155* | |
C18 | 0.5868 (5) | 0.0760 (3) | 0.3673 (3) | 0.0562 (13) | |
H18 | 0.6313 | 0.1180 | 0.3526 | 0.067* | |
C19 | 0.4221 (6) | 0.0003 (4) | 0.4049 (3) | 0.0705 (17) | |
H19 | 0.3336 | −0.0187 | 0.4207 | 0.085* | |
C20 | 0.5487 (5) | −0.0360 (3) | 0.3946 (3) | 0.0595 (13) | |
H20 | 0.5632 | −0.0843 | 0.4019 | 0.071* | |
C21 | 0.8057 (5) | −0.0030 (3) | 0.3545 (3) | 0.0528 (12) | |
H21A | 0.8401 | 0.0315 | 0.3162 | 0.063* | |
H21B | 0.8114 | −0.0493 | 0.3297 | 0.063* | |
C22 | 0.9060 (4) | −0.0014 (2) | 0.4306 (3) | 0.0441 (11) | |
C23 | 0.9503 (5) | 0.0624 (3) | 0.4656 (3) | 0.0528 (12) | |
H23 | 0.9170 | 0.1046 | 0.4426 | 0.063* | |
C24 | 1.0430 (5) | 0.0641 (3) | 0.5338 (3) | 0.0534 (12) | |
H24 | 1.0715 | 0.1073 | 0.5562 | 0.064* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Ag1 | 0.0593 (2) | 0.0896 (4) | 0.0610 (3) | 0.0224 (2) | −0.00078 (18) | 0.0098 (2) |
Cl1 | 0.0484 (6) | 0.0734 (9) | 0.0630 (8) | 0.0091 (6) | −0.0074 (5) | 0.0159 (7) |
Cl2 | 0.1241 (15) | 0.182 (2) | 0.0500 (9) | 0.1001 (15) | 0.0013 (8) | −0.0013 (10) |
Cl3 | 0.0637 (8) | 0.0668 (9) | 0.0896 (10) | 0.0001 (7) | −0.0002 (7) | 0.0261 (7) |
Cl4 | 0.0732 (9) | 0.0768 (10) | 0.1007 (12) | −0.0214 (8) | 0.0226 (8) | −0.0090 (9) |
N1 | 0.065 (2) | 0.052 (3) | 0.039 (2) | −0.005 (2) | 0.0081 (19) | 0.0007 (18) |
N2 | 0.061 (2) | 0.047 (2) | 0.048 (2) | 0.0028 (19) | 0.0142 (19) | 0.0090 (18) |
N3 | 0.048 (2) | 0.040 (2) | 0.047 (2) | −0.0004 (17) | −0.0025 (17) | 0.0009 (17) |
N4 | 0.056 (2) | 0.049 (2) | 0.046 (2) | −0.0019 (19) | −0.0035 (18) | 0.0057 (18) |
N5 | 0.050 (2) | 0.105 (4) | 0.045 (2) | 0.029 (3) | −0.0119 (19) | −0.016 (2) |
N6 | 0.043 (2) | 0.056 (3) | 0.043 (2) | 0.0068 (19) | −0.0067 (16) | −0.0033 (18) |
C1 | 0.068 (3) | 0.094 (5) | 0.059 (3) | −0.003 (3) | −0.004 (3) | 0.005 (3) |
C2 | 0.060 (3) | 0.045 (3) | 0.043 (3) | 0.001 (2) | 0.013 (2) | 0.002 (2) |
C3 | 0.109 (5) | 0.077 (4) | 0.045 (3) | 0.016 (4) | 0.022 (3) | 0.002 (3) |
C4 | 0.094 (4) | 0.087 (5) | 0.063 (4) | 0.035 (4) | 0.036 (3) | 0.015 (3) |
C5 | 0.060 (3) | 0.056 (3) | 0.056 (3) | −0.003 (2) | −0.001 (2) | 0.006 (2) |
C6 | 0.049 (2) | 0.051 (3) | 0.043 (3) | −0.002 (2) | 0.003 (2) | 0.000 (2) |
C7 | 0.044 (2) | 0.054 (3) | 0.058 (3) | 0.009 (2) | 0.010 (2) | 0.004 (2) |
C8 | 0.047 (3) | 0.052 (3) | 0.057 (3) | −0.002 (2) | 0.014 (2) | 0.001 (2) |
C9 | 0.056 (3) | 0.043 (3) | 0.039 (2) | 0.000 (2) | 0.004 (2) | −0.003 (2) |
C10 | 0.048 (3) | 0.058 (3) | 0.048 (3) | 0.012 (2) | 0.005 (2) | 0.001 (2) |
