Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536801004123/bt6020sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536801004123/bt6020Isup2.hkl |
CCDC reference: 162797
Diphenylacetylene (19.5 mg, 0.110 mmol) was added to a red-brown solution of W2Ir2(CO)10(η5-C5H4Me)2 (26.6 mg, 0.023 mmol) in CH2Cl2 (20 ml) and the resultant mixture stirred at reflux for 5.5 h. The resulting dark green solution was taken to dryness on a rotary evaporator, and the residue dissolved in a minimum of CH2Cl2 (ca 3 ml) and applied to preparative TLC plates. Elution with CH2Cl2/petroleum spirit (3/2) gave two bands. The first band (Rf = 0.76) was identified as unreacted starting cluster. The contents of the second and major band (Rf = 0.42) were crystallized from CH2Cl2/methanol at 3 °C to afford dark green crystals identified as W2Ir2(µ4-η2-C2Ph2)(µ-CO)4(CO)4(η-C5H4Me)2 (20.1 mg, 70%). Anal. Calc. for C34H24Ir2O8W2: C 31.11 H 1.84%. Found: C 30.98 H 1.85%. MS (secondary ion, Cs+): [M - nCO]+, n = 0–8. IR (CH2Cl2): ν(CO) 2063 s, 2035 s, 2009w, 1990w, 1812m, 1755m cm-1. 1H NMR: δ 7.22–7.02 (m, 10H, Ph), 4.58 (s, 4H, C5H4Me), 4.44 (s, 4H, C5H4Me), 2.13 (s, 6H, Me) p.p.m..
Data collection: KappaCCD Software (Nonius, 1999); cell refinement: HKL SCALEPACK (Otwinowski & Minor 1997); data reduction: DENZO and SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: PATTY in DIRDIF92 (Beurskens et al., 1992); program(s) used to refine structure: TEXSAN (Molecular Structure Corporation, 1997); software used to prepare material for publication: TEXSAN.
Fig. 1. A view of the title compound with the atom-numbering scheme. Displacement ellipsoids are shown at the 30% probability level. |
[W2Ir2(C6H7)2(C14H10)(CO)10] | F(000) = 2376.00 |
Mr = 1312.70 | Dx = 2.839 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.7107 Å |
a = 16.8073 (1) Å | Cell parameters from 78199 reflections |
b = 9.5849 (1) Å | θ = 3.4–30.0° |
c = 19.0626 (2) Å | µ = 16.20 mm−1 |
β = 90.8932 (6)° | T = 200 K |
V = 3070.54 (4) Å3 | Block, dark green |
Z = 4 | 0.30 × 0.25 × 0.10 mm |
Nonius KappaCCD diffractometer | 8980 independent reflections |
Radiation source: fine-focus sealed tube | 7429 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.077 |
ϕ and ω scans | θmax = 30.0°, θmin = 3.4° |
Absorption correction: integration [Gaussian (Coppens, 1970) implemented in maXus (1999)] | h = −23→23 |
Tmin = 0.050, Tmax = 0.327 | k = −13→13 |
90662 measured reflections | l = −26→26 |
Refinement on F | 0 restraints |
Least-squares matrix: full | 0 constraints |
R[F2 > 2σ(F2)] = 0.026 | H-atom parameters not refined |
wR(F2) = 0.030 | Weighting scheme based on measured s.u.'s w = 1/[σ2(Fo) + 0.00040|Fo|2] |
S = 0.82 | (Δ/σ)max = 0.001 |
7429 reflections | Δρmax = 1.36 e Å−3 |
415 parameters | Δρmin = −2.33 e Å−3 |
[W2Ir2(C6H7)2(C14H10)(CO)10] | V = 3070.54 (4) Å3 |
Mr = 1312.70 | Z = 4 |
