metal-organic compounds
The title complex, [RhHCl2(PMePh2)3]·3CH2Cl2, has octahedral coordination for Rh, with the three phosphine ligands arranged mer and the two chloro ligands mutually cis. Coordination bond lengths are in accord with the relative trans influence of the ligands.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802012242/bt6162sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536802012242/bt6162Isup2.hkl |
CCDC reference: 193704
Computing details top
Data collection: SMART (Siemens, 1994); cell refinement: local programs; data reduction: SAINT (Siemens, 1994); program(s) used to solve structure: SHELXTL (Sheldrick, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and local programs.
hydridodichlorotris(methyldiphenylphosphine)rhodium(III) dichloromethane
trisolvate top
Crystal data top
[RhHCl2(C13H13P)3]·3CH2Cl2 | F(000) = 2096 |
Mr = 1030.21 | Dx = 1.484 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
a = 12.5494 (8) Å | Cell parameters from 16248 reflections |
b = 18.3233 (12) Å | θ = 2.2–28.4° |
c = 20.0687 (13) Å | µ = 0.97 mm−1 |
β = 92.063 (2)° | T = 160 K |
V = 4611.7 (5) Å3 | Block, colourless |
Z = 4 | 0.50 × 0.32 × 0.30 mm |
Data collection top
Siemens SMART CCD diffractometer | 10376 independent reflections |
Radiation source: fine-focus sealed tube | 8288 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.041 |
Detector resolution: 8.192 pixels mm-1 | θmax = 28.4°, θmin = 1.5° |
ω rotation with narrow frames scans | h = −16→11 |
Absorption correction: multi-scan (XPREP in SHELXTL; Sheldrick, 1997) | k = −23→24 |
Tmin = 0.642, Tmax = 0.876 | l = −26→26 |
27485 measured reflections |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.044 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.118 | H-atom parameters constrained |
S = 1.11 | w = 1/[σ2(Fo2) + (0.0449P)2 + 10.9692P] where P = (Fo2 + 2Fc2)/3 |
10376 reflections | (Δ/σ)max = 0.001 |
493 parameters | Δρmax = 1.02 e Å−3 |
0 restraints | Δρmin = −1.51 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Rh | 0.51389 (2) | 0.229024 (13) | 0.729752 (12) | 0.01714 (7) | |
H1 | 0.594 (3) | 0.242 (2) | 0.6746 (19) | 0.025* | |
Cl1 | 0.39325 (7) | 0.20623 (5) | 0.82468 (4) | 0.02745 (18) | |
Cl2 | 0.54299 (7) | 0.35538 (4) | 0.76159 (4) | 0.02479 (17) | |
