Buy article online - an online subscription or single-article purchase is required to access this article.
The crystal structure determination of the title complex, bis[μ-1,3-bis(2-oxybenzoylimino)propane]tricopper(II) diperchlorate, [Cu3(C17N2H16O2)2](ClO4)2, shows that a CuII atom, located on a crystallographic inversion centre, is coordinated by four bridging O atoms of two L ligands [H2L is 1,3-bis(2-hydroxybenzoylimino)propane] and two perchlorate O atoms, in elongated octahedral geometry. The other two CuII atoms are in a distorted square-pyramidal geometry, ligated by N and O atoms of the L ligand and an O atom of a perchlorate ion. In the complex, the Cu—N bond length is 1.948 (4) Å and the Cu—O bond lengths are in the range 1.930 (3)–1.984 (3) Å.
Supporting information
CCDC reference: 239058
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.007 Å
- R factor = 0.053
- wR factor = 0.110
- Data-to-parameter ratio = 16.4
checkCIF/PLATON results
No syntax errors found
Alert level A
PLAT220_ALERT_2_A Large Non-Solvent O Ueq(max)/Ueq(min) ... 5.35 Ratio
| Author Response: For all oxygen atoms, O4 and O6 atoms have high Ueq.
Because the data is collected at 25^o^C. O4 and O6 atoms are disorder.
|
PLAT242_ALERT_2_A Check Low U(eq) as Compared to Neighbors .... Cl1
| Author Response: Because the data is collected at 25^o^C.
|
Alert level C
PLAT213_ALERT_2_C Atom O6 has ADP max/min Ratio ............. 3.30 prolat
PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... O3
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 7
2 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
3 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
4 ALERT type 2 Indicator that the structure model may be wrong or deficient
1 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998) and SHELXTL (Bruker, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL; software used to prepare material for publication: SHELXL97.
bis[µ-1,3-bis(2-hydroxylbenzoylimino)propane]tricopper(II) bis(perchlorate)
top
Crystal data top
[Cu3(C17N2H16O2)2](ClO4)2 | F(000) = 962 |
Mr = 950.19 | Dx = 1.791 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 4098 reflections |
a = 8.8249 (10) Å | θ = 2–28.3° |
b = 11.9200 (13) Å | µ = 2.02 mm−1 |
c = 17.2030 (19) Å | T = 293 K |
β = 103.161 (2)° | Needle, blue |
V = 1762.1 (3) Å3 | 0.15 × 0.10 × 0.05 mm |
Z = 2 | |
Data collection top
