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Acta Cryst. (2005). E61, m2588-m2589
https://doi.org/10.1107/S1600536805036500
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Dichloro-1κCl,3κCl-bis­[μ-methyl­enebis(diphenyl­phosphine)]-1:2κ2P:P′;2:3κ2P:P′-trigold(I) perchlorate

T.-L. Zhang, Y. Qin and X.-G. Meng
The title compound, [Au3Cl2(C25H22P2)2]ClO4, was synthesized from μ-bis­(diphenyl­phosphinometh­yl)dichloro­digold(I) and an excess of silver perchlorate in dichloro­methane/methanol. Three Au atoms in a triangle are connected by two bridging bis­(diphenyl­phosphino)methane ligands.
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Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805036500/cf6461sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805036500/cf6461Isup2.hkl
Contains datablock I

CCDC reference: 293849

checkCIF report

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](l-O) = 0.022 Å
  • R factor = 0.054
  • wR factor = 0.176
  • Data-to-parameter ratio = 21.3

checkCIF/PLATON results

No syntax errors found






Alert level A
PLAT241_ALERT_2_A Check High      Ueq as Compared to Neighbors for        C18
Author Response: Serious disorder. 
PLAT241_ALERT_2_A Check High      Ueq as Compared to Neighbors for        C43
Author Response: Serious disorder. 
PLAT241_ALERT_2_A Check High      Ueq as Compared to Neighbors for        C49
Author Response: Serious disorder. 
PLAT242_ALERT_2_A Check Low       Ueq as Compared to Neighbors for        C17
Author Response: C17 is less disordered than the neighbors. 
PLAT242_ALERT_2_A Check Low       Ueq as Compared to Neighbors for        C45
Author Response: C17 is less disordered than the neighbors. 
PLAT242_ALERT_2_A Check Low       Ueq as Compared to Neighbors for        C48
Author Response: C17 is less disordered than the neighbors. 
PLAT331_ALERT_2_A Small Average Phenyl C-C Dist.   C26    -C31           1.34 Ang.
Author Response: This is also due to serious disorder for all the phenyl groups. We have tried to use distance constraints to refine the structure, but the obtained results are still not satisfactory since the disorder for other phenyl groups becomes more serious. 

Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       4.11 Ratio
PLAT222_ALERT_3_B Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       4.11 Ratio
PLAT230_ALERT_2_B Hirshfeld Test Diff for    C45    -   C46     ..       7.03 su
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C28
Author Response: Serious disorder. 
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C46
Author Response: Serious disorder. 
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C26
Author Response: C17 is less disordered than the neighbors. 
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C29
Author Response: C17 is less disordered than the neighbors. 
PLAT331_ALERT_2_B Small Average Phenyl C-C Dist.   C39    -C44           1.35 Ang.
Author Response: This is also due to serious disorder for all the phenyl groups. We have tried to use distance constraints to refine the structure, but the obtained results are still not satisfactory since the disorder for other phenyl groups becomes more serious. 
PLAT733_ALERT_1_B Torsion Calc   -127.9(7), Rep -127.91(15) ......       4.67 su-Rat
              C15 -C14 -P3  -AU3    1.555   1.555   1.555   1.555


Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.98
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical .          ?
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.09
PLAT199_ALERT_1_C Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_C Check the Reported _diffrn_ambient_temperature .        293 K
PLAT230_ALERT_2_C Hirshfeld Test Diff for    C27    -   C28     ..       5.04 su
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C4
Author Response: Serious disorder. 
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C9
Author Response: Serious disorder. 
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C11
Author Response: Serious disorder. 
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C16
Author Response: Serious disorder. 
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C30
Author Response: Serious disorder. 
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C31
Author Response: Serious disorder. 
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C47
Author Response: Serious disorder. 
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C50
Author Response: Serious disorder. 
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C1
Author Response: C17 is less disordered than the neighbors. 
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C14
Author Response: C17 is less disordered than the neighbors. 
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C39
Author Response: C17 is less disordered than the neighbors. 
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C42
Author Response: C17 is less disordered than the neighbors. 
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        Cl3
PLAT330_ALERT_2_C Large Average Phenyl C-C Dist.   C20    -C25           1.41 Ang.
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C45    -C50           1.36 Ang.
Author Response: This is also due to serious disorder for all the phenyl groups. We have tried to use distance constraints to refine the structure, but the obtained results are still not satisfactory since the disorder for other phenyl groups becomes more serious. 
