metal-organic compounds
Polymeric [Fe2{MoO4}2(C12H8N2)2]n adopts a chain structure that propagates linearly along the b axis of the monoclinic unit cell. The (C12H8N2)Fe moiety lies on a mirror plane, as does the MoO4 moiety; two MoO4 anions link two (C12H8N2)Fe entities to form an eight-membered Fe—O—Mo—O—Fe—O—Mo—O— ring; the Fe atom is five-coordinate in a trigonal bipyramidal environment; the phenanthroline ligand spans the axial–equatorial sites.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804015685/bt6478sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804015685/bt6478Isup2.hkl |
CCDC reference: 248708
Computing details top
Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: atomic coordinates taken from the Zn analog (Hagrman & Zubieta, 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: OPTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.
Dimolybdato(VI)bis[(1,10-phenanthroline)iron(II)] top
Crystal data top
[Fe2Mo2O8(C12H8N2)2] | F(000) = 388 |
Mr = 791.99 | Dx = 2.159 Mg m−3 |
Monoclinic, P21/m | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yb | Cell parameters from 2636 reflections |
a = 8.873 (1) Å | θ = 2.3–27.6° |
b = 6.567 (1) Å | µ = 2.23 mm−1 |
c = 10.629 (2) Å | T = 293 K |
β = 100.437 (2)° | Prism, black |
V = 609.1 (2) Å3 | 0.13 × 0.11 × 0.11 mm |
Z = 1 |
Data collection top
Bruker APEX area-detector diffractometer | 1469 independent reflections |
Radiation source: fine-focus sealed tube | 1360 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.025 |
φ and ω scans | θmax = 27.5°, θmin = 2.0° |
Absorption correction: multi-scan (SADABS; Bruker, 2002) | h = −11→11 |
Tmin = 0.697, Tmax = 0.791 | k = −8→8 |
4906 measured reflections | l = −13→13 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.024 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.065 | H-atom parameters constrained |
S = 1.04 | w = 1/[σ2(Fo2) + (0.0414P)2 + 0.0379P] where P = (Fo2 + 2Fc2)/3 |
1469 reflections | (Δ/σ)max = 0.001 |
118 parameters | Δρmax = 0.39 e Å−3 |
0 restraints | Δρmin = −0.33 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Mo1 | 0.99329 (3) | 0.7500 | 0.83276 (3) | 0.0188 (1) | |
