[1,2-Bis­(di­phenyl­phosphino)­ethane]­di­chloro­(methoxo)­oxorhenium(V) di­chloro­methane solvate

Beauchamp, A.L.; Sigouin, O.

doi:10.1107/S1600536805008718

[1,2-Bis(diphenylphosphino)ethane]dichloro(methoxo)oxorhenium(V) dichloromethane solvate

The title compound, [Re(CH₃O)Cl₂O(C₂₆H₂₄P₂)]·CH₂Cl₂, contains slightly distorted octahedrally coordinated molecules in which the methoxo group is trans to the oxo ligand. A cis arrangement of the Cl atoms is imposed in the equatorial plane by the bidentate diphosphine ligand. The methoxo group is approximately end-on coordinated [Re-O-CH₃ = 168.1 (5)°].

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805008718/cf6416sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536805008718/cf6416Isup2.hkl Contains datablock I

CCDC reference: 270259

checkCIF report

Key indicators

Single-crystal X-ray study
T = 223 K
Mean (C-C) = 0.013 Å
R factor = 0.047
wR factor = 0.122
Data-to-parameter ratio = 19.6

checkCIF/PLATON results

No syntax errors found



Alert level A
CHEMW03_ALERT_2_A ALERT: The ratio of given/expected molecular weight as
            calculated from the _atom_site* data lies outside
            the range 0.90 <> 1.10
           From the CIF: _cell_formula_units_Z                    4
           From the CIF: _chemical_formula_weight           787.45
           TEST: Calculate formula weight from _atom_site_*
           atom     mass    num     sum
           C        12.01   27.00  324.30
           H         1.01   27.00   27.22
           O        16.00    2.00   32.00
           P        30.97    2.00   61.95
           Cl       35.45    2.00   70.91
           Re      186.21    1.00  186.21
           Calculated formula weight              702.57
PLAT043_ALERT_1_A Check Reported Molecular Weight ................     787.45
PLAT044_ALERT_1_A Calculated and Reported Dx Differ ..............          ?
PLAT051_ALERT_1_A Mu(calc) and Mu(CIF) Ratio Differs from 1.0 by .      12.33 Perc.
PLAT601_ALERT_2_A Structure Contains Solvent Accessible VOIDS of .     282.00 A   3  

Alert level C
ABSMU01_ALERT_1_C  The ratio of given/expected absorption coefficient lies
               outside the range 0.99 <> 1.01
            Calculated value of mu =    12.122
            Value of mu given      =    11.960
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)...          ?
PLAT141_ALERT_4_C su on a - Axis Small or Missing (x 100000) .....         10 Ang.
PLAT142_ALERT_4_C su on b - Axis Small or Missing (x 100000) .....         10 Ang.
PLAT143_ALERT_4_C su on c - Axis Small or Missing (x 100000) .....         10 Ang.
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Re     -   O1      ..       7.59 su
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C43
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         12

Alert level G
FORMU01_ALERT_2_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and the formula from the _atom_site* data.
            Atom count from _chemical_formula_sum:C28 H29 Cl4 O2 P2 Re1
            Atom count from the _atom_site data:  C27 H27 Cl2 O2 P2 Re1
CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected.
CELLZ01_ALERT_1_G ALERT: Large difference may be due to a
            symmetry error - see SYMMG tests
           From the CIF: _cell_formula_units_Z    4
           From the CIF: _chemical_formula_sum  C28 H29 Cl4 O2 P2 Re
           TEST: Compare cell contents of formula and atom_site data

           atom    Z*formula  cif sites diff
           C        112.00    108.00    4.00
           H        116.00    108.00    8.00
           Cl        16.00      8.00    8.00
           O          8.00      8.00    0.00
           P          8.00      8.00    0.00
           Re         4.00      4.00    0.00

   5 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   9 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

   8 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 1999); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: UdMX (local program).

