Bis­[1,2-bis­(di­phenyl­phosphino)­ethane]silver(I) bis­(tri­fluoro­acetato)­tri­phenyl­stannate(IV)

The crystal structure of the title compound, [Ag(C₂₆H₂₄P₂)₂][Sn(C₂O₂F₃)₂(C₆H₅)₃], consists of discrete tetrahedral [[(C₆H₅)₂PCH₂CH₂P(C₆H₅)₂]₂Ag]⁺ cations and trans-C₃SnO₂ trig­onal bipyramidal [(C₆H₅)₃Sn(O₂CCF₃)₂]^- anions.

Key indicators

• Single-crystal X-ray study
• T = 168 K
• Mean [sigma](C-C) = 0.008 Å
• R factor = 0.042
• wR factor = 0.122
• Data-to-parameter ratio = 17.0

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level C:



ABSTM_02  Alert C The ratio of expected to reported Tmax/Tmin(RR') is < 0.90
          Tmin and Tmax reported:      0.518     0.742
          Tmin' and Tmax expected:      0.664     0.751
          RR' =      0.790
          Please check that your absorption correction is appropriate.

PLAT_601  Alert C Structure Contains Solvent Accessible VOIDS of      70.00 A   3

PLAT_732  Alert C Angle   Calc    84.70(4), Rep   84.70(10) ....       2.50 su-Ratio
                     P1   -AG1  -P2      1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc   124.30(4), Rep  124.30(10) ....       2.50 su-Ratio
                     P1   -AG1  -P3      1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc   118.51(4), Rep  118.50(10) ....       2.50 su-Ratio
                     P1   -AG1  -P4      1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc   125.24(4), Rep  125.20(10) ....       2.50 su-Ratio
                     P2   -AG1  -P3      1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc   124.72(4), Rep  124.70(10) ....       2.50 su-Ratio
                     P2   -AG1  -P4      1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc    84.23(3), Rep   84.20(10) ....       3.33 su-Ratio
                     P3   -AG1  -P4      1.555   1.555   1.555


 0 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 8 Alert Level C = Please check

---

S1. Comment

One strategy of improving the water solubility of fungicidal triorganotin carboxylates involves the addition of a carboxylato anion to the compound to furnish a di(carboxylato)triorganostannate, whose negative charge is balanced by an ammonium cation. The first example of such an ammonium stannate has the teteramethylammonium cation as counterion (Ng & Das, 1997a,b); other ammonium stannates have also been synthesized (Ng, 1999; Ng & Hook, 1999). Aside from these ammonium salts, the extremely large tetrakis(triphenylphosphine)silver(I) cation has also been used for this purpose; the salt of bis(trifluoroacetato)triphenylstannate consists of discrete tetrahedral cations and five-coordinate trans-trigonal bipyramidal anions. The structure is both twinned and disordered [molecule a: Ag—P 2.563 (4)/2.717 (2) Å and Sn—O 2.234 (6)/2.236 (5) Å; molecule b: Ag—P 2.632 (2)/2.768 (3) Å and Sn—O 2.234 (6)/2.235 (6) Å] (Ng & Rae, 2003). The bis(trifluoroacetato)triphenylstannate anion as isolated in the present bis[1,2-bis(diphenylphosphino)ethane]silver salt (see Scheme) represents yet another uncommon example of such a bimetallic compound. The Ag atom in the cation (Fig. 1) is chelated by the phosphine ligands, which bind in a nearly isobidentate manner [Ag—P 2.488 (1)/2.520 (1) and 2.495 (1)/2.517 (1) Å] to give rise to a tetrahedral environment of the Ag atom (Fig. 1). The Ag—P distances are similar to those found in the bis[1,2-bis(diphenylphosphino)ethene)]silver complex of the dinitratotriphenylstannate anion (Franzoni et al., 1988); the bite angles in the title cation are similar to those [83.9 (1) and 84.1 (1)°] found in this complex, which as a CH═CH fragment. In the bis(trifluoroacetato)triphenylstannate anion (Fig. 2), the O—Sn—O skeleton is nearly linear [Sn—O 2.213 (3)/2.250 (3) Å; O—Sn—O 177.6 (1)°]. The trigonal bipyramidal geometry of the Sn atom is distorted by the two double-bond carbonyl O atoms at about 3.5 Å away. The cations and anions exist as discrete entities in the unit cell (Fig 3).

S2. Experimental

The synthesis was carried out on a mmol scale. The cationic entity was synthesized from the reaction of silver trifluoroacetate and 2 equivalents of 1,2-bis(diphenylphosphine)ethane in acetone to bis[bis-1,2-(diphenylphosphino)ethane)]silver trifluoroacetate in situ. The anionic entity was synthesized from the reaction of triphenyltin hydroxide and trifluoroacetic acid in the same solvent. The two reagents were mixed and the solution briefly heated. Large colorless crystals of the silver stannate separated from the cool solution when it was set aside for a day.

S3. Refinement

One of the Sn-bound phenyl rings is disordered over two sites; the disordered rings were refined as rigid hexagons. The Sn1—C1 and Sn1—C1' bond distances were restrained to be nearly equal by a SADI 0.005 command. Additionally, the C atoms of the rings were restrained to vibrate in an approximate isotropic manner by an ISOR 0.01 instruction in SHELXL97 (Sheldrick, 1997). All H atoms were generated geometrically, and they were allowed to ride on their parent atoms, with U_iso(H) = 1.2U_eq(C). The final difference Fourier map had a peak of 2.2 e Å⁻³ at 1.4 Å from the P2 atom and 2.5 Å from the Ag1 atom, but it was otherwise featureless. The calculations on the low-temperature diffraction intensities from another crystal converged to R = 0.048 for 10599 I > 2σ(I) reflections, but the difference map showed a peak of 1.9 e Å⁻³ at 3 Å from the H35b atom.

Computing details

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Figures

	Fig. 1. ORTEPII (Johnson, 1976) plot of the title cation at the 50% probability level. H atoms are drawn as spheres of arbitrary radii.
	Fig. 2. ORTEPII (Johnson, 1976) plot of the title anion at the 50% probability level. H atoms are draw as sphere of arbitrary radii. The disorder in one of the phenyl rings is shown.
	Fig. 3. ORTEPII (Johnson, 1976) plot of the packing.

Bis[1,2-bis(diphenylphosphino)ethane]silver(I) bis(trifluoroacetato)triphenylstannate(IV)

Crystal data

(C2O2F3)2·(C26H24P2)2·(C18H15Sn)·Ag	F(000) = 3000
Mr = 1480.68	Dx = 1.412 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 15.988 (1) Å	Cell parameters from 7800 reflections
b = 19.115 (1) Å	θ = 1.7–26.5°
c = 23.875 (1) Å	µ = 0.80 mm^−1
β = 107.279 (1)°	T = 168 K
V = 6966.9 (7) Å^3	Block, colorless
Z = 4	0.50 × 0.50 × 0.36 mm

Data collection

Bruker SMART area-detector diffractometer	14277 independent reflections
Radiation source: fine-focus sealed tube	10420 reflections with I > 2σ(I)'
Graphite monochromator	Rint = 0.040
ϕ and ω scans	θmax = 26.5°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −20→19
Tmin = 0.518, Tmax = 0.742	k = −23→21
85582 measured reflections	l = −29→29