P1 | 0.66312 (7) | 0.20692 (5) | 0.80172 (4) | 0.01958 (17) | |
C1 | 0.7910 (3) | 0.24474 (19) | 0.77800 (17) | 0.0233 (7) | |
C2 | 0.8799 (3) | 0.2394 (2) | 0.82212 (19) | 0.0321 (8) | |
H2 | 0.8737 | 0.2146 | 0.8634 | 0.038* | |
C3 | 0.9767 (3) | 0.2699 (3) | 0.8060 (2) | 0.0397 (10) | |
H3 | 1.0367 | 0.2657 | 0.8360 | 0.048* | |
C4 | 0.9855 (3) | 0.3066 (2) | 0.7463 (2) | 0.0397 (10) | |
H4 | 1.0519 | 0.3275 | 0.7354 | 0.048* | |
C5 | 0.8988 (3) | 0.3129 (2) | 0.7026 (2) | 0.0363 (9) | |
H5 | 0.9054 | 0.3382 | 0.6616 | 0.044* | |
C6 | 0.8017 (3) | 0.2823 (2) | 0.71856 (19) | 0.0286 (8) | |
H6 | 0.7420 | 0.2871 | 0.6884 | 0.034* | |
C7 | 0.6943 (3) | 0.11327 (19) | 0.82669 (17) | 0.0251 (7) | |
C8 | 0.7895 (3) | 0.0780 (2) | 0.81223 (18) | 0.0312 (8) | |
H8 | 0.8411 | 0.1027 | 0.7871 | 0.037* | |
C9 | 0.8097 (4) | 0.0074 (2) | 0.8341 (2) | 0.0423 (11) | |
H9 | 0.8743 | −0.0163 | 0.8238 | 0.051* | |
C10 | 0.7346 (4) | −0.0283 (2) | 0.8713 (2) | 0.0496 (13) | |
H10 | 0.7488 | −0.0763 | 0.8873 | 0.060* | |
C11 | 0.6402 (4) | 0.0047 (2) | 0.8852 (2) | 0.0447 (11) | |
H11 | 0.5888 | −0.0207 | 0.9099 | 0.054* | |
C12 | 0.6191 (3) | 0.0758 (2) | 0.86312 (19) | 0.0326 (8) | |
H12 | 0.5535 | 0.0986 | 0.8729 | 0.039* | |
C13 | 0.6449 (3) | 0.2497 (2) | 0.88283 (17) | 0.0273 (7) | |
H13A | 0.7072 | 0.2396 | 0.9122 | 0.041* | |
H13B | 0.5809 | 0.2298 | 0.9027 | 0.041* | |
H13C | 0.6369 | 0.3025 | 0.8770 | 0.041* | |
P2 | 0.50594 (7) | 0.11729 (5) | 0.68241 (4) | 0.01970 (17) | |
C14 | 0.6319 (3) | 0.06878 (19) | 0.67598 (16) | 0.0218 (7) | |
C15 | 0.7156 (3) | 0.1046 (2) | 0.64554 (19) | 0.0307 (8) | |
H15 | 0.7084 | 0.1546 | 0.6335 | 0.037* | |
C16 | 0.8089 (3) | 0.0676 (3) | 0.6328 (2) | 0.0412 (10) | |
H16 | 0.8653 | 0.0920 | 0.6117 | 0.049* | |
C17 | 0.8198 (4) | −0.0051 (2) | 0.6508 (2) | 0.0405 (10) | |
H17 | 0.8836 | −0.0305 | 0.6417 | 0.049* | |
C18 | 0.7389 (3) | −0.0402 (2) | 0.6816 (2) | 0.0355 (9) | |
H18 | 0.7474 | −0.0898 | 0.6945 | 0.043* | |
C19 | 0.6445 (3) | −0.00402 (19) | 0.69412 (17) | 0.0269 (7) | |
H19 | 0.5885 | −0.0290 | 0.7151 | 0.032* | |
C20 | 0.4678 (3) | 0.1160 (2) | 0.59302 (18) | 0.0262 (7) | |
C21 | 0.4086 (3) | 0.0594 (2) | 0.5645 (2) | 0.0349 (9) | |
H21 | 0.3824 | 0.0215 | 0.5918 | 0.042* | |
C22 | 0.3875 (4) | 0.0581 (2) | 0.4955 (2) | 0.0431 (11) | |