Monoclinic, P21/c | Mo Kα radiation |
a = 16.8073 (1) Å | µ = 16.20 mm−1 |
b = 9.5849 (1) Å | T = 200 K |
c = 19.0626 (2) Å | 0.30 × 0.25 × 0.10 mm |
β = 90.8932 (6)° |
Nonius KappaCCD diffractometer | 8980 independent reflections |
Absorption correction: integration [Gaussian (Coppens, 1970) implemented in maXus (1999)] | 7429 reflections with I > 2σ(I) |
Tmin = 0.050, Tmax = 0.327 | Rint = 0.077 |
90662 measured reflections |
R[F2 > 2σ(F2)] = 0.026 | 0 restraints |
wR(F2) = 0.030 | H-atom parameters not refined |
S = 0.82 | Δρmax = 1.36 e Å−3 |
7429 reflections | Δρmin = −2.33 e Å−3 |
415 parameters |
Refinement. H atoms were included in the refinement at idealized positions which were frequently recalculated. |
x | y | z | Uiso*/Ueq | ||
Ir(1) | 0.14894 (1) | 0.20159 (2) | 0.049837 (9) | 0.01724 (4) | |
Ir(2) | 0.21688 (1) | 0.18402 (2) | 0.178536 (9) | 0.01782 (5) | |
W(1) | 0.15352 (1) | 0.44096 (2) | 0.135326 (9) | 0.01711 (5) | |
W(2) | 0.31016 (1) | 0.13818 (2) | 0.05962 (1) | 0.01980 (5) | |
O(1) | 0.1089 (3) | 0.2248 (5) | −0.1057 (2) | 0.050 (1) | |
O(2) | 0.0220 (2) | −0.0166 (5) | 0.0797 (2) | 0.047 (1) | |
O(3) | 0.2880 (3) | 0.2269 (5) | 0.3244 (2) | 0.046 (1) | |
O(4) | 0.1074 (2) | −0.0458 (4) | 0.2296 (2) | 0.041 (1) | |
O(5) | −0.0068 (2) | 0.3827 (4) | 0.0582 (2) | 0.037 (1) | |
O(6) | 0.2027 (2) | −0.0904 (4) | −0.0083 (2) | 0.036 (1) | |
O(7) | 0.0551 (2) | 0.2954 (4) | 0.2506 (2) | 0.033 (1) | |
O(8) | 0.3306 (2) | −0.0718 (4) | 0.1817 (2) | 0.039 (1) | |
C(1) | 0.1217 (3) | 0.2194 (5) | −0.0480 (3) | 0.026 (1) | |
C(2) | 0.0685 (3) | 0.0666 (5) | 0.0683 (3) | 0.027 (1) | |
C(3) | 0.2633 (3) | 0.2107 (5) | 0.2698 (3) | 0.026 (1) | |
C(4) | 0.1486 (3) | 0.0389 (5) | 0.2102 (3) | 0.025 (1) | |
C(5) | 0.0598 (3) | 0.3777 (5) | 0.0792 (3) | 0.025 (1) | |
C(6) | 0.2281 (3) | 0.0107 (5) | 0.0194 (3) | 0.026 (1) | |
C(7) | 0.1018 (3) | 0.3293 (5) | 0.2090 (3) | 0.023 (1) | |
C(8) | 0.3072 (3) | 0.0207 (5) | 0.1459 (3) | 0.027 (1) | |
C(9) | 0.0678 (3) | 0.6138 (5) | 0.1670 (3) | 0.027 (1) | |
C(10) | 0.1022 (3) | 0.6548 (5) | 0.1021 (3) | 0.031 (1) | |
C(11) | 0.1830 (3) | 0.6734 (5) | 0.1139 (3) | 0.029 (1) | |
C(12) | 0.1995 (3) | 0.6479 (5) | 0.1865 (3) | 0.028 (1) | |
C(13) | 0.1278 (3) | 0.6145 (5) | 0.2193 (3) | 0.027 (1) | |
C(14) | 0.1156 (4) | 0.5971 (6) | 0.2970 (3) | 0.039 (2) | |
C(15) | 0.4005 (3) | 0.1811 (5) | −0.0305 (3) | 0.029 (1) | |
C(16) | 0.4394 (3) | 0.2027 (6) | 0.0349 (3) | 0.030 (1) | |
C(17) | 0.4410 (3) | 0.0753 (6) | 0.0712 (3) | 0.035 (2) | |
C(18) | 0.4020 (3) | −0.0250 (6) | 0.0278 (3) | 0.032 (1) | |
C(19) | 0.3789 (3) | 0.0389 (6) | −0.0362 (3) | 0.030 (1) | |
C(20) | 0.3470 (4) | −0.0314 (6) | −0.1011 (3) | 0.039 (2) | |
C(21) | 0.3354 (3) | 0.4910 (5) | −0.0265 (3) | 0.027 (1) | |
C(22) | 0.3487 (3) | 0.5719 (6) | −0.0853 (3) | 0.036 (2) | |
C(23) | 0.2859 (4) | 0.6143 (6) | −0.1272 (3) | 0.040 (2) | |