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         92
            CL2 -AU1 -P1  -C38  -169.10  1.10   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         94
            CL2 -AU1 -P1  -C39    70.40  1.10   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         96
            CL2 -AU1 -P1  -C45   -50.60  1.20   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #        134
            CL1 -AU3 -P3  -C14   -32.20  1.10   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #        136
            CL1 -AU3 -P3  -C20    86.30  1.10   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #        138
            CL1 -AU3 -P3  -C13  -154.90  1.00   1.555   1.555   1.555   1.555
PLAT732_ALERT_1_C Angle   Calc    116.9(6), Rep    116.9(2) ......       3.00 su-Rat
              C19  -C14  -P3      1.555   1.555   1.555
PLAT732_ALERT_1_C Angle   Calc    123.1(6), Rep    123.1(2) ......       3.00 su-Rat
              C15  -C14  -P3      1.555   1.555   1.555
PLAT732_ALERT_1_C Angle   Calc    120.9(5), Rep    120.9(2) ......       2.50 su-Rat
              C25  -C20  -P3      1.555   1.555   1.555
PLAT732_ALERT_1_C Angle   Calc    119.1(5), Rep    119.0(2) ......       2.50 su-Rat
              C21  -C20  -P3      1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc   -179.2(7), Rep   -179.2(2) ......       3.50 su-Rat
              P4  -C1  -C2  -C3     1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    179.2(7), Rep    179.1(2) ......       3.50 su-Rat
              P4  -C1  -C6  -C5     1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc   -179.4(7), Rep   -179.4(2) ......       3.50 su-Rat
              P3  -C14 -C15 -C16    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    179.5(7), Rep    179.5(2) ......       3.50 su-Rat
              P3  -C14 -C19 -C18    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc   -178.5(8), Rep   -178.5(3) ......       2.67 su-Rat
              P1  -C39 -C40 -C41    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    178.6(9), Rep    178.5(3) ......       3.00 su-Rat
              P1  -C39 -C44 -C43    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc   -175.1(8), Rep   -175.1(3) ......       2.67 su-Rat
              P1  -C45 -C46 -C47    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    174.9(9), Rep    174.8(4) ......       2.25 su-Rat
              P1  -C45 -C50 -C49    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc   -130.8(9), Rep   -130.8(4) ......       2.25 su-Rat
              C44 -C39 -P1  -C38    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    120.4(9), Rep    120.4(4) ......       2.25 su-Rat
              C44 -C39 -P1  -C45    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc     -5.4(9), Rep     -5.5(3) ......       3.00 su-Rat
              C44 -C39 -P1  -AU1    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc   -108.7(8), Rep   -108.6(3) ......       2.67 su-Rat
              C50 -C45 -P1  -AU1    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc   -149.6(7), Rep   -149.6(3) ......       2.33 su-Rat
              C27 -C26 -P2  -C32    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc     88.0(7), Rep     88.1(3) ......       2.33 su-Rat
              C27 -C26 -P2  -AU2    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    -88.2(7), Rep    -88.2(2) ......       3.50 su-Rat
              C31 -C26 -P2  -AU2    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    111.4(7), Rep    111.4(3) ......       2.33 su-Rat
              C15 -C14 -P3  -C20    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc     52.7(7), Rep     52.7(3) ......       2.33 su-Rat
              C19 -C14 -P3  -AU3    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    133.4(5), Rep    133.4(2) ......       2.50 su-Rat
              C25 -C20 -P3  -C14    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc   -171.0(4), Rep -171.04(15) ......       2.67 su-Rat
              C21 -C20 -P3  -AU3    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    -40.8(7), Rep    -40.9(3) ......       2.33 su-Rat
              C2  -C1  -P4  -AU2    1.555   1.555   1.555   1.555
PLAT733_ALERT_1_C Torsion Calc    139.9(6), Rep    140.0(2) ......       3.00 su-Rat
              C6  -C1  -P4  -AU2    1.555   1.555   1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.40247, Rep    1.403(3) ......  Senseless su
              C1   -C2      1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.40330, Rep    1.403(3) ......  Senseless su
              C1   -C6      1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.40242, Rep    1.403(3) ......  Senseless su
              C2   -C3      1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.40453, Rep    1.403(2) ......  Senseless su
              C3   -C4      1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.40158, Rep    1.403(3) ......  Senseless su
              C4   -C5      1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.40242, Rep    1.403(2) ......  Senseless su
              C5   -C6      1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.38752, Rep    1.388(2) ......  Senseless su
              C7   -C8      1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.38866, Rep    1.388(2) ......  Senseless su
              C7   -C12     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.38841, Rep    1.388(3) ......  Senseless su
              C8   -C9      1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.38866, Rep    1.388(2) ......  Senseless su
              C9   -C10     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.38752, Rep    1.388(2) ......  Senseless su
              C10  -C11     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.38841, Rep    1.388(2) ......  Senseless su
              C11  -C12     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37431, Rep  1.3742(17) ......  Senseless su
              C14  -C19     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37435, Rep  1.3742(17) ......  Senseless su
              C14  -C15     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37371, Rep  1.3742(17) ......  Senseless su
              C15  -C16     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37465, Rep  1.3742(17) ......  Senseless su
              C16  -C17     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37509, Rep  1.3741(17) ......  Senseless su
              C17  -C18     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37381, Rep  1.3742(17) ......  Senseless su
              C18  -C19     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.41193, Rep  1.4120(17) ......  Senseless su
              C20  -C25     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.41074, Rep  1.4121(18) ......  Senseless su
              C20  -C21     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.41234, Rep  1.4120(18) ......  Senseless su
              C21  -C22     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.41193, Rep  1.4120(17) ......  Senseless su
              C22  -C23     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.41266, Rep  1.4120(17) ......  Senseless su
              C23  -C24     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.41204, Rep  1.4120(17) ......  Senseless su
              C24  -C25     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.33978, Rep  1.3393(16) ......  Senseless su
              C26  -C27     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.33919, Rep  1.3393(16) ......  Senseless su
              C26  -C31     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.33902, Rep  1.3393(17) ......  Senseless su
              C27  -C28     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.33919, Rep  1.3392(16) ......  Senseless su
              C28  -C29     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.33999, Rep  1.3393(16) ......  Senseless su
              C29  -C30     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.33884, Rep  1.3393(16) ......  Senseless su
              C30  -C31     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.38067, Rep    1.379(7) ......  Senseless su
              C32  -C33     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37982, Rep    1.380(7) ......  Senseless su
              C32  -C37     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37929, Rep    1.380(7) ......  Senseless su
              C33  -C34     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37808, Rep    1.380(7) ......  Senseless su
              C34  -C35     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37880, Rep    1.380(7) ......  Senseless su
              C35  -C36     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.37880, Rep    1.379(7) ......  Senseless su
              C36  -C37     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.35131, Rep    1.352(3) ......  Senseless su
              C39  -C40     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.35279, Rep    1.352(3) ......  Senseless su
              C39  -C44     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.35308, Rep    1.352(3) ......  Senseless su
              C40  -C41     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.35178, Rep    1.352(3) ......  Senseless su
              C41  -C42     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.35194, Rep    1.352(3) ......  Senseless su
              C42  -C43     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.35161, Rep    1.352(3) ......  Senseless su
              C43  -C44     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.36074, Rep    1.361(3) ......  Senseless su
              C45  -C46     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.36265, Rep    1.361(3) ......  Senseless su
              C45  -C50     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.36132, Rep    1.361(3) ......  Senseless su
              C46  -C47     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.36183, Rep    1.361(3) ......  Senseless su
              C47  -C48     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.36156, Rep    1.361(3) ......  Senseless su
              C48  -C49     1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     1.36072, Rep    1.361(3) ......  Senseless su
              C49  -C50     1.555   1.555


   7 ALERT level A = In general: serious problem
   9 ALERT level B = Potentially serious problem
 100 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

  29 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  30 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
  55 ALERT type 4 Improvement, methodology, query or suggestion
Computing details top

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 2001); software used to prepare material for publication: SHELXTL.

