Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805006446/ci6523sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805006446/ci6523Isup2.hkl |
CCDC reference: 240983
Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXTL.
[Sb(C6H5)3(C9H7NO3)] | F(000) = 2464 |
Mr = 615.14 | Dx = 1.518 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 1019 reflections |
a = 21.071 (6) Å | θ = 2.8–24.2° |
b = 10.944 (3) Å | µ = 1.25 mm−1 |
c = 25.569 (8) Å | T = 293 K |
β = 114.109 (5)° | Block, colourless |
V = 5382 (3) Å3 | 0.22 × 0.20 × 0.16 mm |
Z = 8 |
Bruker SMART CCD area-detector diffractometer | 9460 independent reflections |
Radiation source: fine-focus sealed tube | 6705 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.041 |
φ and ω scans | θmax = 25.0°, θmin = 1.1° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −25→22 |
Tmin = 0.726, Tmax = 0.818 | k = −13→12 |
27059 measured reflections | l = −23→30 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.042 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.097 | H-atom parameters constrained |
S = 1.08 | w = 1/[σ2(Fo2) + (0.0341P)2 + 5.6596P] where P = (Fo2 + 2Fc2)/3 |
9460 reflections | (Δ/σ)max = 0.005 |
716 parameters | Δρmax = 0.65 e Å−3 |
106 restraints | Δρmin = −0.53 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Sb1 | 0.401069 (17) | 0.43086 (3) | 0.160734 (13) | 0.03832 (10) | |
Sb2 | 0.097829 (17) | 0.83142 (3) | 0.846904 (13) | 0.03971 (10) | |
O1 | 0.49944 (16) | 0.5007 (3) | 0.19483 (13) | 0.0453 (8) | |
O2 | 0.32116 (17) | 0.3024 (3) | 0.13511 (14) | 0.0499 (9) | |
O3 | 0.2903 (2) | 0.1097 (4) | 0.1323 (2) | 0.0924 (15) | |
O4 | −0.00341 (17) | 0.7791 (3) | 0.80617 (13) | 0.0459 (8) | |
O5 | 0.18453 (18) | 0.9461 (3) | 0.87989 (15) | 0.0531 (9) | |
O6 | 0.2290 (2) | 1.1258 (4) | 0.8746 (2) | 0.0857 (14) | |
N1 | 0.4567 (2) | 0.2497 (4) | 0.17339 (15) | 0.0420 (10) | |
N2 | 0.0535 (2) | 1.0216 (4) | 0.83175 (16) | 0.0422 (10) | |
C1 | 0.5540 (3) | 0.4579 (5) | 0.18561 (19) | 0.0442 (13) | |
C2 | 0.6063 (3) | 0.5429 (6) | 0.1903 (2) | 0.0550 (14) | |
H2 | 0.6005 | 0.6245 | 0.1976 | 0.066* | |
C3 | 0.6652 (3) | 0.5078 (7) | 0.1844 (3) | 0.0700 (18) | |
H3 | 0.6991 | 0.5656 | 0.1881 | 0.084* | |
C4 | 0.6750 (3) | 0.3884 (7) | 0.1731 (3) | 0.077 (2) | |
H4 | 0.7150 | 0.3654 | 0.1687 | 0.092* | |
C5 | 0.6253 (3) | 0.3038 (6) | 0.1684 (3) | 0.0682 (17) | |
H5 | 0.6324 | 0.2229 | 0.1610 | 0.082* | |
C6 | 0.5634 (3) | 0.3349 (5) | 0.1743 (2) | 0.0497 (13) | |
C7 | 0.5158 (3) | 0.2368 (5) | 0.1712 (2) | 0.0508 (14) | |
H7 | 0.5295 | 0.1578 | 0.1673 | 0.061* | |
C8 | 0.4106 (3) | 0.1485 (5) | 0.1695 (2) | 0.0561 (15) | |
H8A | 0.4225 | 0.1150 | 0.2075 | 0.067* | |
H8B | 0.4173 | 0.0847 | 0.1459 | 0.067* | |
C9 | 0.3351 (3) | 0.1869 (5) | 0.1442 (2) | 0.0531 (14) | |
C10 | 0.4096 (3) | 0.4076 (4) | 0.2469 (2) | 0.0429 (12) | |
C11 | 0.3516 (3) | 0.4222 (5) | 0.2587 (3) | 0.0673 (17) | |
H11 | 0.3090 | 0.4421 | 0.2294 | 0.081* | |
C12 | 0.3567 (5) | 0.4071 (6) | 0.3144 (4) | 0.092 (2) | |
H12 | 0.3176 | 0.4169 | 0.3221 | 0.111* | |
C13 | 0.4193 (6) | 0.3778 (7) | 0.3579 (3) | 0.099 (3) | |
H13 | 0.4224 | 0.3676 | 0.3949 | 0.119* | |
C14 | 0.4771 (4) | 0.3634 (6) | 0.3471 (3) | 0.081 (2) | |
H14 | 0.5195 | 0.3441 | 0.3768 | 0.097* | |
C15 | 0.4727 (3) | 0.3776 (5) | 0.2919 (2) | 0.0564 (15) | |
H15 | 0.5122 | 0.3672 | 0.2847 | 0.068* | |
C16 | 0.3396 (2) | 0.5933 (4) | 0.1446 (2) | 0.0408 (12) | |
C17 | 0.2796 (3) | 0.6040 (5) | 0.0950 (2) | 0.0562 (15) | |
H17 | 0.2653 | 0.5396 | 0.0690 | 0.067* | |
C18 | 0.2408 (3) | 0.7100 (6) | 0.0838 (2) | 0.0649 (16) | |
