Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805019987/ci6602sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805019987/ci66024sup2.hkl |
CCDC reference: 282275
Data collection: XSCANS (Bruker, 1997); cell refinement: XSCANS; data reduction: XSCANS and XPREP (Bruker, 1997); program(s) used to solve structure: SHELXTL (Bruker, 2000); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
C29H33NO4 | F(000) = 984 |
Mr = 459.56 | Dx = 1.228 Mg m−3 |
Orthorhombic, P212121 | Cu Kα radiation, λ = 1.54178 Å |
Hall symbol: P 2ac 2ab | Cell parameters from 21 reflections |
a = 12.3572 (17) Å | θ = 4.5–22.5° |
b = 12.6676 (11) Å | µ = 0.65 mm−1 |
c = 15.874 (3) Å | T = 297 K |
V = 2484.9 (6) Å3 | Prism, colorless |
Z = 4 | 0.54 × 0.24 × 0.22 mm |
Bruker P4 diffractometer | Rint = 0.053 |
Radiation source: sealed tube | θmax = 69.0°, θmin = 4.5° |
Graphite monochromator | h = −14→1 |
2θ/ω scans | k = −1→15 |
6038 measured reflections | l = −19→19 |
2615 independent reflections | 3 standard reflections every 97 reflections |
2091 reflections with I > 2σ(I) | intensity decay: none |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.053 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.148 | H-atom parameters constrained |
S = 1.04 | w = 1/[σ2(Fo2) + (0.0849P)2 + 0.173P] where P = (Fo2 + 2Fc2)/3 |
2615 reflections | (Δ/σ)max < 0.001 |
310 parameters | Δρmax = 0.21 e Å−3 |
0 restraints | Δρmin = −0.17 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. All H-atoms were refined with the riding model in SHELXL. This results in a weak different peak (<0.2) near O14 which may represent an alternate position for H14. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
C1 | 0.3363 (3) | 0.7853 (3) | 0.82648 (19) | 0.0669 (9) | |
H1A | 0.3370 | 0.7352 | 0.8693 | 0.080* | |
C2 | 0.2803 (3) | 0.8781 (3) | 0.8384 (2) | 0.0681 (9) | |
H2A | 0.2442 | 0.8905 | 0.8888 | 0.082* | |
C3 | 0.2779 (3) | 0.9524 (3) | 0.7753 (2) | 0.0626 (8) | |
O3 | 0.2245 (2) | 1.0470 (2) | 0.77998 (16) | 0.0762 (7) | |
C3A | 0.1554 (4) | 1.0634 (4) | 0.8502 (3) | 0.0994 (15) | |
H3AA | 0.1143 | 1.1269 | 0.8419 | 0.149* | |
H3AB | 0.1981 | 1.0699 | 0.9004 | 0.149* | |