C(24) | 0.2097 (4) | 0.5834 (6) | −0.1080 (3) | 0.035 (1) | |
C(25) | 0.1959 (3) | 0.5034 (5) | −0.0480 (3) | 0.026 (1) | |
C(26) | 0.2592 (3) | 0.4516 (5) | −0.0067 (2) | 0.020 (1) | |
C(27) | 0.2411 (3) | 0.3534 (5) | 0.0526 (2) | 0.017 (1) | |
C(28) | 0.2804 (3) | 0.3411 (5) | 0.1228 (2) | 0.017 (1) | |
C(29) | 0.3540 (3) | 0.4160 (5) | 0.1501 (2) | 0.020 (1) | |
C(30) | 0.4084 (3) | 0.3466 (5) | 0.1944 (3) | 0.027 (1) | |
C(31) | 0.4766 (3) | 0.4108 (6) | 0.2191 (3) | 0.035 (2) | |
C(32) | 0.4941 (3) | 0.5452 (6) | 0.1994 (3) | 0.037 (2) | |
C(33) | 0.4421 (3) | 0.6167 (6) | 0.1564 (3) | 0.035 (2) | |
C(34) | 0.3726 (3) | 0.5533 (5) | 0.1323 (3) | 0.027 (1) | |
H(9) | 0.0136 | 0.5902 | 0.1737 | 0.033* | |
H(10) | 0.0746 | 0.6670 | 0.0587 | 0.037* | |
H(11) | 0.2209 | 0.6986 | 0.0796 | 0.035* | |
H(12) | 0.2503 | 0.6527 | 0.2088 | 0.034* | |
H(14c) | 0.0815 | 0.6688 | 0.3133 | 0.047* | |
H(14a) | 0.0921 | 0.5087 | 0.3056 | 0.047* | |
H(14b) | 0.1654 | 0.6027 | 0.3209 | 0.047* | |
H(15) | 0.3905 | 0.2507 | −0.0650 | 0.034* | |
H(16) | 0.4607 | 0.2886 | 0.0514 | 0.036* | |
H(17) | 0.4638 | 0.0591 | 0.1164 | 0.042* | |
H(18) | 0.3929 | −0.1198 | 0.0398 | 0.039* | |
H(20a) | 0.2986 | 0.0119 | −0.1153 | 0.047* | |
H(20b) | 0.3847 | −0.0234 | −0.1375 | 0.047* | |
H(20c) | 0.3377 | −0.1272 | −0.0914 | 0.047* | |
H(23) | 0.3797 | 0.4614 | 0.0013 | 0.032* | |
H(24) | 0.4015 | 0.5981 | −0.0968 | 0.043* | |
H(25) | 0.2953 | 0.6647 | −0.1692 | 0.048* | |
H(26) | 0.1660 | 0.6165 | −0.1356 | 0.042* | |
H(27) | 0.1427 | 0.4837 | −0.0349 | 0.031* | |
H(30) | 0.3979 | 0.2529 | 0.2077 | 0.032* | |
H(31) | 0.5118 | 0.3619 | 0.2499 | 0.042* | |
H(32) | 0.5420 | 0.5882 | 0.2155 | 0.045* | |
H(33) | 0.4537 | 0.7100 | 0.1431 | 0.042* | |
H(34) | 0.3370 | 0.6045 | 0.1029 | 0.032* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Ir(1) | 0.01412 (9) | 0.01851 (9) | 0.01902 (9) | −0.00117 (6) | −0.00188 (6) | −0.00069 (7) |
Ir(2) | 0.01734 (9) | 0.01721 (9) | 0.01886 (9) | −0.00004 (6) | −0.00177 (7) | 0.00199 (7) |
W(1) | 0.01562 (9) | 0.01679 (9) | 0.0189 (1) | 0.00141 (7) | −0.00072 (7) | 0.00003 (7) |
W(2) | 0.01539 (9) | 0.0204 (1) | 0.0236 (1) | 0.00306 (7) | −0.00027 (7) | 0.00005 (7) |
O(1) | 0.065 (3) | 0.058 (3) | 0.024 (2) | −0.022 (2) | −0.012 (2) | 0.003 (2) |
O(2) | 0.041 (2) | 0.054 (3) | 0.045 (2) | −0.028 (2) | 0.000 (2) | 0.000 (2) |
O(3) | 0.056 (3) | 0.053 (3) | 0.029 (2) | −0.014 (2) | −0.014 (2) | 0.002 (2) |
O(4) | 0.041 (2) | 0.037 (2) | 0.044 (2) | −0.016 (2) | 0.001 (2) | 0.011 (2) |
O(5) | 0.019 (2) | 0.047 (2) | 0.045 (2) | 0.008 (2) | −0.011 (2) | −0.010 (2) |
O(6) | 0.034 (2) | 0.025 (2) | 0.049 (2) | −0.003 (2) | 0.001 (2) | −0.010 (2) |
O(7) | 0.033 (2) | 0.035 (2) | 0.032 (2) | −0.001 (2) | 0.011 (2) | 0.005 (2) |
O(8) | 0.042 (2) | 0.035 (2) | 0.042 (2) | 0.016 (2) | 0.002 (2) | 0.012 (2) |