Dichloro-1κCl,3κCl-bis[µ-methylenebis(diphenylphosphine)]- 1:2κ2P:P';2:3κ2P:P'-trigold(I) perchlorate top
Crystal data top
[Au3Cl2(C25H22P2)2]ClO4Z = 2
Mr = 1529.98F(000) = 1448
Triclinic, P1Dx = 1.989 Mg m−3
Hall symbol: -P1Mo Kα radiation, λ = 0.71073 Å
a = 9.8043 (10) ÅCell parameters from 4862 reflections
b = 15.1538 (16) Åθ = 2.2–24.6°
c = 18.8497 (19) ŵ = 8.92 mm−1
α = 104.648 (2)°T = 293 K
β = 102.068 (2)°Block, black
γ = 101.456 (2)°0.4 × 0.3 × 0.15 mm
V = 2554.3 (5) Å3
Data collection top
Bruker SMART CCD area-detector
diffractometer		9809 independent reflections
Radiation source: fine-focus sealed tube7107 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.028
φ and ω scansθmax = 26.0°, θmin = 2.1°
Absorption correction: multi-scan
(SADABS; Bruker, 2003)		h = −12→11
Tmin = 0.050, Tmax = 0.262k = −18→8
13943 measured reflectionsl = −21→23
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.054Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.176H-atom parameters constrained
S = 1.03 w = 1/[σ2(Fo2) + (0.1057P)2]
where P = (Fo2 + 2Fc2)/3
9809 reflections(Δ/σ)max = 0.010
461 parametersΔρmax = 2.18 e Å−3
324 restraintsΔρmin = −1.04 e Å−3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Au10.64415 (5)0.38640 (3)0.22806 (3)0.05829 (16)
Au20.96100 (5)0.46767 (3)0.23119 (2)0.05446 (16)
Au30.89526 (5)0.54314 (4)0.39019 (2)0.06019 (17)
C10.8285 (7)0.5909 (5)0.1157 (4)0.075 (4)
C20.8235 (8)0.5157 (5)0.0531 (5)0.121 (6)
H20.88260.47560.05900.145*
C30.7295 (10)0.5010 (7)−0.0185 (5)0.153 (8)
H30.72620.4512−0.06010.183*
C40.6403 (10)0.5616 (8)−0.0275 (6)0.165 (9)
H40.57800.5518−0.07500.198*
C50.6453 (9)0.6367 (8)0.0351 (6)0.135 (7)
H50.58620.67680.02920.162*
C60.7393 (8)0.6514 (6)0.1067 (5)0.116 (6)
H60.74260.70120.14830.139*
C71.1212 (6)0.6712 (4)0.1987 (3)0.056 (3)
C81.1298 (6)0.7552 (4)0.1809 (3)0.063 (3)
H81.04750.77680.17090.075*
C91.2611 (8)0.8071 (5)0.1780 (4)0.095 (5)
H91.26680.86340.16610.115*
C101.3839 (8)0.7749 (6)0.1930 (4)0.093 (4)
H101.47190.80970.19110.111*
C111.3753 (8)0.6909 (6)0.2108 (5)0.104 (5)
H111.45760.66940.22080.125*
C121.2440 (7)0.6390 (5)0.2137 (4)0.080 (4)
H121.23830.58270.22560.096*
C140.9322 (7)0.7742 (5)0.4349 (4)0.095 (5)
C150.8617 (8)0.8358 (6)0.4111 (5)0.108 (5)
H150.83280.82970.35950.129*
C160.8340 (9)0.9064 (6)0.4635 (6)0.143 (8)
H160.78630.94800.44740.172*
C170.8767 (10)0.9153 (7)0.5398 (6)0.128 (7)
H170.85790.96310.57530.153*
C180.9472 (10)0.8537 (6)0.5637 (5)0.220 (14)
H180.97610.85980.61530.264*
C190.9749 (8)0.7832 (5)0.5112 (4)0.158 (9)
H191.02260.74150.52730.190*
C201.1655 (5)0.7144 (4)0.3904 (3)0.084 (4)
C211.2378 (7)0.8060 (5)0.3931 (4)0.111 (6)
H211.18580.85020.38770.133*
C221.3890 (7)0.8307 (5)0.4038 (5)0.140 (7)
H221.43660.89110.40560.168*
C231.4679 (7)0.7637 (5)0.4119 (5)0.143 (8)
H231.56740.78000.41900.172*
C241.3956 (6)0.6720 (4)0.4093 (4)0.134 (7)
H241.44750.62790.41460.161*
C251.2444 (5)0.6474 (4)0.3985 (3)0.097 (5)
H251.19680.58700.39680.117*
C261.1746 (7)0.3515 (5)0.3166 (4)0.054 (3)