H18 | 0.2000 | 0.7158 | 0.0506 | 0.078* | |
C19 | 0.2617 (3) | 0.8067 (5) | 0.1208 (2) | 0.0606 (15) | |
H19 | 0.2356 | 0.8782 | 0.1128 | 0.073* | |
C20 | 0.3214 (3) | 0.7974 (5) | 0.1700 (3) | 0.0648 (17) | |
H20 | 0.3362 | 0.8631 | 0.1952 | 0.078* | |
C21 | 0.3594 (3) | 0.6909 (5) | 0.1821 (2) | 0.0550 (14) | |
H21 | 0.3991 | 0.6845 | 0.2161 | 0.066* | |
C22 | 0.4016 (3) | 0.4263 (5) | 0.0770 (2) | 0.0470 (13) | |
C23 | 0.4205 (3) | 0.5313 (6) | 0.0571 (3) | 0.0700 (18) | |
H23 | 0.4321 | 0.6015 | 0.0796 | 0.084* | |
C24 | 0.4221 (4) | 0.5317 (9) | 0.0030 (3) | 0.104 (3) | |
H24 | 0.4349 | 0.6024 | −0.0105 | 0.125* | |
C25 | 0.4048 (4) | 0.4273 (12) | −0.0306 (3) | 0.116 (4) | |
H25 | 0.4071 | 0.4273 | −0.0661 | 0.139* | |
C26 | 0.3846 (4) | 0.3252 (9) | −0.0116 (3) | 0.102 (3) | |
H26 | 0.3716 | 0.2560 | −0.0347 | 0.122* | |
C27 | 0.3831 (3) | 0.3236 (6) | 0.0419 (2) | 0.0681 (17) | |
H27 | 0.3696 | 0.2527 | 0.0547 | 0.082* | |
C28 | −0.0572 (3) | 0.8331 (5) | 0.81284 (19) | 0.0421 (12) | |
C29 | −0.1129 (3) | 0.7604 (6) | 0.8082 (2) | 0.0564 (15) | |
H29 | −0.1105 | 0.6765 | 0.8036 | 0.068* | |
C30 | −0.1720 (3) | 0.8104 (7) | 0.8104 (2) | 0.0706 (18) | |
H30 | −0.2090 | 0.7598 | 0.8067 | 0.085* | |
C31 | −0.1767 (3) | 0.9341 (7) | 0.8179 (3) | 0.0748 (19) | |
H31 | −0.2167 | 0.9671 | 0.8193 | 0.090* | |
C32 | −0.1223 (3) | 1.0075 (6) | 0.8232 (2) | 0.0594 (15) | |
H32 | −0.1257 | 1.0911 | 0.8281 | 0.071* | |
C33 | −0.0612 (3) | 0.9611 (5) | 0.8214 (2) | 0.0461 (13) | |
C34 | −0.0076 (3) | 1.0480 (4) | 0.82639 (19) | 0.0454 (13) | |
H34 | −0.0186 | 1.1305 | 0.8256 | 0.054* | |
C35 | 0.1061 (3) | 1.1117 (5) | 0.8359 (2) | 0.0553 (14) | |
H35A | 0.1014 | 1.1820 | 0.8572 | 0.066* | |
H35B | 0.0985 | 1.1390 | 0.7977 | 0.066* | |
C36 | 0.1794 (3) | 1.0607 (5) | 0.8653 (2) | 0.0568 (15) | |
C37 | 0.0995 (3) | 0.8549 (4) | 0.7638 (2) | 0.0507 (14) | |
C38 | 0.0400 (4) | 0.8864 (5) | 0.7159 (2) | 0.0656 (17) | |
H38 | −0.0020 | 0.8968 | 0.7192 | 0.079* | |
C39 | 0.0431 (5) | 0.9023 (6) | 0.6631 (3) | 0.098 (3) | |
H39 | 0.0035 | 0.9237 | 0.6310 | 0.118* | |
C40 | 0.1058 (7) | 0.8860 (8) | 0.6590 (4) | 0.120 (4) | |
H40 | 0.1078 | 0.8949 | 0.6235 | 0.144* | |
C41 | 0.1652 (5) | 0.8567 (7) | 0.7060 (4) | 0.103 (3) | |
H41 | 0.2074 | 0.8482 | 0.7027 | 0.124* | |
C42 | 0.1613 (4) | 0.8402 (5) | 0.7580 (3) | 0.0706 (18) | |
H42 | 0.2011 | 0.8186 | 0.7898 | 0.085* | |
C43 | 0.0850 (3) | 0.8403 (4) | 0.9265 (2) | 0.0430 (12) | |
C44 | 0.1071 (3) | 0.9374 (5) | 0.9638 (2) | 0.0652 (17) | |
H44 | 0.1303 | 1.0025 | 0.9560 | 0.078* | |
C45 | 0.0946 (4) | 0.9380 (6) | 1.0136 (3) | 0.083 (2) | |
H45 | 0.1091 | 1.0042 | 1.0385 | 0.099* | |
C46 | 0.0616 (4) | 0.8433 (8) | 1.0259 (3) | 0.082 (2) | |
H46 | 0.0537 | 0.8442 | 1.0590 | 0.099* | |
C47 | 0.0404 (3) | 0.7470 (7) | 0.9893 (3) | 0.078 (2) | |
H47 | 0.0174 | 0.6822 | 0.9976 | 0.094* | |
C48 | 0.0522 (3) | 0.7437 (6) | 0.9398 (2) | 0.0593 (15) | |
H48 | 0.0381 | 0.6764 | 0.9155 | 0.071* | |
C49 | 0.1494 (2) | 0.6583 (4) | 0.86485 (19) | 0.0397 (11) | |
C50 | 0.1983 (3) | 0.6321 (5) | 0.9193 (2) | 0.0555 (15) | |
H50 | 0.2093 | 0.6904 | 0.9481 | 0.067* | |
C51 | 0.2308 (3) | 0.5196 (5) | 0.9311 (2) | 0.0631 (16) | |
H51 | 0.2645 | 0.5030 | 0.9676 | 0.076* | |
C52 | 0.2133 (3) | 0.4320 (5) | 0.8887 (2) | 0.0559 (15) | |
H52 | 0.2343 | 0.3555 | 0.8968 | 0.067* | |
C53 | 0.1652 (3) | 0.4576 (5) | 0.8348 (2) | 0.0534 (14) | |
H53 | 0.1533 | 0.3987 | 0.8062 | 0.064* | |
C54 | 0.1344 (3) | 0.5714 (5) | 0.8231 (2) | 0.0487 (13) | |
H54 | 0.1027 | 0.5893 | 0.7861 | 0.058* | |