H22 | 0.3462 | 0.0196 | 0.4763 | 0.052* | |
C23 | 0.4260 (4) | 0.1123 (3) | 0.4554 (2) | 0.0439 (11) | |
H23 | 0.4111 | 0.1112 | 0.4086 | 0.053* | |
C24 | 0.4864 (3) | 0.1682 (3) | 0.48329 (19) | 0.0389 (10) | |
H24 | 0.5133 | 0.2056 | 0.4557 | 0.047* | |
C25 | 0.5079 (3) | 0.1699 (2) | 0.55168 (18) | 0.0288 (8) | |
H25 | 0.5504 | 0.2081 | 0.5705 | 0.035* | |
C26 | 0.4166 (3) | 0.0546 (2) | 0.72142 (19) | 0.0298 (8) | |
H26A | 0.4376 | 0.0493 | 0.7687 | 0.045* | |
H26B | 0.4201 | 0.0069 | 0.6994 | 0.045* | |
H26C | 0.3436 | 0.0734 | 0.7173 | 0.045* | |
P3 | 0.36572 (7) | 0.27458 (5) | 0.66785 (4) | 0.02050 (17) | |
C27 | 0.3948 (3) | 0.32810 (19) | 0.59398 (17) | 0.0245 (7) | |
C28 | 0.3132 (3) | 0.3495 (2) | 0.54909 (19) | 0.0304 (8) | |
H28 | 0.2416 | 0.3358 | 0.5567 | 0.037* | |
C29 | 0.3363 (3) | 0.3910 (2) | 0.49305 (19) | 0.0365 (9) | |
H29 | 0.2806 | 0.4042 | 0.4621 | 0.044* | |
C30 | 0.4390 (4) | 0.4128 (2) | 0.4823 (2) | 0.0391 (9) | |
H30 | 0.4545 | 0.4405 | 0.4438 | 0.047* | |
C31 | 0.5201 (3) | 0.3941 (2) | 0.5280 (2) | 0.0363 (9) | |
H31 | 0.5910 | 0.4101 | 0.5214 | 0.044* | |
C32 | 0.4976 (3) | 0.3520 (2) | 0.58337 (18) | 0.0289 (8) | |
H32 | 0.5535 | 0.3394 | 0.6144 | 0.035* | |
C33 | 0.2596 (3) | 0.21112 (19) | 0.64167 (19) | 0.0269 (7) | |
C34 | 0.2413 (3) | 0.1891 (2) | 0.5752 (2) | 0.0335 (8) | |
H34 | 0.2842 | 0.2081 | 0.5413 | 0.040* | |
C35 | 0.1602 (3) | 0.1395 (3) | 0.5589 (3) | 0.0450 (11) | |
H35 | 0.1474 | 0.1253 | 0.5138 | 0.054* | |
C36 | 0.0984 (3) | 0.1109 (3) | 0.6084 (3) | 0.0499 (12) | |
H36 | 0.0441 | 0.0764 | 0.5973 | 0.060* | |
C37 | 0.1157 (3) | 0.1325 (3) | 0.6738 (3) | 0.0486 (12) | |
H37 | 0.0724 | 0.1132 | 0.7074 | 0.058* | |
C38 | 0.1959 (3) | 0.1821 (2) | 0.6907 (2) | 0.0372 (9) | |
H38 | 0.2074 | 0.1964 | 0.7359 | 0.045* | |
C39 | 0.2896 (3) | 0.3399 (2) | 0.71577 (19) | 0.0280 (7) | |
H39A | 0.2683 | 0.3171 | 0.7574 | 0.042* | |
H39B | 0.2258 | 0.3548 | 0.6896 | 0.042* | |
H39C | 0.3338 | 0.3828 | 0.7260 | 0.042* | |
C40 | 0.8530 (3) | 0.1008 (3) | 0.3812 (2) | 0.0417 (10) | |
H40A | 0.8844 | 0.1429 | 0.3580 | 0.050* | |
H40B | 0.8518 | 0.0587 | 0.3503 | 0.050* | |
Cl3 | 0.93320 (11) | 0.07929 (7) | 0.45250 (6) | 0.0552 (3) | |
Cl4 | 0.72200 (10) | 0.12220 (7) | 0.40219 (8) | 0.0614 (4) | |