C271.1705 (8)0.3611 (5)0.3887 (5)0.118 (6)
H271.08220.35220.40030.142*
C281.2937 (9)0.3834 (5)0.4440 (4)0.154 (8)
H281.29090.39000.49410.185*
C291.4210 (8)0.3962 (5)0.4273 (4)0.116 (6)
H291.50660.41170.46570.139*
C301.4251 (8)0.3867 (5)0.3552 (5)0.144 (7)
H301.51350.39560.34360.172*
C311.3019 (8)0.3643 (5)0.2999 (4)0.122 (6)
H311.30470.35770.24980.147*
C321.0397 (10)0.2597 (7)0.1546 (5)0.068 (3)
C331.0676 (11)0.1728 (7)0.1492 (6)0.093 (4)
H331.07100.14890.19010.112*
C341.0902 (13)0.1216 (8)0.0830 (7)0.116 (6)
H341.10900.06300.07940.139*
C351.0851 (13)0.1571 (10)0.0223 (7)0.126 (6)
H351.10040.1225−0.02230.151*
C361.0573 (13)0.2439 (10)0.0277 (6)0.130 (7)
H361.05380.2679−0.01330.156*
C371.0346 (12)0.2952 (8)0.0938 (6)0.108 (5)
H371.01580.35380.09740.130*
C380.8702 (11)0.2498 (8)0.2642 (7)0.054 (3)
H38A0.88350.18650.25130.065*
H38B0.88140.27120.31860.065*
C390.6647 (8)0.1799 (6)0.1155 (4)0.079 (4)
C400.7017 (8)0.0974 (7)0.0977 (5)0.101 (5)
H400.73760.07300.13610.121*
C410.6866 (11)0.0504 (8)0.0240 (7)0.131 (7)
H410.7121−0.00640.01180.158*
C420.6345 (11)0.0859 (9)−0.0318 (7)0.148 (8)
H420.62410.0535−0.08240.178*
C430.5974 (12)0.1684 (10)−0.0139 (7)0.222 (14)
H430.56160.1929−0.05230.267*
C440.6126 (12)0.2155 (8)0.0597 (6)0.149 (8)
H440.58710.27220.07200.179*
C450.5753 (8)0.1668 (5)0.2502 (4)0.063 (3)
C460.4312 (8)0.1355 (7)0.2142 (5)0.157 (9)
H460.39480.15030.17030.189*
C470.3402 (10)0.0825 (9)0.2424 (6)0.156 (8)
H470.24180.06110.21780.187*
C480.3934 (13)0.0608 (8)0.3067 (7)0.109 (5)
H480.33130.02450.32600.131*
C490.5376 (13)0.0920 (9)0.3427 (7)0.196 (11)
H490.57390.07720.38660.235*
C500.6285 (10)0.1450 (8)0.3145 (5)0.152 (8)
H500.72700.16640.33910.182*
Cl10.8212 (3)0.4101 (2)0.42315 (17)0.0690 (8)
Cl20.5704 (4)0.5216 (2)0.2358 (2)0.0825 (10)
Cl30.8987 (7)0.9437 (3)0.2244 (4)0.1187 (17)
O10.956 (3)0.9321 (18)0.1647 (13)0.237 (10)
O20.902 (2)1.0374 (11)0.2532 (11)0.197 (7)
O30.772 (2)0.8917 (18)0.2228 (16)0.246 (10)
O41.0097 (16)0.9200 (10)0.2781 (8)0.137 (5)
P10.6885 (3)0.2452 (2)0.21414 (17)0.0528 (7)
P21.0112 (3)0.32851 (19)0.24149 (16)0.0476 (6)
P30.9732 (4)0.6835 (2)0.37259 (17)0.0641 (8)
P40.9514 (3)0.6079 (2)0.20545 (16)0.0529 (7)
C130.9044 (12)0.6881 (8)0.2776 (6)0.058 (3)
H13A0.79980.67440.26570.070*
H13B0.94080.75190.27650.070*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Au10.0581 (3)0.0564 (3)0.0675 (3)0.0204 (2)0.0146 (2)0.0293 (2)
Au20.0761 (3)0.0360 (2)0.0535 (3)0.0107 (2)0.0187 (2)0.0200 (2)
Au30.0683 (3)0.0664 (3)0.0466 (3)0.0085 (2)0.0200 (2)0.0224 (2)
C10.107 (8)0.062 (7)0.047 (6)0.001 (6)0.013 (5)0.023 (5)
C20.135 (10)0.119 (10)0.098 (9)0.013 (8)0.025 (7)0.039 (8)
C30.163 (12)0.154 (12)0.135 (11)0.021 (9)0.039 (9)0.051 (9)
C40.167 (12)0.173 (12)0.145 (12)0.029 (9)0.020 (8)0.064 (9)
C50.126 (10)0.145 (11)0.136 (10)0.043 (8)0.015 (8)0.060 (9)
C60.128 (9)0.125 (10)0.087 (8)0.018 (8)0.011 (7)0.048 (8)
C70.077 (6)0.043 (5)0.052 (6)0.016 (5)0.022 (5)0.019 (5)
C80.081 (6)0.053 (6)0.073 (6)0.025 (5)0.033 (5)0.036 (5)
