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The structure of Sm(BrO3)3.9H2O has been solved by the neutron anomalous-dispersion method, with the use of data collected at two wavelengths. Five out of eight atoms in the asymmetric unit were located from the `anomalous difference Patterson' synthesis, and the remaining three from a Fourier synthesis. The structure is centrosymmetric, and the signs of 78% of the reflections were determined correctly from the differences in the Fobs values at the two wavelengths.

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