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.042	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.122	H-atom parameters constrained
S = 1.06	w = 1/[σ^2(Fo^2) + (0.0507P)^2 + 13.3659P] where P = (Fo^2 + 2Fc^2)/3
14277 reflections	(Δ/σ)max = 0.001
842 parameters	Δρmax = 2.20 e Å^−3
73 restraints	Δρmin = −0.62 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Sn1	0.52834 (2)	0.73988 (1)	0.81059 (1)	0.03813 (9)
Ag1	0.67400 (2)	0.77507 (2)	0.50064 (1)	0.03346 (8)
P1	0.69141 (8)	0.69027 (5)	0.42405 (5)	0.0372 (2)
P2	0.66528 (8)	0.86544 (6)	0.42408 (5)	0.0400 (2)
P3	0.77288 (7)	0.78000 (5)	0.60340 (4)	0.0328 (2)
P4	0.55626 (7)	0.75211 (5)	0.54870 (4)	0.0344 (2)
F1	0.3514 (3)	0.5242 (2)	0.7433 (2)	0.125 (2)
F2	0.2337 (2)	0.5795 (3)	0.7209 (2)	0.122 (2)
F3	0.3253 (3)	0.5975 (3)	0.6743 (2)	0.133 (2)
F4	0.6519 (4)	0.9693 (2)	0.8643 (3)	0.175 (3)
F5	0.7639 (3)	0.9045 (2)	0.8926 (2)	0.124 (2)
F6	0.7436 (3)	0.9663 (2)	0.8171 (2)	0.147 (2)
O1	0.4422 (2)	0.6458 (2)	0.7805 (1)	0.048 (1)
O2	0.3138 (2)	0.6812 (2)	0.7898 (2)	0.062 (1)
O3	0.6176 (2)	0.8300 (2)	0.8394 (1)	0.053 (1)
O4	0.6461 (3)	0.8637 (2)	0.7569 (2)	0.069 (1)
C1	0.4283 (5)	0.7975 (4)	0.7480 (3)	0.041 (2)	0.63 (2)
C2	0.3955 (5)	0.7732 (4)	0.6908 (3)	0.060 (3)	0.63 (2)
C3	0.3283 (5)	0.8093 (5)	0.6508 (3)	0.079 (4)	0.63 (2)
C4	0.2941 (4)	0.8697 (5)	0.6680 (4)	0.090 (4)	0.63 (2)
C5	0.3269 (5)	0.8939 (4)	0.7252 (5)	0.086 (4)	0.63 (2)
C6	0.3941 (6)	0.8578 (4)	0.7652 (3)	0.065 (3)	0.63 (2)
C1'	0.4376 (8)	0.8144 (6)	0.7610 (6)	0.047 (5)	0.37 (2)
C2'	0.3897 (9)	0.7999 (7)	0.7034 (6)	0.063 (5)	0.37 (2)
C3'	0.3197 (8)	0.8425 (9)	0.6745 (6)	0.107 (9)	0.37 (2)
C4'	0.2977 (7)	0.8997 (8)	0.7032 (8)	0.070 (6)	0.37 (2)
C5'	0.3457 (9)	0.9142 (6)	0.7609 (8)	0.086 (6)	0.37 (2)
C6'	0.4156 (9)	0.8715 (6)	0.7898 (6)	0.065 (5)	0.37 (2)
C7	0.6254 (3)	0.6839 (2)	0.7838 (2)	0.037 (1)
C8	0.7139 (3)	0.6980 (2)	0.8093 (2)	0.045 (1)
C9	0.7778 (3)	0.6622 (2)	0.7925 (2)	0.049 (1)
C10	0.7548 (3)	0.6125 (2)	0.7486 (2)	0.050 (1)
C11	0.6671 (3)	0.5982 (2)	0.7223 (2)	0.045 (1)
C12	0.6031 (3)	0.6333 (2)	0.7395 (2)	0.040 (1)
C13	0.5248 (3)	0.7347 (2)	0.9001 (2)	0.040 (1)
C14	0.4803 (3)	0.6809 (3)	0.9179 (2)	0.053 (1)
C15	0.4743 (3)	0.6787 (3)	0.9750 (2)	0.060 (1)
C16	0.5141 (4)	0.7286 (3)	1.0151 (2)	0.070 (2)
C17	0.5600 (4)	0.7818 (3)	0.9984 (2)	0.070 (2)
C18	0.5645 (4)	0.7851 (3)	0.9413 (2)	0.055 (1)
C19	0.3606 (3)	0.6443 (2)	0.7701 (2)	0.048 (1)
C20	0.3164 (4)	0.5865 (3)	0.7261 (3)	0.068 (2)
C21	0.6495 (3)	0.8687 (2)	0.8082 (2)	0.047 (1)
C22	0.7018 (4)	0.9288 (3)	0.8460 (3)	0.078 (2)
C23	0.5864 (3)	0.6573 (2)	0.3773 (2)	0.043 (1)
C24	0.5094 (3)	0.6870 (2)	0.3815 (2)	0.050 (1)
C25	0.4288 (4)	0.6673 (3)	0.3436 (2)	0.067 (2)
C26	0.4247 (5)	0.6169 (3)	0.3019 (2)	0.075 (2)
C27	0.5000 (5)	0.5868 (3)	0.2977 (2)	0.078 (2)
C28	0.5813 (4)	0.6066 (3)	0.3344 (2)	0.059 (1)
C29	0.7642 (3)	0.6150 (2)	0.4336 (2)	0.041 (1)
C30	0.8460 (4)	0.6194 (3)	0.4248 (3)	0.063 (1)
C31	0.9017 (4)	0.5619 (3)	0.4348 (3)	0.080 (2)
C32	0.8756 (4)	0.4995 (3)	0.4539 (3)	0.075 (2)
C33	0.7952 (4)	0.4948 (3)	0.4636 (2)	0.065 (2)
C34	0.7399 (3)	0.5521 (2)	0.4538 (2)	0.051 (1)
C35	0.7250 (3)	0.7484 (2)	0.3730 (2)	0.047 (1)
C36	0.6628 (3)	0.8114 (2)	0.3586 (2)	0.049 (1)
C37	0.7583 (3)	0.9247 (2)	0.4331 (2)	0.042 (1)
C38	0.7947 (3)	0.9379 (3)	0.3890 (2)	0.055 (1)
C39	0.8624 (3)	0.9840 (3)	0.3975 (3)	0.062 (1)
C40	0.8944 (3)	1.0207 (3)	0.4491 (2)	0.057 (1)
C41	0.8601 (3)	1.0086 (3)	0.4940 (2)	0.059 (1)
C42	0.7907 (3)	0.9593 (2)	0.4860 (2)	0.052 (1)
C43	0.5718 (3)	0.9235 (2)	0.3945 (2)	0.045 (1)
C44	0.5712 (3)	0.9732 (3)	0.3521 (2)	0.062 (1)
C45	0.4985 (3)	1.0134 (3)	0.3264 (2)	0.058 (1)
C46	0.4241 (3)	1.0045 (2)	0.3427 (2)	0.052 (1)
C47	0.4229 (3)	0.9574 (3)	0.3862 (3)	0.065 (1)
C48	0.4976 (3)	0.9170 (3)	0.4121 (2)	0.057 (1)
C49	0.8291 (3)	0.8622 (2)	0.6283 (2)	0.038 (1)
C50	0.9160 (4)	0.8705 (3)	0.6313 (3)	0.067 (2)
C51	0.9579 (5)	0.9343 (3)	0.6459 (3)	0.078 (2)
C52	0.9128 (4)	0.9917 (3)	0.6571 (2)	0.066 (2)
C53	0.8278 (4)	0.9843 (3)	0.6545 (3)	0.077 (2)
C54	0.7854 (3)	0.9196 (3)	0.6406 (2)	0.063 (1)
C55	0.8591 (3)	0.7146 (2)	0.6304 (2)	0.041 (1)
C56	0.9051 (4)	0.7092 (3)	0.6897 (2)	0.066 (2)
C57	0.9667 (4)	0.6567 (4)	0.7082 (3)	0.084 (2)
C58	0.9839 (4)	0.6106 (3)	0.6691 (3)	0.080 (2)
C59	0.9381 (4)	0.6148 (3)	0.6114 (3)	0.071 (2)
C60	0.8744 (3)	0.6661 (2)	0.5920 (2)	0.052 (1)
C61	0.6996 (3)	0.7658 (2)	0.6497 (2)	0.043 (1)
C62	0.6055 (3)	0.7896 (2)	0.6229 (2)	0.040 (1)
C63	0.4442 (3)	0.7860 (2)	0.5252 (2)	0.043 (1)
C64	0.4240 (3)	0.8524 (3)	0.5399 (2)	0.063 (1)