C90.115 (8)0.076 (8)0.108 (8)0.021 (6)0.043 (7)0.042 (7)
C100.085 (7)0.096 (8)0.108 (8)0.016 (6)0.037 (6)0.048 (7)
C110.104 (8)0.104 (9)0.117 (9)0.019 (7)0.045 (7)0.052 (7)
C120.087 (7)0.068 (7)0.098 (8)0.034 (6)0.034 (6)0.031 (6)
C140.103 (8)0.094 (8)0.080 (8)0.002 (7)0.035 (6)0.027 (7)
C150.101 (8)0.103 (9)0.117 (9)0.020 (7)0.056 (7)0.013 (7)
C160.142 (11)0.137 (11)0.144 (11)0.018 (8)0.046 (8)0.038 (9)
C170.130 (10)0.123 (10)0.129 (10)0.037 (8)0.056 (8)0.017 (8)
C180.230 (16)0.221 (16)0.213 (16)0.076 (10)0.047 (10)0.072 (10)
C190.178 (12)0.154 (12)0.144 (12)0.070 (9)0.038 (9)0.032 (9)
C200.087 (7)0.086 (8)0.077 (7)−0.001 (6)0.020 (6)0.042 (6)
C210.112 (9)0.116 (10)0.095 (8)0.002 (7)0.044 (7)0.029 (7)
C220.132 (10)0.147 (11)0.142 (11)0.003 (8)0.061 (8)0.053 (9)
C230.119 (10)0.152 (11)0.157 (11)0.038 (8)0.016 (8)0.061 (9)
C240.101 (9)0.150 (11)0.155 (11)0.048 (8)0.019 (7)0.054 (8)
C250.088 (8)0.124 (9)0.093 (8)0.033 (7)0.026 (6)0.049 (7)
C260.054 (5)0.051 (6)0.060 (6)0.009 (4)0.021 (4)0.021 (5)
C270.089 (8)0.166 (11)0.100 (9)0.042 (8)0.014 (7)0.045 (8)
C280.134 (11)0.184 (12)0.144 (11)0.025 (8)0.054 (9)0.050 (9)
C290.108 (9)0.131 (10)0.103 (9)0.012 (7)0.037 (7)0.034 (8)
C300.119 (10)0.181 (12)0.132 (10)0.019 (8)0.060 (8)0.044 (8)
C310.086 (8)0.166 (11)0.109 (9)0.021 (7)0.026 (7)0.042 (8)
C320.071 (6)0.055 (6)0.075 (7)0.005 (5)0.027 (5)0.017 (6)
C330.107 (8)0.073 (8)0.099 (8)0.020 (6)0.055 (7)0.006 (6)
C340.114 (9)0.117 (10)0.119 (9)0.034 (7)0.050 (7)0.025 (8)
C350.135 (10)0.125 (10)0.110 (9)0.021 (8)0.058 (8)0.013 (8)
C360.143 (10)0.140 (11)0.115 (10)0.023 (8)0.058 (8)0.044 (8)
C370.139 (9)0.114 (9)0.077 (8)0.017 (7)0.052 (7)0.033 (7)
C380.060 (5)0.047 (5)0.063 (6)0.012 (4)0.025 (5)0.028 (5)
C390.079 (7)0.079 (7)0.082 (7)0.019 (6)0.029 (6)0.024 (6)
C400.094 (8)0.096 (9)0.099 (8)0.028 (7)0.029 (7)0.005 (7)
C410.121 (10)0.129 (11)0.135 (10)0.027 (8)0.049 (8)0.020 (8)
C420.161 (11)0.150 (12)0.134 (11)0.019 (8)0.064 (9)0.041 (9)
C430.257 (16)0.221 (16)0.200 (16)0.052 (10)0.076 (10)0.081 (11)
C440.197 (12)0.133 (11)0.122 (10)0.044 (9)0.040 (8)0.049 (9)
C450.063 (6)0.057 (6)0.070 (6)0.010 (5)0.022 (5)0.022 (5)
C460.151 (11)0.156 (12)0.166 (12)0.015 (8)0.057 (9)0.062 (9)
C470.147 (11)0.154 (12)0.173 (12)0.025 (8)0.059 (9)0.059 (9)
C480.106 (9)0.116 (9)0.113 (9)0.009 (7)0.048 (7)0.048 (8)
C490.193 (14)0.201 (14)0.200 (14)0.028 (9)0.059 (10)0.089 (10)
C500.146 (11)0.167 (12)0.152 (11)0.018 (8)0.045 (8)0.079 (9)
Cl10.0763 (18)0.074 (2)0.0641 (19)0.0140 (16)0.0257 (15)0.0333 (17)
Cl20.0719 (19)0.063 (2)0.117 (3)0.0266 (16)0.0153 (19)0.037 (2)
Cl30.170 (5)0.059 (2)0.157 (5)0.042 (3)0.076 (4)0.049 (3)
O10.319 (19)0.229 (17)0.198 (15)0.068 (14)0.114 (14)0.092 (13)
O20.284 (16)0.093 (9)0.227 (15)0.096 (10)0.046 (12)0.059 (10)
O30.194 (15)0.211 (16)0.323 (19)0.021 (13)0.078 (14)0.084 (15)
O40.177 (11)0.121 (10)0.136 (10)0.082 (9)0.041 (8)0.047 (8)
P10.0547 (15)0.0506 (17)0.0582 (17)0.0144 (13)0.0192 (13)0.0219 (15)
P20.0560 (15)0.0370 (14)0.0553 (16)0.0120 (12)0.0219 (13)0.0182 (13)