(Bis(diphenylphosphino)ethane)dichloro(oxo)methoxorhenium(V) top

Crystal data top

C₂₇H₂₇Cl₂O₂P₂Re·CH₂Cl₂	F(000) = 1544
M_r = 787.45	D_x = 1.703 Mg m⁻³
Monoclinic, P2₁/c	Cu Kα radiation, λ = 1.54178 Å
Hall symbol: -P 2ybc	Cell parameters from 27775 reflections
a = 11.3352 (1) Å	θ = 3.3–72.8°
b = 20.4411 (1) Å	µ = 11.96 mm⁻¹
c = 13.9594 (1) Å	T = 223 K
β = 108.303 (1)°	Platelet, purple
V = 3070.81 (4) Å³	0.42 × 0.12 × 0.06 mm
Z = 4

Data collection top

Bruker AXS Smart 2K/Platform diffractometer	6069 independent reflections
Radiation source: fine-focus sealed tube	5369 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.064
Detector resolution: 5.5 pixels mm^-1	θ_max = 72.9°, θ_min = 4.0°
ω scans	h = −14→14
Absorption correction: gaussian (ABSORP in NRCVAX; Gabe et al., 1989)	k = −24→25
T_min = 0.080, T_max = 0.530	l = −15→17
36674 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.047	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.122	H-atom parameters constrained
S = 1.11	w = 1/[σ²(F_o²) + (0.058P)² + 12.2591P] where P = (F_o² + 2F_c²)/3
6069 reflections	(Δ/σ)_max = 0.004
309 parameters	Δρ_max = 2.34 e Å⁻³
0 restraints	Δρ_min = −1.35 e Å⁻³

Special details top

Experimental. Compound characterization. Yield 65%. Anal. Calcd. For C₂₇H₂₇O₂P₂Cl₂Re (%): C 46,16, H 3.87; found: C 45,96, H 3,82. ¹H NMR (DMSO-d₆) (ppm) δ: 8.11 (m, 8H, H_o), 7.49 (m, 12H, H_m,p), _{3.30 (m, 2H, CH}2_{, partly masked by water peak),
3.15 (m, 2H, CH}2_{), 1.93 (s, 3H, OCH}3_{). ³¹P{¹H} NMR
(DMSO-d}6_{) (ppm)}_δ_{: 16.3 (s). IR (CsI, cm^-1): 947(s)}_ν_{(Re=O);
276(w)}_ν_(Re-Cl).

X-ray crystallographic data for (I) were collected from a single crystal sample, which was mounted on a loop fiber. Data were collected using a Bruker Platform diffractometer, equipped with a Bruker SMART 2K Charged-Coupled Device (CCD) Area Detector using the program SMART and normal focus sealed tube source graphite monochromated Cu-K_α_{radiation.
The crystal-to-detector distance was 4.908 cm, and the data collection
was carried out in 512 x 512 pixel mode, utilizing 4 x 4 pixel binning.
The initial unit cell parameters were determined by a least-squares fit
of the angular setting of strong reflections, collected by a 9.0 degree
scan in 30 frames over four different parts of the reciprocal space
(120 frames total). One complete sphere of data was collected, to
better than 0.8Å resolution. Upon completion of the data collection,
the first 101 frames were recollected in order to improve the decay
correction analysis.}