C41 | 0.9013 (4) | 0.2684 (3) | 0.5054 (3) | 0.0530 (13) | |
H41A | 0.9024 | 0.2558 | 0.4574 | 0.064* | |
H41B | 0.9295 | 0.2260 | 0.5311 | 0.064* | |
Cl5 | 0.98438 (12) | 0.34426 (8) | 0.52105 (7) | 0.0608 (4) | |
Cl6 | 0.76911 (12) | 0.28492 (8) | 0.52718 (7) | 0.0624 (4) | |
C42 | 0.2668 (6) | 0.0515 (4) | 0.9049 (4) | 0.103 (3) | |
H42A | 0.2963 | 0.1000 | 0.8939 | 0.123* | |
H42B | 0.2445 | 0.0531 | 0.9517 | 0.123* | |
Cl7 | 0.35908 (15) | −0.00962 (10) | 0.89810 (9) | 0.0852 (5) | |
Cl8 | 0.14466 (19) | 0.03221 (11) | 0.84745 (12) | 0.1052 (7) |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Rh | 0.01747 (13) | 0.01812 (12) | 0.01592 (12) | −0.00080 (9) | 0.00175 (8) | −0.00049 (9) |
Cl1 | 0.0271 (4) | 0.0314 (4) | 0.0244 (4) | −0.0033 (3) | 0.0087 (3) | −0.0002 (3) |
Cl2 | 0.0264 (4) | 0.0198 (4) | 0.0281 (4) | −0.0025 (3) | 0.0001 (3) | −0.0033 (3) |
P1 | 0.0218 (4) | 0.0210 (4) | 0.0159 (4) | −0.0015 (3) | 0.0010 (3) | 0.0010 (3) |
C1 | 0.0198 (16) | 0.0246 (16) | 0.0256 (17) | −0.0017 (13) | 0.0035 (13) | −0.0033 (13) |
C2 | 0.0288 (19) | 0.042 (2) | 0.0249 (18) | −0.0034 (16) | −0.0014 (15) | −0.0018 (16) |
C3 | 0.0239 (19) | 0.056 (3) | 0.039 (2) | −0.0038 (18) | −0.0023 (16) | −0.010 (2) |
C4 | 0.0243 (19) | 0.048 (3) | 0.047 (2) | −0.0086 (18) | 0.0110 (17) | −0.005 (2) |
C5 | 0.032 (2) | 0.037 (2) | 0.040 (2) | −0.0028 (17) | 0.0088 (17) | 0.0088 (18) |
C6 | 0.0248 (18) | 0.0295 (19) | 0.0316 (19) | 0.0020 (14) | 0.0009 (15) | 0.0044 (15) |
C7 | 0.0331 (19) | 0.0234 (17) | 0.0183 (16) | −0.0012 (14) | −0.0044 (14) | 0.0008 (13) |
C8 | 0.041 (2) | 0.0294 (19) | 0.0222 (17) | 0.0041 (16) | −0.0098 (15) | −0.0046 (14) |
C9 | 0.056 (3) | 0.032 (2) | 0.037 (2) | 0.0133 (19) | −0.021 (2) | −0.0071 (17) |
C10 | 0.075 (3) | 0.025 (2) | 0.046 (3) | −0.002 (2) | −0.032 (2) | 0.0012 (18) |
C11 | 0.059 (3) | 0.034 (2) | 0.039 (2) | −0.019 (2) | −0.015 (2) | 0.0124 (18) |
C12 | 0.041 (2) | 0.0289 (19) | 0.0277 (19) | −0.0081 (16) | −0.0057 (16) | 0.0050 (15) |
C13 | 0.0285 (18) | 0.0319 (18) | 0.0216 (17) | −0.0050 (15) | 0.0024 (14) | −0.0014 (14) |
P2 | 0.0201 (4) | 0.0194 (4) | 0.0196 (4) | −0.0009 (3) | 0.0006 (3) | −0.0015 (3) |
C14 | 0.0232 (16) | 0.0246 (17) | 0.0174 (15) | 0.0043 (13) | −0.0011 (12) | −0.0022 (12) |
