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In the title dinuclear molybdenum–chloro–oxo–sulfido–pyridine complex, di-μ-sulfido-bis[chloro(oxo)bis(pyridine-N)molybdenum] (MoMo) bis(pyridine) solvate, [Mo2Cl2(O)2(S)2(C5H5N)4].2C5H5N, the two Mo atoms are each coordinated by one chloro, one oxo and two pyridine ligands, and are bridged by two μ-S ligands. The distance between the Mo atoms is 2.837 (1) Å, suggesting the existence of a Mo—Mo single bond.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock default

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 128368

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