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Re	0.59317 (2)	0.171338 (12)	0.508670 (19)	0.03032 (10)
Cl11	0.45095 (15)	0.13484 (8)	0.34626 (11)	0.0434 (4)
Cl12	0.76127 (15)	0.13097 (9)	0.45048 (13)	0.0461 (4)
P1	0.72678 (14)	0.20443 (8)	0.67489 (12)	0.0334 (3)
P2	0.42920 (13)	0.20565 (8)	0.57480 (12)	0.0324 (3)
O1	0.6016 (4)	0.2505 (2)	0.4708 (3)	0.0403 (10)
O2	0.5811 (4)	0.0898 (2)	0.5659 (3)	0.0362 (9)
C61	0.5695 (8)	0.0368 (4)	0.6251 (6)	0.058 (2)
H61A	0.5633	0.0526	0.6889	0.087*
H61B	0.6417	0.0087	0.6374	0.087*
H61C	0.4952	0.0122	0.5901	0.087*
C11	0.7919 (6)	0.1354 (3)	0.7574 (5)	0.0388 (14)
C12	0.8595 (6)	0.0905 (4)	0.7223 (6)	0.0458 (16)
H12	0.8714	0.0972	0.6593	0.055*
C13	0.9098 (7)	0.0360 (4)	0.7781 (7)	0.058 (2)
H13	0.9564	0.0058	0.7540	0.069*
C14	0.8906 (8)	0.0262 (4)	0.8710 (6)	0.061 (2)
H14	0.9230	−0.0113	0.9091	0.073*
C15	0.8255 (9)	0.0703 (4)	0.9069 (6)	0.061 (2)
H15	0.8152	0.0640	0.9705	0.074*
C16	0.7738 (8)	0.1254 (4)	0.8490 (5)	0.0531 (18)
H16	0.7267	0.1554	0.8729	0.064*
C21	0.8590 (6)	0.2574 (3)	0.6850 (5)	0.0388 (14)
C22	0.9287 (8)	0.2800 (5)	0.7799 (6)	0.063 (2)
H22	0.9053	0.2688	0.8367	0.076*
C23	1.0312 (9)	0.3184 (5)	0.7910 (8)	0.079 (3)
H23	1.0778	0.3334	0.8555	0.095*
C24	1.0671 (8)	0.3355 (4)	0.7067 (8)	0.066 (2)
H24	1.1381	0.3613	0.7141	0.079*
C25	0.9969 (8)	0.3139 (4)	0.6138 (7)	0.062 (2)
H25	1.0188	0.3257	0.5565	0.074*
C26	0.8930 (7)	0.2745 (4)	0.6028 (6)	0.0518 (18)
H26	0.8460	0.2597	0.5384	0.062*
C31	0.2980 (6)	0.1526 (4)	0.5611 (6)	0.0439 (15)
C32	0.2017 (7)	0.1753 (4)	0.5967 (7)	0.059 (2)
H32	0.2099	0.2157	0.6304	0.070*
C33	0.0970 (8)	0.1388 (5)	0.5824 (9)	0.077 (3)
H33	0.0328	0.1546	0.6054	0.092*
C34	0.0841 (9)	0.0796 (5)	0.5350 (10)	0.089 (4)
H34	0.0129	0.0542	0.5282	0.106*
C35	0.1746 (8)	0.0569 (4)	0.4971 (9)	0.073 (3)
H35	0.1647	0.0165	0.4634	0.088*
C36	0.2813 (6)	0.0943 (3)	0.5091 (6)	0.0487 (17)
H36	0.3422	0.0796	0.4814	0.058*
C41	0.3570 (6)	0.2826 (3)	0.5243 (5)	0.0386 (14)
C42	0.2970 (10)	0.2869 (5)	0.4229 (6)	0.073 (3)
H42	0.3021	0.2520	0.3806	0.087*
C43	0.2291 (13)	0.3418 (6)	0.3816 (8)	0.096 (4)
H43	0.1849	0.3432	0.3123	0.116*
C44	0.2262 (9)	0.3952 (5)	0.4429 (8)	0.074 (3)
H44	0.1828	0.4334	0.4152	0.089*
C45	0.2867 (9)	0.3909 (4)	0.5429 (8)	0.067 (2)
H45	0.2837	0.4263	0.5850	0.081*
C46	0.3531 (8)	0.3354 (4)	0.5845 (7)	0.0558 (19)
H46	0.3957	0.3337	0.6541	0.067*
C51	0.6274 (6)	0.2502 (3)	0.7330 (5)	0.0390 (14)
H51A	0.6681	0.2531	0.8060	0.047*