C55 | 0.1516 (13) | 0.3056 (14) | 0.0398 (6) | 0.121 (9) | 0.557 (7) |
H55A | 0.1902 | 0.3144 | 0.0769 | 0.146* | 0.557 (7) |
H55B | 0.1188 | 0.2485 | 0.0440 | 0.146* | 0.557 (7) |
Cl1 | 0.1821 (4) | 0.2463 (4) | −0.0079 (2) | 0.133 (2) | 0.557 (7) |
Cl2 | 0.1115 (2) | 0.4453 (4) | 0.0187 (3) | 0.131 (2) | 0.557 (7) |
C55' | 0.1494 (18) | 0.2770 (16) | 0.0409 (4) | 0.126 (12) | 0.443 (7) |
H55C | 0.1300 | 0.2092 | 0.0540 | 0.152* | 0.443 (7) |
H55D | 0.1994 | 0.2656 | 0.0560 | 0.152* | 0.443 (7) |
Cl1' | 0.1156 (6) | 0.2765 (8) | −0.0328 (3) | 0.166 (4) | 0.443 (7) |
Cl2' | 0.1315 (4) | 0.4116 (6) | 0.0671 (4) | 0.133 (3) | 0.443 (7) |
C56 | 0.3513 (15) | 0.622 (2) | 0.4893 (19) | 0.25 (2) | 0.414 (4) |
H56A | 0.3613 | 0.7002 | 0.5084 | 0.299* | 0.414 (4) |
H56B | 0.3157 | 0.6338 | 0.4509 | 0.299* | 0.414 (4) |
Cl3 | 0.3199 (4) | 0.5244 (7) | 0.5260 (3) | 0.114 (2) | 0.414 (4) |
Cl4 | 0.4256 (4) | 0.5664 (11) | 0.4847 (4) | 0.161 (4) | 0.414 (4) |
C56' | 0.3422 (9) | 0.565 (2) | 0.4674 (8) | 0.067 (7) | 0.330 (6) |
H56C | 0.3027 | 0.5869 | 0.4326 | 0.080* | 0.330 (6) |
H56D | 0.3487 | 0.4772 | 0.4670 | 0.080* | 0.330 (6) |
Cl3' | 0.3251 (5) | 0.6030 (10) | 0.5257 (4) | 0.110 (3) | 0.330 (6) |
Cl4' | 0.4153 (8) | 0.6380 (13) | 0.4691 (7) | 0.201 (7) | 0.330 (6) |
C56" | 0.3464 (7) | 0.539 (2) | 0.4841 (15) | 0.097 (15) | 0.256 (4) |
H56E | 0.3327 | 0.5600 | 0.5148 | 0.117* | 0.256 (4) |
H56F | 0.3118 | 0.4843 | 0.4580 | 0.117* | 0.256 (4) |
Cl3" | 0.4261 (4) | 0.4676 (7) | 0.5119 (4) | 0.101 (3) | 0.256 (4) |
Cl4" | 0.3500 (6) | 0.6704 (9) | 0.4479 (5) | 0.156 (5) | 0.256 (4) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Sb1 | 0.0377 (2) | 0.0385 (2) | 0.03867 (19) | 0.00309 (16) | 0.01550 (15) | 0.00003 (15) |
Sb2 | 0.0435 (2) | 0.03455 (19) | 0.04037 (19) | 0.00382 (16) | 0.01647 (16) | 0.00048 (15) |
O1 | 0.040 (2) | 0.046 (2) | 0.051 (2) | −0.0021 (17) | 0.0198 (17) | −0.0050 (16) |
O2 | 0.045 (2) | 0.045 (2) | 0.057 (2) | −0.0038 (18) | 0.0182 (18) | −0.0056 (17) |
O3 | 0.079 (3) | 0.058 (3) | 0.160 (5) | −0.019 (3) | 0.069 (3) | −0.012 (3) |
O4 | 0.044 (2) | 0.042 (2) | 0.048 (2) | 0.0026 (17) | 0.0144 (17) | −0.0047 (16) |
O5 | 0.052 (2) | 0.045 (2) | 0.059 (2) | −0.0033 (18) | 0.0192 (18) | −0.0041 (18) |
O6 | 0.075 (3) | 0.054 (3) | 0.137 (4) | −0.023 (2) | 0.053 (3) | −0.008 (3) |
N1 | 0.047 (3) | 0.043 (3) | 0.035 (2) | 0.003 (2) | 0.016 (2) | 0.0013 (18) |
N2 | 0.047 (3) | 0.036 (2) | 0.042 (2) | 0.002 (2) | 0.016 (2) | −0.0010 (18) |
C1 | 0.038 (3) | 0.062 (4) | 0.029 (3) | 0.006 (3) | 0.010 (2) | 0.006 (2) |
C2 | 0.046 (3) | 0.071 (4) | 0.048 (3) | 0.002 (3) | 0.019 (3) | 0.011 (3) |
C3 | 0.050 (4) | 0.092 (5) | 0.070 (4) | 0.003 (4) | 0.026 (3) | 0.020 (4) |
C4 | 0.044 (4) | 0.109 (6) | 0.089 (5) | 0.014 (4) | 0.038 (4) | 0.023 (4) |
C5 | 0.063 (4) | 0.075 (4) | 0.073 (4) | 0.029 (4) | 0.035 (3) | 0.016 (3) |
C6 | 0.043 (3) | 0.064 (4) | 0.042 (3) | 0.012 (3) | 0.017 (2) | 0.008 (3) |
C7 | 0.059 (4) | 0.052 (3) | 0.042 (3) | 0.020 (3) | 0.022 (3) | 0.004 (2) |
C8 | 0.076 (4) | 0.040 (3) | 0.058 (3) | 0.005 (3) | 0.033 (3) | 0.007 (3) |
C9 | 0.057 (4) | 0.048 (4) | 0.063 (4) | −0.004 (3) | 0.035 (3) | −0.004 (3) |
C10 | 0.054 (3) | 0.040 (3) | 0.038 (3) | −0.005 (3) | 0.022 (3) | −0.001 (2) |
C11 | 0.080 (4) | 0.066 (4) | 0.075 (4) | 0.002 (3) | 0.051 (4) | 0.003 (3) |
C12 | 0.141 (7) | 0.080 (5) | 0.097 (6) | −0.004 (5) | 0.090 (6) | −0.005 (4) |
C13 | 0.181 (9) | 0.081 (5) | 0.057 (5) | −0.017 (6) | 0.071 (6) | −0.005 (4) |
C14 | 0.126 (6) | 0.068 (4) | 0.039 (4) | −0.009 (4) | 0.024 (4) | −0.001 (3) |