H3AC | 0.1069 | 1.0046 | 0.8557 | 0.149* | |
C4 | 0.3336 (3) | 0.9332 (3) | 0.70022 (19) | 0.0560 (8) | |
O4 | 0.3309 (2) | 1.0117 (2) | 0.63923 (16) | 0.0741 (7) | |
C4A | 0.2302 (4) | 1.0282 (4) | 0.5995 (3) | 0.0902 (13) | |
H4AA | 0.2336 | 1.0911 | 0.5659 | 0.135* | |
H4AB | 0.1748 | 1.0357 | 0.6415 | 0.135* | |
H4AC | 0.2137 | 0.9689 | 0.5641 | 0.135* | |
C5 | 0.4972 (3) | 0.9051 (3) | 0.5527 (2) | 0.0655 (9) | |
H5A | 0.5137 | 0.8801 | 0.4964 | 0.079* | |
H5B | 0.4421 | 0.9592 | 0.5474 | 0.079* | |
C6 | 0.5967 (3) | 0.9549 (3) | 0.5882 (2) | 0.0663 (9) | |
O6 | 0.6194 (3) | 1.0466 (2) | 0.56964 (17) | 0.0873 (9) | |
C7 | 0.6709 (3) | 0.8908 (3) | 0.6413 (2) | 0.0642 (9) | |
C8 | 0.6293 (3) | 0.7875 (3) | 0.6758 (2) | 0.0622 (8) | |
H8A | 0.6896 | 0.7392 | 0.6820 | 0.075* | |
H8B | 0.5991 | 0.7997 | 0.7314 | 0.075* | |
C9 | 0.5001 (3) | 0.6356 (3) | 0.66045 (19) | 0.0623 (8) | |
H9A | 0.5616 | 0.5885 | 0.6705 | 0.075* | |
C10 | 0.4481 (3) | 0.6590 (3) | 0.74579 (19) | 0.0641 (9) | |
H10A | 0.3960 | 0.6038 | 0.7580 | 0.077* | |
H10B | 0.5039 | 0.6559 | 0.7887 | 0.077* | |
C11 | 0.3916 (3) | 0.7646 (3) | 0.75224 (18) | 0.0585 (8) | |
C12 | 0.3931 (3) | 0.8403 (3) | 0.68755 (18) | 0.0548 (7) | |
C13 | 0.4489 (3) | 0.8123 (3) | 0.60330 (18) | 0.0570 (8) | |
O14 | 0.5958 (2) | 0.7076 (2) | 0.54320 (14) | 0.0713 (7) | |
H14 | 0.5644 | 0.6569 | 0.5223 | 0.107* | |
C14 | 0.5440 (3) | 0.7361 (3) | 0.62131 (18) | 0.0575 (8) | |
C15 | 0.3644 (3) | 0.7556 (3) | 0.5472 (2) | 0.0656 (9) | |
H15A | 0.2999 | 0.7990 | 0.5435 | 0.079* | |
H15B | 0.3935 | 0.7480 | 0.4908 | 0.079* | |
C16 | 0.3334 (4) | 0.6474 (3) | 0.5807 (2) | 0.0733 (10) | |
H16A | 0.2921 | 0.6551 | 0.6323 | 0.088* | |
H16B | 0.2884 | 0.6112 | 0.5398 | 0.088* | |
N17 | 0.4305 (3) | 0.5851 (2) | 0.59714 (18) | 0.0681 (8) | |
C18 | 0.4059 (5) | 0.4742 (3) | 0.6206 (2) | 0.0838 (12) | |
H18A | 0.4714 | 0.4409 | 0.6413 | 0.101* | |
H18B | 0.3534 | 0.4740 | 0.6660 | 0.101* | |
C19 | 0.3630 (6) | 0.4118 (4) | 0.5498 (3) | 0.1061 (17) | |
H19A | 0.2918 | 0.4322 | 0.5281 | 0.127* | |
C20 | 0.4409 (7) | 0.3724 (4) | 0.4889 (4) | 0.130 (2) | |
H20A | 0.5165 | 0.3899 | 0.4978 | 0.156* | |
H20B | 0.4189 | 0.3705 | 0.4302 | 0.156* | |