C15 | 0.0285 (19) | 0.033 (2) | 0.0308 (19) | 0.0071 (15) | 0.0022 (15) | 0.0057 (15) |
C16 | 0.029 (2) | 0.055 (3) | 0.040 (2) | 0.0093 (19) | 0.0106 (17) | 0.011 (2) |
C17 | 0.038 (2) | 0.048 (2) | 0.035 (2) | 0.0216 (19) | −0.0001 (18) | −0.0028 (18) |
C18 | 0.043 (2) | 0.030 (2) | 0.033 (2) | 0.0127 (17) | −0.0090 (17) | −0.0040 (16) |
C19 | 0.0331 (19) | 0.0252 (18) | 0.0221 (17) | 0.0029 (14) | −0.0052 (14) | −0.0022 (13) |
C20 | 0.0251 (17) | 0.0278 (18) | 0.0254 (17) | 0.0058 (14) | −0.0042 (14) | −0.0061 (14) |
C21 | 0.037 (2) | 0.031 (2) | 0.036 (2) | 0.0058 (16) | −0.0105 (17) | −0.0074 (16) |
C22 | 0.049 (3) | 0.039 (2) | 0.041 (2) | 0.0087 (19) | −0.015 (2) | −0.0203 (19) |
C23 | 0.052 (3) | 0.053 (3) | 0.025 (2) | 0.016 (2) | −0.0071 (18) | −0.0098 (19) |
C24 | 0.041 (2) | 0.052 (3) | 0.0235 (19) | 0.0094 (19) | 0.0009 (17) | −0.0020 (17) |
C25 | 0.0267 (18) | 0.038 (2) | 0.0219 (17) | 0.0040 (15) | −0.0019 (14) | −0.0033 (15) |
C26 | 0.0282 (19) | 0.0275 (18) | 0.034 (2) | −0.0069 (15) | 0.0093 (15) | −0.0027 (15) |
P3 | 0.0183 (4) | 0.0210 (4) | 0.0222 (4) | 0.0002 (3) | 0.0002 (3) | −0.0017 (3) |
C27 | 0.0272 (18) | 0.0236 (17) | 0.0227 (16) | 0.0041 (14) | −0.0001 (13) | −0.0002 (13) |
C28 | 0.0308 (19) | 0.0303 (19) | 0.0298 (19) | 0.0049 (15) | −0.0047 (15) | −0.0007 (15) |
C29 | 0.045 (2) | 0.037 (2) | 0.0269 (19) | 0.0047 (18) | −0.0111 (17) | 0.0048 (16) |
C30 | 0.053 (3) | 0.037 (2) | 0.0270 (19) | −0.0012 (19) | −0.0023 (18) | 0.0091 (16) |
C31 | 0.037 (2) | 0.039 (2) | 0.033 (2) | −0.0046 (17) | −0.0006 (17) | 0.0087 (17) |
C32 | 0.0287 (19) | 0.0301 (19) | 0.0274 (18) | −0.0009 (15) | −0.0043 (15) | 0.0072 (15) |
C33 | 0.0205 (17) | 0.0247 (18) | 0.035 (2) | 0.0009 (13) | −0.0018 (14) | −0.0052 (14) |
C34 | 0.0226 (18) | 0.039 (2) | 0.039 (2) | 0.0020 (16) | −0.0025 (15) | −0.0088 (17) |
C35 | 0.029 (2) | 0.049 (3) | 0.057 (3) | −0.0017 (19) | −0.0061 (19) | −0.020 (2) |
C36 | 0.026 (2) | 0.044 (3) | 0.079 (4) | −0.0070 (18) | −0.006 (2) | −0.017 (2) |
C37 | 0.029 (2) | 0.047 (3) | 0.071 (3) | −0.0107 (19) | 0.008 (2) | 0.005 (2) |
C38 | 0.030 (2) | 0.037 (2) | 0.044 (2) | −0.0057 (17) | 0.0019 (17) | −0.0005 (18) |
C39 | 0.0229 (17) | 0.0289 (18) | 0.0322 (19) | 0.0046 (14) | 0.0022 (14) | −0.0032 (15) |
C40 | 0.038 (2) | 0.052 (3) | 0.035 (2) | 0.004 (2) | 0.0042 (18) | 0.0019 (19) |