C15 | 0.071 (4) | 0.049 (3) | 0.048 (3) | 0.000 (3) | 0.022 (3) | 0.000 (3) |
C16 | 0.035 (3) | 0.043 (3) | 0.043 (3) | 0.007 (2) | 0.015 (2) | 0.002 (2) |
C17 | 0.056 (4) | 0.051 (3) | 0.051 (3) | 0.010 (3) | 0.012 (3) | −0.012 (3) |
C18 | 0.053 (4) | 0.074 (4) | 0.050 (3) | 0.015 (3) | 0.003 (3) | −0.004 (3) |
C19 | 0.063 (4) | 0.048 (4) | 0.068 (4) | 0.018 (3) | 0.024 (3) | 0.003 (3) |
C20 | 0.067 (4) | 0.044 (3) | 0.068 (4) | 0.004 (3) | 0.012 (3) | −0.013 (3) |
C21 | 0.058 (4) | 0.042 (3) | 0.048 (3) | 0.007 (3) | 0.004 (3) | −0.008 (3) |
C22 | 0.045 (3) | 0.062 (4) | 0.037 (3) | 0.017 (3) | 0.019 (2) | 0.009 (3) |
C23 | 0.058 (4) | 0.093 (5) | 0.062 (4) | 0.009 (4) | 0.027 (3) | 0.021 (4) |
C24 | 0.071 (5) | 0.164 (9) | 0.085 (6) | 0.020 (6) | 0.040 (5) | 0.061 (6) |
C25 | 0.083 (6) | 0.220 (12) | 0.051 (5) | 0.049 (7) | 0.035 (4) | 0.036 (6) |
C26 | 0.098 (6) | 0.165 (8) | 0.038 (4) | 0.044 (6) | 0.023 (4) | −0.006 (5) |
C27 | 0.070 (4) | 0.085 (5) | 0.046 (3) | 0.022 (4) | 0.020 (3) | 0.000 (3) |
C28 | 0.041 (3) | 0.052 (3) | 0.030 (2) | 0.006 (3) | 0.011 (2) | 0.003 (2) |
C29 | 0.057 (4) | 0.063 (4) | 0.049 (3) | −0.002 (3) | 0.022 (3) | 0.007 (3) |
C30 | 0.053 (4) | 0.099 (6) | 0.064 (4) | −0.004 (4) | 0.028 (3) | 0.004 (4) |
C31 | 0.060 (4) | 0.095 (6) | 0.079 (5) | 0.010 (4) | 0.038 (4) | −0.003 (4) |
C32 | 0.064 (4) | 0.064 (4) | 0.051 (3) | 0.017 (3) | 0.024 (3) | −0.001 (3) |
C33 | 0.053 (3) | 0.049 (3) | 0.036 (3) | 0.010 (3) | 0.018 (2) | 0.006 (2) |
C34 | 0.068 (4) | 0.029 (3) | 0.037 (3) | 0.016 (3) | 0.019 (3) | 0.005 (2) |
C35 | 0.075 (4) | 0.036 (3) | 0.057 (3) | −0.002 (3) | 0.029 (3) | −0.003 (3) |
C36 | 0.068 (4) | 0.045 (4) | 0.063 (4) | −0.008 (3) | 0.032 (3) | −0.010 (3) |
C37 | 0.076 (4) | 0.035 (3) | 0.051 (3) | 0.007 (3) | 0.036 (3) | 0.000 (2) |
C38 | 0.099 (5) | 0.044 (3) | 0.052 (4) | 0.001 (3) | 0.029 (4) | 0.003 (3) |
C39 | 0.164 (9) | 0.067 (5) | 0.053 (4) | −0.002 (5) | 0.034 (5) | 0.007 (3) |
C40 | 0.244 (14) | 0.071 (5) | 0.075 (6) | −0.031 (7) | 0.096 (8) | −0.005 (4) |
C41 | 0.166 (9) | 0.077 (5) | 0.123 (7) | −0.008 (6) | 0.116 (7) | −0.009 (5) |
C42 | 0.100 (5) | 0.051 (4) | 0.090 (5) | 0.005 (4) | 0.069 (4) | 0.000 (3) |
C43 | 0.046 (3) | 0.039 (3) | 0.042 (3) | 0.011 (2) | 0.016 (2) | 0.003 (2) |
C44 | 0.094 (5) | 0.049 (4) | 0.051 (3) | 0.012 (3) | 0.028 (3) | 0.002 (3) |
C45 | 0.132 (7) | 0.066 (5) | 0.054 (4) | 0.027 (5) | 0.041 (4) | −0.004 (3) |
C46 | 0.090 (5) | 0.111 (6) | 0.054 (4) | 0.037 (5) | 0.037 (4) | 0.015 (4) |
C47 | 0.063 (4) | 0.113 (6) | 0.064 (4) | 0.001 (4) | 0.031 (4) | 0.022 (4) |
C48 | 0.060 (4) | 0.067 (4) | 0.050 (3) | −0.003 (3) | 0.022 (3) | 0.005 (3) |
C49 | 0.046 (3) | 0.037 (3) | 0.037 (3) | 0.005 (2) | 0.018 (2) | 0.001 (2) |
C50 | 0.069 (4) | 0.050 (3) | 0.044 (3) | 0.009 (3) | 0.019 (3) | −0.009 (3) |
C51 | 0.068 (4) | 0.065 (4) | 0.046 (3) | 0.019 (3) | 0.013 (3) | 0.007 (3) |
C52 | 0.063 (4) | 0.036 (3) | 0.073 (4) | 0.009 (3) | 0.032 (3) | 0.009 (3) |
C53 | 0.063 (4) | 0.038 (3) | 0.051 (3) | −0.001 (3) | 0.015 (3) | −0.011 (3) |
C54 | 0.046 (3) | 0.049 (3) | 0.041 (3) | 0.001 (3) | 0.008 (2) | −0.007 (3) |
C55 | 0.117 (12) | 0.104 (11) | 0.126 (12) | 0.000 (8) | 0.032 (8) | −0.018 (8) |
Cl1 | 0.175 (6) | 0.120 (4) | 0.115 (4) | −0.044 (3) | 0.069 (4) | −0.024 (3) |
Cl2 | 0.105 (3) | 0.114 (3) | 0.161 (5) | −0.016 (3) | 0.040 (3) | 0.002 (3) |
C55' | 0.126 (15) | 0.118 (14) | 0.124 (15) | 0.002 (9) | 0.040 (9) | −0.005 (9) |
Cl1' | 0.198 (8) | 0.190 (6) | 0.141 (5) | −0.023 (6) | 0.100 (5) | −0.024 (4) |
Cl2' | 0.147 (5) | 0.101 (4) | 0.158 (6) | −0.021 (4) | 0.069 (5) | −0.039 (4) |
