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metal-organic compounds
The crystal structure of [Mn(C36H44N4)(C2H6O)]ClO4 has been determined. The average Mn-Np bond distance is 1.997 (5) Å and the axial Mn-O bond length is 2.145 (2) Å. The manganese(III) ion has a displacement of 0.17 Å from the mean plane of the 24-atom porphinato core.