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The title compound, C21H17N3S, prepared by the reaction of phenyl isothiocyanate with a low-valent titanium reagent, has an intramolecular N—H...N hydrogen bond between the two exocyclic NH groups, and a C=S bond length of 1.660 (3) Å.

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Supplementary material

CCDC reference: 1273349

-1
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