C56 | 0.23 (2) | 0.27 (2) | 0.25 (2) | 0.001 (10) | 0.097 (13) | −0.001 (10) |
Cl3 | 0.135 (5) | 0.127 (5) | 0.088 (4) | 0.033 (5) | 0.053 (3) | 0.018 (4) |
Cl4 | 0.101 (4) | 0.216 (8) | 0.154 (6) | 0.039 (5) | 0.040 (4) | −0.053 (6) |
C56' | 0.053 (10) | 0.080 (10) | 0.060 (9) | −0.011 (8) | 0.017 (7) | −0.003 (8) |
Cl3' | 0.104 (5) | 0.143 (7) | 0.086 (5) | 0.029 (5) | 0.043 (4) | −0.010 (5) |
Cl4' | 0.226 (11) | 0.181 (9) | 0.196 (9) | −0.035 (8) | 0.088 (8) | 0.025 (7) |
C56" | 0.084 (17) | 0.092 (18) | 0.108 (18) | −0.018 (9) | 0.030 (11) | −0.001 (10) |
Cl3" | 0.101 (6) | 0.079 (5) | 0.101 (6) | 0.014 (4) | 0.017 (4) | −0.002 (4) |
Cl4" | 0.109 (7) | 0.131 (7) | 0.187 (9) | −0.010 (6) | 0.021 (6) | 0.062 (6) |
Sb1—O1 | 2.041 (3) | C27—H27 | 0.93 |
Sb1—O2 | 2.083 (3) | C28—C29 | 1.382 (7) |
Sb1—C16 | 2.138 (5) | C28—C33 | 1.426 (7) |
Sb1—C22 | 2.147 (5) | C29—C30 | 1.382 (8) |
Sb1—C10 | 2.151 (5) | C29—H29 | 0.93 |
Sb1—N1 | 2.259 (4) | C30—C31 | 1.377 (9) |
Sb2—O4 | 2.037 (3) | C30—H30 | 0.93 |
Sb2—O5 | 2.089 (4) | C31—C32 | 1.362 (8) |
Sb2—C49 | 2.139 (5) | C31—H31 | 0.93 |
Sb2—C37 | 2.156 (5) | C32—C33 | 1.400 (7) |
Sb2—C43 | 2.162 (5) | C32—H32 | 0.93 |
Sb2—N2 | 2.249 (4) | C33—C34 | 1.444 (7) |
O1—C1 | 1.349 (5) | C34—H34 | 0.93 |
O2—C9 | 1.298 (6) | C35—C36 | 1.521 (8) |
O3—C9 | 1.210 (6) | C35—H35A | 0.97 |
O4—C28 | 1.350 (5) | C35—H35B | 0.97 |
O5—C36 | 1.300 (6) | C37—C42 | 1.379 (7) |
O6—C36 | 1.207 (6) | C37—C38 | 1.391 (8) |
N1—C7 | 1.277 (6) | C38—C39 | 1.388 (9) |
N1—C8 | 1.449 (6) | C38—H38 | 0.93 |
N2—C34 | 1.270 (6) | C39—C40 | 1.378 (12) |
N2—C35 | 1.455 (6) | C39—H39 | 0.93 |
C1—C6 | 1.408 (7) | C40—C41 | 1.373 (12) |
C1—C2 | 1.408 (7) | C40—H40 | 0.93 |
C2—C3 | 1.366 (7) | C41—C42 | 1.378 (9) |
C2—H2 | 0.93 | C41—H41 | 0.93 |
C3—C4 | 1.372 (9) | C42—H42 | 0.93 |
C3—H3 | 0.93 | C43—C44 | 1.376 (7) |
C4—C5 | 1.366 (8) | C43—C48 | 1.378 (7) |
C4—H4 | 0.93 | C44—C45 | 1.402 (8) |
C5—C6 | 1.415 (7) | C44—H44 | 0.93 |
C5—H5 | 0.93 | C45—C46 | 1.354 (9) |
C6—C7 | 1.449 (7) | C45—H45 | 0.93 |
C7—H7 | 0.93 | C46—C47 | 1.356 (9) |
C8—C9 | 1.512 (7) | C46—H46 | 0.93 |
C8—H8A | 0.97 | C47—C48 | 1.390 (7) |
C8—H8B | 0.97 | C47—H47 | 0.93 |
C10—C11 | 1.382 (7) | C48—H48 | 0.93 |
C10—C15 | 1.397 (7) | C49—C54 | 1.367 (6) |
C11—C12 | 1.394 (8) | C49—C50 | 1.381 (7) |
C11—H11 | 0.93 | C50—C51 | 1.381 (7) |
C12—C13 | 1.371 (10) | C50—H50 | 0.93 |
C12—H12 | 0.93 | C51—C52 | 1.380 (7) |
C13—C14 | 1.364 (10) | C51—H51 | 0.93 |
C13—H13 | 0.93 | C52—C53 | 1.365 (7) |
C14—C15 | 1.385 (7) | C52—H52 | 0.93 |
C14—H14 | 0.93 | C53—C54 | 1.380 (7) |
C15—H15 | 0.93 | C53—H53 | 0.93 |
C16—C21 | 1.381 (7) | C54—H54 | 0.93 |
C16—C17 | 1.384 (7) | C55—Cl1 | 1.720 (5) |
C17—C18 | 1.379 (7) | C55—Cl2 | 1.724 (5) |
C17—H17 | 0.93 | C55—H55A | 0.97 |
C18—C19 | 1.368 (7) | C55—H55B | 0.97 |
C18—H18 | 0.93 | C55'—Cl2' | 1.722 (5) |
C19—C20 | 1.372 (7) | C55'—Cl1' | 1.722 (5) |
C19—H19 | 0.93 | C55'—H55C | 0.97 |
C20—C21 | 1.375 (7) | C55'—H55D | 0.97 |
C20—H20 | 0.93 | C56—Cl3 | 1.719 (5) |
C21—H21 | 0.93 | C56—Cl4 | 1.726 (5) |
C22—C23 | 1.380 (8) | C56—H56A | 0.97 |
C22—C27 | 1.391 (7) | C56—H56B | 0.97 |
C23—C24 | 1.397 (9) | C56'—Cl3' | 1.720 (5) |
C23—H23 | 0.93 | C56'—Cl4' | 1.722 (5) |
C24—C25 | 1.385 (12) | C56'—H56C | 0.97 |
C24—H24 | 0.93 | C56'—H56D | 0.97 |
C25—C26 | 1.354 (12) | C56"—Cl3" | 1.722 (5) |
C25—H25 | 0.93 | C56"—Cl4" | 1.724 (5) |
C26—C27 | 1.381 (8) | C56"—H56E | 0.97 |
C26—H26 | 0.93 | C56"—H56F | 0.97 |
O1—Sb1—O2 | 159.49 (14) | C25—C26—H26 | 119.9 |
O1—Sb1—C16 | 101.55 (16) | C27—C26—H26 | 119.9 |