C(1) | 0.022 (2) | 0.029 (3) | 0.026 (3) | −0.006 (2) | −0.002 (2) | 0.000 (2) |
C(2) | 0.024 (3) | 0.034 (3) | 0.022 (2) | −0.005 (2) | −0.002 (2) | −0.003 (2) |
C(3) | 0.029 (3) | 0.023 (2) | 0.025 (3) | 0.000 (2) | −0.002 (2) | 0.005 (2) |
C(4) | 0.027 (3) | 0.026 (3) | 0.022 (2) | 0.002 (2) | −0.002 (2) | −0.002 (2) |
C(5) | 0.025 (3) | 0.026 (2) | 0.023 (2) | 0.003 (2) | −0.002 (2) | −0.001 (2) |
C(6) | 0.023 (2) | 0.026 (3) | 0.029 (3) | 0.000 (2) | 0.003 (2) | 0.003 (2) |
C(7) | 0.023 (2) | 0.023 (2) | 0.024 (2) | 0.003 (2) | −0.003 (2) | 0.001 (2) |
C(8) | 0.026 (3) | 0.020 (2) | 0.033 (3) | 0.006 (2) | 0.003 (2) | 0.001 (2) |
C(9) | 0.028 (3) | 0.023 (2) | 0.031 (3) | 0.007 (2) | 0.002 (2) | −0.002 (2) |
C(10) | 0.038 (3) | 0.022 (2) | 0.033 (3) | 0.010 (2) | −0.003 (2) | 0.003 (2) |
C(11) | 0.032 (3) | 0.020 (2) | 0.035 (3) | 0.002 (2) | 0.009 (2) | 0.003 (2) |
C(12) | 0.026 (3) | 0.022 (2) | 0.036 (3) | −0.003 (2) | −0.001 (2) | −0.008 (2) |
C(13) | 0.031 (3) | 0.020 (2) | 0.031 (3) | 0.001 (2) | 0.000 (2) | −0.007 (2) |
C(14) | 0.049 (4) | 0.039 (3) | 0.030 (3) | −0.009 (3) | 0.007 (3) | −0.010 (3) |
C(15) | 0.023 (3) | 0.032 (3) | 0.032 (3) | 0.001 (2) | 0.008 (2) | −0.002 (2) |
C(16) | 0.017 (2) | 0.039 (3) | 0.035 (3) | −0.002 (2) | 0.000 (2) | −0.004 (2) |
C(17) | 0.015 (2) | 0.048 (3) | 0.042 (3) | 0.011 (2) | 0.002 (2) | −0.002 (3) |
C(18) | 0.026 (3) | 0.035 (3) | 0.036 (3) | 0.014 (2) | 0.009 (2) | 0.003 (2) |
C(19) | 0.025 (3) | 0.032 (3) | 0.034 (3) | 0.006 (2) | 0.007 (2) | −0.004 (2) |
C(20) | 0.045 (4) | 0.038 (3) | 0.035 (3) | −0.005 (3) | 0.008 (3) | −0.007 (3) |
C(21) | 0.030 (3) | 0.023 (2) | 0.028 (3) | −0.002 (2) | 0.005 (2) | −0.002 (2) |
C(22) | 0.040 (3) | 0.031 (3) | 0.036 (3) | −0.011 (2) | 0.012 (3) | −0.001 (2) |
C(23) | 0.065 (4) | 0.027 (3) | 0.029 (3) | −0.009 (3) | 0.009 (3) | 0.005 (2) |
C(24) | 0.053 (4) | 0.026 (3) | 0.025 (3) | 0.003 (3) | −0.006 (2) | 0.002 (2) |
C(25) | 0.031 (3) | 0.022 (2) | 0.024 (2) | −0.001 (2) | 0.001 (2) | 0.002 (2) |
C(26) | 0.022 (2) | 0.016 (2) | 0.021 (2) | −0.001 (2) | 0.000 (2) | 0.002 (2) |
C(27) | 0.013 (2) | 0.019 (2) | 0.019 (2) | −0.001 (2) | 0.003 (2) | 0.001 (2) |
C(28) | 0.011 (2) | 0.021 (2) | 0.018 (2) | −0.002 (2) | −0.004 (2) | 0.002 (2) |
C(29) | 0.013 (2) | 0.027 (2) | 0.020 (2) | 0.000 (2) | 0.000 (2) | −0.002 (2) |
C(30) | 0.020 (2) | 0.031 (3) | 0.029 (3) | −0.003 (2) | −0.005 (2) | 0.000 (2) |
C(31) | 0.024 (3) | 0.042 (3) | 0.039 (3) | −0.002 (2) | −0.013 (2) | 0.001 (3) |
C(32) | 0.024 (3) | 0.041 (3) | 0.047 (3) | −0.012 (2) | −0.010 (2) | −0.011 (3) |
C(33) | 0.031 (3) | 0.029 (3) | 0.044 (3) | −0.007 (2) | −0.003 (2) | −0.008 (2) |
C(34) | 0.022 (2) | 0.027 (3) | 0.031 (3) | −0.002 (2) | −0.003 (2) | −0.004 (2) |
Ir(1)—Ir(2) | 2.6951 (2) | C(11)—C(12) | 1.429 (7) |
Ir(1)—W(1) | 2.8145 (2) | C(11)—H(11) | 0.95 |
Ir(1)—W(2) | 2.7804 (2) | C(12)—C(13) | 1.404 (7) |