Cl3 | 0.0712 (8) | 0.0545 (7) | 0.0391 (6) | 0.0093 (6) | −0.0110 (6) | −0.0049 (5) |
Cl4 | 0.0416 (6) | 0.0535 (7) | 0.0905 (10) | 0.0003 (5) | 0.0199 (6) | 0.0045 (7) |
C41 | 0.074 (4) | 0.040 (3) | 0.046 (3) | 0.002 (2) | 0.020 (2) | −0.006 (2) |
Cl5 | 0.0686 (8) | 0.0597 (8) | 0.0559 (7) | −0.0097 (6) | 0.0281 (6) | −0.0187 (6) |
Cl6 | 0.0681 (8) | 0.0673 (8) | 0.0529 (7) | −0.0132 (7) | 0.0162 (6) | −0.0094 (6) |
C42 | 0.130 (6) | 0.081 (4) | 0.103 (5) | −0.076 (5) | 0.081 (5) | −0.050 (4) |
Cl7 | 0.0852 (11) | 0.0865 (12) | 0.0848 (11) | −0.0322 (10) | 0.0146 (9) | 0.0115 (9) |
Cl8 | 0.1156 (16) | 0.0764 (12) | 0.1259 (17) | 0.0174 (11) | 0.0369 (13) | 0.0120 (11) |
Geometric parameters (Å, º) top
Rh—H1 | 1.54 (4) | C21—C22 | 1.401 (6) |
Rh—Cl1 | 2.5107 (8) | C22—H22 | 0.950 |
Rh—Cl2 | 2.4260 (8) | C22—C23 | 1.377 (7) |
Rh—P1 | 2.3585 (9) | C23—H23 | 0.950 |
Rh—P2 | 2.2577 (9) | C23—C24 | 1.381 (6) |
Rh—P3 | 2.3518 (9) | C24—H24 | 0.950 |
P1—C1 | 1.827 (3) | C24—C25 | 1.390 (5) |
P1—C7 | 1.826 (4) | C25—H25 | 0.950 |
P1—C13 | 1.828 (4) | C26—H26A | 0.980 |
C1—C2 | 1.403 (5) | C26—H26B | 0.980 |
C1—C6 | 1.388 (5) | C26—H26C | 0.980 |
C2—H2 | 0.950 | P3—C27 | 1.825 (4) |
C2—C3 | 1.386 (6) | P3—C33 | 1.831 (4) |
C3—H3 | 0.950 | P3—C39 | 1.826 (4) |
C3—C4 | 1.381 (6) | C27—C28 | 1.395 (5) |
C4—H4 | 0.950 | C27—C32 | 1.386 (5) |
C4—C5 | 1.379 (6) | C28—H28 | 0.950 |
C5—H5 | 0.950 | C28—C29 | 1.396 (6) |
C5—C6 | 1.389 (5) | C29—H29 | 0.950 |
C6—H6 | 0.950 | C29—C30 | 1.374 (6) |
C7—C8 | 1.398 (5) | C30—H30 | 0.950 |
C7—C12 | 1.395 (5) | C30—C31 | 1.387 (6) |
C8—H8 | 0.950 | C31—H31 | 0.950 |
C8—C9 | 1.387 (6) | C31—C32 | 1.390 (5) |
C9—H9 | 0.950 | C32—H32 | 0.950 |
C9—C10 | 1.387 (7) | C33—C34 | 1.404 (5) |
C10—H10 | 0.950 | C33—C38 | 1.395 (6) |
C10—C11 | 1.368 (7) | C34—H34 | 0.950 |
C11—H11 | 0.950 | C34—C35 | 1.395 (6) |
C11—C12 | 1.398 (6) | C35—H35 | 0.950 |
C12—H12 | 0.950 | C35—C36 | 1.384 (7) |
C13—H13A | 0.980 | C36—H36 | 0.950 |
C13—H13B | 0.980 | C36—C37 | 1.380 (7) |
C13—H13C | 0.980 | C37—H37 | 0.950 |
P2—C14 | 1.822 (3) | C37—C38 | 1.390 (6) |
P2—C20 | 1.840 (4) | C38—H38 | 0.950 |
P2—C26 | 1.804 (4) | C39—H39A | 0.980 |
C14—C15 | 1.398 (5) | C39—H39B | 0.980 |
C14—C19 | 1.390 (5) | C39—H39C | 0.980 |
C15—H15 | 0.950 | C40—H40A | 0.990 |
