Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807008823/ci2284sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536807008823/ci2284Isup2.hkl |
CCDC reference: 640298
Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1994); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXL97.
[Mn(C7H3N2O6)2(C10H8N2)] | Z = 2 |
Mr = 633.20 | F(000) = 642 |
Triclinic, P1 | Dx = 1.623 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 7.8100 (5) Å | Cell parameters from 5853 reflections |
b = 11.9700 (4) Å | θ = 3.0–27.5° |
c = 14.7695 (3) Å | µ = 0.59 mm−1 |
α = 103.834 (3)° | T = 293 K |
β = 104.393 (3)° | Block, yellow |
γ = 90.169 (3)° | 0.26 × 0.16 × 0.11 mm |
V = 1295.75 (10) Å3 |
Siemens SMART CCD area-detector diffractometer | 5856 independent reflections |
Radiation source: fine-focus sealed tube | 4729 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.027 |
φ and ω scans | θmax = 27.5°, θmin = 3.0° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −10→9 |
Tmin = 0.893, Tmax = 0.937 | k = −15→15 |
12799 measured reflections | l = −19→19 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.042 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.124 | H-atom parameters constrained |
S = 1.00 | w = 1/[σ2(Fo2) + (0.0818P)2 + 0.0886P] where P = (Fo2 + 2Fc2)/3 |
5853 reflections | (Δ/σ)max = 0.001 |
388 parameters | Δρmax = 0.48 e Å−3 |
18 restraints | Δρmin = −0.48 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Mn1 | 0.27297 (4) | 0.04131 (3) | 0.58413 (2) | 0.02962 (12) | |
O1 | 0.4926 (2) | 0.14433 (16) | 0.56730 (12) | 0.0442 (4) | |
O2 | 0.7470 (3) | 0.06908 (19) | 0.55183 (13) | 0.0590 (6) | |
O3 | 0.6478 (6) | 0.5202 (3) | 0.8170 (3) | 0.1218 (13) | |
O4 | 0.7802 (5) | 0.5083 (3) | 0.95874 (19) | 0.1132 (12) | |
O5 | 1.0905 (4) | 0.0325 (3) | 0.8799 (3) | 0.1058 (10) | |
O6 | 1.0929 (6) | 0.1715 (4) | 1.0015 (2) | 0.1369 (15) | |
O7 | −0.1068 (2) | −0.16237 (14) | 0.46826 (12) | 0.0423 (4) | |
O8 | 0.0830 (2) | −0.07221 (15) | 0.60781 (12) | 0.0450 (4) | |
O9 | 0.0975 (6) | −0.4286 (4) | 0.8537 (3) | 0.1349 (15) | |
O10 | 0.2323 (5) | −0.2680 (4) | 0.8667 (2) | 0.1324 (15) | |
O11 | −0.3519 (6) | −0.5428 (3) | 0.4340 (3) | 0.1342 (14) | |