C21 | 0.3913 (6) | 0.2953 (4) | 0.5465 (3) | 0.120 (2) | |
H21A | 0.4357 | 0.2667 | 0.5914 | 0.144* | |
H21B | 0.3378 | 0.2471 | 0.5236 | 0.144* | |
C22 | 0.7717 (3) | 0.9249 (3) | 0.6518 (2) | 0.0729 (10) | |
H22A | 0.7873 | 0.9900 | 0.6277 | 0.088* | |
C23 | 0.8613 (3) | 0.8743 (4) | 0.6959 (2) | 0.0754 (11) | |
C24 | 0.9625 (3) | 0.8696 (4) | 0.6593 (3) | 0.0851 (12) | |
H24A | 0.9735 | 0.9034 | 0.6079 | 0.102* | |
C25 | 1.0465 (4) | 0.8177 (5) | 0.6953 (4) | 0.1096 (18) | |
H25A | 1.1128 | 0.8134 | 0.6679 | 0.132* | |
C26 | 1.0323 (4) | 0.7707 (5) | 0.7739 (4) | 0.124 (2) | |
H26A | 1.0894 | 0.7352 | 0.7996 | 0.149* | |
C27 | 0.9347 (4) | 0.7770 (5) | 0.8126 (3) | 0.1116 (18) | |
H27A | 0.9263 | 0.7475 | 0.8658 | 0.134* | |
C28 | 0.8485 (4) | 0.8255 (4) | 0.7755 (3) | 0.0931 (14) | |
H28A | 0.7816 | 0.8266 | 0.8023 | 0.112* |
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.077 (2) | 0.081 (2) | 0.0427 (15) | −0.004 (2) | 0.0014 (16) | 0.0046 (16) |
C2 | 0.073 (2) | 0.085 (2) | 0.0469 (16) | 0.001 (2) | 0.0068 (17) | −0.0069 (17) |
C3 | 0.0662 (19) | 0.068 (2) | 0.0534 (16) | −0.0014 (19) | 0.0007 (17) | −0.0069 (16) |
O3 | 0.0866 (16) | 0.0746 (16) | 0.0674 (14) | 0.0126 (15) | 0.0141 (14) | −0.0093 (13) |
C3A | 0.109 (3) | 0.093 (3) | 0.096 (3) | 0.019 (3) | 0.037 (3) | −0.008 (3) |
C4 | 0.0591 (17) | 0.0612 (18) | 0.0476 (15) | −0.0004 (16) | 0.0013 (14) | 0.0006 (13) |
O4 | 0.0856 (17) | 0.0694 (14) | 0.0673 (14) | 0.0068 (14) | 0.0143 (14) | 0.0107 (12) |
C4A | 0.101 (3) | 0.097 (3) | 0.072 (2) | 0.018 (3) | −0.007 (2) | 0.013 (2) |
C5 | 0.076 (2) | 0.075 (2) | 0.0462 (15) | 0.008 (2) | 0.0079 (16) | 0.0071 (16) |
C6 | 0.084 (2) | 0.069 (2) | 0.0460 (15) | 0.009 (2) | 0.0113 (17) | 0.0025 (16) |
O6 | 0.113 (2) | 0.0672 (16) | 0.0814 (17) | −0.0057 (18) | −0.0024 (17) | 0.0100 (14) |
C7 | 0.074 (2) | 0.074 (2) | 0.0450 (15) | −0.0006 (19) | 0.0038 (16) | −0.0032 (15) |
C8 | 0.0642 (18) | 0.070 (2) | 0.0525 (16) | 0.0034 (17) | −0.0043 (16) | 0.0077 (16) |
C9 | 0.073 (2) | 0.0629 (18) | 0.0513 (15) | 0.0033 (18) | −0.0068 (16) | 0.0007 (15) |
C10 | 0.083 (2) | 0.0629 (19) | 0.0464 (15) | 0.0004 (18) | −0.0049 (17) | 0.0041 (14) |