O2—Sb1—C16 | 98.78 (16) | C26—C27—C22 | 121.0 (7) |
O1—Sb1—C22 | 90.96 (17) | C26—C27—H27 | 119.5 |
O2—Sb1—C22 | 90.19 (18) | C22—C27—H27 | 119.5 |
C16—Sb1—C22 | 94.37 (18) | O4—C28—C29 | 117.7 (5) |
O1—Sb1—C10 | 87.81 (16) | O4—C28—C33 | 123.7 (5) |
O2—Sb1—C10 | 87.73 (16) | C29—C28—C33 | 118.5 (5) |
C16—Sb1—C10 | 94.99 (18) | C30—C29—C28 | 121.1 (6) |
C22—Sb1—C10 | 170.62 (19) | C30—C29—H29 | 119.5 |
O1—Sb1—N1 | 83.71 (14) | C28—C29—H29 | 119.5 |
O2—Sb1—N1 | 76.01 (14) | C31—C30—C29 | 120.9 (6) |
C16—Sb1—N1 | 174.70 (17) | C31—C30—H30 | 119.6 |
C22—Sb1—N1 | 84.75 (16) | C29—C30—H30 | 119.6 |
C10—Sb1—N1 | 85.87 (16) | C32—C31—C30 | 119.2 (6) |
O4—Sb2—O5 | 159.35 (14) | C32—C31—H31 | 120.4 |
O4—Sb2—C49 | 101.26 (16) | C30—C31—H31 | 120.4 |
O5—Sb2—C49 | 99.29 (17) | C31—C32—C33 | 122.0 (6) |
O4—Sb2—C37 | 87.97 (18) | C31—C32—H32 | 119.0 |
O5—Sb2—C37 | 87.87 (18) | C33—C32—H32 | 119.0 |
C49—Sb2—C37 | 96.07 (18) | C32—C33—C28 | 118.4 (5) |
O4—Sb2—C43 | 89.22 (16) | C32—C33—C34 | 117.0 (5) |
O5—Sb2—C43 | 91.03 (17) | C28—C33—C34 | 124.6 (5) |
C49—Sb2—C43 | 94.93 (17) | N2—C34—C33 | 125.6 (5) |
C37—Sb2—C43 | 168.98 (18) | N2—C34—H34 | 117.2 |
O4—Sb2—N2 | 84.11 (14) | C33—C34—H34 | 117.2 |
O5—Sb2—N2 | 75.34 (14) | N2—C35—C36 | 112.1 (4) |
C49—Sb2—N2 | 174.63 (17) | N2—C35—H35A | 109.2 |
C37—Sb2—N2 | 83.83 (16) | C36—C35—H35A | 109.2 |
C43—Sb2—N2 | 85.28 (16) | N2—C35—H35B | 109.2 |
C1—O1—Sb1 | 125.8 (3) | C36—C35—H35B | 109.2 |
C9—O2—Sb1 | 120.4 (3) | H35A—C35—H35B | 107.9 |
C28—O4—Sb2 | 124.8 (3) | O6—C36—O5 | 123.3 (6) |
C36—O5—Sb2 | 120.5 (4) | O6—C36—C35 | 120.2 (5) |
C7—N1—C8 | 123.4 (5) | O5—C36—C35 | 116.4 (5) |
C7—N1—Sb1 | 123.3 (4) | C42—C37—C38 | 119.0 (5) |
C8—N1—Sb1 | 111.5 (3) | C42—C37—Sb2 | 119.2 (4) |
C34—N2—C35 | 124.2 (4) | C38—C37—Sb2 | 121.8 (4) |
C34—N2—Sb2 | 124.1 (3) | C39—C38—C37 | 120.2 (7) |
C35—N2—Sb2 | 111.3 (3) | C39—C38—H38 | 119.9 |
O1—C1—C6 | 124.7 (5) | C37—C38—H38 | 119.9 |
O1—C1—C2 | 116.6 (5) | C40—C39—C38 | 119.1 (8) |
C6—C1—C2 | 118.6 (5) | C40—C39—H39 | 120.5 |
C3—C2—C1 | 121.2 (6) | C38—C39—H39 | 120.5 |
C3—C2—H2 | 119.4 | C41—C40—C39 | 121.5 (7) |
C1—C2—H2 | 119.4 | C41—C40—H40 | 119.3 |
C2—C3—C4 | 120.9 (6) | C39—C40—H40 | 119.3 |
C2—C3—H3 | 119.5 | C40—C41—C42 | 118.8 (8) |
C4—C3—H3 | 119.5 | C40—C41—H41 | 120.6 |
C5—C4—C3 | 119.2 (6) | C42—C41—H41 | 120.6 |
C5—C4—H4 | 120.4 | C41—C42—C37 | 121.3 (7) |
C3—C4—H4 | 120.4 | C41—C42—H42 | 119.3 |
C4—C5—C6 | 122.3 (6) | C37—C42—H42 | 119.3 |
C4—C5—H5 | 118.9 | C44—C43—C48 | 119.0 (5) |
C6—C5—H5 | 118.9 | C44—C43—Sb2 | 123.3 (4) |
C1—C6—C5 | 117.7 (5) | C48—C43—Sb2 | 117.7 (4) |
C1—C6—C7 | 124.6 (5) | C43—C44—C45 | 119.8 (6) |
C5—C6—C7 | 117.6 (5) | C43—C44—H44 | 120.1 |
N1—C7—C6 | 125.6 (5) | C45—C44—H44 | 120.1 |
N1—C7—H7 | 117.2 | C46—C45—C44 | 120.8 (6) |
C6—C7—H7 | 117.2 | C46—C45—H45 | 119.6 |
N1—C8—C9 | 112.1 (4) | C44—C45—H45 | 119.6 |
N1—C8—H8A | 109.2 | C45—C46—C47 | 119.4 (6) |
C9—C8—H8A | 109.2 | C45—C46—H46 | 120.3 |
N1—C8—H8B | 109.2 | C47—C46—H46 | 120.3 |
C9—C8—H8B | 109.2 | C46—C47—C48 | 121.1 (7) |
H8A—C8—H8B | 107.9 | C46—C47—H47 | 119.5 |
O3—C9—O2 | 122.6 (6) | C48—C47—H47 | 119.5 |
O3—C9—C8 | 119.4 (5) | C43—C48—C47 | 120.0 (6) |
O2—C9—C8 | 118.0 (5) | C43—C48—H48 | 120.0 |
C11—C10—C15 | 118.5 (5) | C47—C48—H48 | 120.0 |
C11—C10—Sb1 | 119.9 (4) | C54—C49—C50 | 118.8 (5) |
C15—C10—Sb1 | 121.6 (4) | C54—C49—Sb2 | 120.9 (4) |
C10—C11—C12 | 120.2 (6) | C50—C49—Sb2 | 120.3 (4) |
C10—C11—H11 | 119.9 | C51—C50—C49 | 120.4 (5) |
C12—C11—H11 | 119.9 | C51—C50—H50 | 119.8 |
C13—C12—C11 | 120.2 (7) | C49—C50—H50 | 119.8 |
C13—C12—H12 | 119.9 | C52—C51—C50 | 119.8 (5) |