O12 | −0.2728 (7) | −0.6312 (3) | 0.5459 (3) | 0.1453 (15) | |
N1 | 0.4654 (3) | −0.05014 (18) | 0.68421 (13) | 0.0375 (4) | |
N2 | 0.3243 (3) | 0.14950 (17) | 0.73943 (13) | 0.0360 (4) | |
N3 | 0.7301 (5) | 0.4692 (3) | 0.8727 (2) | 0.0754 (9) | |
N4 | 1.0439 (4) | 0.1239 (4) | 0.9159 (2) | 0.0804 (9) | |
N5 | −0.2685 (6) | −0.5478 (3) | 0.5140 (3) | 0.0967 (12) | |
N6 | 0.1307 (6) | −0.3488 (4) | 0.8210 (3) | 0.0920 (11) | |
C1 | 0.5137 (4) | −0.1568 (2) | 0.65319 (18) | 0.0483 (6) | |
H1 | 0.4993 | −0.1861 | 0.5873 | 0.058* | |
C2 | 0.5833 (4) | −0.2247 (3) | 0.7139 (2) | 0.0585 (8) | |
H2 | 0.6133 | −0.2990 | 0.6896 | 0.070* | |
C3 | 0.6081 (5) | −0.1816 (3) | 0.8109 (2) | 0.0671 (9) | |
H3 | 0.6559 | −0.2261 | 0.8536 | 0.080* | |
C4 | 0.5617 (4) | −0.0721 (3) | 0.84453 (18) | 0.0597 (8) | |
H4 | 0.5788 | −0.0412 | 0.9104 | 0.072* | |
C5 | 0.2694 (4) | 0.2554 (2) | 0.76242 (19) | 0.0460 (6) | |
H5 | 0.1952 | 0.2836 | 0.7143 | 0.055* | |
C6 | 0.3189 (4) | 0.3250 (3) | 0.8554 (2) | 0.0590 (8) | |
H6 | 0.2777 | 0.3984 | 0.8695 | 0.071* | |
C7 | 0.4284 (4) | 0.2848 (3) | 0.9258 (2) | 0.0614 (8) | |
H7 | 0.4631 | 0.3304 | 0.9887 | 0.074* | |
C8 | 0.4872 (4) | 0.1762 (3) | 0.90345 (17) | 0.0510 (6) | |
H8 | 0.5631 | 0.1475 | 0.9506 | 0.061* | |
C9 | 0.4892 (3) | −0.0078 (2) | 0.77955 (15) | 0.0375 (5) | |
C10 | 0.4316 (3) | 0.1099 (2) | 0.80903 (15) | 0.0374 (5) | |
C11 | 0.7405 (3) | 0.1884 (2) | 0.70068 (15) | 0.0379 (5) | |
C12 | 0.6962 (3) | 0.2983 (2) | 0.73835 (17) | 0.0436 (6) | |
H12 | 0.6151 | 0.3359 | 0.7003 | 0.052* | |
C13 | 0.7750 (4) | 0.3510 (3) | 0.83374 (18) | 0.0532 (7) | |
C14 | 0.8860 (4) | 0.2973 (3) | 0.89399 (18) | 0.0598 (8) | |
H14 | 0.9326 | 0.3330 | 0.9589 | 0.072* | |
C15 | 0.9260 (4) | 0.1880 (3) | 0.85439 (19) | 0.0542 (7) | |
C16 | 0.8593 (3) | 0.1328 (3) | 0.75767 (18) | 0.0453 (6) | |
H16 | 0.8938 | 0.0603 | 0.7320 | 0.054* | |
C17 | 0.6523 (3) | 0.1282 (2) | 0.59720 (15) | 0.0379 (5) | |
C18 | −0.1566 (5) | −0.4458 (2) | 0.5745 (2) | 0.0649 (9) | |
C19 | −0.1453 (4) | −0.3521 (2) | 0.5370 (2) | 0.0493 (6) | |
H19 | −0.2108 | −0.3527 | 0.4750 | 0.059* | |
C20 | −0.0353 (3) | −0.2573 (2) | 0.59295 (17) | 0.0389 (5) | |
C21 | 0.0565 (4) | −0.2563 (3) | 0.6862 (2) | 0.0500 (6) | |