C11 | 0.040 (2) | 0.066 (3) | 0.047 (3) | 0.000 (2) | 0.006 (2) | 0.004 (2) |
C12 | 0.082 (4) | 0.047 (3) | 0.062 (3) | 0.005 (3) | 0.016 (3) | −0.008 (2) |
C13 | 0.046 (3) | 0.051 (3) | 0.049 (3) | −0.005 (2) | −0.010 (2) | −0.003 (2) |
C14 | 0.046 (3) | 0.054 (3) | 0.084 (4) | −0.003 (2) | −0.024 (3) | 0.006 (3) |
C15 | 0.072 (3) | 0.059 (3) | 0.057 (3) | −0.006 (3) | −0.029 (3) | 0.008 (3) |
C16 | 0.089 (4) | 0.098 (5) | 0.064 (4) | −0.010 (4) | 0.020 (3) | 0.011 (3) |
C17 | 0.076 (4) | 0.158 (7) | 0.074 (4) | 0.073 (4) | −0.010 (3) | −0.017 (4) |
C18 | 0.051 (3) | 0.066 (4) | 0.050 (3) | 0.012 (2) | −0.011 (2) | −0.004 (2) |
C19 | 0.042 (3) | 0.118 (6) | 0.051 (3) | −0.001 (3) | −0.003 (2) | −0.013 (3) |
C20 | 0.055 (3) | 0.074 (4) | 0.048 (3) | −0.002 (3) | −0.009 (2) | −0.009 (3) |
C21 | 0.042 (2) | 0.070 (3) | 0.046 (3) | 0.013 (2) | 0.000 (2) | −0.004 (2) |
C22 | 0.032 (2) | 0.053 (3) | 0.048 (3) | 0.004 (2) | 0.0069 (18) | −0.001 (2) |
C23 | 0.055 (3) | 0.040 (3) | 0.062 (3) | 0.008 (2) | −0.006 (2) | 0.007 (2) |
C24 | 0.051 (3) | 0.048 (3) | 0.060 (3) | 0.003 (2) | 0.000 (2) | −0.003 (2) |
Geometric parameters (Å, º) top
Ag1—Cl1 | 2.539 (1) | C7—C8 | 1.383 (7) |
Ag1—Cl3 | 2.576 (2) | C7—H7 | 0.93 |
Ag1—Cl4 | 2.589 (2) | C8—C9 | 1.388 (6) |
Ag1—Cl2 | 2.591 (2) | C8—H8 | 0.93 |
N1—C2 | 1.320 (5) | C9—C10 | 1.382 (6) |
N1—C3 | 1.367 (7) | C9—C12 | 1.511 (7) |
N1—C1 | 1.479 (6) | C10—C11 | 1.383 (7) |
N2—C2 | 1.327 (6) | C10—H10 | 0.93 |
N2—C4 | 1.362 (6) | C11—H11 | 0.93 |
N2—C5 | 1.482 (6) | C12—H12A | 0.97 |
N3—C13 | 1.331 (6) | C12—H12B | 0.97 |
N3—C14 | 1.375 (6) | C13—H13 | 0.93 |
N3—C12 | 1.475 (6) | C14—C15 | 1.328 (7) |
N4—C13 | 1.318 (5) | C14—H14 | 0.93 |
N4—C15 | 1.372 (6) | C15—H15 | 0.93 |
N4—C16 | 1.463 (6) | C16—H16A | 0.96 |
N5—C18 | 1.334 (6) | C16—H16B | 0.96 |
N5—C19 | 1.344 (8) | C16—H16C | 0.96 |
N5—C17 | 1.486 (7) | C17—H17A | 0.96 |
N6—C18 | 1.339 (6) | C17—H17B | 0.96 |
N6—C20 | 1.373 (6) | C17—H17C | 0.96 |
N6—C21 | 1.476 (5) | C18—H18 | 0.93 |
C1—H1A | 0.96 | C19—C20 | 1.359 (7) |
C1—H1B | 0.96 | C19—H19 | 0.93 |
C1—H1C | 0.96 | C20—H20 | 0.93 |
C2—H2 | 0.93 | C21—C22 | 1.524 (6) |
C3—C4 | 1.341 (8) | C21—H21A | 0.97 |
C3—H3 | 0.93 | C21—H21B | 0.97 |
C4—H4 | 0.93 | C22—C23 | 1.391 (6) |
C5—C6 | 1.514 (7) | C22—C24i | 1.396 (6) |
C5—H5A | 0.97 | C23—C24 | 1.382 (6) |
C5—H5B | 0.97 | C23—H23 | 0.93 |
C6—C11 | 1.394 (6) | C24—C22i | 1.396 (6) |
C6—C7 | 1.399 (6) | C24—H24 | 0.93 |
| | | |