Bruker SMART CCD area-detector diffractometer | 4099 independent reflections |
Radiation source: fine-focus sealed tube | 2716 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.061 |
φ and ω scans | θmax = 28.3°, θmin = 2.1° |
Absorption correction: multi-scan (SADABS; Bruker, 1998) | h = −11→11 |
Tmin = 0.788, Tmax = 0.899 | k = −12→15 |
10495 measured reflections | l = −22→20 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.053 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.110 | H-atom parameters constrained |
S = 0.96 | w = 1/[σ2(Fo2) + (0.0367P)2] where P = (Fo2 + 2Fc2)/3 |
4099 reflections | (Δ/σ)max < 0.001 |
250 parameters | Δρmax = 0.62 e Å−3 |
10 restraints | Δρmin = −0.39 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Cu1 | 0.82135 (6) | 0.17767 (4) | 0.05775 (3) | 0.03302 (17) | |
Cu2 | 1.0000 | 0.0000 | 0.0000 | 0.0316 (2) | |
O1 | 0.9814 (3) | 0.0683 (2) | 0.09910 (17) | 0.0350 (7) | |
O2 | 0.7888 (3) | 0.0671 (2) | −0.02754 (17) | 0.0344 (7) | |
N1 | 0.9020 (4) | 0.2777 (3) | 0.1471 (2) | 0.0387 (9) | |
N2 | 0.6279 (4) | 0.2554 (3) | 0.0110 (2) | 0.0385 (10) | |
C1 | 1.0477 (5) | 0.0503 (4) | 0.1760 (3) | 0.0321 (10) | |
C2 | 1.1039 (5) | −0.0558 (4) | 0.2023 (3) | 0.0380 (11) | |
H2A | 1.0908 | −0.1178 | 0.1658 | 0.080* | |
C3 | 1.1779 (6) | −0.0717 (4) | 0.2805 (3) | 0.0472 (13) | |
H3A | 1.2124 | −0.1456 | 0.2985 | 0.080* | |
C4 | 1.2049 (6) | 0.0168 (5) | 0.3348 (3) | 0.0573 (15) | |
H4B | 1.2620 | 0.0056 | 0.3888 | 0.080* | |
C5 | 1.1470 (6) | 0.1201 (4) | 0.3091 (3) | 0.0508 (13) | |
H5A | 1.1651 | 0.1819 | 0.3458 | 0.080* | |
C6 | 1.0634 (5) | 0.1384 (4) | 0.2310 (3) | 0.0356 (11) | |
C7 | 0.9965 (5) | 0.2483 (4) | 0.2110 (3) | 0.0402 (12) | |
H7A | 1.0274 | 0.3058 | 0.2505 | 0.080* | |
C8 | 0.8517 (6) | 0.3961 (4) | 0.1390 (3) | 0.0509 (14) | |
H8A | 0.8914 | 0.4312 | 0.0975 | 0.080* | |
H8B | 0.8930 | 0.4354 | 0.1880 | 0.080* | |
C9 | 0.6777 (6) | 0.4039 (4) | 0.1191 (3) | 0.0548 (15) | |
H9A | 0.6486 | 0.4793 | 0.1288 | 0.080* | |
H9B | 0.6379 | 0.3553 | 0.1542 | 0.080* | |
C10 | 0.6032 (6) | 0.3733 (4) | 0.0338 (3) | 0.0521 (14) | |
H10A | 0.4932 | 0.3862 | 0.0252 | 0.080* | |
H10B | 0.6423 | 0.4227 | −0.0011 | 0.080* | |
C11 | 0.5184 (5) | 0.2096 (4) | −0.0404 (3) | 0.0409 (12) | |
H11A | 0.4244 | 0.2525 | −0.0561 | 0.080* | |
C12 | 0.5185 (5) | 0.1003 (4) | −0.0786 (3) | 0.0346 (11) | |
C13 | 0.3785 (6) | 0.0644 (4) | −0.1268 (3) | 0.0469 (13) | |