H21 | 0.1305 | −0.1926 | 0.7247 | 0.060* | |
C22 | 0.0368 (5) | −0.3514 (3) | 0.7215 (2) | 0.0614 (8) | |
C23 | −0.0685 (5) | −0.4480 (3) | 0.6664 (3) | 0.0712 (10) | |
H23 | −0.0793 | −0.5119 | 0.6905 | 0.085* | |
C24 | −0.0180 (3) | −0.1546 (2) | 0.55254 (16) | 0.0355 (5) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Mn1 | 0.03053 (19) | 0.02918 (19) | 0.02440 (17) | −0.00030 (13) | 0.00124 (13) | 0.00366 (12) |
O1 | 0.0393 (9) | 0.0550 (11) | 0.0352 (8) | −0.0084 (8) | 0.0051 (7) | 0.0101 (7) |
O2 | 0.0468 (10) | 0.0725 (13) | 0.0392 (9) | −0.0048 (10) | 0.0099 (9) | −0.0201 (9) |
O3 | 0.196 (4) | 0.0604 (17) | 0.098 (2) | 0.028 (2) | 0.038 (2) | −0.0012 (16) |
O4 | 0.153 (3) | 0.095 (2) | 0.0660 (16) | −0.004 (2) | 0.0388 (19) | −0.0389 (15) |
O5 | 0.096 (2) | 0.122 (3) | 0.101 (2) | 0.031 (2) | 0.0058 (18) | 0.052 (2) |
O6 | 0.139 (3) | 0.186 (4) | 0.0575 (16) | 0.004 (3) | −0.0332 (18) | 0.037 (2) |
O7 | 0.0440 (9) | 0.0370 (8) | 0.0404 (8) | 0.0037 (7) | −0.0025 (7) | 0.0131 (7) |
O8 | 0.0496 (10) | 0.0395 (9) | 0.0418 (9) | −0.0127 (8) | 0.0026 (8) | 0.0118 (7) |
O9 | 0.185 (4) | 0.135 (3) | 0.116 (3) | 0.027 (3) | 0.031 (3) | 0.096 (3) |
O10 | 0.128 (3) | 0.181 (4) | 0.080 (2) | −0.033 (3) | −0.029 (2) | 0.076 (2) |
O11 | 0.186 (3) | 0.089 (2) | 0.103 (2) | −0.074 (2) | 0.011 (2) | 0.0053 (18) |
O12 | 0.258 (4) | 0.0625 (17) | 0.126 (2) | −0.060 (2) | 0.075 (3) | 0.0179 (16) |
N1 | 0.0384 (10) | 0.0409 (10) | 0.0273 (8) | 0.0032 (8) | 0.0009 (8) | 0.0051 (8) |
N2 | 0.0386 (10) | 0.0367 (10) | 0.0304 (9) | −0.0016 (8) | 0.0096 (8) | 0.0029 (8) |
N3 | 0.104 (2) | 0.0537 (16) | 0.0596 (16) | −0.0104 (16) | 0.0344 (17) | −0.0166 (13) |
N4 | 0.0609 (17) | 0.118 (3) | 0.0574 (17) | −0.0075 (19) | −0.0051 (14) | 0.0347 (18) |
N5 | 0.150 (3) | 0.0545 (17) | 0.088 (2) | −0.0367 (19) | 0.049 (2) | 0.0044 (16) |
N6 | 0.105 (3) | 0.110 (3) | 0.076 (2) | 0.018 (2) | 0.011 (2) | 0.064 (2) |
C1 | 0.0555 (15) | 0.0459 (14) | 0.0360 (12) | 0.0148 (12) | 0.0040 (11) | 0.0037 (10) |
C2 | 0.0646 (18) | 0.0476 (15) | 0.0535 (15) | 0.0183 (14) | −0.0001 (14) | 0.0096 (12) |
C3 | 0.082 (2) | 0.0616 (19) | 0.0534 (16) | 0.0170 (17) | −0.0032 (16) | 0.0274 (15) |