C11 | 0.0661 (19) | 0.0656 (19) | 0.0438 (15) | −0.0011 (17) | −0.0047 (14) | 0.0014 (14) |
C12 | 0.0563 (17) | 0.0682 (19) | 0.0401 (13) | −0.0044 (16) | −0.0022 (13) | 0.0022 (14) |
C13 | 0.0639 (18) | 0.0677 (19) | 0.0392 (13) | 0.0054 (18) | −0.0004 (14) | 0.0010 (13) |
O14 | 0.0796 (16) | 0.0810 (16) | 0.0533 (12) | 0.0105 (14) | 0.0111 (12) | −0.0055 (12) |
C14 | 0.0660 (18) | 0.0631 (18) | 0.0433 (14) | 0.0049 (17) | 0.0058 (14) | −0.0025 (14) |
C15 | 0.072 (2) | 0.078 (2) | 0.0466 (15) | 0.007 (2) | −0.0068 (16) | −0.0030 (16) |
C16 | 0.079 (2) | 0.084 (2) | 0.0570 (18) | −0.009 (2) | −0.0086 (19) | −0.0061 (17) |
N17 | 0.086 (2) | 0.0648 (16) | 0.0535 (14) | −0.0051 (17) | −0.0033 (15) | −0.0033 (13) |
C18 | 0.116 (3) | 0.076 (2) | 0.060 (2) | −0.015 (3) | −0.002 (2) | −0.0003 (18) |
C19 | 0.158 (5) | 0.082 (3) | 0.078 (3) | −0.008 (3) | −0.015 (3) | −0.006 (2) |
C20 | 0.194 (6) | 0.097 (3) | 0.098 (3) | 0.040 (5) | 0.013 (4) | −0.012 (3) |
C21 | 0.190 (6) | 0.069 (3) | 0.100 (3) | −0.005 (4) | −0.026 (4) | −0.015 (3) |
C22 | 0.081 (2) | 0.081 (2) | 0.0563 (18) | −0.009 (2) | 0.0032 (19) | 0.0012 (18) |
C23 | 0.078 (2) | 0.086 (2) | 0.0619 (19) | −0.024 (2) | −0.0059 (19) | −0.0016 (19) |
C24 | 0.075 (3) | 0.097 (3) | 0.084 (3) | −0.024 (2) | −0.008 (2) | 0.007 (2) |
C25 | 0.068 (2) | 0.124 (4) | 0.137 (4) | −0.021 (3) | −0.005 (3) | 0.012 (4) |
C26 | 0.078 (3) | 0.141 (5) | 0.154 (5) | −0.027 (3) | −0.039 (3) | 0.053 (5) |
C27 | 0.097 (4) | 0.137 (4) | 0.101 (3) | −0.024 (3) | −0.032 (3) | 0.044 (3) |
C28 | 0.083 (3) | 0.126 (4) | 0.070 (2) | −0.022 (3) | −0.007 (2) | 0.015 (3) |
C1—C2 | 1.378 (5) | C12—C13 | 1.546 (4) |
C1—C11 | 1.387 (4) | C13—C15 | 1.549 (5) |
C1—H1A | 0.9300 | C13—C14 | 1.548 (5) |
C2—C3 | 1.375 (5) | O14—C14 | 1.441 (3) |
C2—H2A | 0.9300 | O14—H14 | 0.8200 |
C3—O3 | 1.370 (4) | C15—C16 | 1.520 (5) |
C3—C4 | 1.397 (4) | C15—H15A | 0.9700 |
O3—C3A | 1.419 (5) | C15—H15B | 0.9700 |
C3A—H3AA | 0.9600 | C16—N17 | 1.460 (5) |
C3A—H3AB | 0.9600 | C16—H16A | 0.9700 |
C3A—H3AC | 0.9600 | C16—H16B | 0.9700 |
C4—O4 | 1.388 (4) | N17—C18 | 1.485 (5) |
C4—C12 | 1.403 (5) | C18—C19 | 1.472 (6) |
O4—C4A | 1.410 (5) | C18—H18A | 0.9700 |