H13A | 0.2875 | 0.1104 | −0.1316 | 0.080* | |
C14 | 0.3665 (6) | −0.0356 (4) | −0.1678 (3) | 0.0482 (13) | |
H14A | 0.2689 | −0.0589 | −0.2009 | 0.080* | |
C15 | 0.4994 (6) | −0.1018 (4) | −0.1603 (3) | 0.0451 (12) | |
H15A | 0.4934 | −0.1716 | −0.1887 | 0.080* | |
C16 | 0.6386 (5) | −0.0678 (4) | −0.1124 (3) | 0.0383 (11) | |
H16A | 0.7280 | −0.1154 | −0.1073 | 0.080* | |
C17 | 0.6534 (5) | 0.0329 (4) | −0.0713 (2) | 0.0308 (10) | |
Cl1 | 0.91122 (16) | −0.29566 (10) | 0.04110 (9) | 0.0531 (4) | |
O3 | 0.8836 (4) | −0.1766 (3) | 0.0370 (2) | 0.0667 (11) | |
O4 | 0.8927 (7) | −0.3300 (4) | 0.1151 (4) | 0.147 (3) | |
O5 | 1.0623 (5) | −0.3150 (3) | 0.0307 (3) | 0.0833 (14) | |
O6 | 0.8018 (6) | −0.3447 (5) | −0.0178 (5) | 0.184 (3) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Cu1 | 0.0366 (3) | 0.0287 (3) | 0.0333 (3) | 0.0106 (2) | 0.0071 (3) | −0.0026 (2) |
Cu2 | 0.0296 (4) | 0.0347 (4) | 0.0285 (4) | 0.0104 (3) | 0.0026 (3) | −0.0078 (3) |
O1 | 0.0428 (19) | 0.0316 (17) | 0.0281 (18) | 0.0144 (14) | 0.0027 (15) | −0.0049 (13) |
O2 | 0.0274 (17) | 0.0394 (18) | 0.0348 (19) | 0.0070 (14) | 0.0040 (14) | −0.0050 (14) |
N1 | 0.046 (3) | 0.030 (2) | 0.041 (3) | 0.0061 (18) | 0.011 (2) | −0.0047 (17) |
N2 | 0.038 (2) | 0.033 (2) | 0.047 (3) | 0.0104 (18) | 0.015 (2) | 0.0039 (18) |
C1 | 0.027 (2) | 0.037 (3) | 0.033 (3) | −0.0011 (19) | 0.007 (2) | −0.002 (2) |
C2 | 0.035 (3) | 0.041 (3) | 0.037 (3) | 0.005 (2) | 0.007 (2) | 0.003 (2) |
C3 | 0.042 (3) | 0.052 (3) | 0.050 (4) | 0.007 (2) | 0.014 (3) | 0.014 (3) |
C4 | 0.063 (4) | 0.074 (4) | 0.032 (3) | 0.014 (3) | 0.006 (3) | 0.003 (3) |
C5 | 0.059 (4) | 0.057 (3) | 0.033 (3) | 0.006 (3) | 0.003 (3) | −0.009 (2) |
C6 | 0.031 (3) | 0.044 (3) | 0.031 (3) | 0.003 (2) | 0.006 (2) | −0.006 (2) |
C7 | 0.045 (3) | 0.038 (3) | 0.041 (3) | −0.004 (2) | 0.017 (3) | −0.011 (2) |
C8 | 0.061 (4) | 0.030 (3) | 0.063 (4) | 0.013 (2) | 0.017 (3) | −0.009 (2) |
C9 | 0.076 (4) | 0.025 (3) | 0.072 (4) | 0.015 (3) | 0.034 (3) | −0.006 (2) |
C10 | 0.053 (3) | 0.034 (3) | 0.071 (4) | 0.017 (2) | 0.017 (3) | 0.000 (3) |
C11 | 0.032 (3) | 0.045 (3) | 0.047 (3) | 0.012 (2) | 0.012 (2) | 0.016 (2) |
C12 | 0.030 (3) | 0.042 (3) | 0.033 (3) | 0.008 (2) | 0.010 (2) | 0.009 (2) |
C13 | 0.029 (3) | 0.066 (4) | 0.046 (3) | 0.000 (2) | 0.008 (2) | 0.011 (3) |
C14 | 0.035 (3) | 0.066 (4) | 0.043 (3) | −0.012 (3) | 0.007 (2) | 0.002 (3) |