P30.075 (2)0.063 (2)0.0475 (17)−0.0001 (16)0.0216 (14)0.0150 (16)
P40.0771 (19)0.0380 (15)0.0444 (15)0.0102 (13)0.0150 (13)0.0191 (13)
C130.065 (6)0.051 (6)0.061 (6)0.008 (5)0.015 (5)0.028 (5)
Geometric parameters (Å, º) top
Au1—P12.230 (3)C26—P21.809 (8)
Au1—Cl22.286 (3)C27—C281.3393 (17)
Au1—Au23.0883 (7)C27—H270.930
Au2—P22.304 (3)C28—C291.3392 (16)
Au2—P42.311 (3)C28—H280.930
Au2—Au33.1738 (7)C29—C301.3393 (16)
Au3—P32.243 (3)C29—H290.930
Au3—Cl12.285 (3)C30—C311.3393 (16)
C1—C21.403 (3)C30—H300.930
C1—C61.403 (3)C31—H310.930
C1—P41.784 (7)C32—C331.379 (7)
C2—C31.403 (3)C32—C371.380 (7)
C2—H20.930C32—P21.815 (9)
C3—C41.403 (2)C33—C341.380 (7)
C3—H30.930C33—H330.930
C4—C51.403 (3)C34—C351.380 (7)
C4—H40.930C34—H340.930
C5—C61.403 (2)C35—C361.380 (7)
C5—H50.930C35—H350.930
C6—H60.930C36—C371.379 (7)
C7—C81.388 (2)C36—H360.930
C7—C121.388 (2)C37—H370.930
C7—P41.795 (6)C38—P11.812 (11)
C8—C91.388 (3)C38—P21.835 (10)
C8—H80.930C38—H38A0.970
C9—C101.388 (2)C38—H38B0.970
C9—H90.930C39—C401.352 (3)
C10—C111.388 (2)C39—C441.352 (3)
C10—H100.930C39—P11.813 (8)
C11—C121.388 (2)C40—C411.352 (3)
C11—H110.930C40—H400.930
C12—H120.930C41—C421.352 (3)
C14—C191.3742 (17)C41—H410.930
C14—C151.3742 (17)C42—C431.352 (3)
C14—P31.741 (8)C42—H420.930
C15—C161.3742 (17)C43—C441.352 (3)
C15—H150.930C43—H430.930
C16—C171.3742 (17)C44—H440.930
C16—H160.930C45—C461.361 (3)
C17—C181.3741 (17)C45—C501.361 (3)
C17—H170.930C45—P11.818 (8)
C18—C191.3742 (17)C46—C471.361 (3)
C18—H180.930C46—H460.930
C19—H190.930C47—C481.361 (3)
C20—C251.4120 (17)C47—H470.930
C20—C211.4121 (18)C48—C491.361 (3)
C20—P31.787 (6)C48—H480.930
C21—C221.4120 (18)C49—C501.361 (3)
C21—H210.930C49—H490.930
C22—C231.4120 (17)C50—H500.930
C22—H220.930Cl3—O31.33 (2)
C23—C241.4120 (17)Cl3—O11.34 (2)
C23—H230.930Cl3—O21.378 (15)
C24—C251.4120 (17)Cl3—O41.490 (13)
C24—H240.930P3—C131.801 (11)
C25—H250.930P4—C131.785 (12)
C26—C271.3393 (16)C13—H13A0.970
C26—C311.3393 (16)C13—H13B0.970
P1—Au1—Cl2173.19 (11)C26—C31—C30120.0
P1—Au1—Au288.40 (7)C26—C31—H31120.0
Cl2—Au1—Au297.84 (9)C30—C31—H31120.0
P2—Au2—P4166.55 (10)C33—C32—C37120.0
P2—Au2—Au189.71 (7)C33—C32—P2120.5 (6)
P4—Au2—Au1101.67 (8)C37—C32—P2119.5 (6)
P2—Au2—Au3100.00 (7)C32—C33—C34120.0
P4—Au2—Au391.15 (8)C32—C33—H33120.0
Au1—Au2—Au366.846 (16)C34—C33—H33120.0
P3—Au3—Cl1173.15 (11)C33—C34—C35120.0
P3—Au3—Au281.96 (8)C33—C34—H34120.0
Cl1—Au3—Au2104.52 (8)C35—C34—H34120.0
C2—C1—C6120.0C36—C35—C34120.0
C2—C1—P4118.5 (3)C36—C35—H35120.0
C6—C1—P4121.5 (3)C34—C35—H35120.0
C1—C2—C3120.0C37—C36—C35120.0
C1—C2—H2120.0C37—C36—H36120.0
C3—C2—H2120.0C35—C36—H36120.0
C2—C3—C4120.0C36—C37—C32120.0
C2—C3—H3120.0C36—C37—H37120.0
C4—C3—H3120.0C32—C37—H37120.0
C5—C4—C3120.0P1—C38—P2113.2 (6)
C5—C4—H4120.0P1—C38—H38A108.9
C3—C4—H4120.0P2—C38—H38A108.9
C6—C5—C4120.0P1—C38—H38B108.9
C6—C5—H5120.0P2—C38—H38B108.9
C4—C5—H5120.0H38A—C38—H38B107.7
C5—C6—C1120.0C40—C39—C44120.0
C5—C6—H6120.0C40—C39—P1120.5 (4)
C1—C6—H6120.0C44—C39—P1119.5 (4)
C8—C7—C12120.0C41—C40—C39120.0