C65	0.3396 (4)	0.8787 (4)	0.5188 (3)	0.087 (2)
C66	0.2740 (4)	0.8385 (4)	0.4827 (3)	0.085 (2)
C67	0.2926 (3)	0.7725 (4)	0.4672 (2)	0.068 (2)
C68	0.3780 (3)	0.7463 (3)	0.4878 (2)	0.051 (1)
C69	0.5428 (3)	0.6595 (2)	0.5627 (2)	0.038 (1)
C70	0.4782 (3)	0.6348 (2)	0.5862 (2)	0.045 (1)
C71	0.4705 (3)	0.5636 (3)	0.5954 (2)	0.052 (1)
C72	0.5259 (4)	0.5166 (2)	0.5817 (2)	0.054 (1)
C73	0.5920 (3)	0.5401 (2)	0.5598 (2)	0.051 (1)
C74	0.5992 (3)	0.6113 (2)	0.5498 (2)	0.043 (1)
H2	0.4189	0.7320	0.6790	0.072*	0.63 (2)
H3	0.3059	0.7928	0.6116	0.095*	0.63 (2)
H4	0.2482	0.8943	0.6406	0.108*	0.63 (2)
H5	0.3035	0.9351	0.7370	0.103*	0.63 (2)
H6	0.4165	0.8744	0.8044	0.078*	0.63 (2)
H2'	0.4047	0.7608	0.6837	0.076*	0.37 (2)
H3'	0.2870	0.8326	0.6351	0.128*	0.37 (2)
H4'	0.2499	0.9288	0.6835	0.084*	0.37 (2)
H5'	0.3306	0.9532	0.7806	0.103*	0.37 (2)
H6'	0.4484	0.8815	0.8292	0.077*	0.37(2
H8	0.7308	0.7329	0.8389	0.054*
H9	0.8379	0.6719	0.8114	0.059*
H10	0.7986	0.5885	0.7366	0.060*
H11	0.6506	0.5639	0.6922	0.054*
H12	0.5432	0.6229	0.7209	0.048*
H14	0.4536	0.6452	0.8909	0.063*
H15	0.4422	0.6421	0.9861	0.072*
H16	0.5102	0.7267	1.0540	0.085*
H17	0.5886	0.8163	1.0261	0.084*
H18	0.5954	0.8225	0.9302	0.066*
H24	0.5118	0.7213	0.4107	0.059*
H25	0.3766	0.6887	0.3465	0.081*
H26	0.3697	0.6030	0.2761	0.090*
H27	0.4966	0.5516	0.2690	0.094*
H28	0.6331	0.5858	0.3303	0.071*
H30	0.8641	0.6622	0.4118	0.076*
H31	0.9575	0.5654	0.4285	0.096*
H32	0.9133	0.4600	0.4603	0.091*
H33	0.7775	0.4521	0.4770	0.078*
H34	0.6848	0.5485	0.4610	0.062*
H35a	0.7858	0.7646	0.3912	0.056*
H35b	0.7227	0.7227	0.3366	0.056*
H36a	0.6023	0.7944	0.3404	0.059*
H36b	0.6788	0.8413	0.3295	0.059*
H38	0.7727	0.9148	0.3523	0.066*
H39	0.8883	0.9910	0.3669	0.074*
H40	0.9399	1.0540	0.4533	0.069*
H41	0.8821	1.0327	0.5302	0.071*
H42	0.7666	0.9502	0.5172	0.062*
H44	0.6225	0.9798	0.3404	0.075*
H45	0.4999	1.0471	0.2974	0.069*
H46	0.3730	1.0308	0.3241	0.063*
H47	0.3719	0.9523	0.3985	0.078*
H48	0.4971	0.8847	0.4423	0.068*
H50	0.9477	0.8317	0.6231	0.080*
H51	1.0180	0.9386	0.6483	0.094*
H52	0.9412	1.0356	0.6665	0.080*
H53	0.7963	1.0235	0.6621	0.093*
H54	0.7258	0.9152	0.6397	0.075*
H56	0.8943	0.7412	0.7172	0.080*
H57	0.9976	0.6525	0.7487	0.101*
H58	1.0278	0.5759	0.6823	0.096*
H59	0.9495	0.5826	0.5842	0.085*
H60	0.8411	0.6677	0.5518	0.063*
H61a	0.6994	0.7153	0.6587	0.051*
H61b	0.7244	0.7908	0.6873	0.051*
H62a	0.6039	0.8413	0.6203	0.047*
H62b	0.5703	0.7752	0.6488	0.047*
H64	0.4686	0.8805	0.5650	0.076*
H65	0.3270	0.9246	0.5292	0.104*
H66	0.2161	0.8564	0.4687	0.102*
H67	0.2475	0.7446	0.4424	0.081*
H68	0.3909	0.7011	0.4761	0.061*
H70	0.4393	0.6669	0.5960	0.054*
H71	0.4262	0.5474	0.6113	0.062*
H72	0.5191	0.4680	0.5873	0.064*
H73	0.6321	0.5078	0.5516	0.061*
H74	0.6436	0.6271	0.5338	0.051*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Sn1	0.0490 (2)	0.0309 (1)	0.0384 (2)	−0.0013 (1)	0.0190 (1)	0.0001 (1)
Ag1	0.0401 (2)	0.0316 (2)	0.0289 (2)	−0.0008 (1)	0.0105 (1)	0.0008 (1)
P1	0.0514 (6)	0.0289 (5)	0.0341 (5)	−0.0027 (5)	0.0172 (5)	−0.0022 (4)
P2	0.0462 (6)	0.0324 (5)	0.0397 (6)	−0.0014 (5)	0.0104 (5)	0.0033 (4)
P3	0.0364 (5)	0.0326 (5)	0.0286 (5)	0.0007 (4)	0.0086 (4)	−0.0015 (4)
P4	0.0366 (5)	0.0349 (5)	0.0321 (5)	−0.0007 (4)	0.0109 (4)	0.0008 (4)
F1	0.126 (4)	0.068 (3)	0.162 (4)	−0.005 (2)	0.013 (3)	−0.049 (3)
F2	0.060 (2)	0.140 (4)	0.157 (4)	−0.035 (2)	0.021 (2)	−0.052 (3)
F3	0.159 (4)	0.182 (5)	0.063 (2)	−0.071 (4)	0.041 (3)	−0.053 (3)
F4	0.155 (5)	0.081 (3)	0.290 (8)	−0.007 (3)	0.065 (5)	−0.103 (4)
F5	0.122 (4)	0.092 (3)	0.125 (4)	−0.045 (3)	−0.012 (3)	0.013 (3)
F6	0.141 (4)	0.104 (3)	0.180 (5)	−0.071 (3)	0.022 (4)	0.054 (3)
O1	0.043 (2)	0.041 (2)	0.060 (2)	−0.002 (1)	0.015 (2)	−0.006 (1)
O2	0.065 (2)	0.072 (2)	0.060 (2)	0.006 (2)	0.034 (2)	−0.004 (2)
O3	0.078 (2)	0.038 (2)	0.055 (2)	−0.020 (2)	0.038 (2)	−0.008 (1)
O4	0.098 (3)	0.058 (2)	0.065 (2)	0.011 (2)	0.046 (2)	0.023 (2)
C1	0.050 (5)	0.030 (4)	0.046 (5)	0.001 (4)	0.020 (4)	0.005 (4)
C2	0.072 (5)	0.055 (5)	0.054 (5)	0.011 (4)	0.021 (4)	0.009 (4)
C3	0.083 (6)	0.084 (6)	0.068 (6)	0.009 (5)	0.018 (5)	0.029 (5)
C4	0.085 (7)	0.074 (7)	0.106 (8)	0.013 (6)	0.022 (6)	0.033 (6)
C5	0.083 (7)	0.070 (6)	0.102 (9)	0.031 (5)	0.024 (6)	0.021 (6)
C6	0.080 (6)	0.047 (5)	0.075 (6)	0.008 (5)	0.033 (5)	−0.008 (4)
C1'	0.052 (8)	0.038 (7)	0.055 (7)	0.000 (6)	0.019 (6)	0.001 (6)
C2'	0.064 (8)	0.058 (8)	0.063 (8)	−0.001 (6)	0.011 (6)	0.017 (7)
C3'	0.11 (1)	0.10 (1)	0.11 (1)	0.008 (9)	0.030 (8)	0.013 (9)
C4'	0.073 (9)	0.070 (9)	0.064 (9)	0.014 (7)	0.013 (7)	0.032 (7)