C15—C16 | 1.385 (5) | C40—H40B | 0.990 |
C16—H16 | 0.950 | C40—Cl3 | 1.764 (4) |
C16—C17 | 1.385 (6) | C40—Cl4 | 1.756 (4) |
C17—H17 | 0.950 | C41—H41A | 0.990 |
C17—C18 | 1.369 (6) | C41—H41B | 0.990 |
C18—H18 | 0.950 | C41—Cl5 | 1.759 (5) |
C18—C19 | 1.388 (5) | C41—Cl6 | 1.757 (5) |
C19—H19 | 0.950 | C42—H42A | 0.990 |
C20—C21 | 1.387 (5) | C42—H42B | 0.990 |
C20—C25 | 1.395 (5) | C42—Cl7 | 1.621 (9) |
C21—H21 | 0.950 | C42—Cl8 | 1.918 (9) |
H1—Rh—Cl1 | 176.3 (14) | C21—C20—C25 | 118.9 (3) |
H1—Rh—Cl2 | 86.8 (14) | C20—C21—H21 | 120.0 |
H1—Rh—P1 | 86.6 (14) | C20—C21—C22 | 120.0 (4) |
H1—Rh—P2 | 81.9 (14) | H21—C21—C22 | 120.0 |
H1—Rh—P3 | 95.2 (14) | C21—C22—H22 | 119.7 |
Cl1—Rh—Cl2 | 92.75 (3) | C21—C22—C23 | 120.6 (4) |
Cl1—Rh—P1 | 89.66 (3) | H22—C22—C23 | 119.7 |
Cl1—Rh—P2 | 98.61 (3) | C22—C23—H23 | 120.1 |
Cl1—Rh—P3 | 88.45 (3) | C22—C23—C24 | 119.8 (4) |
Cl2—Rh—P1 | 83.91 (3) | H23—C23—C24 | 120.1 |
Cl2—Rh—P2 | 168.58 (3) | C23—C24—H24 | 120.0 |
Cl2—Rh—P3 | 84.78 (3) | C23—C24—C25 | 120.1 (4) |
P1—Rh—P2 | 97.13 (3) | H24—C24—C25 | 120.0 |
P1—Rh—P3 | 168.43 (3) | C20—C25—C24 | 120.7 (4) |
P2—Rh—P3 | 94.44 (3) | C20—C25—H25 | 119.7 |
Rh—P1—C1 | 117.45 (12) | C24—C25—H25 | 119.7 |
Rh—P1—C7 | 119.13 (12) | P2—C26—H26A | 109.5 |
Rh—P1—C13 | 110.48 (13) | P2—C26—H26B | 109.5 |
C1—P1—C7 | 104.27 (17) | P2—C26—H26C | 109.5 |
C1—P1—C13 | 102.04 (16) | H26A—C26—H26B | 109.5 |
C7—P1—C13 | 100.99 (17) | H26A—C26—H26C | 109.5 |
P1—C1—C2 | 119.7 (3) | H26B—C26—H26C | 109.5 |
P1—C1—C6 | 121.7 (3) | Rh—P3—C27 | 116.26 (12) |
C2—C1—C6 | 118.5 (3) | Rh—P3—C33 | 118.65 (12) |
C1—C2—H2 | 119.7 | Rh—P3—C39 | 111.90 (12) |
C1—C2—C3 | 120.6 (4) | C27—P3—C33 | 105.82 (17) |
H2—C2—C3 | 119.7 | C27—P3—C39 | 101.49 (17) |
C2—C3—H3 | 120.1 | C33—P3—C39 | 100.27 (17) |
C2—C3—C4 | 119.8 (4) | P3—C27—C28 | 120.8 (3) |
H3—C3—C4 | 120.1 | P3—C27—C32 | 120.6 (3) |
C3—C4—H4 | 119.8 | C28—C27—C32 | 118.5 (3) |
C3—C4—C5 | 120.5 (4) | C27—C28—H28 | 119.9 |
H4—C4—C5 | 119.8 | C27—C28—C29 | 120.3 (4) |
C4—C5—H5 | 120.1 | H28—C28—C29 | 119.9 |
C4—C5—C6 | 119.8 (4) | C28—C29—H29 | 119.8 |
H5—C5—C6 | 120.1 | C28—C29—C30 | 120.5 (4) |
C1—C6—C5 | 120.8 (4) | H29—C29—C30 | 119.8 |
C1—C6—H6 | 119.6 | C29—C30—H30 | 120.2 |
C5—C6—H6 | 119.6 | C29—C30—C31 | 119.7 (4) |
P1—C7—C8 | 123.6 (3) | H30—C30—C31 | 120.2 |