H51B	0.6151	0.2948	0.7058	0.047*
C52	0.5016 (6)	0.2165 (3)	0.7117 (5)	0.0389 (14)
H52A	0.4473	0.2429	0.7387	0.047*
H52B	0.5129	0.1737	0.7452	0.047*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Re	0.02876 (15)	0.03297 (15)	0.03016 (16)	0.00007 (10)	0.01060 (10)	0.00066 (10)
Cl11	0.0456 (9)	0.0472 (8)	0.0339 (7)	−0.0047 (7)	0.0073 (6)	0.0001 (6)
Cl12	0.0395 (8)	0.0581 (10)	0.0458 (9)	0.0073 (7)	0.0206 (7)	−0.0038 (7)
P1	0.0282 (7)	0.0387 (8)	0.0322 (8)	0.0010 (6)	0.0080 (6)	0.0000 (6)
P2	0.0251 (7)	0.0375 (8)	0.0351 (8)	0.0003 (6)	0.0102 (6)	−0.0007 (6)
O1	0.034 (2)	0.048 (3)	0.039 (2)	0.0043 (19)	0.0116 (19)	−0.002 (2)
O2	0.035 (2)	0.034 (2)	0.039 (2)	0.0003 (18)	0.0115 (18)	0.0027 (18)
C61	0.058 (5)	0.050 (4)	0.058 (5)	−0.009 (4)	0.007 (4)	0.012 (4)
C11	0.033 (3)	0.046 (4)	0.032 (3)	0.000 (3)	0.002 (2)	0.002 (3)
C12	0.037 (4)	0.051 (4)	0.049 (4)	0.006 (3)	0.013 (3)	0.008 (3)
C13	0.045 (4)	0.054 (4)	0.069 (5)	0.009 (3)	0.010 (4)	0.007 (4)
C14	0.056 (5)	0.059 (5)	0.053 (5)	0.001 (4)	−0.003 (4)	0.022 (4)
C15	0.075 (6)	0.064 (5)	0.043 (4)	−0.003 (4)	0.016 (4)	0.008 (4)
C16	0.060 (5)	0.060 (5)	0.039 (4)	0.000 (4)	0.015 (3)	0.005 (3)
C21	0.028 (3)	0.038 (3)	0.047 (4)	0.002 (2)	0.008 (3)	0.001 (3)
C22	0.056 (5)	0.078 (6)	0.053 (5)	−0.018 (4)	0.012 (4)	−0.008 (4)
C23	0.050 (5)	0.102 (8)	0.074 (6)	−0.033 (5)	0.003 (5)	−0.018 (6)
C24	0.043 (4)	0.065 (5)	0.087 (7)	−0.011 (4)	0.016 (4)	−0.002 (5)
C25	0.046 (4)	0.069 (5)	0.076 (6)	−0.007 (4)	0.026 (4)	0.005 (4)
C26	0.045 (4)	0.059 (4)	0.051 (4)	−0.012 (3)	0.015 (3)	−0.001 (4)
C31	0.032 (3)	0.051 (4)	0.055 (4)	0.002 (3)	0.022 (3)	0.000 (3)
C32	0.042 (4)	0.062 (5)	0.087 (6)	−0.012 (3)	0.042 (4)	−0.014 (4)
C33	0.046 (5)	0.075 (6)	0.124 (9)	−0.019 (4)	0.049 (5)	−0.019 (6)
C34	0.053 (5)	0.069 (6)	0.164 (11)	−0.025 (5)	0.064 (7)	−0.027 (7)
C35	0.052 (5)	0.056 (5)	0.122 (8)	−0.015 (4)	0.042 (5)	−0.024 (5)
C36	0.035 (3)	0.044 (4)	0.072 (5)	−0.001 (3)	0.024 (3)	−0.005 (3)
C41	0.029 (3)	0.046 (4)	0.043 (4)	0.004 (3)	0.014 (3)	0.002 (3)
C42	0.089 (7)	0.073 (6)	0.047 (5)	0.033 (5)	0.008 (4)	0.001 (4)
C43	0.121 (10)	0.097 (8)	0.055 (6)	0.052 (7)	0.005 (6)	0.012 (5)
C44	0.074 (6)	0.068 (6)	0.079 (6)	0.024 (5)	0.022 (5)	0.023 (5)
C45	0.074 (6)	0.048 (4)	0.085 (7)	0.020 (4)	0.032 (5)	0.002 (4)
C46	0.057 (5)	0.049 (4)	0.057 (5)	0.011 (3)	0.012 (4)	−0.003 (3)
C51	0.035 (3)	0.051 (4)	0.031 (3)	0.004 (3)	0.010 (3)	−0.009 (3)
C52	0.036 (3)	0.049 (4)	0.035 (3)	0.007 (3)	0.015 (3)	0.001 (3)