Ir(1)—C(1) | 1.920 (5) | C(12)—H(12) | 0.95 |
Ir(1)—C(2) | 1.908 (5) | C(13)—C(14) | 1.506 (8) |
Ir(1)—C(5) | 2.331 (5) | C(14)—H(14c) | 0.95 |
Ir(1)—C(6) | 2.340 (5) | C(14)—H(14a) | 0.95 |
Ir(1)—C(27) | 2.125 (4) | C(14)—H(14b) | 0.95 |
Ir(2)—W(1) | 2.8018 (2) | C(15)—C(16) | 1.414 (7) |
Ir(2)—W(2) | 2.8109 (3) | C(15)—C(19) | 1.414 (7) |
Ir(2)—C(3) | 1.913 (5) | C(15)—H(15) | 0.95 |
Ir(2)—C(4) | 1.907 (5) | C(16)—C(17) | 1.404 (8) |
Ir(2)—C(7) | 2.461 (5) | C(16)—H(16) | 0.95 |
Ir(2)—C(8) | 2.274 (5) | C(17)—C(18) | 1.423 (8) |
Ir(2)—C(28) | 2.138 (4) | C(17)—H(17) | 0.95 |
W(1)—C(5) | 1.985 (5) | C(18)—C(19) | 1.413 (7) |
W(1)—C(7) | 1.977 (5) | C(18)—H(18) | 0.95 |
W(1)—C(9) | 2.283 (5) | C(19)—C(20) | 1.500 (8) |
W(1)—C(10) | 2.308 (5) | C(20)—H(20a) | 0.95 |
W(1)—C(11) | 2.320 (5) | C(20)—H(20b) | 0.95 |
W(1)—C(12) | 2.336 (5) | C(20)—H(20c) | 0.95 |
W(1)—C(13) | 2.354 (5) | C(21)—C(22) | 1.385 (7) |
W(1)—C(27) | 2.331 (4) | C(21)—C(26) | 1.392 (7) |
W(1)—C(28) | 2.353 (4) | C(21)—H(23) | 0.95 |
W(2)—C(6) | 1.988 (5) | C(22)—C(23) | 1.375 (9) |
W(2)—C(8) | 1.994 (5) | C(22)—H(24) | 0.95 |
W(2)—C(15) | 2.346 (5) | C(23)—C(24) | 1.370 (9) |
W(2)—C(16) | 2.314 (5) | C(23)—H(25) | 0.95 |
W(2)—C(17) | 2.287 (5) | C(24)—C(25) | 1.400 (7) |
W(2)—C(18) | 2.286 (5) | C(24)—H(26) | 0.95 |
W(2)—C(19) | 2.375 (5) | C(25)—C(26) | 1.405 (7) |
W(2)—C(27) | 2.369 (4) | C(25)—H(27) | 0.95 |
W(2)—C(28) | 2.345 (4) | C(26)—C(27) | 1.506 (6) |
O(1)—C(1) | 1.120 (6) | C(27)—C(28) | 1.487 (6) |
O(2)—C(2) | 1.140 (6) | C(28)—C(29) | 1.516 (6) |
O(3)—C(3) | 1.124 (6) | C(29)—C(30) | 1.401 (7) |
O(4)—C(4) | 1.134 (6) | C(29)—C(34) | 1.397 (7) |
O(5)—C(5) | 1.184 (6) | C(30)—C(31) | 1.378 (7) |
O(6)—C(6) | 1.179 (6) | C(30)—H(30) | 0.95 |
O(7)—C(7) | 1.170 (6) | C(31)—C(32) | 1.374 (8) |
O(8)—C(8) | 1.183 (6) | C(31)—H(31) | 0.95 |
C(9)—C(10) | 1.429 (7) | C(32)—C(33) | 1.373 (8) |
C(9)—C(13) | 1.406 (7) | C(32)—H(32) | 0.95 |
C(9)—H(9) | 0.95 | C(33)—C(34) | 1.389 (7) |
C(10)—C(11) | 1.384 (8) | C(33)—H(33) | 0.95 |
C(10)—H(10) | 0.95 | C(34)—H(34) | 0.95 |
O(1)···O(7)i | 2.877 (5) | O(4)···C(9)iv | 3.533 (7) |
O(1)···O(2)ii | 3.017 (6) | O(4)···C(24)vi | 3.536 (7) |
O(1)···O(3)i | 3.344 (7) | O(5)···O(5)iii | 3.169 (8) |
O(1)···C(9)iii | 3.530 (7) | O(5)···C(25)iii | 3.363 (6) |
O(1)···C(7)i | 3.570 (6) | O(5)···C(10)iii | 3.447 (7) |
O(1)···C(3)i | 3.598 (7) | O(5)···C(24)iii | 3.568 (7) |
O(2)···O(2)ii | 3.131 (8) | O(5)···C(5)iii | 3.584 (6) |
O(2)···C(1)ii | 3.152 (6) | O(6)···C(11)iv | 3.268 (6) |
O(2)···C(2)ii | 3.220 (6) | O(7)···C(9)v | 3.141 (6) |
O(2)···C(10)iv | 3.451 (7) | O(7)···C(14)v | 3.547 (8) |
O(2)···C(14)v | 3.497 (7) | O(7)···C(13)v | 3.583 (6) |
O(3)···C(20)vi | 3.388 (7) | O(8)···C(12)iv | 3.477 (7) |
O(3)···C(23)vi | 3.398 (7) | O(8)···C(33)iv | 3.562 (7) |
O(3)···C(15)vi | 3.441 (7) | C(16)···C(18)vii | 3.397 (7) |
