metal-organic compounds
In the structure of catena-poly[copper(I)-μ-[hexakis(methylthio)benzene-S1,S2:S4,S5]] hexafluorophosphate, {[Cu(C12H18S6)]PF6}n, each Cu atom is coordinated to four sulfur atoms of two hexakis(methylthio)benzene ligands in a tetrahedral arrangement to give a cationic linear chain polymer. The electrical resistivity of compacted pellets was measured by the conventional two-probe technique. Iodine-doped black products in powder form behave as a semiconductor with a conductivity of 1.5 × 10−6 S cm−1.
Supporting information
Crystallographic Information File (CIF) |
CCDC reference: 130550