Cl1—Ag1—Cl3 | 115.34 (5) | C9—C10—C11 | 120.6 (4) |
Cl1—Ag1—Cl4 | 106.04 (6) | C9—C10—H10 | 119.7 |
Cl1—Ag1—Cl2 | 107.27 (5) | C11—C10—H10 | 119.7 |
Cl3—Ag1—Cl4 | 107.83 (6) | C10—C11—C6 | 120.7 (4) |
Cl3—Ag1—Cl2 | 104.58 (7) | C10—C11—H11 | 119.7 |
Cl4—Ag1—Cl2 | 116.14 (7) | C6—C11—H11 | 119.7 |
C2—N1—C3 | 107.8 (4) | N3—C12—C9 | 114.7 (4) |
C2—N1—C1 | 125.9 (4) | N3—C12—H12A | 108.6 |
C3—N1—C1 | 126.3 (4) | C9—C12—H12A | 108.6 |
C2—N2—C4 | 107.9 (4) | N3—C12—H12B | 108.6 |
C2—N2—C5 | 126.3 (4) | C9—C12—H12B | 108.6 |
C4—N2—C5 | 125.8 (5) | H12A—C12—H12B | 107.6 |
C13—N3—C14 | 107.7 (4) | N4—C13—N3 | 108.9 (4) |
C13—N3—C12 | 126.5 (4) | N4—C13—H13 | 125.5 |
C14—N3—C12 | 125.7 (4) | N3—C13—H13 | 125.5 |
C13—N4—C15 | 108.3 (4) | C15—C14—N3 | 107.6 (4) |
C13—N4—C16 | 126.0 (4) | C15—C14—H14 | 126.2 |
C15—N4—C16 | 125.6 (5) | N3—C14—H14 | 126.2 |
C18—N5—C19 | 109.2 (5) | C14—C15—N4 | 107.4 (4) |
C18—N5—C17 | 124.9 (6) | C14—C15—H15 | 126.3 |
C19—N5—C17 | 125.8 (5) | N4—C15—H15 | 126.3 |
C18—N6—C20 | 108.2 (4) | N4—C16—H16A | 109.5 |
C18—N6—C21 | 125.9 (4) | N4—C16—H16B | 109.5 |
C20—N6—C21 | 125.8 (4) | H16A—C16—H16B | 109.5 |
N1—C1—H1A | 109.5 | N4—C16—H16C | 109.5 |
N1—C1—H1B | 109.5 | H16A—C16—H16C | 109.5 |
H1A—C1—H1B | 109.5 | H16B—C16—H16C | 109.5 |
N1—C1—H1C | 109.5 | N5—C17—H17A | 109.5 |
H1A—C1—H1C | 109.5 | N5—C17—H17B | 109.5 |
H1B—C1—H1C | 109.5 | H17A—C17—H17B | 109.5 |
N1—C2—N2 | 109.4 (4) | N5—C17—H17C | 109.5 |
N1—C2—H2 | 125.3 | H17A—C17—H17C | 109.5 |
N2—C2—H2 | 125.3 | H17B—C17—H17C | 109.5 |
C4—C3—N1 | 107.5 (5) | N5—C18—N6 | 108.1 (5) |
C4—C3—H3 | 126.2 | N5—C18—H18 | 125.9 |
N1—C3—H3 | 126.2 | N6—C18—H18 | 125.9 |
C3—C4—N2 | 107.4 (5) | N5—C19—C20 | 107.7 (5) |
C3—C4—H4 | 126.3 | N5—C19—H19 | 126.1 |
N2—C4—H4 | 126.3 | C20—C19—H19 | 126.1 |
N2—C5—C6 | 112.1 (4) | C19—C20—N6 | 106.7 (5) |
N2—C5—H5A | 109.2 | C19—C20—H20 | 126.6 |
C6—C5—H5A | 109.2 | N6—C20—H20 | 126.6 |
N2—C5—H5B | 109.2 | N6—C21—C22 | 112.6 (4) |
C6—C5—H5B | 109.2 | N6—C21—H21A | 109.1 |
H5A—C5—H5B | 107.9 | C22—C21—H21A | 109.1 |
C11—C6—C7 | 118.5 (4) | N6—C21—H21B | 109.1 |
C11—C6—C5 | 121.6 (4) | C22—C21—H21B | 109.1 |
C7—C6—C5 | 119.9 (4) | H21A—C21—H21B | 107.8 |
C8—C7—C6 | 120.4 (4) | C23—C22—C24i | 118.4 (4) |
C8—C7—H7 | 119.8 | C23—C22—C21 | 121.0 (4) |
C6—C7—H7 | 119.8 | C24i—C22—C21 | 120.6 (4) |
C7—C8—C9 | 120.6 (4) | C24—C23—C22 | 121.1 (4) |
C7—C8—H8 | 119.7 | C24—C23—H23 | 119.4 |
C9—C8—H8 | 119.7 | C22—C23—H23 | 119.4 |
C10—C9—C8 | 119.2 (4) | C23—C24—C22i | 120.5 (4) |