P1—C7—C12 | 117.6 (3) | C30—C31—H31 | 120.0 |
C8—C7—C12 | 118.7 (3) | C30—C31—C32 | 120.0 (4) |
C7—C8—H8 | 119.6 | H31—C31—C32 | 120.0 |
C7—C8—C9 | 120.9 (4) | C27—C32—C31 | 121.0 (3) |
H8—C8—C9 | 119.6 | C27—C32—H32 | 119.5 |
C8—C9—H9 | 120.3 | C31—C32—H32 | 119.5 |
C8—C9—C10 | 119.4 (4) | P3—C33—C34 | 123.2 (3) |
H9—C9—C10 | 120.3 | P3—C33—C38 | 117.9 (3) |
C9—C10—H10 | 119.7 | C34—C33—C38 | 118.8 (4) |
C9—C10—C11 | 120.7 (4) | C33—C34—H34 | 119.9 |
H10—C10—C11 | 119.7 | C33—C34—C35 | 120.2 (4) |
C10—C11—H11 | 119.9 | H34—C34—C35 | 119.9 |
C10—C11—C12 | 120.3 (4) | C34—C35—H35 | 120.0 |
H11—C11—C12 | 119.9 | C34—C35—C36 | 120.0 (4) |
C7—C12—C11 | 120.0 (4) | H35—C35—C36 | 120.0 |
C7—C12—H12 | 120.0 | C35—C36—H36 | 120.0 |
C11—C12—H12 | 120.0 | C35—C36—C37 | 120.1 (4) |
P1—C13—H13A | 109.5 | H36—C36—C37 | 120.0 |
P1—C13—H13B | 109.5 | C36—C37—H37 | 119.7 |
P1—C13—H13C | 109.5 | C36—C37—C38 | 120.5 (4) |
H13A—C13—H13B | 109.5 | H37—C37—C38 | 119.7 |
H13A—C13—H13C | 109.5 | C33—C38—C37 | 120.3 (4) |
H13B—C13—H13C | 109.5 | C33—C38—H38 | 119.9 |
Rh—P2—C14 | 116.55 (11) | C37—C38—H38 | 119.9 |
Rh—P2—C20 | 115.36 (12) | P3—C39—H39A | 109.5 |
Rh—P2—C26 | 114.45 (13) | P3—C39—H39B | 109.5 |
C14—P2—C20 | 96.89 (15) | P3—C39—H39C | 109.5 |
C14—P2—C26 | 105.91 (17) | H39A—C39—H39B | 109.5 |
C20—P2—C26 | 105.72 (18) | H39A—C39—H39C | 109.5 |
P2—C14—C15 | 118.0 (3) | H39B—C39—H39C | 109.5 |
P2—C14—C19 | 122.7 (3) | H40A—C40—H40B | 108.0 |
C15—C14—C19 | 119.0 (3) | H40A—C40—Cl3 | 109.3 |
C14—C15—H15 | 119.9 | H40A—C40—Cl4 | 109.3 |
C14—C15—C16 | 120.3 (4) | H40B—C40—Cl3 | 109.3 |
H15—C15—C16 | 119.9 | H40B—C40—Cl4 | 109.3 |
C15—C16—H16 | 120.0 | Cl3—C40—Cl4 | 111.6 (2) |
C15—C16—C17 | 119.9 (4) | H41A—C41—H41B | 107.9 |
H16—C16—C17 | 120.0 | H41A—C41—Cl5 | 109.2 |
C16—C17—H17 | 119.9 | H41A—C41—Cl6 | 109.2 |
C16—C17—C18 | 120.1 (4) | H41B—C41—Cl5 | 109.2 |
H17—C17—C18 | 119.9 | H41B—C41—Cl6 | 109.2 |
C17—C18—H18 | 119.7 | Cl5—C41—Cl6 | 112.2 (3) |
C17—C18—C19 | 120.6 (4) | H42A—C42—H42B | 107.9 |
H18—C18—C19 | 119.7 | H42A—C42—Cl7 | 109.1 |
C14—C19—C18 | 120.0 (4) | H42A—C42—Cl8 | 109.1 |
C14—C19—H19 | 120.0 | H42B—C42—Cl7 | 109.1 |
C18—C19—H19 | 120.0 | H42B—C42—Cl8 | 109.1 |
P2—C20—C21 | 121.9 (3) | Cl7—C42—Cl8 | 112.3 (3) |
P2—C20—C25 | 118.9 (3) |