C5'	0.085 (9)	0.073 (9)	0.10 (1)	0.004 (7)	0.030 (8)	0.016 (7)
C6'	0.070 (8)	0.048 (7)	0.077 (9)	0.001 (6)	0.024 (7)	0.004 (6)
C7	0.044 (2)	0.031 (2)	0.035 (2)	0.001 (2)	0.012 (2)	0.002 (2)
C8	0.054 (3)	0.042 (2)	0.038 (2)	−0.001 (2)	0.010 (2)	−0.005 (2)
C9	0.043 (3)	0.052 (3)	0.048 (3)	0.004 (2)	0.005 (2)	0.004 (2)
C10	0.057 (3)	0.045 (3)	0.050 (3)	0.015 (2)	0.020 (2)	0.005 (2)
C11	0.057 (3)	0.041 (2)	0.037 (2)	0.008 (2)	0.013 (2)	0.000 (2)
C12	0.046 (2)	0.038 (2)	0.034 (2)	0.001 (2)	0.010 (2)	0.002 (2)
C13	0.046 (2)	0.038 (2)	0.039 (2)	0.003 (2)	0.018 (2)	0.005 (2)
C14	0.054 (3)	0.056 (3)	0.044 (3)	−0.014 (2)	0.009 (2)	0.009 (2)
C15	0.057 (3)	0.074 (3)	0.048 (3)	−0.016 (3)	0.014 (2)	0.020 (3)
C16	0.090 (4)	0.086 (4)	0.041 (3)	−0.011 (3)	0.029 (3)	0.008 (3)
C17	0.102 (5)	0.067 (3)	0.050 (3)	−0.022 (3)	0.038 (3)	−0.015 (3)
C18	0.077 (3)	0.045 (3)	0.051 (3)	−0.010 (2)	0.031 (3)	−0.002 (2)
C19	0.054 (3)	0.050 (3)	0.045 (3)	−0.003 (2)	0.021 (2)	0.002 (2)
C20	0.058 (3)	0.080 (4)	0.067 (4)	−0.013 (3)	0.022 (3)	−0.025 (3)
C21	0.049 (3)	0.033 (2)	0.063 (3)	0.005 (2)	0.026 (2)	0.008 (2)
C22	0.068 (4)	0.039 (3)	0.122 (6)	−0.012 (3)	0.022 (4)	0.013 (3)
C23	0.061 (3)	0.034 (2)	0.032 (2)	−0.005 (2)	0.011 (2)	0.002 (2)
C24	0.057 (3)	0.041 (2)	0.044 (3)	−0.006 (2)	0.006 (2)	0.001 (2)
C25	0.062 (3)	0.059 (3)	0.067 (4)	−0.007 (3)	−0.002 (3)	0.014 (3)
C26	0.087 (4)	0.069 (4)	0.048 (3)	−0.021 (3)	−0.014 (3)	0.008 (3)
C27	0.108 (5)	0.077 (4)	0.039 (3)	−0.017 (4)	0.006 (3)	−0.018 (3)
C28	0.085 (4)	0.055 (3)	0.033 (2)	−0.010 (3)	0.012 (2)	−0.011 (2)
C29	0.056 (3)	0.035 (2)	0.037 (2)	−0.001 (2)	0.020 (2)	−0.004 (2)
C30	0.064 (3)	0.047 (3)	0.087 (4)	0.007 (2)	0.034 (3)	0.005 (3)
C31	0.071 (4)	0.070 (4)	0.110 (5)	0.017 (3)	0.043 (4)	0.009 (4)
C32	0.084 (4)	0.054 (3)	0.089 (4)	0.026 (3)	0.027 (4)	0.004 (3)
C33	0.088 (4)	0.040 (3)	0.068 (4)	0.008 (3)	0.024 (3)	0.005 (2)
C34	0.064 (3)	0.038 (2)	0.057 (3)	0.000 (2)	0.025 (2)	0.002 (2)
C35	0.068 (3)	0.035 (2)	0.045 (2)	−0.007 (2)	0.027 (2)	0.001 (2)
C36	0.067 (3)	0.042 (2)	0.037 (2)	−0.008 (2)	0.014 (2)	0.005 (2)
C37	0.038 (2)	0.031 (2)	0.050 (3)	0.004 (2)	0.003 (2)	0.004 (2)
C38	0.047 (3)	0.051 (3)	0.069 (3)	−0.002 (2)	0.019 (2)	−0.003 (2)
C39	0.042 (3)	0.071 (4)	0.074 (4)	−0.005 (2)	0.020 (3)	0.002 (3)
C40	0.041 (3)	0.046 (3)	0.077 (4)	−0.006 (2)	0.007 (2)	0.012 (3)
C41	0.061 (3)	0.047 (3)	0.060 (3)	0.006 (2)	0.003 (3)	0.000 (2)
C42	0.058 (3)	0.042 (2)	0.058 (3)	0.003 (2)	0.022 (2)	0.007 (2)
C43	0.040 (2)	0.037 (2)	0.053 (3)	−0.003 (2)	0.005 (2)	0.008 (2)
C44	0.050 (3)	0.058 (3)	0.081 (4)	0.008 (2)	0.022 (3)	0.025 (3)
C45	0.055 (3)	0.050 (3)	0.064 (3)	0.007 (2)	0.012 (3)	0.018 (2)
C46	0.049 (3)	0.047 (3)	0.056 (3)	0.009 (2)	0.008 (2)	0.004 (2)
C47	0.048 (3)	0.074 (4)	0.075 (4)	0.003 (3)	0.021 (3)	0.013 (3)
C48	0.053 (3)	0.053 (3)	0.063 (3)	−0.001 (2)	0.015 (2)	0.016 (2)
C49	0.051 (3)	0.039 (2)	0.025 (2)	−0.005 (2)	0.012 (2)	−0.005 (2)
C50	0.080 (4)	0.058 (3)	0.084 (4)	−0.027 (3)	0.058 (3)	−0.027 (3)
C51	0.105 (5)	0.072 (4)	0.081 (4)	−0.042 (4)	0.063 (4)	−0.025 (3)
C52	0.097 (5)	0.048 (3)	0.046 (3)	−0.022 (3)	0.011 (3)	−0.004 (2)
C53	0.086 (4)	0.048 (3)	0.073 (4)	0.015 (3)	−0.015 (3)	−0.025 (3)
C54	0.050 (3)	0.054 (3)	0.072 (3)	0.004 (2)	−0.001 (3)	−0.028 (3)
C55	0.040 (2)	0.036 (2)	0.040 (2)	0.006 (2)	0.002 (2)	−0.003 (2)
C56	0.064 (3)	0.073 (4)	0.049 (3)	0.018 (3)	−0.003 (3)	−0.009 (3)
C57	0.074 (4)	0.091 (5)	0.065 (4)	0.028 (4)	−0.012 (3)	0.003 (3)
C58	0.061 (4)	0.073 (4)	0.091 (5)	0.029 (3)	−0.001 (3)	0.000 (3)
C59	0.071 (4)	0.064 (3)	0.072 (4)	0.023 (3)	0.014 (3)	−0.007 (3)
C60	0.054 (3)	0.052 (3)	0.045 (3)	0.013 (2)	0.007 (2)	−0.007 (2)
C61	0.046 (2)	0.050 (3)	0.032 (2)	0.001 (2)	0.012 (2)	0.006 (2)
C62	0.041 (2)	0.046 (2)	0.035 (2)	0.001 (2)	0.016 (2)	−0.002 (2)
C63	0.040 (2)	0.055 (3)	0.034 (2)	0.004 (2)	0.011 (2)	0.005 (2)
C64	0.055 (3)	0.065 (3)	0.061 (3)	0.017 (3)	0.005 (3)	−0.011 (3)
C65	0.068 (4)	0.096 (5)	0.082 (4)	0.041 (4)	−0.001 (3)	−0.013 (4)
C66	0.055 (4)	0.128 (6)	0.061 (4)	0.034 (4)	0.003 (3)	0.000 (4)
C67	0.045 (3)	0.106 (5)	0.046 (3)	0.004 (3)	0.004 (2)	−0.001 (3)
C68	0.046 (3)	0.068 (3)	0.036 (2)	0.002 (2)	0.009 (2)	0.001 (2)
C69	0.044 (2)	0.039 (2)	0.028 (2)	−0.008 (2)	0.006 (2)	0.002 (2)
C70	0.048 (3)	0.049 (3)	0.039 (2)	−0.011 (2)	0.015 (2)	−0.002 (2)
C71	0.060 (3)	0.053 (3)	0.043 (3)	−0.022 (2)	0.015 (2)	−0.001 (2)
C72	0.079 (4)	0.041 (2)	0.036 (2)	−0.014 (2)	0.008 (2)	0.002 (2)
C73	0.069 (3)	0.040 (2)	0.042 (2)	0.003 (2)	0.013 (2)	0.003 (2)
C74	0.053 (3)	0.040 (2)	0.037 (2)	0.001 (2)	0.015 (2)	0.006 (2)