C10—C9—C12 | 119.9 (4) | C23—C24—H24 | 119.8 |
C8—C9—C12 | 120.7 (4) | C22i—C24—H24 | 119.8 |
| | | |
C3—N1—C2—N2 | −1.1 (6) | C8—C9—C12—N3 | 58.7 (6) |
C1—N1—C2—N2 | 178.0 (5) | C15—N4—C13—N3 | 0.1 (5) |
C4—N2—C2—N1 | 0.6 (6) | C16—N4—C13—N3 | 178.1 (5) |
C5—N2—C2—N1 | 179.3 (4) | C14—N3—C13—N4 | −0.3 (5) |
C2—N1—C3—C4 | 1.2 (6) | C12—N3—C13—N4 | −176.8 (4) |
C1—N1—C3—C4 | −177.9 (5) | C13—N3—C14—C15 | 0.4 (6) |
N1—C3—C4—N2 | −0.8 (7) | C12—N3—C14—C15 | 176.9 (4) |
C2—N2—C4—C3 | 0.2 (7) | N3—C14—C15—N4 | −0.3 (6) |
C5—N2—C4—C3 | −178.6 (5) | C13—N4—C15—C14 | 0.1 (6) |
C2—N2—C5—C6 | −101.8 (5) | C16—N4—C15—C14 | −177.8 (5) |
C4—N2—C5—C6 | 76.8 (6) | C19—N5—C18—N6 | −0.4 (5) |
N2—C5—C6—C11 | −100.5 (5) | C17—N5—C18—N6 | 178.3 (4) |
N2—C5—C6—C7 | 79.1 (6) | C20—N6—C18—N5 | 0.5 (5) |
C11—C6—C7—C8 | 1.0 (7) | C21—N6—C18—N5 | −179.0 (4) |
C5—C6—C7—C8 | −178.6 (4) | C18—N5—C19—C20 | 0.1 (6) |
C6—C7—C8—C9 | −1.6 (7) | C17—N5—C19—C20 | −178.6 (4) |
C7—C8—C9—C10 | 0.9 (7) | N5—C19—C20—N6 | 0.2 (5) |
C7—C8—C9—C12 | 177.3 (5) | C18—N6—C20—C19 | −0.5 (5) |
C8—C9—C10—C11 | 0.5 (7) | C21—N6—C20—C19 | 179.1 (4) |
C12—C9—C10—C11 | −175.9 (4) | C18—N6—C21—C22 | 93.4 (5) |
C9—C10—C11—C6 | −1.2 (7) | C20—N6—C21—C22 | −86.1 (5) |
C7—C6—C11—C10 | 0.4 (7) | N6—C21—C22—C23 | −76.5 (6) |
C5—C6—C11—C10 | −180.0 (4) | N6—C21—C22—C24i | 104.3 (5) |
C13—N3—C12—C9 | −106.3 (5) | C24i—C22—C23—C24 | 0.2 (8) |
C14—N3—C12—C9 | 77.8 (6) | C21—C22—C23—C24 | −179.0 (4) |
C10—C9—C12—N3 | −124.9 (5) | C22—C23—C24—C22i | −0.2 (8) |
Symmetry code: (i) −x+2, −y, −z+1. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
C1—H1C···Cl4i | 0.96 | 2.81 | 3.703 (6) | 154 |
C5—H5A···Cl4ii | 0.97 | 2.68 | 3.617 (5) | 162 |
C5—H5B···Cl1i | 0.97 | 2.76 | 3.643 (5) | 151 |
C12—H12A···Cl1iii | 0.97 | 2.65 | 3.536 (6) | 152 |
C12—H12B···Cl2iv | 0.97 | 2.62 | 3.487 (6) | 148 |
C14—H14···Cl3iii | 0.93 | 2.64 | 3.529 (5) | 160 |
C15—H15···Cl2 | 0.93 | 2.53 | 3.453 (5) | 171 |
C16—H16C···Cl3iv | 0.96 | 2.73 | 3.627 (6) | 157 |
C17—H17A···Cl3iii | 0.96 | 2.80 | 3.732 (7) | 165 |
C17—H17B···Cl1v | 0.96 | 2.73 | 3.557 (7) | 145 |
C17—H17C···Cl2 | 0.96 | 2.82 | 3.711 (7) | 154 |
C18—H18···Cl2 | 0.93 | 2.73 | 3.548 (6) | 148 |
C20—H20···Cl3vi | 0.93 | 2.60 | 3.487 (6) | 161 |
Symmetry codes: (i) −x+2, −y, −z+1; (ii) −x+1, −y, −z+1; (iii) x−1/2, −y+1/2, z+1/2; (iv) x+1/2, −y+1/2, z+1/2; (v) x−1, y, z; (vi) −x+3/2, y−1/2, −z+1/2. |
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