C4A—H4AA | 0.9600 | C18—H18B | 0.9700 |
C4A—H4AB | 0.9600 | C19—C20 | 1.453 (8) |
C4A—H4AC | 0.9600 | C19—C21 | 1.517 (7) |
C5—C6 | 1.492 (5) | C19—H19A | 0.9800 |
C5—C13 | 1.543 (5) | C20—C21 | 1.473 (8) |
C5—H5A | 0.9700 | C20—H20A | 0.9700 |
C5—H5B | 0.9700 | C20—H20B | 0.9700 |
C6—O6 | 1.230 (5) | C21—H21A | 0.9700 |
C6—C7 | 1.487 (5) | C21—H21B | 0.9700 |
C7—C22 | 1.329 (5) | C22—C23 | 1.458 (6) |
C7—C8 | 1.509 (5) | C22—H22A | 0.9300 |
C8—C14 | 1.511 (5) | C23—C24 | 1.380 (6) |
C8—H8A | 0.9700 | C23—C28 | 1.415 (6) |
C8—H8B | 0.9700 | C24—C25 | 1.355 (7) |
C9—N17 | 1.470 (4) | C24—H24A | 0.9300 |
C9—C14 | 1.516 (5) | C25—C26 | 1.393 (8) |
C9—C10 | 1.528 (4) | C25—H25A | 0.9300 |
C9—H9A | 0.9800 | C26—C27 | 1.356 (8) |
C10—C11 | 1.513 (5) | C26—H26A | 0.9300 |
C10—H10A | 0.9700 | C27—C28 | 1.364 (7) |
C10—H10B | 0.9700 | C27—H27A | 0.9300 |
C11—C12 | 1.405 (4) | C28—H28A | 0.9300 |
C2—C1—C11 | 121.7 (3) | C14—O14—H14 | 109.5 |
C2—C1—H1A | 119.2 | O14—C14—C8 | 106.9 (3) |
C11—C1—H1A | 119.2 | O14—C14—C9 | 107.6 (3) |
C3—C2—C1 | 119.7 (3) | C8—C14—C9 | 112.1 (3) |
C3—C2—H2A | 120.2 | O14—C14—C13 | 109.5 (2) |
C1—C2—H2A | 120.2 | C8—C14—C13 | 111.5 (3) |
O3—C3—C2 | 124.7 (3) | C9—C14—C13 | 109.1 (3) |
O3—C3—C4 | 115.9 (3) | C16—C15—C13 | 112.8 (3) |
C2—C3—C4 | 119.5 (3) | C16—C15—H15A | 109.0 |
C3—O3—C3A | 117.5 (3) | C13—C15—H15A | 109.0 |
O3—C3A—H3AA | 109.5 | C16—C15—H15B | 109.0 |
O3—C3A—H3AB | 109.5 | C13—C15—H15B | 109.0 |
H3AA—C3A—H3AB | 109.5 | H15A—C15—H15B | 107.8 |
O3—C3A—H3AC | 109.5 | N17—C16—C15 | 110.1 (3) |
H3AA—C3A—H3AC | 109.5 | N17—C16—H16A | 109.6 |
H3AB—C3A—H3AC | 109.5 | C15—C16—H16A | 109.6 |
O4—C4—C3 | 117.3 (3) | N17—C16—H16B | 109.6 |
O4—C4—C12 | 120.9 (3) | C15—C16—H16B | 109.6 |
C3—C4—C12 | 121.8 (3) | H16A—C16—H16B | 108.2 |
C4—O4—C4A | 116.1 (3) | C16—N17—C9 | 111.6 (3) |
O4—C4A—H4AA | 109.5 | C16—N17—C18 | 112.8 (4) |
O4—C4A—H4AB | 109.5 | C9—N17—C18 | 111.2 (3) |
H4AA—C4A—H4AB | 109.5 | C19—C18—N17 | 113.0 (3) |
O4—C4A—H4AC | 109.5 | C19—C18—H18A | 109.0 |
H4AA—C4A—H4AC | 109.5 | N17—C18—H18A | 109.0 |
H4AB—C4A—H4AC | 109.5 | C19—C18—H18B | 109.0 |
C6—C5—C13 | 116.4 (3) | N17—C18—H18B | 109.0 |