C4 | 0.078 (2) | 0.0630 (18) | 0.0306 (12) | 0.0100 (16) | −0.0007 (13) | 0.0133 (12) |
C5 | 0.0510 (14) | 0.0403 (13) | 0.0463 (13) | 0.0041 (11) | 0.0184 (12) | 0.0043 (11) |
C6 | 0.0699 (19) | 0.0443 (15) | 0.0585 (17) | 0.0035 (14) | 0.0291 (16) | −0.0086 (13) |
C7 | 0.076 (2) | 0.0598 (18) | 0.0368 (13) | −0.0063 (16) | 0.0163 (14) | −0.0117 (12) |
C8 | 0.0588 (16) | 0.0577 (16) | 0.0291 (11) | −0.0048 (13) | 0.0084 (11) | −0.0002 (11) |
C9 | 0.0374 (11) | 0.0416 (12) | 0.0288 (10) | −0.0019 (10) | 0.0017 (9) | 0.0067 (9) |
C10 | 0.0388 (12) | 0.0416 (12) | 0.0292 (10) | −0.0039 (10) | 0.0097 (9) | 0.0029 (9) |
C11 | 0.0348 (11) | 0.0444 (13) | 0.0290 (10) | −0.0091 (10) | 0.0091 (9) | −0.0024 (9) |
C12 | 0.0500 (14) | 0.0451 (14) | 0.0323 (11) | −0.0077 (11) | 0.0137 (11) | −0.0001 (10) |
C13 | 0.0612 (17) | 0.0528 (16) | 0.0381 (13) | −0.0144 (13) | 0.0194 (13) | −0.0096 (11) |
C14 | 0.0620 (17) | 0.078 (2) | 0.0282 (11) | −0.0223 (16) | 0.0083 (12) | −0.0051 (12) |
C15 | 0.0426 (14) | 0.077 (2) | 0.0371 (12) | −0.0113 (14) | 0.0021 (11) | 0.0129 (13) |
C16 | 0.0370 (12) | 0.0533 (15) | 0.0408 (12) | −0.0052 (11) | 0.0082 (11) | 0.0042 (11) |
C17 | 0.0380 (12) | 0.0398 (12) | 0.0307 (10) | −0.0121 (10) | 0.0077 (10) | 0.0005 (9) |
C18 | 0.094 (2) | 0.0348 (14) | 0.073 (2) | −0.0106 (14) | 0.0431 (19) | 0.0057 (13) |
C19 | 0.0582 (16) | 0.0396 (13) | 0.0495 (14) | −0.0089 (11) | 0.0152 (13) | 0.0088 (11) |
C20 | 0.0383 (12) | 0.0358 (12) | 0.0446 (12) | 0.0017 (10) | 0.0090 (10) | 0.0154 (10) |
C21 | 0.0470 (14) | 0.0525 (15) | 0.0528 (14) | 0.0012 (12) | 0.0053 (12) | 0.0249 (12) |
C22 | 0.0700 (19) | 0.0637 (19) | 0.0623 (17) | 0.0149 (16) | 0.0175 (15) | 0.0374 (15) |
C23 | 0.111 (3) | 0.0457 (17) | 0.079 (2) | 0.0155 (18) | 0.047 (2) | 0.0338 (16) |
C24 | 0.0326 (11) | 0.0338 (11) | 0.0401 (11) | 0.0016 (9) | 0.0063 (9) | 0.0124 (9) |
Mn1—O2i | 2.0921 (17) | C3—H3 | 0.93 |
Mn1—O7ii | 2.1049 (16) | C4—C9 | 1.385 (4) |
Mn1—O8 | 2.1548 (17) | C4—H4 | 0.93 |
Mn1—O1 | 2.2072 (17) | C5—C6 | 1.384 (4) |
Mn1—N2 | 2.2843 (18) | C5—H5 | 0.93 |
Mn1—N1 | 2.3068 (19) | C6—C7 | 1.359 (5) |
O1—C17 | 1.247 (3) | C6—H6 | 0.93 |
O2—C17 | 1.232 (3) | C7—C8 | 1.372 (4) |
O2—Mn1i | 2.0921 (17) | C7—H7 | 0.93 |