C11—C12—H12 | 119.9 | C52—C51—H51 | 120.1 |
C14—C13—C12 | 120.4 (6) | C50—C51—H51 | 120.1 |
C14—C13—H13 | 119.8 | C53—C52—C51 | 120.1 (5) |
C12—C13—H13 | 119.8 | C53—C52—H52 | 120.0 |
C13—C14—C15 | 120.0 (7) | C51—C52—H52 | 120.0 |
C13—C14—H14 | 120.0 | C52—C53—C54 | 119.6 (5) |
C15—C14—H14 | 120.0 | C52—C53—H53 | 120.2 |
C14—C15—C10 | 120.6 (6) | C54—C53—H53 | 120.2 |
C14—C15—H15 | 119.7 | C49—C54—C53 | 121.4 (5) |
C10—C15—H15 | 119.7 | C49—C54—H54 | 119.3 |
C21—C16—C17 | 118.3 (5) | C53—C54—H54 | 119.3 |
C21—C16—Sb1 | 121.5 (4) | Cl1—C55—Cl2 | 113.0 (5) |
C17—C16—Sb1 | 120.2 (4) | Cl1—C55—H55A | 109.0 |
C18—C17—C16 | 120.3 (5) | Cl2—C55—H55A | 109.0 |
C18—C17—H17 | 119.9 | Cl1—C55—H55B | 109.0 |
C16—C17—H17 | 119.9 | Cl2—C55—H55B | 109.0 |
C19—C18—C17 | 120.7 (5) | H55A—C55—H55B | 107.8 |
C19—C18—H18 | 119.6 | Cl2'—C55'—Cl1' | 111.7 (6) |
C17—C18—H18 | 119.6 | Cl2'—C55'—H55C | 109.3 |
C18—C19—C20 | 119.6 (5) | Cl1'—C55'—H55C | 109.3 |
C18—C19—H19 | 120.2 | Cl2'—C55'—H55D | 109.3 |
C20—C19—H19 | 120.2 | Cl1'—C55'—H55D | 109.3 |
C19—C20—C21 | 120.0 (5) | H55C—C55'—H55D | 107.9 |
C19—C20—H20 | 120.0 | Cl3—C56—Cl4 | 112.5 (6) |
C21—C20—H20 | 120.0 | Cl3—C56—H56A | 109.1 |
C20—C21—C16 | 121.1 (5) | Cl4—C56—H56A | 109.1 |
C20—C21—H21 | 119.4 | Cl3—C56—H56B | 109.1 |
C16—C21—H21 | 119.4 | Cl4—C56—H56B | 109.1 |
C23—C22—C27 | 118.8 (5) | H56A—C56—H56B | 107.8 |
C23—C22—Sb1 | 117.9 (4) | Cl3'—C56'—Cl4' | 111.6 (6) |
C27—C22—Sb1 | 123.3 (4) | Cl3'—C56'—H56C | 109.3 |
C22—C23—C24 | 119.7 (7) | Cl4'—C56'—H56C | 109.3 |
C22—C23—H23 | 120.2 | Cl3'—C56'—H56D | 109.3 |
C24—C23—H23 | 120.2 | Cl4'—C56'—H56D | 109.3 |
C25—C24—C23 | 120.2 (8) | H56C—C56'—H56D | 108.0 |
C25—C24—H24 | 119.9 | Cl3"—C56"—Cl4" | 110.7 (6) |
C23—C24—H24 | 119.9 | Cl3"—C56"—H56E | 109.5 |
C26—C25—C24 | 120.1 (7) | Cl4"—C56"—H56E | 109.5 |
C26—C25—H25 | 120.0 | Cl3"—C56"—H56F | 109.5 |
C24—C25—H25 | 120.0 | Cl4"—C56"—H56F | 109.5 |
C25—C26—C27 | 120.2 (8) | H56E—C56"—H56F | 108.1 |
O2—Sb1—O1—C1 | 45.3 (6) | O1—Sb1—C22—C23 | −50.8 (4) |
C16—Sb1—O1—C1 | −142.5 (4) | O2—Sb1—C22—C23 | 149.7 (4) |
C22—Sb1—O1—C1 | −47.8 (4) | C16—Sb1—C22—C23 | 50.8 (4) |
C10—Sb1—O1—C1 | 122.9 (4) | N1—Sb1—C22—C23 | −134.4 (4) |
N1—Sb1—O1—C1 | 36.8 (4) | O1—Sb1—C22—C27 | 129.9 (4) |
O1—Sb1—O2—C9 | 0.8 (6) | O2—Sb1—C22—C27 | −29.6 (5) |
C16—Sb1—O2—C9 | −171.5 (4) | C16—Sb1—C22—C27 | −128.4 (5) |
C22—Sb1—O2—C9 | 94.1 (4) | N1—Sb1—C22—C27 | 46.3 (4) |
C10—Sb1—O2—C9 | −76.8 (4) | C27—C22—C23—C24 | −1.3 (8) |
N1—Sb1—O2—C9 | 9.5 (4) | Sb1—C22—C23—C24 | 179.4 (5) |
O5—Sb2—O4—C28 | −44.4 (6) | C22—C23—C24—C25 | 0.0 (10) |
C49—Sb2—O4—C28 | 141.3 (4) | C23—C24—C25—C26 | 1.6 (12) |
C37—Sb2—O4—C28 | −122.9 (4) | C24—C25—C26—C27 | −2.0 (12) |
C43—Sb2—O4—C28 | 46.5 (4) | C25—C26—C27—C22 | 0.7 (10) |
N2—Sb2—O4—C28 | −38.9 (3) | C23—C22—C27—C26 | 1.0 (9) |
O4—Sb2—O5—C36 | −12.1 (6) | Sb1—C22—C27—C26 | −179.8 (5) |
C49—Sb2—O5—C36 | 162.2 (4) | Sb2—O4—C28—C29 | −147.8 (3) |
C37—Sb2—O5—C36 | 66.4 (4) | Sb2—O4—C28—C33 | 35.4 (6) |
C43—Sb2—O5—C36 | −102.7 (4) | O4—C28—C29—C30 | −175.3 (5) |
N2—Sb2—O5—C36 | −17.8 (4) | C33—C28—C29—C30 | 1.6 (7) |
O1—Sb1—N1—C7 | −30.2 (4) | C28—C29—C30—C31 | −0.8 (9) |
O2—Sb1—N1—C7 | 152.9 (4) | C29—C30—C31—C32 | 0.0 (9) |
C22—Sb1—N1—C7 | 61.4 (4) | C30—C31—C32—C33 | −0.2 (9) |
C10—Sb1—N1—C7 | −118.4 (4) | C31—C32—C33—C28 | 1.1 (8) |
O1—Sb1—N1—C8 | 164.5 (3) | C31—C32—C33—C34 | 178.8 (5) |
O2—Sb1—N1—C8 | −12.5 (3) | O4—C28—C33—C32 | 174.9 (4) |
C22—Sb1—N1—C8 | −104.0 (3) | C29—C28—C33—C32 | −1.8 (7) |
C10—Sb1—N1—C8 | 76.2 (3) | O4—C28—C33—C34 | −2.6 (7) |