C6—C5—H5A | 108.2 | H18A—C18—H18B | 107.8 |
C13—C5—H5A | 108.2 | C20—C19—C18 | 117.0 (6) |
C6—C5—H5B | 108.2 | C20—C19—C21 | 59.4 (4) |
C13—C5—H5B | 108.2 | C18—C19—C21 | 117.8 (5) |
H5A—C5—H5B | 107.3 | C20—C19—H19A | 116.8 |
O6—C6—C7 | 120.7 (4) | C18—C19—H19A | 116.8 |
O6—C6—C5 | 119.8 (4) | C21—C19—H19A | 116.8 |
C7—C6—C5 | 119.4 (3) | C19—C20—C21 | 62.4 (4) |
C22—C7—C6 | 118.1 (4) | C19—C20—H20A | 117.5 |
C22—C7—C8 | 123.8 (4) | C21—C20—H20A | 117.5 |
C6—C7—C8 | 118.0 (3) | C19—C20—H20B | 117.5 |
C14—C8—C7 | 113.9 (3) | C21—C20—H20B | 117.5 |
C14—C8—H8A | 108.8 | H20A—C20—H20B | 114.6 |
C7—C8—H8A | 108.8 | C20—C21—C19 | 58.2 (4) |
C14—C8—H8B | 108.8 | C20—C21—H21A | 118.0 |
C7—C8—H8B | 108.8 | C19—C21—H21A | 118.0 |
H8A—C8—H8B | 107.7 | C20—C21—H21B | 118.0 |
N17—C9—C14 | 107.2 (3) | C19—C21—H21B | 118.0 |
N17—C9—C10 | 116.4 (3) | H21A—C21—H21B | 115.1 |
C14—C9—C10 | 110.6 (3) | C7—C22—C23 | 129.0 (4) |
N17—C9—H9A | 107.4 | C7—C22—H22A | 115.5 |
C14—C9—H9A | 107.4 | C23—C22—H22A | 115.5 |
C10—C9—H9A | 107.4 | C24—C23—C28 | 117.3 (4) |
C11—C10—C9 | 115.2 (3) | C24—C23—C22 | 120.3 (4) |
C11—C10—H10A | 108.5 | C28—C23—C22 | 122.4 (4) |
C9—C10—H10A | 108.5 | C25—C24—C23 | 122.5 (5) |
C11—C10—H10B | 108.5 | C25—C24—H24A | 118.8 |
C9—C10—H10B | 108.5 | C23—C24—H24A | 118.8 |
H10A—C10—H10B | 107.5 | C24—C25—C26 | 119.3 (5) |
C1—C11—C12 | 119.9 (3) | C24—C25—H25A | 120.4 |
C1—C11—C10 | 116.9 (3) | C26—C25—H25A | 120.4 |
C12—C11—C10 | 123.2 (3) | C27—C26—C25 | 119.5 (5) |
C4—C12—C11 | 117.4 (3) | C27—C26—H26A | 120.3 |
C4—C12—C13 | 123.4 (3) | C25—C26—H26A | 120.3 |
C11—C12—C13 | 118.9 (3) | C26—C27—C28 | 121.7 (5) |
C5—C13—C12 | 116.7 (3) | C26—C27—H27A | 119.1 |
C5—C13—C15 | 108.4 (3) | C28—C27—H27A | 119.1 |
C12—C13—C15 | 107.6 (3) | C27—C28—C23 | 119.7 (5) |
C5—C13—C14 | 106.1 (3) | C27—C28—H28A | 120.2 |
C12—C13—C14 | 108.8 (2) | C23—C28—H28A | 120.2 |
C15—C13—C14 | 109.2 (3) | ||
C11—C1—C2—C3 | 0.5 (6) | C7—C8—C14—C13 | −54.3 (4) |
C1—C2—C3—O3 | 179.6 (3) | N17—C9—C14—O14 | −54.7 (4) |
C1—C2—C3—C4 | −0.8 (5) | C10—C9—C14—O14 | 177.5 (3) |
C2—C3—O3—C3A | −8.6 (5) | N17—C9—C14—C8 | −172.0 (3) |
C4—C3—O3—C3A | 171.8 (4) | C10—C9—C14—C8 | 60.2 (4) |