Fe1 | 0.80930 (5) | 0.2500 | 0.81847 (5) | 0.0206 (1) | |
O1 | 0.8794 (2) | 0.5295 (3) | 0.7894 (2) | 0.0381 (5) | |
O2 | 1.0671 (3) | 0.7500 | 0.9968 (2) | 0.0388 (7) | |
O3 | 1.1433 (4) | 0.7500 | 0.7522 (3) | 0.0577 (9) | |
N1 | 0.5842 (3) | 0.2500 | 0.8650 (3) | 0.0252 (6) | |
N2 | 0.6595 (3) | 0.2500 | 0.6304 (3) | 0.0225 (6) | |
C1 | 0.5498 (4) | 0.2500 | 0.9819 (3) | 0.031 (1) | |
C2 | 0.3985 (4) | 0.2500 | 1.0016 (4) | 0.038 (1) | |
C3 | 0.2805 (4) | 0.2500 | 0.8997 (4) | 0.038 (1) | |
C4 | 0.3128 (4) | 0.2500 | 0.7733 (4) | 0.030 (1) | |
C5 | 0.4679 (4) | 0.2500 | 0.7622 (3) | 0.025 (1) | |
C6 | 0.1979 (4) | 0.2500 | 0.6619 (4) | 0.040 (1) | |
C7 | 0.2347 (4) | 0.2500 | 0.5446 (4) | 0.034 (1) | |
C8 | 0.3922 (4) | 0.2500 | 0.5289 (3) | 0.025 (1) | |
C9 | 0.5077 (3) | 0.2500 | 0.6361 (3) | 0.022 (1) | |
C10 | 0.4368 (4) | 0.2500 | 0.4078 (3) | 0.029 (1) | |
C11 | 0.5889 (4) | 0.2500 | 0.4024 (4) | 0.030 (1) | |
C12 | 0.6965 (4) | 0.2500 | 0.5146 (3) | 0.027 (1) | |
H1 | 0.6289 | 0.2500 | 1.0525 | 0.037* | |
H2 | 0.3782 | 0.2500 | 1.0844 | 0.045* | |
H3 | 0.1796 | 0.2500 | 0.9126 | 0.045* | |
H6 | 0.0953 | 0.2500 | 0.6699 | 0.048* | |
H7 | 0.1572 | 0.2500 | 0.4727 | 0.041* | |
H10 | 0.3635 | 0.2500 | 0.3332 | 0.034* | |
H11 | 0.6205 | 0.2500 | 0.3236 | 0.036* | |
H12 | 0.7998 | 0.2500 | 0.5086 | 0.032* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Mo1 | 0.0197 (2) | 0.0169 (2) | 0.0186 (2) | 0.000 | 0.0005 (1) | 0.000 |
Fe1 | 0.0187 (2) | 0.0181 (2) | 0.0227 (3) | 0.000 | −0.0024 (2) | 0.000 |
O1 | 0.048 (1) | 0.024 (1) | 0.036 (1) | −0.013 (1) | −0.010 (1) | 0.0042 (8) |
O2 | 0.047 (2) | 0.036 (2) | 0.027 (1) | 0.000 | −0.012 (1) | 0.000 |
O3 | 0.043 (2) | 0.078 (2) | 0.061 (2) | 0.000 | 0.032 (2) | 0.000 |
N1 | 0.026 (1) | 0.025 (1) | 0.023 (2) | 0.000 | 0.001 (1) | 0.000 |
N2 | 0.021 (1) | 0.020 (1) | 0.025 (2) | 0.000 | −0.001 (1) | 0.000 |
C1 | 0.031 (2) | 0.035 (2) | 0.024 (2) | 0.000 | 0.001 (2) | 0.000 |
C2 | 0.041 (2) | 0.045 (2) | 0.031 (2) | 0.000 | 0.015 (2) | 0.000 |
C3 | 0.032 (2) | 0.046 (2) | 0.038 (2) | 0.000 | 0.016 (2) | 0.000 |