C15 | 0.041 (3) | 0.051 (3) | 0.043 (3) | −0.010 (2) | 0.009 (3) | 0.000 (2) |
C16 | 0.033 (3) | 0.041 (3) | 0.040 (3) | −0.002 (2) | 0.007 (2) | −0.004 (2) |
C17 | 0.026 (2) | 0.039 (3) | 0.028 (3) | −0.0015 (19) | 0.006 (2) | 0.0039 (19) |
Cl1 | 0.0484 (8) | 0.0382 (7) | 0.0777 (11) | −0.0033 (6) | 0.0249 (8) | −0.0071 (6) |
O3 | 0.071 (3) | 0.044 (2) | 0.086 (3) | −0.0028 (19) | 0.020 (2) | 0.0118 (19) |
O4 | 0.214 (6) | 0.095 (4) | 0.184 (6) | 0.057 (4) | 0.150 (6) | 0.080 (4) |
O5 | 0.060 (3) | 0.100 (3) | 0.098 (4) | 0.023 (2) | 0.033 (3) | 0.015 (3) |
O6 | 0.089 (4) | 0.154 (5) | 0.290 (9) | −0.020 (4) | 0.003 (5) | −0.163 (6) |
Geometric parameters (Å, º) top
Cu1—O1 | 1.935 (3) | C6—C7 | 1.446 (6) |
Cu1—O2 | 1.944 (3) | C7—H7A | 0.96 |
Cu1—N2 | 1.948 (4) | C8—C9 | 1.498 (7) |
Cu1—N1 | 1.948 (4) | C8—H8A | 0.96 |
Cu1—Cu2 | 2.9446 (5) | C8—H8B | 0.96 |
Cu2—O1i | 1.930 (3) | C9—C10 | 1.510 (7) |
Cu2—O1 | 1.930 (3) | C9—H9A | 0.96 |
Cu2—O2 | 1.984 (3) | C9—H9B | 0.96 |
Cu2—O2i | 1.984 (3) | C10—H10A | 0.96 |
Cu2—Cu1i | 2.9446 (5) | C10—H10B | 0.96 |
O1—C1 | 1.336 (5) | C11—C12 | 1.459 (6) |
O2—C17 | 1.323 (5) | C11—H11A | 0.96 |
N1—C7 | 1.268 (6) | C12—C13 | 1.390 (6) |
N1—C8 | 1.476 (5) | C12—C17 | 1.418 (6) |
N2—C11 | 1.275 (6) | C13—C14 | 1.377 (7) |
N2—C10 | 1.488 (5) | C13—H13A | 0.96 |
C1—C2 | 1.396 (6) | C14—C15 | 1.395 (6) |
C1—C6 | 1.398 (6) | C14—H14A | 0.96 |
C2—C3 | 1.367 (6) | C15—C16 | 1.375 (6) |
C2—H2A | 0.96 | C15—H15A | 0.96 |
C3—C4 | 1.394 (7) | C16—C17 | 1.384 (6) |
C3—H3A | 0.96 | C16—H16A | 0.96 |
C4—C5 | 1.367 (7) | Cl1—O6 | 1.362 (5) |
C4—H4B | 0.96 | Cl1—O4 | 1.381 (5) |
C5—C6 | 1.395 (6) | Cl1—O5 | 1.404 (4) |
C5—H5A | 0.96 | Cl1—O3 | 1.439 (3) |
| | | |
O1—Cu1—O2 | 77.93 (12) | C5—C6—C1 | 118.9 (4) |
O1—Cu1—N2 | 165.97 (14) | C5—C6—C7 | 117.9 (4) |
O2—Cu1—N2 | 92.62 (14) | C1—C6—C7 | 123.2 (4) |
O1—Cu1—N1 | 90.98 (14) | N1—C7—C6 | 127.5 (4) |
O2—Cu1—N1 | 167.22 (14) | N1—C7—H7A | 116.2 |
N2—Cu1—N1 | 99.40 (16) | C6—C7—H7A | 116.3 |
O1—Cu1—Cu2 | 40.30 (8) | N1—C8—C9 | 110.6 (4) |
O2—Cu1—Cu2 | 41.96 (8) | N1—C8—H8A | 109.5 |
N2—Cu1—Cu2 | 133.54 (12) | C9—C8—H8A | 109.3 |
N1—Cu1—Cu2 | 125.38 (11) | N1—C8—H8B | 109.8 |
O1i—Cu2—O1 | 180.0 | C9—C8—H8B | 109.6 |
O1i—Cu2—O2 | 102.91 (12) | H8A—C8—H8B | 108.0 |
O1—Cu2—O2 | 77.09 (12) | C8—C9—C10 | 113.9 (4) |
O1i—Cu2—O2i | 77.09 (12) | C8—C9—H9A | 108.6 |
O1—Cu2—O2i | 102.91 (12) | C10—C9—H9A | 108.8 |
O2—Cu2—O2i | 180.0 | C8—C9—H9B | 108.7 |