Geometric parameters (Å, º) top

Re—O1	1.714 (5)	C24—C25	1.365 (13)
Re—O2	1.872 (4)	C24—H24	0.94
Re—P2	2.4241 (15)	C25—C26	1.394 (11)
Re—P1	2.4348 (16)	C25—H25	0.94
Re—Cl12	2.4380 (15)	C26—H26	0.94
Re—Cl11	2.4495 (15)	C31—C36	1.377 (10)
P1—C21	1.818 (7)	C31—C32	1.413 (9)
P1—C11	1.824 (7)	C32—C33	1.363 (11)
P1—C51	1.838 (6)	C32—H32	0.94
P2—C31	1.802 (7)	C33—C34	1.364 (13)
P2—C41	1.811 (7)	C33—H33	0.94
P2—C52	1.841 (6)	C34—C35	1.373 (12)
O2—C61	1.393 (8)	C34—H34	0.94
C61—H61a	0.97	C35—C36	1.396 (10)
C61—H61b	0.97	C35—H35	0.94
C61—H61c	0.97	C36—H36	0.94
C11—C16	1.372 (10)	C41—C42	1.368 (10)
C11—C12	1.382 (10)	C41—C46	1.376 (10)
C12—C13	1.376 (10)	C42—C43	1.381 (13)
C12—H12	0.94	C42—H42	0.94
C13—C14	1.396 (12)	C43—C44	1.392 (15)
C13—H13	0.94	C43—H43	0.94
C14—C15	1.357 (12)	C44—C45	1.351 (13)
C14—H14	0.94	C44—H44	0.94
C15—C16	1.402 (11)	C45—C46	1.385 (11)
C15—H15	0.94	C45—H45	0.94
C16—H16	0.94	C46—H46	0.94
C21—C26	1.365 (10)	C51—C52	1.527 (9)
C21—C22	1.391 (10)	C51—H51a	0.98
C22—C23	1.370 (12)	C51—H51b	0.98
C22—H22	0.94	C52—H52a	0.98
C23—C24	1.406 (14)	C52—H52b	0.98
C23—H23	0.94