O(3)···C(22)vi | 3.486 (7) | C(17)···C(19)vii | 3.298 (7) |
O(3)···C(24)vi | 3.507 (7) | C(17)···C(18)vii | 3.304 (7) |
O(4)···O(7)v | 3.154 (5) | C(18)···C(18)vii | 3.51 (1) |
O(4)···C(13)iv | 3.280 (6) | C(20)···C(23)iv | 3.581 (8) |
O(4)···C(12)iv | 3.425 (7) | ||
Ir(2)—Ir(1)—W(1) | 61.086 (6) | C(16)—W(2)—C(28) | 95.2 (2) |
Ir(2)—Ir(1)—W(2) | 61.751 (7) | C(17)—W(2)—C(18) | 36.3 (2) |
Ir(2)—Ir(1)—C(1) | 168.7 (1) | C(17)—W(2)—C(19) | 59.4 (2) |
Ir(2)—Ir(1)—C(2) | 94.6 (1) | C(17)—W(2)—C(27) | 134.7 (2) |
Ir(2)—Ir(1)—C(5) | 95.3 (1) | C(17)—W(2)—C(28) | 112.4 (2) |
Ir(2)—Ir(1)—C(6) | 86.7 (1) | C(18)—W(2)—C(19) | 35.2 (2) |
Ir(2)—Ir(1)—C(27) | 73.9 (1) | C(18)—W(2)—C(27) | 155.9 (2) |
W(1)—Ir(1)—W(2) | 96.983 (7) | C(18)—W(2)—C(28) | 148.7 (2) |
W(1)—Ir(1)—C(1) | 119.6 (2) | C(19)—W(2)—C(27) | 123.3 (2) |
W(1)—Ir(1)—C(2) | 117.3 (2) | C(19)—W(2)—C(28) | 146.8 (2) |
W(1)—Ir(1)—C(5) | 44.2 (1) | C(27)—W(2)—C(28) | 36.8 (1) |
W(1)—Ir(1)—C(6) | 140.4 (1) | Ir(1)—C(1)—O(1) | 176.3 (5) |
W(1)—Ir(1)—C(27) | 54.2 (1) | Ir(1)—C(2)—O(2) | 178.2 (5) |
W(2)—Ir(1)—C(1) | 107.6 (1) | Ir(2)—C(3)—O(3) | 177.6 (5) |
W(2)—Ir(1)—C(2) | 122.1 (2) | Ir(2)—C(4)—O(4) | 178.9 (5) |
W(2)—Ir(1)—C(5) | 140.5 (1) | Ir(1)—C(5)—W(1) | 81.0 (2) |
W(2)—Ir(1)—C(6) | 44.7 (1) | Ir(1)—C(5)—O(5) | 123.8 (4) |
W(2)—Ir(1)—C(27) | 55.8 (1) | W(1)—C(5)—O(5) | 155.2 (4) |
C(1)—Ir(1)—C(2) | 94.6 (2) | Ir(1)—C(6)—W(2) | 79.5 (2) |
C(1)—Ir(1)—C(5) | 91.4 (2) | Ir(1)—C(6)—O(6) | 123.4 (4) |
C(1)—Ir(1)—C(6) | 87.5 (2) | W(2)—C(6)—O(6) | 157.1 (4) |
C(1)—Ir(1)—C(27) | 97.2 (2) | Ir(2)—C(7)—W(1) | 77.5 (2) |
C(2)—Ir(1)—C(5) | 89.3 (2) | Ir(2)—C(7)—O(7) | 122.7 (4) |
C(2)—Ir(1)—C(6) | 85.6 (2) | W(1)—C(7)—O(7) | 159.8 (4) |
C(2)—Ir(1)—C(27) | 167.9 (2) | Ir(2)—C(8)—W(2) | 82.1 (2) |
C(5)—Ir(1)—C(6) | 174.6 (2) | Ir(2)—C(8)—O(8) | 125.1 (4) |
C(5)—Ir(1)—C(27) | 88.2 (2) | W(2)—C(8)—O(8) | 152.5 (4) |
C(6)—Ir(1)—C(27) | 97.1 (2) | W(1)—C(9)—C(10) | 72.8 (3) |
Ir(1)—Ir(2)—W(1) | 61.560 (6) | W(1)—C(9)—C(13) | 75.1 (3) |
Ir(1)—Ir(2)—W(2) | 60.617 (6) | W(1)—C(9)—H(9) | 118.2 |
Ir(1)—Ir(2)—C(3) | 168.7 (1) | C(10)—C(9)—C(13) | 108.5 (5) |
Ir(1)—Ir(2)—C(4) | 94.9 (1) | C(10)—C(9)—H(9) | 125.7 |
Ir(1)—Ir(2)—C(7) | 81.7 (1) | C(13)—C(9)—H(9) | 125.7 |
Ir(1)—Ir(2)—C(8) | 93.9 (1) | W(1)—C(10)—C(9) | 70.9 (3) |
Ir(1)—Ir(2)—C(28) | 73.2 (1) | W(1)—C(10)—C(11) | 73.1 (3) |
W(1)—Ir(2)—W(2) | 96.576 (7) | W(1)—C(10)—H(10) | 121.6 |
W(1)—Ir(2)—C(3) | 107.3 (1) | C(9)—C(10)—C(11) | 107.7 (5) |
W(1)—Ir(2)—C(4) | 120.4 (1) | C(9)—C(10)—H(10) | 126.1 |
W(1)—Ir(2)—C(7) | 43.5 (1) | C(11)—C(10)—H(10) | 126.1 |
W(1)—Ir(2)—C(8) | 141.0 (1) | W(1)—C(11)—C(10) | 72.1 (3) |
W(1)—Ir(2)—C(28) | 54.9 (1) | W(1)—C(11)—C(12) | 72.8 (3) |
W(2)—Ir(2)—C(3) | 122.0 (2) | W(1)—C(11)—H(11) | 120.9 |
W(2)—Ir(2)—C(4) | 119.1 (1) | C(10)—C(11)—C(12) | 108.0 (5) |
W(2)—Ir(2)—C(7) | 136.8 (1) | C(10)—C(11)—H(11) | 126.0 |