O3—N3 | 1.200 (5) | C8—C10 | 1.390 (3) |
O4—N3 | 1.206 (4) | C8—H8 | 0.93 |
O5—N4 | 1.197 (5) | C9—C10 | 1.479 (3) |
O6—N4 | 1.218 (4) | C11—C16 | 1.377 (4) |
O7—C24 | 1.247 (3) | C11—C12 | 1.381 (4) |
O7—Mn1ii | 2.1049 (16) | C11—C17 | 1.509 (3) |
O8—C24 | 1.246 (3) | C12—C13 | 1.380 (3) |
O9—N6 | 1.221 (5) | C12—H12 | 0.93 |
O10—N6 | 1.199 (5) | C13—C14 | 1.360 (5) |
O11—N5 | 1.214 (5) | C14—C15 | 1.371 (5) |
O12—N5 | 1.206 (4) | C14—H14 | 0.93 |
N1—C1 | 1.338 (3) | C15—C16 | 1.387 (4) |
N1—C9 | 1.343 (3) | C16—H16 | 0.93 |
N2—C5 | 1.333 (3) | C18—C23 | 1.366 (5) |
N2—C10 | 1.338 (3) | C18—C19 | 1.377 (4) |
N3—C13 | 1.473 (4) | C19—C20 | 1.379 (4) |
N4—C15 | 1.477 (4) | C19—H19 | 0.93 |
N5—C18 | 1.462 (5) | C20—C21 | 1.383 (4) |
N6—C22 | 1.464 (4) | C20—C24 | 1.509 (3) |
C1—C2 | 1.367 (4) | C21—C22 | 1.383 (4) |
C1—H1 | 0.93 | C21—H21 | 0.93 |
C2—C3 | 1.364 (4) | C22—C23 | 1.374 (5) |
C2—H2 | 0.93 | C23—H23 | 0.93 |
C3—C4 | 1.371 (4) | ||
O2i—Mn1—O7ii | 95.08 (8) | C6—C7—C8 | 119.4 (2) |
O2i—Mn1—O8 | 89.38 (8) | C6—C7—H7 | 120.3 |
O7ii—Mn1—O8 | 100.91 (7) | C8—C7—H7 | 120.3 |
O2i—Mn1—O1 | 90.37 (7) | C7—C8—C10 | 118.8 (3) |
O7ii—Mn1—O1 | 86.11 (7) | C7—C8—H8 | 120.6 |
O8—Mn1—O1 | 172.96 (7) | C10—C8—H8 | 120.6 |
O2i—Mn1—N2 | 172.86 (8) | N1—C9—C4 | 121.3 (2) |
O7ii—Mn1—N2 | 91.82 (7) | N1—C9—C10 | 115.5 (2) |
O8—Mn1—N2 | 91.12 (7) | C4—C9—C10 | 123.2 (2) |
O1—Mn1—N2 | 88.26 (7) | N2—C10—C8 | 121.9 (2) |
O2i—Mn1—N1 | 101.98 (8) | N2—C10—C9 | 116.23 (18) |
O7ii—Mn1—N1 | 162.86 (7) | C8—C10—C9 | 121.9 (2) |
O8—Mn1—N1 | 81.18 (7) | C16—C11—C12 | 120.5 (2) |
O1—Mn1—N1 | 91.99 (7) | C16—C11—C17 | 120.2 (2) |
N2—Mn1—N1 | 71.08 (7) | C12—C11—C17 | 119.3 (2) |
C17—O1—Mn1 | 123.87 (16) | C13—C12—C11 | 118.5 (3) |
C17—O2—Mn1i | 139.47 (17) | C13—C12—H12 | 120.8 |
C24—O7—Mn1ii | 127.85 (15) | C11—C12—H12 | 120.8 |
C24—O8—Mn1 | 132.18 (15) | C14—C13—C12 | 123.1 (3) |
C1—N1—C9 | 118.1 (2) | C14—C13—N3 | 118.8 (3) |
C1—N1—Mn1 | 122.49 (15) | C12—C13—N3 | 118.1 (3) |
C9—N1—Mn1 | 116.87 (15) | C13—C14—C15 | 116.8 (2) |
C5—N2—C10 | 118.4 (2) | C13—C14—H14 | 121.6 |
C5—N2—Mn1 | 123.03 (17) | C15—C14—H14 | 121.6 |
C10—N2—Mn1 | 118.08 (14) | C14—C15—C16 | 122.8 (3) |
O3—N3—O4 | 124.6 (3) | C14—C15—N4 | 119.7 (3) |