C4 | 0.024 (2) | 0.033 (2) | 0.033 (2) | 0.000 | 0.003 (2) | 0.000 |
C5 | 0.023 (2) | 0.022 (2) | 0.027 (2) | 0.000 | 0.001 (1) | 0.000 |
C6 | 0.017 (2) | 0.053 (2) | 0.047 (3) | 0.000 | 0.002 (2) | 0.000 |
C7 | 0.020 (2) | 0.046 (2) | 0.031 (2) | 0.000 | −0.005 (1) | 0.000 |
C8 | 0.023 (2) | 0.024 (2) | 0.027 (2) | 0.000 | 0.000 (1) | 0.000 |
C9 | 0.022 (2) | 0.016 (1) | 0.027 (2) | 0.000 | 0.002 (1) | 0.000 |
C10 | 0.029 (2) | 0.031 (2) | 0.022 (2) | 0.000 | −0.004 (1) | 0.000 |
C11 | 0.037 (2) | 0.029 (2) | 0.024 (2) | 0.000 | 0.005 (2) | 0.000 |
C12 | 0.022 (2) | 0.027 (2) | 0.032 (2) | 0.000 | 0.004 (1) | 0.000 |
Geometric parameters (Å, º) top
Mo1—O1 | 1.778 (2) | C4—C6 | 1.416 (5) |
Mo1—O1i | 1.778 (2) | C5—C9 | 1.447 (5) |
Mo1—O2 | 1.748 (2) | C6—C7 | 1.345 (5) |
Mo1—O3 | 1.708 (3) | C7—C8 | 1.437 (5) |
Fe1—O1 | 1.980 (2) | C8—C9 | 1.388 (5) |
Fe1—O1ii | 1.980 (2) | C8—C10 | 1.414 (5) |
Fe1—O2iii | 2.068 (3) | C10—C11 | 1.361 (5) |
Fe1—N1 | 2.143 (3) | C11—C12 | 1.386 (5) |
Fe1—N2 | 2.190 (3) | C1—H1 | 0.93 |
N1—C1 | 1.332 (4) | C2—H2 | 0.93 |
N1—C5 | 1.361 (4) | C3—H3 | 0.93 |
N2—C12 | 1.331 (4) | C6—H6 | 0.93 |
N2—C9 | 1.359 (4) | C7—H7 | 0.93 |
C1—C2 | 1.395 (5) | C10—H10 | 0.93 |
C2—C3 | 1.364 (5) | C11—H11 | 0.93 |
C3—C4 | 1.423 (5) | C12—H12 | 0.93 |
C4—C5 | 1.403 (5) | ||
O1—Mo1—O1i | 109.1 (1) | N1—C5—C4 | 123.1 (3) |
O1—Mo1—O2 | 110.6 (1) | N1—C5—C9 | 117.8 (3) |
O1—Mo1—O3 | 109.2 (1) | C4—C5—C9 | 119.1 (3) |
O1i—Mo1—O2 | 110.6 (1) | C7—C6—C4 | 121.1 (3) |
O1i—Mo1—O3 | 109.2 (1) | C6—C7—C8 | 120.8 (3) |
O2—Mo1—O3 | 108.4 (2) | C9—C8—C10 | 117.4 (3) |
O1—Fe1—O1ii | 135.9 (1) | C9—C8—C7 | 119.6 (3) |
O1—Fe1—O2iii | 91.2 (1) | C10—C8—C7 | 123.0 (3) |
O1—Fe1—N1 | 111.6 (1) | N2—C9—C8 | 123.7 (3) |
O1—Fe1—N2 | 90.8 (1) | N2—C9—C5 | 116.8 (3) |
O1ii—Fe1—O2iii | 91.2 (1) | C8—C9—C5 | 119.5 (3) |
O1ii—Fe1—N1 | 111.6 (1) | C11—C10—C8 | 118.8 (3) |
O1ii—Fe1—N2 | 90.8 (1) | C10—C11—C12 | 119.8 (4) |
O2iii—Fe1—N1 | 97.9 (1) | N2—C12—C11 | 123.3 (3) |
O2iii—Fe1—N2 | 174.8 (1) | N1—C1—H1 | 119.0 |
N1—Fe1—N2 | 76.9 (1) | C2—C1—H1 | 119.0 |
Mo1—O1—Fe1 | 153.4 (1) | C3—C2—H2 | 119.9 |
