Chiral Hydroxylamines. III. 1-(N-Benzyl-N-hydroxyamino)-1-deoxy-1-(2-furyl)-2,3:4,5-di-O-isopropylidene-L-manno-pentitol

The molecular structure of the title compound, C₂₂H₂₉NO₆, determined crystallographically, confirms the previous assignment on the basis of chemical and spectroscopic evidence. In addition, it supports the previously described furan sector rule for the determination of the absolute configuration of chiral 2-furylalkylhydroxylamines by the dichroic circular method. The crystal structure is stabilized entirely by van der Waals interactions.

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