O3—N3—C13 | 118.1 (3) | C16—C15—N4 | 117.5 (3) |
O4—N3—C13 | 117.3 (4) | C11—C16—C15 | 118.2 (3) |
O5—N4—O6 | 124.0 (4) | C11—C16—H16 | 120.9 |
O5—N4—C15 | 119.7 (3) | C15—C16—H16 | 120.9 |
O6—N4—C15 | 116.2 (4) | O2—C17—O1 | 127.5 (2) |
O12—N5—O11 | 124.0 (4) | O2—C17—C11 | 116.1 (2) |
O12—N5—C18 | 118.5 (4) | O1—C17—C11 | 116.4 (2) |
O11—N5—C18 | 117.5 (3) | C23—C18—C19 | 123.0 (3) |
O10—N6—O9 | 123.6 (4) | C23—C18—N5 | 118.2 (3) |
O10—N6—C22 | 118.7 (3) | C19—C18—N5 | 118.8 (3) |
O9—N6—C22 | 117.7 (4) | C18—C19—C20 | 118.9 (3) |
N1—C1—C2 | 123.0 (2) | C18—C19—H19 | 120.6 |
N1—C1—H1 | 118.5 | C20—C19—H19 | 120.6 |
C2—C1—H1 | 118.5 | C19—C20—C21 | 119.8 (2) |
C3—C2—C1 | 118.9 (3) | C19—C20—C24 | 119.8 (2) |
C3—C2—H2 | 120.6 | C21—C20—C24 | 120.4 (2) |
C1—C2—H2 | 120.6 | C22—C21—C20 | 119.0 (3) |
C2—C3—C4 | 119.2 (3) | C22—C21—H21 | 120.5 |
C2—C3—H3 | 120.4 | C20—C21—H21 | 120.5 |
C4—C3—H3 | 120.4 | C23—C22—C21 | 122.3 (3) |
C3—C4—C9 | 119.4 (2) | C23—C22—N6 | 118.9 (3) |
C3—C4—H4 | 120.3 | C21—C22—N6 | 118.9 (3) |
C9—C4—H4 | 120.3 | C18—C23—C22 | 117.0 (3) |
N2—C5—C6 | 122.3 (3) | C18—C23—H23 | 121.5 |
N2—C5—H5 | 118.8 | C22—C23—H23 | 121.5 |
C6—C5—H5 | 118.8 | O8—C24—O7 | 128.0 (2) |
C7—C6—C5 | 119.1 (3) | O8—C24—C20 | 115.8 (2) |
C7—C6—H6 | 120.4 | O7—C24—C20 | 116.1 (2) |
C5—C6—H6 | 120.4 | ||
O2i—Mn1—O1—C17 | −93.31 (18) | C11—C12—C13—C14 | −4.1 (4) |
O7ii—Mn1—O1—C17 | 171.63 (18) | C11—C12—C13—N3 | 178.6 (2) |
N2—Mn1—O1—C17 | 79.68 (18) | O3—N3—C13—C14 | 172.1 (4) |
N1—Mn1—O1—C17 | 8.69 (18) | O4—N3—C13—C14 | −7.4 (5) |
O2i—Mn1—O8—C24 | −12.4 (2) | O3—N3—C13—C12 | −10.5 (5) |
O7ii—Mn1—O8—C24 | 82.6 (2) | O4—N3—C13—C12 | 170.1 (3) |
N2—Mn1—O8—C24 | 174.7 (2) | C12—C13—C14—C15 | 3.5 (4) |
N1—Mn1—O8—C24 | −114.6 (2) | N3—C13—C14—C15 | −179.2 (3) |
O2i—Mn1—N1—C1 | −10.2 (2) | C13—C14—C15—C16 | 0.4 (4) |
O7ii—Mn1—N1—C1 | 175.7 (2) | C13—C14—C15—N4 | −179.2 (3) |
O8—Mn1—N1—C1 | 77.3 (2) | O5—N4—C15—C14 | −173.9 (3) |
O1—Mn1—N1—C1 | −101.0 (2) | O6—N4—C15—C14 | 3.6 (5) |
N2—Mn1—N1—C1 | 171.5 (2) | O5—N4—C15—C16 | 6.5 (5) |
O2i—Mn1—N1—C9 | −171.87 (17) | O6—N4—C15—C16 | −176.0 (3) |
O7ii—Mn1—N1—C9 | 14.1 (4) | C12—C11—C16—C15 | 3.0 (4) |