W(2)—Ir(2)—C(8) | 44.6 (1) | C(12)—C(11)—H(11) | 126.0 |
W(2)—Ir(2)—C(28) | 54.5 (1) | W(1)—C(12)—C(11) | 71.5 (3) |
C(3)—Ir(2)—C(4) | 92.8 (2) | W(1)—C(12)—C(13) | 73.3 (3) |
C(3)—Ir(2)—C(7) | 91.2 (2) | W(1)—C(12)—H(12) | 121.2 |
C(3)—Ir(2)—C(8) | 94.4 (2) | C(11)—C(12)—C(13) | 108.5 (5) |
C(3)—Ir(2)—C(28) | 99.1 (2) | C(11)—C(12)—H(12) | 125.8 |
C(4)—Ir(2)—C(7) | 81.9 (2) | C(13)—C(12)—H(12) | 125.8 |
C(4)—Ir(2)—C(8) | 89.5 (2) | W(1)—C(13)—C(9) | 69.6 (3) |
C(4)—Ir(2)—C(28) | 168.1 (2) | W(1)—C(13)—C(12) | 71.9 (3) |
C(7)—Ir(2)—C(8) | 170.0 (2) | W(1)—C(13)—C(14) | 128.3 (4) |
C(7)—Ir(2)—C(28) | 96.9 (2) | C(9)—C(13)—C(12) | 107.2 (5) |
C(8)—Ir(2)—C(28) | 90.4 (2) | C(9)—C(13)—C(14) | 126.1 (5) |
Ir(1)—W(1)—Ir(2) | 57.353 (6) | C(12)—C(13)—C(14) | 126.5 (5) |
Ir(1)—W(1)—C(5) | 54.9 (1) | C(13)—C(14)—H(14c) | 109.5 |
Ir(1)—W(1)—C(7) | 87.8 (1) | C(13)—C(14)—H(14a) | 109.5 |
Ir(1)—W(1)—C(9) | 137.2 (1) | C(13)—C(14)—H(14b) | 109.5 |
Ir(1)—W(1)—C(10) | 123.9 (1) | H(14c)—C(14)—H(14a) | 109.5 |
Ir(1)—W(1)—C(11) | 133.2 (1) | H(14c)—C(14)—H(14b) | 109.5 |
Ir(1)—W(1)—C(12) | 160.0 (1) | H(14a)—C(14)—H(14b) | 109.5 |
Ir(1)—W(1)—C(13) | 165.1 (1) | W(2)—C(15)—C(16) | 71.1 (3) |
Ir(1)—W(1)—C(27) | 47.7 (1) | W(2)—C(15)—C(19) | 73.7 (3) |
Ir(1)—W(1)—C(28) | 68.0 (1) | W(2)—C(15)—H(15) | 121.4 |
Ir(2)—W(1)—C(5) | 100.6 (1) | C(16)—C(15)—C(19) | 108.8 (5) |
Ir(2)—W(1)—C(7) | 59.0 (1) | C(16)—C(15)—H(15) | 125.6 |
Ir(2)—W(1)—C(9) | 143.0 (1) | C(19)—C(15)—H(15) | 125.6 |
Ir(2)—W(1)—C(10) | 178.7 (1) | W(2)—C(16)—C(15) | 73.6 (3) |
Ir(2)—W(1)—C(11) | 144.5 (1) | W(2)—C(16)—C(17) | 71.2 (3) |
Ir(2)—W(1)—C(12) | 120.1 (1) | W(2)—C(16)—H(16) | 121.0 |
Ir(2)—W(1)—C(13) | 119.6 (1) | C(15)—C(16)—C(17) | 108.2 (5) |
Ir(2)—W(1)—C(27) | 69.0 (1) | C(15)—C(16)—H(16) | 125.9 |
Ir(2)—W(1)—C(28) | 48.0 (1) | C(17)—C(16)—H(16) | 125.9 |
C(5)—W(1)—C(7) | 82.2 (2) | W(2)—C(17)—C(16) | 73.3 (3) |
C(5)—W(1)—C(9) | 82.3 (2) | W(2)—C(17)—C(18) | 71.8 (3) |
C(5)—W(1)—C(10) | 80.4 (2) | W(2)—C(17)—H(17) | 120.3 |
C(5)—W(1)—C(11) | 111.6 (2) | C(16)—C(17)—C(18) | 107.2 (5) |
C(5)—W(1)—C(12) | 137.6 (2) | C(16)—C(17)—H(17) | 126.4 |
C(5)—W(1)—C(13) | 115.5 (2) | C(18)—C(17)—H(17) | 126.4 |
C(5)—W(1)—C(27) | 91.7 (2) | W(2)—C(18)—C(17) | 71.9 (3) |
C(5)—W(1)—C(28) | 122.2 (2) | W(2)—C(18)—C(19) | 75.8 (3) |
C(7)—W(1)—C(9) | 85.3 (2) | W(2)—C(18)—H(18) | 118.6 |
C(7)—W(1)—C(10) | 120.6 (2) | C(17)—C(18)—C(19) | 109.1 (5) |
C(7)—W(1)—C(11) | 137.9 (2) | C(17)—C(18)—H(18) | 125.5 |
C(7)—W(1)—C(12) | 108.0 (2) | C(19)—C(18)—H(18) | 125.5 |
C(7)—W(1)—C(13) | 79.2 (2) | W(2)—C(19)—C(15) | 71.5 (3) |
C(7)—W(1)—C(27) | 125.1 (2) | W(2)—C(19)—C(18) | 68.9 (3) |
C(7)—W(1)—C(28) | 105.2 (2) | W(2)—C(19)—C(20) | 130.0 (4) |
C(9)—W(1)—C(10) | 36.3 (2) | C(15)—C(19)—C(18) | 106.6 (5) |
C(9)—W(1)—C(11) | 59.2 (2) | C(15)—C(19)—C(20) | 125.7 (5) |