O1—Re—O2	172.18 (19)	C22—C23—H23	119.8
O1—Re—P2	88.15 (15)	C24—C23—H23	119.8
O2—Re—P2	85.83 (14)	C25—C24—C23	118.6 (8)
O1—Re—P1	87.33 (15)	C25—C24—H24	120.7
O2—Re—P1	86.98 (14)	C23—C24—H24	120.7
P2—Re—P1	83.02 (5)	C24—C25—C26	120.8 (8)
O1—Re—Cl12	95.27 (15)	C24—C25—H25	119.6
O2—Re—Cl12	90.60 (14)	C26—C25—H25	119.6
P2—Re—Cl12	176.17 (6)	C21—C26—C25	120.4 (8)
P1—Re—Cl12	95.41 (5)	C21—C26—H26	119.8
O1—Re—Cl11	94.95 (15)	C25—C26—H26	119.8
O2—Re—Cl11	90.52 (14)	C36—C31—C32	118.5 (7)
P2—Re—Cl11	94.59 (5)	C36—C31—P2	123.3 (5)
P1—Re—Cl11	176.66 (5)	C32—C31—P2	117.9 (6)
Cl12—Re—Cl11	86.82 (6)	C33—C32—C31	120.1 (8)
C21—P1—C11	104.6 (3)	C33—C32—H32	120
C21—P1—C51	105.5 (3)	C31—C32—H32	120
C11—P1—C51	107.3 (3)	C32—C33—C34	120.9 (8)
C21—P1—Re	119.3 (2)	C32—C33—H33	119.6
C11—P1—Re	113.2 (2)	C34—C33—H33	119.6
C51—P1—Re	106.1 (2)	C33—C34—C35	120.4 (8)
C31—P2—C41	102.9 (3)	C33—C34—H34	119.8
C31—P2—C52	105.5 (3)	C35—C34—H34	119.8
C41—P2—C52	107.4 (3)	C34—C35—C36	119.6 (8)
C31—P2—Re	119.4 (2)	C34—C35—H35	120.2
C41—P2—Re	114.2 (2)	C36—C35—H35	120.2
C52—P2—Re	106.5 (2)	C31—C36—C35	120.5 (7)
C61—O2—Re	168.1 (5)	C31—C36—H36	119.8
O2—C61—H61A	109.5	C35—C36—H36	119.8
O2—C61—H61B	109.5	C42—C41—C46	118.8 (7)
H61A—C61—H61B	109.5	C42—C41—P2	118.4 (6)
O2—C61—H61C	109.5	C46—C41—P2	122.7 (6)
H61A—C61—H61C	109.5	C41—C42—C43	121.0 (9)
H61B—C61—H61C	109.5	C41—C42—H42	119.5
C16—C11—C12	119.5 (7)	C43—C42—H42	119.5
C16—C11—P1	123.7 (6)	C42—C43—C44	119.9 (9)
C12—C11—P1	116.7 (5)	C42—C43—H43	120.1
C13—C12—C11	121.0 (7)	C44—C43—H43	120.1
C13—C12—H12	119.5	C45—C44—C43	118.8 (9)
C11—C12—H12	119.5	C45—C44—H44	120.6
C12—C13—C14	118.9 (8)	C43—C44—H44	120.6
C12—C13—H13	120.5	C44—C45—C46	121.3 (9)
C14—C13—H13	120.5	C44—C45—H45	119.4
C15—C14—C13	120.6 (7)	C46—C45—H45	119.4
C15—C14—H14	119.7	C41—C46—C45	120.2 (8)
C13—C14—H14	119.7	C41—C46—H46	119.9
C14—C15—C16	119.9 (8)	C45—C46—H46	119.9
C14—C15—H15	120.1	C52—C51—P1	110.4 (4)
C16—C15—H15	120.1	C52—C51—H51A	109.6
C11—C16—C15	120.0 (8)	P1—C51—H51A	109.6
C11—C16—H16	120	C52—C51—H51B	109.6
C15—C16—H16	120	P1—C51—H51B	109.6
C26—C21—C22	119.3 (7)	H51A—C51—H51B	108.1
C26—C21—P1	122.1 (5)	C51—C52—P2	109.9 (4)
C22—C21—P1	118.6 (6)	C51—C52—H52A	109.7
C23—C22—C21	120.4 (9)	P2—C52—H52A	109.7
C23—C22—H22	119.8	C51—C52—H52B	109.7
C21—C22—H22	119.8	P2—C52—H52B	109.7
C22—C23—C24	120.4 (9)	H52A—C52—H52B	108.2