Geometric parameters (Å, º)

Sn1—C1	2.140 (4)	C53—C54	1.403 (8)
Sn1—C1'	2.125 (5)	C55—C60	1.374 (6)
Sn1—C7	2.133 (4)	C55—C56	1.394 (6)
Sn1—C13	2.156 (4)	C56—C57	1.383 (8)
Sn1—O1	2.250 (3)	C57—C58	1.368 (9)
Sn1—O3	2.213 (3)	C58—C59	1.357 (8)
Ag1—P1	2.520 (1)	C59—C60	1.391 (7)
Ag1—P2	2.488 (1)	C61—C62	1.520 (6)
Ag1—P3	2.495 (1)	C63—C64	1.381 (7)
Ag1—P4	2.517 (1)	C63—C68	1.389 (6)
P1—C23	1.829 (5)	C64—C65	1.387 (7)
P1—C29	1.822 (4)	C65—C66	1.376 (9)
P1—C35	1.842 (4)	C66—C67	1.372 (9)
P2—C36	1.864 (5)	C67—C68	1.399 (7)
P2—C37	1.830 (4)	C69—C74	1.387 (6)
P2—C43	1.827 (4)	C69—C70	1.397 (6)
P3—C49	1.821 (4)	C70—C71	1.390 (6)
P3—C55	1.831 (4)	C71—C72	1.368 (7)
P3—C61	1.853 (4)	C72—C73	1.387 (7)
P4—C62	1.856 (4)	C73—C74	1.392 (6)
P4—C63	1.829 (4)	C2—H2	0.95
P4—C69	1.826 (4)	C3—H3	0.95
F1—C20	1.329 (7)	C4—H4	0.95
F2—C20	1.298 (6)	C5—H5	0.95
F3—C20	1.303 (7)	C6—H6	0.95
F4—C22	1.277 (8)	C2'—H2'	0.95
F5—C22	1.334 (7)	C3'—H3'	0.95
F6—C22	1.309 (7)	C4'—H4'	0.95
O1—C19	1.254 (5)	C5'—H5'	0.95
O2—C19	1.220 (5)	C6'—H6'	0.95
O3—C21	1.259 (5)	C8—H8	0.95
O4—C21	1.213 (6)	C9—H9	0.95
C1—C2	1.39	C10—H10	0.95
C1—C6	1.39	C11—H11	0.95
C2—C3	1.39	C12—H12	0.95
C3—C4	1.39	C14—H14	0.95
C4—C5	1.39	C15—H15	0.95
C5—C6	1.39	C16—H16	0.95
C1'—C2'	1.39	C17—H17	0.95
C1'—C6'	1.39	C18—H18	0.95
C2'—C3'	1.39	C24—H24	0.95
C3'—C4'	1.39	C25—H25	0.95
C4'—C5'	1.39	C26—H26	0.95
C5'—C6'	1.39	C27—H27	0.95
C7—C8	1.391 (6)	C28—H28	0.95
C7—C12	1.399 (6)	C30—H30	0.95
C8—C9	1.384 (6)	C31—H31	0.95
C9—C10	1.382 (7)	C32—H32	0.95
C10—C11	1.383 (7)	C33—H33	0.95
C11—C12	1.383 (6)	C34—H34	0.95
C13—C14	1.387 (6)	C35—H35a	0.99
C13—C18	1.388 (6)	C35—H35b	0.99
C14—C15	1.395 (7)	C36—H36a	0.99
C15—C16	1.367 (8)	C36—H36b	0.99
C16—C17	1.380 (8)	C38—H38	0.95
C17—C18	1.387 (7)	C39—H39	0.95
C19—C20	1.544 (7)	C40—H40	0.95
C21—C22	1.546 (8)	C41—H41	0.95
C23—C24	1.386 (7)	C42—H42	0.95
C23—C28	1.395 (6)	C44—H44	0.95
C24—C25	1.388 (7)	C45—H45	0.95
C25—C26	1.373 (8)	C46—H46	0.95
C26—C27	1.364 (9)	C47—H47	0.95
C27—C28	1.387 (8)	C48—H48	0.95
C29—C30	1.388 (7)	C50—H50	0.95
C29—C34	1.393 (6)	C51—H51	0.95
C30—C31	1.390 (7)	C52—H52	0.95
C31—C32	1.385 (8)	C53—H53	0.95
C32—C33	1.376 (8)	C54—H54	0.95
C33—C34	1.382 (7)	C56—H56	0.95
C35—C36	1.535 (6)	C57—H57	0.95
C37—C38	1.369 (7)	C58—H58	0.95
C37—C42	1.384 (6)	C59—H59	0.95
C38—C39	1.364 (7)	C60—H60	0.95
C39—C40	1.376 (7)	C61—H61a	0.99
C40—C41	1.362 (7)	C61—H61b	0.99
C41—C42	1.423 (7)	C62—H62a	0.99
C43—C48	1.377 (7)	C62—H62b	0.99
C43—C44	1.387 (6)	C64—H64	0.95
C44—C45	1.376 (7)	C65—H65	0.95
C45—C46	1.368 (7)	C66—H66	0.95
C46—C47	1.378 (7)	C67—H67	0.95
C47—C48	1.403 (7)	C68—H68	0.95
C49—C54	1.378 (6)	C70—H70	0.95
C49—C50	1.379 (7)	C71—H71	0.95
C50—C51	1.385 (7)	C72—H72	0.95
C51—C52	1.381 (8)	C73—H73	0.95
C52—C53	1.348 (8)	C74—H74	0.95
C1—Sn1—C7	120.5 (2)	C66—C65—C64	120.2 (6)
C1—Sn1—C13	118.8 (2)	C67—C66—C65	119.8 (5)
C1—Sn1—O1	85.9 (3)	C66—C67—C68	120.1 (5)
C1—Sn1—O3	95.5 (3)	C63—C68—C67	120.5 (5)
C1'—Sn1—C7	127.3 (5)	C74—C69—C70	118.2 (4)
C1'—Sn1—C13	111.6 (5)	C74—C69—P4	119.0 (3)
C1'—Sn1—O1	96.1 (4)	C70—C69—P4	122.8 (3)
C1'—Sn1—O3	85.5 (4)	C71—C70—C69	120.3 (5)
C7—Sn1—C13	120.7 (2)	C72—C71—C70	120.8 (4)
C7—Sn1—O1	86.2 (1)	C71—C72—C73	119.9 (4)
C7—Sn1—O3	91.4 (1)	C72—C73—C74	119.4 (5)
C13—Sn1—O3	86.1 (1)	C69—C74—C73	121.3 (4)
C13—Sn1—O1	95.0 (1)	C3—C2—H2	120.0
O1—Sn1—O3	177.6 (1)	C1—C2—H2	120.0
P1—Ag1—P2	84.7 (1)	C2—C3—H3	120.0
P1—Ag1—P3	124.3 (1)	C4—C3—H3	120.0
P1—Ag1—P4	118.5 (1)	C5—C4—H4	120.0
P2—Ag1—P3	125.2 (1)	C3—C4—H4	120.0
P2—Ag1—P4	124.7 (1)	C6—C5—H5	120.0
P3—Ag1—P4	84.2 (1)	C4—C5—H5	120.0
C29—P1—C23	103.9 (2)	C5—C6—H6	120.0
C29—P1—C35	105.0 (2)	C1—C6—H6	120.0
C23—P1—C35	101.5 (2)	C3'—C2'—H2'	120.0
C29—P1—Ag1	128.4 (1)	C1'—C2'—H2'	120.0