O8—Mn1—N1—C9 | −84.40 (18) | C17—C11—C16—C15 | −174.8 (2) |
O1—Mn1—N1—C9 | 97.33 (18) | C14—C15—C16—C11 | −3.6 (4) |
N2—Mn1—N1—C9 | 9.86 (17) | N4—C15—C16—C11 | 176.0 (2) |
O7ii—Mn1—N2—C5 | −7.62 (19) | Mn1i—O2—C17—O1 | −3.9 (5) |
O8—Mn1—N2—C5 | −108.58 (19) | Mn1i—O2—C17—C11 | 176.5 (2) |
O1—Mn1—N2—C5 | 78.43 (19) | Mn1—O1—C17—O2 | 94.1 (3) |
N1—Mn1—N2—C5 | 171.1 (2) | Mn1—O1—C17—C11 | −86.3 (2) |
O7ii—Mn1—N2—C10 | −179.63 (17) | C16—C11—C17—O2 | −40.1 (3) |
O8—Mn1—N2—C10 | 79.41 (17) | C12—C11—C17—O2 | 142.1 (3) |
O1—Mn1—N2—C10 | −93.58 (17) | C16—C11—C17—O1 | 140.3 (2) |
N1—Mn1—N2—C10 | −0.87 (16) | C12—C11—C17—O1 | −37.6 (3) |
C9—N1—C1—C2 | 1.0 (4) | O12—N5—C18—C23 | −3.1 (6) |
Mn1—N1—C1—C2 | −160.4 (2) | O11—N5—C18—C23 | 176.9 (4) |
N1—C1—C2—C3 | −1.2 (5) | O12—N5—C18—C19 | 177.2 (4) |
C1—C2—C3—C4 | 0.4 (6) | O11—N5—C18—C19 | −2.7 (6) |
C2—C3—C4—C9 | 0.6 (6) | C23—C18—C19—C20 | 2.4 (5) |
C10—N2—C5—C6 | −0.3 (4) | N5—C18—C19—C20 | −177.9 (3) |
Mn1—N2—C5—C6 | −172.3 (2) | C18—C19—C20—C21 | −2.2 (4) |
N2—C5—C6—C7 | 0.6 (4) | C18—C19—C20—C24 | 178.8 (2) |
C5—C6—C7—C8 | −0.1 (5) | C19—C20—C21—C22 | 0.4 (4) |
C6—C7—C8—C10 | −0.6 (5) | C24—C20—C21—C22 | 179.5 (2) |
C1—N1—C9—C4 | 0.0 (4) | C20—C21—C22—C23 | 1.2 (5) |
Mn1—N1—C9—C4 | 162.5 (2) | C20—C21—C22—N6 | −178.5 (3) |
C1—N1—C9—C10 | −179.4 (2) | O10—N6—C22—C23 | 174.7 (4) |
Mn1—N1—C9—C10 | −16.9 (3) | O9—N6—C22—C23 | −7.0 (6) |
C3—C4—C9—N1 | −0.8 (5) | O10—N6—C22—C21 | −5.6 (6) |
C3—C4—C9—C10 | 178.6 (3) | O9—N6—C22—C21 | 172.8 (4) |
C5—N2—C10—C8 | −0.4 (3) | C19—C18—C23—C22 | −0.8 (5) |
Mn1—N2—C10—C8 | 172.00 (19) | N5—C18—C23—C22 | 179.5 (3) |
C5—N2—C10—C9 | −179.7 (2) | C21—C22—C23—C18 | −1.0 (5) |
Mn1—N2—C10—C9 | −7.3 (3) | N6—C22—C23—C18 | 178.7 (3) |
C7—C8—C10—N2 | 0.8 (4) | Mn1—O8—C24—O7 | −40.7 (4) |
C7—C8—C10—C9 | −179.9 (2) | Mn1—O8—C24—C20 | 139.60 (18) |
N1—C9—C10—N2 | 16.1 (3) | Mn1ii—O7—C24—O8 | −48.5 (3) |
C4—C9—C10—N2 | −163.3 (3) | Mn1ii—O7—C24—C20 | 131.17 (18) |
N1—C9—C10—C8 | −163.2 (2) | C19—C20—C24—O8 | 179.5 (2) |
C4—C9—C10—C8 | 17.3 (4) | C21—C20—C24—O8 | 0.5 (3) |
C16—C11—C12—C13 | 0.6 (4) | C19—C20—C24—O7 | −0.2 (3) |
C17—C11—C12—C13 | 178.5 (2) | C21—C20—C24—O7 | −179.3 (2) |
Symmetry codes: (i) −x+1, −y, −z+1; (ii) −x, −y, −z+1. |