O1—Re—P1—C21	−42.7 (3)	C51—P1—C21—C22	56.0 (7)
O2—Re—P1—C21	142.7 (3)	Re—P1—C21—C22	175.1 (6)
P2—Re—P1—C21	−131.2 (2)	C26—C21—C22—C23	−0.7 (13)
Cl12—Re—P1—C21	52.3 (2)	P1—C21—C22—C23	178.0 (8)
O1—Re—P1—C11	−166.4 (3)	C21—C22—C23—C24	0.0 (16)
O2—Re—P1—C11	18.9 (3)	C22—C23—C24—C25	1.0 (16)
P2—Re—P1—C11	105.1 (2)	C23—C24—C25—C26	−1.3 (14)
Cl12—Re—P1—C11	−71.4 (2)	C22—C21—C26—C25	0.4 (12)
O1—Re—P1—C51	76.1 (3)	P1—C21—C26—C25	−178.3 (6)
O2—Re—P1—C51	−98.6 (3)	C24—C25—C26—C21	0.6 (13)
P2—Re—P1—C51	−12.4 (2)	C41—P2—C31—C36	123.8 (7)
Cl12—Re—P1—C51	171.1 (2)	C52—P2—C31—C36	−123.7 (7)
O1—Re—P2—C31	140.9 (3)	Re—P2—C31—C36	−4.0 (8)
O2—Re—P2—C31	−44.2 (3)	C41—P2—C31—C32	−49.6 (7)
P1—Re—P2—C31	−131.6 (3)	C52—P2—C31—C32	62.9 (7)
Cl11—Re—P2—C31	46.0 (3)	Re—P2—C31—C32	−177.4 (6)
O1—Re—P2—C41	18.4 (3)	C36—C31—C32—C33	2.1 (14)
O2—Re—P2—C41	−166.6 (3)	P2—C31—C32—C33	175.9 (8)
P1—Re—P2—C41	106.0 (2)	C31—C32—C33—C34	1.0 (17)
Cl11—Re—P2—C41	−76.4 (2)	C32—C33—C34—C35	−3 (2)
O1—Re—P2—C52	−100.0 (3)	C33—C34—C35—C36	1.2 (19)
O2—Re—P2—C52	75.0 (3)	C32—C31—C36—C35	−3.6 (13)
P1—Re—P2—C52	−12.4 (2)	P2—C31—C36—C35	−177.0 (7)
Cl11—Re—P2—C52	165.2 (2)	C34—C35—C36—C31	2.0 (16)
P2—Re—O2—C61	−40 (2)	C31—P2—C41—C42	−69.3 (7)
P1—Re—O2—C61	43 (2)	C52—P2—C41—C42	179.7 (7)
Cl12—Re—O2—C61	138 (2)	Re—P2—C41—C42	61.8 (7)
Cl11—Re—O2—C61	−135 (2)	C31—P2—C41—C46	106.4 (7)
C21—P1—C11—C16	107.2 (6)	C52—P2—C41—C46	−4.6 (7)
C51—P1—C11—C16	−4.5 (7)	Re—P2—C41—C46	−122.5 (6)
Re—P1—C11—C16	−121.3 (6)	C46—C41—C42—C43	−2.9 (16)
C21—P1—C11—C12	−74.9 (6)	P2—C41—C42—C43	173 (1)
C51—P1—C11—C12	173.4 (5)	C41—C42—C43—C44	3 (2)
Re—P1—C11—C12	56.6 (6)	C42—C43—C44—C45	−2.4 (19)
C16—C11—C12—C13	−0.5 (11)	C43—C44—C45—C46	1.4 (17)
P1—C11—C12—C13	−178.5 (6)	C42—C41—C46—C45	1.8 (13)
C11—C12—C13—C14	0.6 (12)	P2—C41—C46—C45	−173.9 (7)
C12—C13—C14—C15	−1.3 (13)	C44—C45—C46—C41	−1.1 (15)
C13—C14—C15—C16	1.9 (13)	C21—P1—C51—C52	169.4 (5)
C12—C11—C16—C15	1.1 (11)	C11—P1—C51—C52	−79.5 (5)
P1—C11—C16—C15	178.9 (6)	Re—P1—C51—C52	41.8 (5)
C14—C15—C16—C11	−1.8 (13)	P1—C51—C52—P2	−55.2 (5)
C11—P1—C21—C26	121.7 (6)	C31—P2—C52—C51	169.6 (5)
C51—P1—C21—C26	−125.3 (6)	C41—P2—C52—C51	−81.1 (5)
Re—P1—C21—C26	−6.2 (7)	Re—P2—C52—C51	41.7 (5)
C11—P1—C21—C22	−57.1 (7)

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[1,2-Bis­(di­phenyl­phosphino)­ethane]­di­chloro­(methoxo)­oxorhenium(V) di­chloro­methane solvate

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[1,2-Bis(diphenylphosphino)ethane]dichloro(methoxo)oxorhenium(V) dichloromethane solvate