O1i—Cu2—Cu1i | 40.42 (8) | C10—C9—H9B | 109.0 |
O1—Cu2—Cu1i | 139.58 (8) | H9A—C9—H9B | 107.7 |
O2—Cu2—Cu1i | 139.07 (8) | N2—C10—C9 | 115.3 (4) |
O2i—Cu2—Cu1i | 40.93 (8) | N2—C10—H10A | 108.3 |
O1i—Cu2—Cu1 | 139.58 (8) | C9—C10—H10A | 108.2 |
O1—Cu2—Cu1 | 40.42 (8) | N2—C10—H10B | 108.6 |
O2—Cu2—Cu1 | 40.93 (8) | C9—C10—H10B | 108.7 |
O2i—Cu2—Cu1 | 139.07 (8) | H10A—C10—H10B | 107.5 |
Cu1i—Cu2—Cu1 | 180.0 | N2—C11—C12 | 128.1 (4) |
C1—O1—Cu2 | 134.5 (3) | N2—C11—H11A | 115.9 |
C1—O1—Cu1 | 126.2 (2) | C12—C11—H11A | 116.0 |
Cu2—O1—Cu1 | 99.28 (13) | C13—C12—C17 | 119.5 (4) |
C17—O2—Cu1 | 126.7 (3) | C13—C12—C11 | 116.9 (4) |
C17—O2—Cu2 | 133.6 (3) | C17—C12—C11 | 123.5 (4) |
Cu1—O2—Cu2 | 97.11 (13) | C14—C13—C12 | 121.7 (5) |
C7—N1—C8 | 118.1 (4) | C14—C13—H13A | 119.1 |
C7—N1—Cu1 | 124.4 (3) | C12—C13—H13A | 119.2 |
C8—N1—Cu1 | 117.6 (3) | C13—C14—C15 | 118.6 (5) |
C11—N2—C10 | 117.0 (4) | C13—C14—H14A | 120.6 |
C11—N2—Cu1 | 122.5 (3) | C15—C14—H14A | 120.9 |
C10—N2—Cu1 | 120.5 (3) | C16—C15—C14 | 120.4 (5) |
O1—C1—C2 | 120.6 (4) | C16—C15—H15A | 119.9 |
O1—C1—C6 | 120.2 (4) | C14—C15—H15A | 119.7 |
C2—C1—C6 | 119.2 (4) | C15—C16—C17 | 122.0 (4) |
C3—C2—C1 | 120.0 (4) | C15—C16—H16A | 118.9 |
C3—C2—H2A | 119.7 | C17—C16—H16A | 119.1 |
C1—C2—H2A | 120.3 | O2—C17—C16 | 121.7 (4) |
C2—C3—C4 | 121.6 (5) | O2—C17—C12 | 120.5 (4) |
C2—C3—H3A | 119.4 | C16—C17—C12 | 117.8 (4) |
C4—C3—H3A | 119.0 | O6—Cl1—O4 | 110.2 (4) |
C5—C4—C3 | 118.1 (5) | O6—Cl1—O5 | 111.6 (3) |
C5—C4—H4B | 120.9 | O4—Cl1—O5 | 112.6 (3) |
C3—C4—H4B | 121.0 | O6—Cl1—O3 | 107.7 (3) |
C4—C5—C6 | 121.9 (5) | O4—Cl1—O3 | 106.4 (3) |
C4—C5—H5A | 118.9 | O5—Cl1—O3 | 108.1 (2) |
C6—C5—H5A | 119.1 | | |
| | | |
O1—Cu1—Cu2—O1i | 180.0 | N1—Cu1—N2—C11 | −165.4 (4) |
O2—Cu1—Cu2—O1i | 34.11 (18) | Cu2—Cu1—N2—C11 | 29.4 (4) |
N2—Cu1—Cu2—O1i | 18.4 (2) | O1—Cu1—N2—C10 | 152.6 (5) |
N1—Cu1—Cu2—O1i | −143.60 (19) | O2—Cu1—N2—C10 | −160.3 (3) |
O2—Cu1—Cu2—O1 | −145.89 (18) | N1—Cu1—N2—C10 | 15.3 (3) |
N2—Cu1—Cu2—O1 | −161.6 (2) | Cu2—Cu1—N2—C10 | −149.9 (3) |
N1—Cu1—Cu2—O1 | 36.40 (19) | Cu2—O1—C1—C2 | −26.7 (6) |
O1—Cu1—Cu2—O2 | 145.89 (18) | Cu1—O1—C1—C2 | 150.6 (3) |
N2—Cu1—Cu2—O2 | −15.68 (19) | Cu2—O1—C1—C6 | 152.4 (3) |
N1—Cu1—Cu2—O2 | −177.71 (19) | Cu1—O1—C1—C6 | −30.4 (5) |
O1—Cu1—Cu2—O2i | −34.11 (18) | O1—C1—C2—C3 | 176.9 (4) |
O2—Cu1—Cu2—O2i | 180.0 | C6—C1—C2—C3 | −2.1 (6) |
N2—Cu1—Cu2—O2i | 164.32 (19) | C1—C2—C3—C4 | −2.6 (7) |