O3—C3—C4—O4 | 1.1 (4) | N17—C9—C14—C13 | 64.1 (3) |
C2—C3—C4—O4 | −178.5 (3) | C10—C9—C14—C13 | −63.8 (3) |
O3—C3—C4—C12 | 179.0 (3) | C5—C13—C14—O14 | −54.8 (3) |
C2—C3—C4—C12 | −0.7 (5) | C12—C13—C14—O14 | 178.9 (3) |
C3—C4—O4—C4A | −69.4 (4) | C15—C13—C14—O14 | 61.8 (3) |
C12—C4—O4—C4A | 112.7 (4) | C5—C13—C14—C8 | 63.3 (3) |
C13—C5—C6—O6 | −156.1 (3) | C12—C13—C14—C8 | −62.9 (3) |
C13—C5—C6—C7 | 27.8 (4) | C15—C13—C14—C8 | 179.9 (3) |
O6—C6—C7—C22 | −15.4 (5) | C5—C13—C14—C9 | −172.3 (2) |
C5—C6—C7—C22 | 160.8 (3) | C12—C13—C14—C9 | 61.4 (3) |
O6—C6—C7—C8 | 168.3 (3) | C15—C13—C14—C9 | −55.7 (3) |
C5—C6—C7—C8 | −15.5 (4) | C5—C13—C15—C16 | 164.8 (3) |
C22—C7—C8—C14 | −147.4 (4) | C12—C13—C15—C16 | −68.3 (4) |
C6—C7—C8—C14 | 28.7 (4) | C14—C13—C15—C16 | 49.6 (4) |
N17—C9—C10—C11 | −88.0 (4) | C13—C15—C16—N17 | −51.5 (4) |
C14—C9—C10—C11 | 34.5 (4) | C15—C16—N17—C9 | 60.7 (4) |
C2—C1—C11—C12 | 1.3 (5) | C15—C16—N17—C18 | −173.4 (3) |
C2—C1—C11—C10 | −178.7 (3) | C14—C9—N17—C16 | −67.4 (4) |
C9—C10—C11—C1 | 175.2 (3) | C10—C9—N17—C16 | 56.9 (4) |
C9—C10—C11—C12 | −4.9 (5) | C14—C9—N17—C18 | 165.7 (3) |
O4—C4—C12—C11 | −179.9 (3) | C10—C9—N17—C18 | −70.0 (4) |
C3—C4—C12—C11 | 2.3 (5) | C16—N17—C18—C19 | 69.8 (5) |
O4—C4—C12—C13 | −6.8 (5) | C9—N17—C18—C19 | −164.0 (4) |
C3—C4—C12—C13 | 175.4 (3) | N17—C18—C19—C20 | 79.1 (6) |
C1—C11—C12—C4 | −2.6 (5) | N17—C18—C19—C21 | 146.9 (5) |
C10—C11—C12—C4 | 177.4 (3) | C18—C19—C20—C21 | 107.8 (6) |
C1—C11—C12—C13 | −176.0 (3) | C18—C19—C21—C20 | −106.5 (7) |
C10—C11—C12—C13 | 4.0 (5) | C6—C7—C22—C23 | −175.8 (4) |
C6—C5—C13—C12 | 71.4 (4) | C8—C7—C22—C23 | 0.2 (6) |
C6—C5—C13—C15 | −167.0 (3) | C7—C22—C23—C24 | 133.9 (4) |
C6—C5—C13—C14 | −49.9 (4) | C7—C22—C23—C28 | −44.1 (7) |
C4—C12—C13—C5 | 35.4 (4) | C28—C23—C24—C25 | 2.4 (7) |
C11—C12—C13—C5 | −151.6 (3) | C22—C23—C24—C25 | −175.7 (5) |
C4—C12—C13—C15 | −86.5 (4) | C23—C24—C25—C26 | −2.7 (8) |
C11—C12—C13—C15 | 86.5 (4) | C24—C25—C26—C27 | 0.5 (10) |
C4—C12—C13—C14 | 155.3 (3) | C25—C26—C27—C28 | 2.1 (10) |
C11—C12—C13—C14 | −31.7 (4) | C26—C27—C28—C23 | −2.4 (9) |
C7—C8—C14—O14 | 65.4 (4) | C24—C23—C28—C27 | 0.2 (7) |
C7—C8—C14—C9 | −176.9 (3) | C22—C23—C28—C27 | 178.3 (5) |