O4—Sb2—N2—C34 | 26.6 (4) | C29—C28—C33—C34 | −179.3 (4) |
O5—Sb2—N2—C34 | −155.4 (4) | C35—N2—C34—C33 | 179.2 (4) |
C37—Sb2—N2—C34 | 115.2 (4) | Sb2—N2—C34—C33 | −8.7 (7) |
C43—Sb2—N2—C34 | −63.1 (4) | C32—C33—C34—N2 | 172.1 (5) |
O4—Sb2—N2—C35 | −160.4 (3) | C28—C33—C34—N2 | −10.3 (8) |
O5—Sb2—N2—C35 | 17.6 (3) | C34—N2—C35—C36 | 156.7 (5) |
C37—Sb2—N2—C35 | −71.8 (3) | Sb2—N2—C35—C36 | −16.3 (5) |
C43—Sb2—N2—C35 | 109.9 (3) | Sb2—O5—C36—O6 | −166.5 (4) |
Sb1—O1—C1—C6 | −30.2 (6) | Sb2—O5—C36—C35 | 14.1 (6) |
Sb1—O1—C1—C2 | 152.6 (3) | N2—C35—C36—O6 | −176.4 (5) |
O1—C1—C2—C3 | 177.0 (5) | N2—C35—C36—O5 | 2.9 (7) |
C6—C1—C2—C3 | −0.3 (7) | O4—Sb2—C37—C42 | −151.6 (4) |
C1—C2—C3—C4 | 0.6 (9) | O5—Sb2—C37—C42 | 48.6 (4) |
C2—C3—C4—C5 | −0.7 (9) | C49—Sb2—C37—C42 | −50.5 (4) |
C3—C4—C5—C6 | 0.5 (9) | C43—Sb2—C37—C42 | 133.1 (10) |
O1—C1—C6—C5 | −176.9 (4) | N2—Sb2—C37—C42 | 124.1 (4) |
C2—C1—C6—C5 | 0.1 (7) | O4—Sb2—C37—C38 | 29.4 (4) |
O1—C1—C6—C7 | −0.3 (8) | O5—Sb2—C37—C38 | −130.4 (4) |
C2—C1—C6—C7 | 176.7 (4) | C49—Sb2—C37—C38 | 130.5 (4) |
C4—C5—C6—C1 | −0.2 (8) | C43—Sb2—C37—C38 | −46.0 (13) |
C4—C5—C6—C7 | −177.1 (5) | N2—Sb2—C37—C38 | −54.9 (4) |
C8—N1—C7—C6 | 179.3 (4) | C42—C37—C38—C39 | 0.1 (8) |
Sb1—N1—C7—C6 | 15.7 (7) | Sb2—C37—C38—C39 | 179.2 (5) |
C1—C6—C7—N1 | 6.4 (8) | C37—C38—C39—C40 | 0.3 (10) |
C5—C6—C7—N1 | −177.0 (5) | C38—C39—C40—C41 | −1.3 (13) |
C7—N1—C8—C9 | −151.5 (5) | C39—C40—C41—C42 | 1.8 (13) |
Sb1—N1—C8—C9 | 13.8 (5) | C40—C41—C42—C37 | −1.4 (11) |
Sb1—O2—C9—O3 | 176.7 (4) | C38—C37—C42—C41 | 0.4 (9) |
Sb1—O2—C9—C8 | −4.7 (6) | Sb2—C37—C42—C41 | −178.6 (5) |
N1—C8—C9—O3 | 171.7 (5) | O4—Sb2—C43—C44 | −132.7 (5) |
N1—C8—C9—O2 | −7.0 (7) | O5—Sb2—C43—C44 | 26.6 (5) |
O1—Sb1—C10—C11 | 145.8 (4) | C49—Sb2—C43—C44 | 126.1 (5) |
O2—Sb1—C10—C11 | −54.2 (4) | C37—Sb2—C43—C44 | −57.5 (13) |
C16—Sb1—C10—C11 | 44.4 (4) | N2—Sb2—C43—C44 | −48.6 (5) |
N1—Sb1—C10—C11 | −130.3 (4) | O4—Sb2—C43—C48 | 46.6 (4) |
O1—Sb1—C10—C15 | −34.2 (4) | O5—Sb2—C43—C48 | −154.1 (4) |
O2—Sb1—C10—C15 | 125.8 (4) | C49—Sb2—C43—C48 | −54.7 (4) |
C16—Sb1—C10—C15 | −135.6 (4) | C37—Sb2—C43—C48 | 121.8 (10) |
N1—Sb1—C10—C15 | 49.6 (4) | N2—Sb2—C43—C48 | 130.7 (4) |
C15—C10—C11—C12 | 0.0 (8) | C48—C43—C44—C45 | −1.5 (8) |
Sb1—C10—C11—C12 | 179.9 (5) | Sb2—C43—C44—C45 | 177.7 (4) |
C10—C11—C12—C13 | 0.1 (10) | C43—C44—C45—C46 | 0.8 (10) |
C11—C12—C13—C14 | 0.2 (12) | C44—C45—C46—C47 | −0.2 (11) |
C12—C13—C14—C15 | −0.4 (11) | C45—C46—C47—C48 | 0.4 (10) |
C13—C14—C15—C10 | 0.5 (9) | C44—C43—C48—C47 | 1.7 (8) |
C11—C10—C15—C14 | −0.2 (8) | Sb2—C43—C48—C47 | −177.6 (4) |
Sb1—C10—C15—C14 | 179.8 (4) | C46—C47—C48—C43 | −1.2 (9) |
O1—Sb1—C16—C21 | −38.2 (4) | O4—Sb2—C49—C54 | 48.7 (4) |
O2—Sb1—C16—C21 | 139.0 (4) | O5—Sb2—C49—C54 | −129.3 (4) |
C22—Sb1—C16—C21 | −130.1 (4) | C37—Sb2—C49—C54 | −40.5 (4) |
C10—Sb1—C16—C21 | 50.5 (4) | C43—Sb2—C49—C54 | 138.9 (4) |
O1—Sb1—C16—C17 | 140.0 (4) | O4—Sb2—C49—C50 | −130.7 (4) |
O2—Sb1—C16—C17 | −42.8 (4) | O5—Sb2—C49—C50 | 51.4 (4) |
C22—Sb1—C16—C17 | 48.1 (4) | C37—Sb2—C49—C50 | 140.2 (4) |
C10—Sb1—C16—C17 | −131.3 (4) | C43—Sb2—C49—C50 | −40.5 (4) |
C21—C16—C17—C18 | −0.1 (8) | C54—C49—C50—C51 | −0.4 (8) |
Sb1—C16—C17—C18 | −178.3 (4) | Sb2—C49—C50—C51 | 179.0 (4) |
C16—C17—C18—C19 | 1.2 (9) | C49—C50—C51—C52 | −1.5 (9) |
C17—C18—C19—C20 | −0.8 (9) | C50—C51—C52—C53 | 1.6 (9) |
C18—C19—C20—C21 | −0.8 (9) | C51—C52—C53—C54 | 0.1 (8) |
C19—C20—C21—C16 | 1.9 (9) | C50—C49—C54—C53 | 2.1 (8) |
C17—C16—C21—C20 | −1.5 (8) | Sb2—C49—C54—C53 | −177.2 (4) |
Sb1—C16—C21—C20 | 176.8 (4) | C52—C53—C54—C49 | −2.0 (8) |