N1—Cu1—Cu2—O2i | 2.29 (19) | C2—C3—C4—C5 | 3.8 (8) |
O2—Cu2—O1—C1 | 155.6 (4) | C3—C4—C5—C6 | −0.2 (8) |
O2i—Cu2—O1—C1 | −24.4 (4) | C4—C5—C6—C1 | −4.5 (7) |
Cu1i—Cu2—O1—C1 | −2.3 (5) | C4—C5—C6—C7 | 175.3 (5) |
Cu1—Cu2—O1—C1 | 177.7 (5) | O1—C1—C6—C5 | −173.5 (4) |
O2—Cu2—O1—Cu1 | −22.14 (12) | C2—C1—C6—C5 | 5.6 (6) |
O2i—Cu2—O1—Cu1 | 157.86 (12) | O1—C1—C6—C7 | 6.7 (7) |
Cu1i—Cu2—O1—Cu1 | 180.0 | C2—C1—C6—C7 | −174.2 (4) |
O2—Cu1—O1—C1 | −155.5 (3) | C8—N1—C7—C6 | −178.6 (4) |
N2—Cu1—O1—C1 | −107.0 (6) | Cu1—N1—C7—C6 | 0.2 (7) |
N1—Cu1—O1—C1 | 30.9 (3) | C5—C6—C7—N1 | −170.8 (5) |
Cu2—Cu1—O1—C1 | −178.0 (4) | C1—C6—C7—N1 | 9.0 (7) |
O2—Cu1—O1—Cu2 | 22.54 (12) | C7—N1—C8—C9 | −126.2 (5) |
N2—Cu1—O1—Cu2 | 71.0 (6) | Cu1—N1—C8—C9 | 54.9 (5) |
N1—Cu1—O1—Cu2 | −151.06 (15) | N1—C8—C9—C10 | −74.6 (5) |
O1—Cu1—O2—C17 | 141.7 (3) | C11—N2—C10—C9 | 147.3 (5) |
N2—Cu1—O2—C17 | −27.8 (3) | Cu1—N2—C10—C9 | −33.4 (5) |
N1—Cu1—O2—C17 | 172.0 (6) | C8—C9—C10—N2 | 63.0 (6) |
Cu2—Cu1—O2—C17 | 163.5 (4) | C10—N2—C11—C12 | 173.5 (4) |
O1—Cu1—O2—Cu2 | −21.77 (12) | Cu1—N2—C11—C12 | −5.8 (7) |
N2—Cu1—O2—Cu2 | 168.69 (14) | N2—C11—C12—C13 | 173.6 (5) |
N1—Cu1—O2—Cu2 | 8.5 (7) | N2—C11—C12—C17 | −8.9 (7) |
O1i—Cu2—O2—C17 | 40.2 (4) | C17—C12—C13—C14 | 0.2 (7) |
Cu1i—Cu2—O2—C17 | 18.3 (4) | C11—C12—C13—C14 | 177.9 (4) |
Cu1—Cu2—O2—C17 | −161.7 (4) | C12—C13—C14—C15 | −0.1 (7) |
O1i—Cu2—O2—Cu1 | −158.10 (12) | C13—C14—C15—C16 | 0.5 (7) |
O1—Cu2—O2—Cu1 | 21.90 (12) | C14—C15—C16—C17 | −1.2 (7) |
Cu1i—Cu2—O2—Cu1 | 180.0 | Cu1—O2—C17—C16 | −159.6 (3) |
O1—Cu1—N1—C7 | −15.4 (4) | Cu2—O2—C17—C16 | −2.5 (6) |
O2—Cu1—N1—C7 | −44.9 (9) | Cu1—O2—C17—C12 | 21.5 (5) |
N2—Cu1—N1—C7 | 155.1 (4) | Cu2—O2—C17—C12 | 178.6 (3) |
Cu2—Cu1—N1—C7 | −38.0 (4) | C15—C16—C17—O2 | −177.6 (4) |
O1—Cu1—N1—C8 | 163.4 (3) | C15—C16—C17—C12 | 1.3 (7) |
O2—Cu1—N1—C8 | 133.9 (6) | C13—C12—C17—O2 | 178.1 (4) |
N2—Cu1—N1—C8 | −26.1 (3) | C11—C12—C17—O2 | 0.6 (6) |
Cu2—Cu1—N1—C8 | 140.8 (3) | C13—C12—C17—C16 | −0.8 (6) |
O1—Cu1—N2—C11 | −28.1 (8) | C11—C12—C17—C16 | −178.3 (4) |
O2—Cu1—N2—C11 | 19.0 (4) | | |
Symmetry code: (i) −x+2, −y, −z. |
Subscribe to Acta Crystallographica Section E: Crystallographic Communications
The full text of this article is available to subscribers to the journal.
If you have already registered and are using a computer listed in your registration details, please email
support@iucr.org for assistance.