C8—C7—P4119.0 (3)C41—C40—H40120.0
C12—C7—P4121.0 (3)C39—C40—H40120.0
C7—C8—C9120.0C40—C41—C42120.0
C7—C8—H8120.0C40—C41—H41120.0
C9—C8—H8120.0C42—C41—H41120.0
C10—C9—C8120.0C41—C42—C43120.0
C10—C9—H9120.0C41—C42—H42120.0
C8—C9—H9120.0C43—C42—H42120.0
C9—C10—C11120.0C44—C43—C42120.0
C9—C10—H10120.0C44—C43—H43120.0
C11—C10—H10120.0C42—C43—H43120.0
C12—C11—C10120.0C43—C44—C39120.0
C12—C11—H11120.0C43—C44—H44120.0
C10—C11—H11120.0C39—C44—H44120.0
C11—C12—C7120.0C46—C45—C50120.0
C11—C12—H12120.0C46—C45—P1117.7 (4)
C7—C12—H12120.0C50—C45—P1122.1 (4)
C19—C14—C15120.0C47—C46—C45120.0
C19—C14—P3116.9 (2)C47—C46—H46120.0
C15—C14—P3123.1 (2)C45—C46—H46120.0
C16—C15—C14120.0C46—C47—C48120.0
C16—C15—H15120.0C46—C47—H47120.0
C14—C15—H15120.0C48—C47—H47120.0
C15—C16—C17120.0C47—C48—C49120.0
C15—C16—H16120.0C47—C48—H48120.0
C17—C16—H16120.0C49—C48—H48120.0
C18—C17—C16120.0C50—C49—C48120.0
C18—C17—H17120.0C50—C49—H49120.0
C16—C17—H17120.0C48—C49—H49120.0
C17—C18—C19120.0C49—C50—C45120.0
C17—C18—H18120.0C49—C50—H50120.0
C19—C18—H18120.0C45—C50—H50120.0
C18—C19—C14120.0O3—Cl3—O1123.9 (17)
C18—C19—H19120.0O3—Cl3—O2107.8 (15)
C14—C19—H19120.0O1—Cl3—O2109.8 (14)
C25—C20—C21120.0O3—Cl3—O4106.2 (13)
C25—C20—P3120.9 (2)O1—Cl3—O499.0 (13)
C21—C20—P3119.0 (2)O2—Cl3—O4109.2 (10)
C22—C21—C20120.0C38—P1—C39105.5 (5)
C22—C21—H21120.0C38—P1—C45103.1 (4)
C20—C21—H21120.0C39—P1—C45105.7 (4)
C23—C22—C21120.0C38—P1—Au1114.2 (4)
C23—C22—H22120.0C39—P1—Au1112.9 (3)
C21—C22—H22120.0C45—P1—Au1114.5 (3)
C22—C23—C24120.0C26—P2—C32106.6 (4)
C22—C23—H23120.0C26—P2—C38105.6 (4)
C24—C23—H23120.0C32—P2—C38106.4 (5)
C25—C24—C23120.0C26—P2—Au2111.0 (2)
C25—C24—H24120.0C32—P2—Au2112.1 (3)
C23—C24—H24120.0C38—P2—Au2114.5 (4)
C20—C25—C24120.0C14—P3—C20106.6 (3)
C20—C25—H25120.0C14—P3—C13107.3 (5)
C24—C25—H25120.0C20—P3—C13105.2 (4)
C27—C26—C31120.0C14—P3—Au3111.9 (3)
C27—C26—P2121.1 (3)C20—P3—Au3110.3 (3)
C31—C26—P2118.8 (3)C13—P3—Au3115.0 (4)
C28—C27—C26120.0C1—P4—C13108.4 (5)
C28—C27—H27120.0C1—P4—C7103.8 (3)
C26—C27—H27120.0C13—P4—C7105.7 (4)
C29—C28—C27120.0C1—P4—Au2113.0 (3)
C29—C28—H28120.0C13—P4—Au2112.5 (4)
C27—C28—H28120.0C7—P4—Au2112.8 (2)
C28—C29—C30120.0P4—C13—P3114.4 (6)
C28—C29—H29120.0P4—C13—H13A108.7
C30—C29—H29120.0P3—C13—H13A108.7
C29—C30—C31120.0P4—C13—H13B108.7
C29—C30—H30120.0P3—C13—H13B108.7
C31—C30—H30120.0H13A—C13—H13B107.6
P1—Au1—Au2—P2−10.83 (10)C40—C39—P1—Au1173.1 (4)
Cl2—Au1—Au2—P2171.92 (13)C44—C39—P1—Au1−5.5 (3)
P1—Au1—Au2—P4161.95 (11)C46—C45—P1—C38−169.1 (5)
Cl2—Au1—Au2—P4−15.30 (13)C50—C45—P1—C3816.0 (5)
P1—Au1—Au2—Au3−111.84 (8)C46—C45—P1—C39−58.6 (7)
Cl2—Au1—Au2—Au370.91 (11)C50—C45—P1—C39126.5 (4)
P2—Au2—Au3—P3152.35 (12)C46—C45—P1—Au166.3 (4)
P4—Au2—Au3—P3−20.08 (12)C50—C45—P1—Au1−108.6 (3)
Au1—Au2—Au3—P3−122.30 (9)Cl2—Au1—P1—C38−169.1 (11)
P2—Au2—Au3—Cl1−25.39 (11)Au2—Au1—P1—C3834.5 (4)
P4—Au2—Au3—Cl1162.17 (11)Cl2—Au1—P1—C3970.4 (11)
Au1—Au2—Au3—Cl159.96 (8)Au2—Au1—P1—C39−86.0 (3)
C6—C1—C2—C30.0Cl2—Au1—P1—C45−50.6 (12)
P4—C1—C2—C3−179.2 (2)Au2—Au1—P1—C45153.0 (3)
