metal-organic compounds
The title compound, [Ni(C5H10NS2)3](C8N5), forms a structure with sheets consisting of alternate rows of cations and anions. The Ni atom in the cation has a distorted octahedral geometry. The planar [C3(CN)5]- anion is significantly distorted from C2v symmetry. The Ni-S distances range from 2.246 (2) to 2.257 (2) Å and the C-C distances in the allyl group of the anion are 1.19 (2) and 1.35 (2) Å.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 128268