Mo1—O2—Fe1iii | 170.2 (2) | C1—C2—H2 | 119.9 |
C1—N1—C5 | 118.7 (3) | C2—C3—H3 | 120.2 |
C1—N1—Fe1 | 126.6 (2) | C4—C3—H3 | 120.2 |
C5—N1—Fe1 | 114.7 (2) | C7—C6—H6 | 119.4 |
C12—N2—C9 | 117.0 (3) | C4—C6—H6 | 119.4 |
C12—N2—Fe1 | 129.3 (2) | C6—C7—H7 | 119.6 |
C9—N2—Fe1 | 113.7 (2) | C8—C7—H7 | 119.6 |
N1—C1—C2 | 122.0 (4) | C11—C10—H10 | 120.6 |
C3—C2—C1 | 120.1 (4) | C8—C10—H10 | 120.6 |
C2—C3—C4 | 119.6 (3) | C10—C11—H11 | 120.1 |
C5—C4—C6 | 119.9 (3) | C12—C11—H11 | 120.1 |
C5—C4—C3 | 116.6 (3) | N2—C12—H12 | 118.3 |
C6—C4—C3 | 123.5 (3) | C11—C12—H12 | 118.3 |
O3—Mo1—O1—Fe1 | 100.9 (3) | C1—N1—C5—C4 | 0.0 |
O2—Mo1—O1—Fe1 | −18.2 (3) | Fe1—N1—C5—C4 | 180.0 |
O1i—Mo1—O1—Fe1 | −139.9 (2) | C1—N1—C5—C9 | 180.0 |
O1ii—Fe1—O1—Mo1 | −85.0 (3) | Fe1—N1—C5—C9 | 0.0 |
O2iii—Fe1—O1—Mo1 | 7.9 (3) | C6—C4—C5—N1 | 180.0 |
N1—Fe1—O1—Mo1 | 106.8 (3) | C3—C4—C5—N1 | 0.0 |
N2—Fe1—O1—Mo1 | −176.9 (3) | C6—C4—C5—C9 | 0.0 |
O3—Mo1—O2—Fe1iii | 0.0 | C3—C4—C5—C9 | 180.0 |
O1—Mo1—O2—Fe1iii | 119.6 (1) | C5—C4—C6—C7 | 0.0 |
O1i—Mo1—O2—Fe1iii | −119.6 (1) | C3—C4—C6—C7 | 180.0 |
O1ii—Fe1—N1—C1 | 94.4 (1) | C4—C6—C7—C8 | 0.0 |
O1—Fe1—N1—C1 | −94.4 (1) | C6—C7—C8—C9 | 0.0 |
O2iii—Fe1—N1—C1 | 0.0 | C6—C7—C8—C10 | 180.0 |
N2—Fe1—N1—C1 | 180.0 | C12—N2—C9—C8 | 0.0 |
O1ii—Fe1—N1—C5 | −85.6 (1) | Fe1—N2—C9—C8 | 180.0 |
O1—Fe1—N1—C5 | 85.6 (1) | C12—N2—C9—C5 | 180.0 |
O2iii—Fe1—N1—C5 | 180.0 | Fe1—N2—C9—C5 | 0.0 |
N2—Fe1—N1—C5 | 0.0 | C10—C8—C9—N2 | 0.0 |
O1ii—Fe1—N2—C12 | −68.0 (1) | C7—C8—C9—N2 | 180.0 |
O1—Fe1—N2—C12 | 68.0 (1) | C10—C8—C9—C5 | 180.0 |
O2iii—Fe1—N2—C12 | 180.0 | C7—C8—C9—C5 | 0.0 |
N1—Fe1—N2—C12 | 180.0 | N1—C5—C9—N2 | 0.0 |
O1ii—Fe1—N2—C9 | 112.0 (1) | C4—C5—C9—N2 | 180.0 |
O1—Fe1—N2—C9 | −112.0 (1) | N1—C5—C9—C8 | 180.0 |
O2iii—Fe1—N2—C9 | 0.0 | C4—C5—C9—C8 | 0.0 |
N1—Fe1—N2—C9 | 0.0 | C9—C8—C10—C11 | 0.0 |
C5—N1—C1—C2 | 0.0 | C7—C8—C10—C11 | 180.0 |
Fe1—N1—C1—C2 | 180.0 | C8—C10—C11—C12 | 0.0 |
N1—C1—C2—C3 | 0.0 | C9—N2—C12—C11 | 0.0 |
C1—C2—C3—C4 | 0.0 | Fe1—N2—C12—C11 | 180.0 |
C2—C3—C4—C5 | 0.0 | C10—C11—C12—N2 | 0.0 |
C2—C3—C4—C6 | 180.0 |
Symmetry codes: (i) x, −y+3/2, z; (ii) x, −y+1/2, z; (iii) −x+2, −y+1, −z+2. |