C1—C2—C3—C40.0C27—C26—P2—C32−149.6 (3)
C2—C3—C4—C50.0C31—C26—P2—C3234.2 (4)
C3—C4—C5—C60.0C27—C26—P2—C38−36.6 (5)
C4—C5—C6—C10.0C31—C26—P2—C38147.1 (4)
C2—C1—C6—C50.0C27—C26—P2—Au288.1 (3)
P4—C1—C6—C5179.1 (2)C31—C26—P2—Au2−88.2 (2)
C12—C7—C8—C90.0C33—C32—P2—C2660.0 (6)
P4—C7—C8—C9177.7 (3)C37—C32—P2—C26−119.5 (6)
C7—C8—C9—C100.0C33—C32—P2—C38−52.4 (7)
C8—C9—C10—C110.0C37—C32—P2—C38128.1 (6)
C9—C10—C11—C120.0C33—C32—P2—Au2−178.4 (5)
C10—C11—C12—C70.0C37—C32—P2—Au22.2 (6)
C8—C7—C12—C110.0P1—C38—P2—C26162.6 (5)
P4—C7—C12—C11−177.7 (3)P1—C38—P2—C32−84.3 (7)
C19—C14—C15—C160.0P1—C38—P2—Au240.2 (7)
P3—C14—C15—C16−179.4 (2)P4—Au2—P2—C2679.7 (5)
C14—C15—C16—C170.0Au1—Au2—P2—C26−132.2 (3)
C15—C16—C17—C180.0Au3—Au2—P2—C26−65.8 (3)
C16—C17—C18—C190.0P4—Au2—P2—C32−39.4 (6)
C17—C18—C19—C140.0Au1—Au2—P2—C32108.6 (3)
C15—C14—C19—C180.0Au3—Au2—P2—C32175.0 (3)
P3—C14—C19—C18179.5 (2)P4—Au2—P2—C38−160.8 (5)
C25—C20—C21—C220.0Au1—Au2—P2—C38−12.8 (4)
P3—C20—C21—C22−177.3 (3)Au3—Au2—P2—C3853.6 (4)
C20—C21—C22—C230.0C19—C14—P3—C20−68.0 (4)
C21—C22—C23—C240.0C15—C14—P3—C20111.4 (3)
C22—C23—C24—C250.0C19—C14—P3—C13179.7 (4)
C21—C20—C25—C240.0C15—C14—P3—C13−0.9 (5)
P3—C20—C25—C24177.2 (3)C19—C14—P3—Au352.7 (3)
C23—C24—C25—C200.0C15—C14—P3—Au3−127.91 (15)
C31—C26—C27—C280.0C25—C20—P3—C14133.4 (2)
P2—C26—C27—C28−176.2 (3)C21—C20—P3—C14−49.4 (4)
C26—C27—C28—C290.0C25—C20—P3—C13−113.0 (4)
C27—C28—C29—C300.0C21—C20—P3—C1364.3 (5)
C28—C29—C30—C310.0C25—C20—P3—Au311.7 (3)
C27—C26—C31—C300.0C21—C20—P3—Au3−171.04 (15)
P2—C26—C31—C30176.3 (3)Cl1—Au3—P3—C14−32.2 (11)
C29—C30—C31—C260.0Au2—Au3—P3—C14166.4 (3)
C37—C32—C33—C340.0Cl1—Au3—P3—C2086.3 (11)
P2—C32—C33—C34−179.4 (7)Au2—Au3—P3—C20−75.1 (2)
C32—C33—C34—C350.0Cl1—Au3—P3—C13−154.9 (10)
C33—C34—C35—C360.0Au2—Au3—P3—C1343.7 (4)
C34—C35—C36—C370.0C2—C1—P4—C13−166.3 (4)
C35—C36—C37—C320.0C6—C1—P4—C1314.6 (5)
C33—C32—C37—C360.0C2—C1—P4—C781.7 (4)
P2—C32—C37—C36179.5 (7)C6—C1—P4—C7−97.4 (4)
C44—C39—C40—C410.0C2—C1—P4—Au2−40.9 (3)
P1—C39—C40—C41−178.5 (3)C6—C1—P4—Au2140.0 (2)
C39—C40—C41—C420.0C8—C7—P4—C155.1 (5)
C40—C41—C42—C430.0C12—C7—P4—C1−127.2 (3)
C41—C42—C43—C440.0C8—C7—P4—C13−58.8 (5)
C42—C43—C44—C390.0C12—C7—P4—C13118.9 (4)
C40—C39—C44—C430.0C8—C7—P4—Au2177.9 (3)
P1—C39—C44—C43178.5 (3)C12—C7—P4—Au2−4.4 (3)
C50—C45—C46—C470.0P2—Au2—P4—C187.5 (5)
P1—C45—C46—C47−175.1 (3)Au1—Au2—P4—C1−59.8 (3)
C45—C46—C47—C480.0Au3—Au2—P4—C1−126.4 (3)
C46—C47—C48—C490.0P2—Au2—P4—C13−149.4 (5)
C47—C48—C49—C500.0Au1—Au2—P4—C1363.3 (4)
C48—C49—C50—C450.0Au3—Au2—P4—C13−3.2 (4)
C46—C45—C50—C490.0P2—Au2—P4—C7−29.9 (5)
P1—C45—C50—C49174.8 (4)Au1—Au2—P4—C7−177.2 (2)
P2—C38—P1—C3971.4 (7)Au3—Au2—P4—C7116.2 (2)
P2—C38—P1—C45−178.0 (5)C1—P4—C13—P3160.0 (5)
P2—C38—P1—Au1−53.2 (7)C7—P4—C13—P3−89.2 (6)
C40—C39—P1—C3847.7 (6)Au2—P4—C13—P334.4 (7)
C44—C39—P1—C38−130.8 (4)C14—P3—C13—P4174.0 (5)
C40—C39—P1—C45−61.1 (7)C20—P3—C13—P460.8 (7)
C44—C39—P1—C45120.4 (4)Au3—P3—C13—P4−60.8 (7)
 

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