C23—P1—Ag1	112.7 (2)	C2'—C3'—H3'	120.0
C35—P1—Ag1	102.0 (1)	C4'—C3'—H3'	120.0
C43—P2—C37	102.2 (2)	C5'—C4'—H4'	120.0
C43—P2—C36	101.6 (2)	C3'—C4'—H4'	120.0
C37—P2—C36	104.8 (2)	C4'—C5'—H5'	120.0
C43—P2—Ag1	124.5 (2)	C6'—C5'—H5'	120.0
C37—P2—Ag1	118.5 (1)	C5'—C6'—H6'	120.0
C36—P2—Ag1	102.4 (1)	C1'—C6'—H6'	120.0
C49—P3—C55	103.2 (2)	C9—C8—H8	119.4
C49—P3—C61	105.6 (2)	C7—C8—H8	119.4
C55—P3—C61	103.5 (2)	C10—C9—H9	119.8
C49—P3—Ag1	117.5 (1)	C8—C9—H9	119.8
C55—P3—Ag1	120.7 (1)	C9—C10—H10	120.5
C61—P3—Ag1	104.6 (1)	C11—C10—H10	120.5
C69—P4—C63	104.0 (2)	C10—C11—H11	119.7
C69—P4—C62	103.8 (2)	C12—C11—H11	119.7
C63—P4—C62	104.8 (2)	C11—C12—H12	119.5
C69—P4—Ag1	113.4 (1)	C7—C12—H12	119.5
C63—P4—Ag1	126.5 (1)	C13—C14—H14	119.5
C62—P4—Ag1	101.9 (1)	C15—C14—H14	119.5
C19—O1—Sn1	125.6 (3)	C16—C15—H15	119.7
C21—O3—Sn1	127.6 (3)	C14—C15—H15	119.7
C2—C1—C6	120.0	C15—C16—H16	120.4
C2—C1—Sn1	120.0 (4)	C17—C16—H16	120.4
C6—C1—Sn1	119.9 (4)	C16—C17—H17	119.9
C3—C2—C1	120.0	C18—C17—H17	119.9
C2—C3—C4	120.0	C17—C18—H18	119.4
C5—C4—C3	120.0	C13—C18—H18	119.4
C6—C5—C4	120.0	C23—C24—H24	119.5
C5—C6—C1	120.0	C25—C24—H24	119.5
C2'—C1'—C6'	120.0	C26—C25—H25	120.1
C2'—C1'—Sn1	120.1 (6)	C24—C25—H25	120.1
C6'—C1'—Sn1	118.9 (7)	C27—C26—H26	120.1
C3'—C2'—C1'	120.0	C25—C26—H26	120.1
C2'—C3'—C4'	120.0	C26—C27—H27	119.3
C5'—C4'—C3'	120.0	C28—C27—H27	119.3
C4'—C5'—C6'	120.0	C27—C28—H28	120.2
C5'—C6'—C1'	120.0	C23—C28—H28	120.2
C8—C7—C12	117.6 (4)	C29—C30—H30	119.7
C8—C7—Sn1	120.5 (3)	C31—C30—H30	119.7
C12—C7—Sn1	122.0 (3)	C32—C31—H31	120.1
C9—C8—C7	121.3 (4)	C30—C31—H31	120.1
C10—C9—C8	120.5 (4)	C33—C32—H32	120.0
C9—C10—C11	119.0 (4)	C31—C32—H32	120.0
C10—C11—C12	120.6 (4)	C32—C33—H33	119.9
C11—C12—C7	121.0 (4)	C34—C33—H33	119.9
C14—C13—C18	117.7 (4)	C33—C34—H34	119.6
C14—C13—Sn1	120.4 (3)	C29—C34—H34	119.6
C18—C13—Sn1	122.0 (3)	C36—C35—H35a	109.9
C13—C14—C15	120.9 (5)	P1—C35—H35a	109.9
C16—C15—C14	120.6 (5)	C36—C35—H35b	109.9
C15—C16—C17	119.3 (5)	P1—C35—H35b	109.9
C16—C17—C18	120.3 (5)	H35a—C35—H35b	108.3
C17—C18—C13	121.2 (5)	C35—C36—H36a	108.9
O1—C19—O2	129.3 (5)	P2—C36—H36a	108.9
O2—C19—C20	117.8 (5)	C35—C36—H36b	108.9
O1—C19—C20	112.9 (4)	P2—C36—H36b	108.9
F2—C20—F3	108.8 (6)	H36a—C36—H36b	107.7
F2—C20—F1	105.1 (6)	C39—C38—H38	119.8
F3—C20—F1	106.4 (5)	C37—C38—H38	119.8
F2—C20—C19	112.8 (5)	C38—C39—H39	119.0
F3—C20—C19	111.9 (5)	C40—C39—H39	119.0
F1—C20—C19	111.4 (5)	C41—C40—H40	120.4
O3—C21—O4	130.3 (5)	C39—C40—H40	120.4
O4—C21—C22	120.2 (5)	C40—C41—H41	120.5
O3—C21—C22	109.5 (5)	C42—C41—H41	120.5
F4—C22—F6	108.4 (6)	C37—C42—H42	119.8
F4—C22—F5	108.3 (7)	C41—C42—H42	119.8
F6—C22—F5	105.1 (5)	C45—C44—H44	119.0
F4—C22—C21	111.5 (5)	C43—C44—H44	119.0
F6—C22—C21	111.8 (6)	C46—C45—H45	120.2
F5—C22—C21	111.5 (4)	C44—C45—H45	120.2
C24—C23—C28	118.5 (4)	C45—C46—H46	119.9
C24—C23—P1	119.3 (3)	C47—C46—H46	119.9
C28—C23—P1	122.0 (4)	C46—C47—H47	120.3
C23—C24—C25	121.0 (5)	C48—C47—H47	120.3
C26—C25—C24	119.8 (6)	C43—C48—H48	119.6
C27—C26—C25	119.8 (5)	C47—C48—H48	119.6
C26—C27—C28	121.4 (5)	C49—C50—H50	119.4
C27—C28—C23	119.5 (6)	C51—C50—H50	119.4
C30—C29—C34	118.5 (4)	C52—C51—H51	119.7
C30—C29—P1	121.9 (3)	C50—C51—H51	119.7
C34—C29—P1	119.5 (3)	C53—C52—H52	120.5
C29—C30—C31	120.7 (5)	C51—C52—H52	120.5
C32—C31—C30	119.8 (6)	C52—C53—H53	119.6
C33—C32—C31	120.0 (5)	C54—C53—H53	119.6
C32—C33—C34	120.2 (5)	C49—C54—H54	119.6
C33—C34—C29	120.8 (5)	C53—C54—H54	119.6
C36—C35—P1	109.0 (3)	C57—C56—H56	120.4
C35—C36—P2	113.3 (3)	C55—C56—H56	120.4
C38—C37—C42	118.9 (4)	C58—C57—H57	119.4
C38—C37—P2	122.7 (4)	C56—C57—H57	119.4
C42—C37—P2	118.3 (4)	C59—C58—H58	120.1
C39—C38—C37	120.4 (5)	C57—C58—H58	120.1
C38—C39—C40	121.9 (5)	C58—C59—H59	120.0
C41—C40—C39	119.3 (5)	C60—C59—H59	120.0
C40—C41—C42	119.1 (5)	C55—C60—H60	119.6
C37—C42—C41	120.3 (5)	C59—C60—H60	119.6
C48—C43—C44	117.7 (4)	C62—C61—H61a	108.4
C48—C43—P2	120.5 (3)	P3—C61—H61a	108.4
C44—C43—P2	121.8 (4)	C62—C61—H61b	108.4
C45—C44—C43	122.0 (5)	P3—C61—H61b	108.4
C46—C45—C44	119.6 (5)	H61a—C61—H61b	107.5
C45—C46—C47	120.3 (5)	C61—C62—H62a	109.3
C46—C47—C48	119.4 (5)	P4—C62—H62a	109.3
C43—C48—C47	120.9 (5)	C61—C62—H62b	109.3
C54—C49—C50	117.7 (4)	P4—C62—H62b	109.3
C54—C49—P3	121.6 (4)	H62a—C62—H62b	107.9
C50—C49—P3	120.5 (3)	C63—C64—H64	119.4
C49—C50—C51	121.1 (5)	C65—C64—H64	119.4
C52—C51—C50	120.5 (6)	C66—C65—H65	119.9
C53—C52—C51	119.0 (5)	C64—C65—H65	119.9
C52—C53—C54	120.9 (5)	C67—C66—H66	120.1
C49—C54—C53	120.8 (5)	C65—C66—H66	120.1
C60—C55—C56	118.9 (4)	C66—C67—H67	120.0
C60—C55—P3	119.4 (3)	C68—C67—H67	120.0
C56—C55—P3	121.5 (4)	C63—C68—H68	119.7
C57—C56—C55	119.2 (5)	C67—C68—H68	119.7
C58—C57—C56	121.2 (6)	C71—C70—H70	119.9
C59—C58—C57	119.8 (5)	C69—C70—H70	119.9
C58—C59—C60	120.0 (5)	C72—C71—H71	119.6
C55—C60—C59	120.8 (5)	C70—C71—H71	119.6
C62—C61—P3	115.3 (3)	C71—C72—H72	120.0
C61—C62—P4	111.8 (3)	C73—C72—H72	120.0
C64—C63—C68	118.3 (4)	C72—C73—H73	120.3
C64—C63—P4	122.0 (4)	C74—C73—H73	120.3
C68—C63—P4	119.6 (4)	C69—C74—H74	119.3
C63—C64—C65	121.1 (5)	C73—C74—H74	119.3
P2—Ag1—P1—C29	139.4 (2)	O3—C21—C22—F5	56.2 (7)
P3—Ag1—P1—C29	9.7 (2)	C29—P1—C23—C24	151.7 (3)
P4—Ag1—P1—C29	−93.7 (2)	C35—P1—C23—C24	−99.6 (4)
P2—Ag1—P1—C23	−89.1 (2)	Ag1—P1—C23—C24	8.8 (4)
P3—Ag1—P1—C23	141.2 (1)	C29—P1—C23—C28	−33.3 (4)
P4—Ag1—P1—C23	37.8 (2)	C35—P1—C23—C28	75.5 (4)
P2—Ag1—P1—C35	18.9 (2)	Ag1—P1—C23—C28	−176.1 (3)
P3—Ag1—P1—C35	−110.7 (2)	C28—C23—C24—C25	−0.5 (7)
P4—Ag1—P1—C35	145.8 (2)	P1—C23—C24—C25	174.8 (4)
P3—Ag1—P2—C43	−110.6 (2)	C23—C24—C25—C26	1.1 (8)
P4—Ag1—P2—C43	−0.7 (2)	C24—C25—C26—C27	−0.6 (9)
P1—Ag1—P2—C43	120.5 (2)	C25—C26—C27—C28	−0.6 (9)
P3—Ag1—P2—C37	21.2 (2)	C26—C27—C28—C23	1.3 (9)
P4—Ag1—P2—C37	131.0 (2)	C24—C23—C28—C27	−0.7 (7)
P1—Ag1—P2—C37	−107.7 (2)	P1—C23—C28—C27	−175.8 (4)
P3—Ag1—P2—C36	135.8 (2)	C23—P1—C29—C30	130.7 (4)
P4—Ag1—P2—C36	−114.4 (2)	C35—P1—C29—C30	24.5 (5)
P1—Ag1—P2—C36	6.9 (2)	Ag1—P1—C29—C30	−94.7 (4)
P2—Ag1—P3—C49	11.2 (2)	C23—P1—C29—C34	−53.5 (4)
P4—Ag1—P3—C49	−117.8 (2)	C35—P1—C29—C34	−159.7 (4)
P1—Ag1—P3—C49	121.4 (2)	Ag1—P1—C29—C34	81.1 (4)
P2—Ag1—P3—C55	−116.2 (2)	C34—C29—C30—C31	1.4 (8)
P4—Ag1—P3—C55	114.8 (2)	P1—C29—C30—C31	177.2 (5)
P1—Ag1—P3—C55	−6.0 (2)	C29—C30—C31—C32	0 (1)
P2—Ag1—P3—C61	128.0 (2)	C30—C31—C32—C33	−1 (1)
P4—Ag1—P3—C61	−1.0 (2)	C31—C32—C33—C34	1 (1)
P1—Ag1—P3—C61	−121.8 (2)	C32—C33—C34—C29	0.7 (8)
P2—Ag1—P4—C69	142.4 (1)	C30—C29—C34—C33	−1.6 (7)
P3—Ag1—P4—C69	−88.2 (1)	P1—C29—C34—C33	−177.6 (4)
P1—Ag1—P4—C69	38.0 (2)	C29—P1—C35—C36	175.9 (3)
P2—Ag1—P4—C63	12.0 (2)	C23—P1—C35—C36	68.0 (3)
P3—Ag1—P4—C63	141.4 (2)	Ag1—P1—C35—C36	−48.4 (3)
P1—Ag1—P4—C63	−92.4 (2)	P1—C35—C36—P2	61.8 (4)
P2—Ag1—P4—C62	−106.7 (2)	C43—P2—C36—C35	−169.8 (3)
P3—Ag1—P4—C62	22.7 (1)	C37—P2—C36—C35	84.1 (3)
P1—Ag1—P4—C62	148.9 (1)	Ag1—P2—C36—C35	−40.2 (3)
C1'—Sn1—O1—C19	−35.8 (6)	C43—P2—C37—C38	−87.4 (4)
C7—Sn1—O1—C19	−162.9 (4)	C36—P2—C37—C38	18.3 (4)
C1—Sn1—O1—C19	−42.0 (4)	Ag1—P2—C37—C38	131.6 (3)
C13—Sn1—O1—C19	76.6 (4)	C43—P2—C37—C42	90.2 (4)
C1'—Sn1—O3—C21	−64.1 (6)	C36—P2—C37—C42	−164.1 (3)
C7—Sn1—O3—C21	63.2 (4)	Ag1—P2—C37—C42	−50.8 (4)
C1—Sn1—O3—C21	−57.6 (4)	C42—C37—C38—C39	0.6 (7)
C13—Sn1—O3—C21	−176.1 (4)	P2—C37—C38—C39	178.2 (4)
C7—Sn1—C1—C2	33.8 (5)	C37—C38—C39—C40	−2.5 (8)
C13—Sn1—C1—C2	−142.8 (4)	C38—C39—C40—C41	2.8 (8)
O3—Sn1—C1—C2	128.6 (4)	C39—C40—C41—C42	−1.3 (7)
O1—Sn1—C1—C2	−49.4 (4)	C38—C37—C42—C41	0.8 (7)
C7—Sn1—C1—C6	−148.5 (4)	P2—C37—C42—C41	−176.8 (3)
C13—Sn1—C1—C6	34.9 (6)	C40—C41—C42—C37	−0.5 (7)
O3—Sn1—C1—C6	−53.7 (5)	C37—P2—C43—C48	−141.1 (4)
O1—Sn1—C1—C6	128.3 (5)	C36—P2—C43—C48	110.7 (4)
C6—C1—C2—C3	0.0	Ag1—P2—C43—C48	−3.3 (5)
Sn1—C1—C2—C3	177.7 (6)	C37—P2—C43—C44	41.7 (5)
C1—C2—C3—C4	0.0	C36—P2—C43—C44	−66.5 (5)
C2—C3—C4—C5	0.0	Ag1—P2—C43—C44	179.6 (4)
C3—C4—C5—C6	0.0	C48—C43—C44—C45	−2.4 (8)
C4—C5—C6—C1	0.0	P2—C43—C44—C45	174.9 (4)
C2—C1—C6—C5	0.0	C43—C44—C45—C46	−0.1 (9)
Sn1—C1—C6—C5	−177.7 (6)	C44—C45—C46—C47	2.3 (8)
C7—Sn1—C1'—C2'	47.4 (9)	C45—C46—C47—C48	−2.1 (8)
C13—Sn1—C1'—C2'	−140.2 (7)	C44—C43—C48—C47	2.6 (8)
O3—Sn1—C1'—C2'	135.7 (8)	P2—C43—C48—C47	−174.7 (4)
O1—Sn1—C1'—C2'	−42.4 (8)	C46—C47—C48—C43	−0.4 (8)
C7—Sn1—C1'—C6'	−143.9 (6)	C55—P3—C49—C54	−151.1 (4)
C13—Sn1—C1'—C6'	28.4 (8)	C61—P3—C49—C54	−42.7 (4)
O3—Sn1—C1'—C6'	−55.6 (7)	Ag1—P3—C49—C54	73.4 (4)
O1—Sn1—C1'—C6'	126.2 (7)	C55—P3—C49—C50	33.8 (4)
C6'—C1'—C2'—C3'	0.0	C61—P3—C49—C50	142.1 (4)
Sn1—C1'—C2'—C3'	169 (1)	Ag1—P3—C49—C50	−101.7 (4)
C1'—C2'—C3'—C4'	0.0	C54—C49—C50—C51	−0.2 (8)
C2'—C3'—C4'—C5'	0.0	P3—C49—C50—C51	175.1 (5)
C3'—C4'—C5'—C6'	0.0	C49—C50—C51—C52	−1.0 (9)
C4'—C5'—C6'—C1'	0.0	C50—C51—C52—C53	1.0 (9)
C2'—C1'—C6'—C5'	0.0	C51—C52—C53—C54	0.1 (9)
Sn1—C1'—C6'—C5'	−169 (1)	C50—C49—C54—C53	1.3 (8)
C1'—Sn1—C7—C8	110.9 (6)	P3—C49—C54—C53	−174.0 (4)
C1—Sn1—C7—C8	122.7 (4)	C52—C53—C54—C49	−1.2 (9)
C13—Sn1—C7—C8	−60.8 (4)	C49—P3—C55—C60	−127.8 (4)
O3—Sn1—C7—C8	25.5 (3)	C61—P3—C55—C60	122.3 (4)
O1—Sn1—C7—C8	−154.3 (3)	Ag1—P3—C55—C60	5.9 (5)
C1'—Sn1—C7—C12	−67.7 (6)	C49—P3—C55—C56	57.3 (5)
C1—Sn1—C7—C12	−55.9 (5)	C61—P3—C55—C56	−52.6 (5)
C13—Sn1—C7—C12	120.6 (3)	Ag1—P3—C55—C56	−169.0 (4)
O3—Sn1—C7—C12	−153.0 (3)	C60—C55—C56—C57	2.0 (9)
O1—Sn1—C7—C12	27.1 (3)	P3—C55—C56—C57	176.9 (5)
C12—C7—C8—C9	−1.4 (6)	C55—C56—C57—C58	1 (1)
Sn1—C7—C8—C9	179.9 (3)	C56—C57—C58—C59	−2 (1)
C7—C8—C9—C10	1.7 (7)	C57—C58—C59—C60	1 (1)
C8—C9—C10—C11	−1.1 (7)	C56—C55—C60—C59	−3.5 (8)
C9—C10—C11—C12	0.4 (7)	P3—C55—C60—C59	−178.6 (4)
C10—C11—C12—C7	−0.2 (6)	C58—C59—C60—C55	2.3 (9)
C8—C7—C12—C11	0.7 (6)	C49—P3—C61—C62	96.2 (3)
Sn1—C7—C12—C11	179.3 (3)	C55—P3—C61—C62	−155.7 (3)
C1'—Sn1—C13—C14	101.1 (6)	Ag1—P3—C61—C62	−28.4 (4)
C7—Sn1—C13—C14	−86.0 (4)	P3—C61—C62—P4	52.7 (4)
C1—Sn1—C13—C14	90.6 (5)	C69—P4—C62—C61	70.5 (3)
O3—Sn1—C13—C14	−175.3 (4)	C63—P4—C62—C61	179.3 (3)
O1—Sn1—C13—C14	2.5 (4)	Ag1—P4—C62—C61	−47.5 (3)
C1'—Sn1—C13—C18	−77.4 (6)	C69—P4—C63—C64	144.1 (4)
C7—Sn1—C13—C18	95.5 (4)	C62—P4—C63—C64	35.4 (5)
C1—Sn1—C13—C18	−87.9 (5)	Ag1—P4—C63—C64	−81.9 (4)
O3—Sn1—C13—C18	6.2 (4)	C69—P4—C63—C68	−40.8 (4)
O1—Sn1—C13—C18	−175.9 (4)	C62—P4—C63—C68	−149.5 (4)
C18—C13—C14—C15	1.3 (7)	Ag1—P4—C63—C68	93.1 (4)
Sn1—C13—C14—C15	−177.2 (4)	C68—C63—C64—C65	1.0 (8)
C13—C14—C15—C16	−1.6 (8)	P4—C63—C64—C65	176.1 (5)
C14—C15—C16—C17	0.4 (9)	C63—C64—C65—C66	0 (1)
C15—C16—C17—C18	1 (1)	C64—C65—C66—C67	−1 (1)
C16—C17—C18—C13	−1.3 (9)	C65—C66—C67—C68	0 (1)
C14—C13—C18—C17	0.1 (8)	C64—C63—C68—C67	−1.9 (7)
Sn1—C13—C18—C17	178.6 (4)	P4—C63—C68—C67	−177.2 (4)
Sn1—O1—C19—O2	−25.7 (7)	C66—C67—C68—C63	1.6 (8)
Sn1—O1—C19—C20	154.6 (4)	C63—P4—C69—C74	144.6 (3)
O2—C19—C20—F2	−7.7 (8)	C62—P4—C69—C74	−106.0 (3)
O1—C19—C20—F2	172.1 (5)	Ag1—P4—C69—C74	3.7 (4)
O2—C19—C20—F3	115.4 (6)	C63—P4—C69—C70	−35.7 (4)
O1—C19—C20—F3	−64.9 (7)	C62—P4—C69—C70	73.7 (4)
O2—C19—C20—F1	−125.6 (5)	Ag1—P4—C69—C70	−176.6 (3)
O1—C19—C20—F1	54.1 (6)	C74—C69—C70—C71	−0.9 (6)
Sn1—O3—C21—O4	−6.7 (8)	P4—C69—C70—C71	179.3 (3)
Sn1—O3—C21—C22	175.1 (3)	C69—C70—C71—C72	0.1 (7)
O4—C21—C22—F4	116.7 (7)	C70—C71—C72—C73	1.5 (7)
O3—C21—C22—F4	−65.0 (7)	C71—C72—C73—C74	−2.4 (7)
O4—C21—C22—F6	−4.8 (8)	C70—C69—C74—C73	0.1 (6)
O3—C21—C22—F6	173.5 (5)	P4—C69—C74—C73	179.8 (3)
O4—C21—C22—F5	−122.1 (6)	C72—C73—C74—C69	1.6 (7)