C(9)—W(1)—C(12) | 58.6 (2) | C(18)—C(19)—C(20) | 127.3 (5) |
C(9)—W(1)—C(13) | 35.3 (2) | C(19)—C(20)—H(20a) | 109.5 |
C(9)—W(1)—C(27) | 148.0 (2) | C(19)—C(20)—H(20b) | 109.5 |
C(9)—W(1)—C(28) | 154.0 (2) | C(19)—C(20)—H(20c) | 109.5 |
C(10)—W(1)—C(11) | 34.8 (2) | H(20a)—C(20)—H(20b) | 109.5 |
C(10)—W(1)—C(12) | 58.7 (2) | H(20a)—C(20)—H(20c) | 109.5 |
C(10)—W(1)—C(13) | 59.2 (2) | H(20b)—C(20)—H(20c) | 109.5 |
C(10)—W(1)—C(27) | 111.8 (2) | C(22)—C(21)—C(26) | 122.2 (5) |
C(10)—W(1)—C(28) | 132.0 (2) | C(22)—C(21)—H(23) | 118.9 |
C(11)—W(1)—C(12) | 35.7 (2) | C(26)—C(21)—H(23) | 118.9 |
C(11)—W(1)—C(13) | 58.9 (2) | C(21)—C(22)—C(23) | 120.2 (5) |
C(11)—W(1)—C(27) | 95.0 (2) | C(21)—C(22)—H(24) | 119.9 |
C(11)—W(1)—C(28) | 100.1 (2) | C(23)—C(22)—H(24) | 119.9 |
C(12)—W(1)—C(13) | 34.8 (2) | C(22)—C(23)—C(24) | 119.6 (5) |
C(12)—W(1)—C(27) | 112.3 (2) | C(22)—C(23)—H(25) | 120.2 |
C(12)—W(1)—C(28) | 95.4 (2) | C(24)—C(23)—H(25) | 120.2 |
C(13)—W(1)—C(27) | 147.1 (2) | C(23)—C(24)—C(25) | 120.2 (5) |
C(13)—W(1)—C(28) | 122.2 (2) | C(23)—C(24)—H(26) | 119.9 |
C(27)—W(1)—C(28) | 37.0 (1) | C(25)—C(24)—H(26) | 119.9 |
Ir(1)—W(2)—Ir(2) | 57.631 (6) | C(24)—C(25)—C(26) | 121.2 (5) |
Ir(1)—W(2)—C(6) | 55.8 (1) | C(24)—C(25)—H(27) | 119.4 |
Ir(1)—W(2)—C(8) | 98.1 (1) | C(26)—C(25)—H(27) | 119.4 |
Ir(1)—W(2)—C(15) | 123.6 (1) | C(21)—C(26)—C(25) | 116.4 (4) |
Ir(1)—W(2)—C(16) | 147.7 (1) | C(21)—C(26)—C(27) | 124.8 (4) |
Ir(1)—W(2)—C(17) | 176.8 (2) | C(25)—C(26)—C(27) | 118.7 (4) |
Ir(1)—W(2)—C(18) | 142.5 (1) | Ir(1)—C(27)—W(1) | 78.2 (1) |
Ir(1)—W(2)—C(19) | 121.4 (1) | Ir(1)—C(27)—W(2) | 76.2 (1) |
Ir(1)—W(2)—C(27) | 47.9 (1) | Ir(1)—C(27)—C(26) | 124.4 (3) |
Ir(1)—W(2)—C(28) | 68.8 (1) | Ir(1)—C(27)—C(28) | 106.3 (3) |
Ir(2)—W(2)—C(6) | 90.8 (1) | W(1)—C(27)—W(2) | 126.1 (2) |
Ir(2)—W(2)—C(8) | 53.3 (1) | W(1)—C(27)—C(26) | 114.8 (3) |
Ir(2)—W(2)—C(15) | 159.8 (1) | W(1)—C(27)—C(28) | 72.3 (2) |
Ir(2)—W(2)—C(16) | 131.3 (1) | W(2)—C(27)—C(26) | 118.8 (3) |
Ir(2)—W(2)—C(17) | 120.7 (1) | W(2)—C(27)—C(28) | 70.7 (2) |
Ir(2)—W(2)—C(18) | 135.1 (1) | C(26)—C(27)—C(28) | 129.2 (4) |
Ir(2)—W(2)—C(19) | 165.2 (1) | Ir(2)—C(28)—W(1) | 77.0 (1) |
Ir(2)—W(2)—C(27) | 68.3 (1) | Ir(2)—C(28)—W(2) | 77.5 (1) |
Ir(2)—W(2)—C(28) | 48.0 (1) | Ir(2)—C(28)—C(27) | 106.6 (3) |
C(6)—W(2)—C(8) | 86.9 (2) | Ir(2)—C(28)—C(29) | 125.0 (3) |
C(6)—W(2)—C(15) | 106.1 (2) | W(1)—C(28)—W(2) | 126.2 (2) |
C(6)—W(2)—C(16) | 137.2 (2) | W(1)—C(28)—C(27) | 70.7 (2) |
C(6)—W(2)—C(17) | 122.4 (2) | W(1)—C(28)—C(29) | 120.6 (3) |
C(6)—W(2)—C(18) | 86.8 (2) | W(2)—C(28)—C(27) | 72.5 (2) |
C(6)—W(2)—C(19) | 78.5 (2) | W(2)—C(28)—C(29) | 112.9 (3) |
C(6)—W(2)—C(27) | 100.2 (2) | C(27)—C(28)—C(29) | 128.4 (4) |
C(6)—W(2)—C(28) | 123.7 (2) | C(28)—C(29)—C(30) | 120.2 (4) |
C(8)—W(2)—C(15) | 136.7 (2) | C(28)—C(29)—C(34) | 123.2 (4) |
C(8)—W(2)—C(16) | 110.8 (2) | C(30)—C(29)—C(34) | 116.6 (4) |
C(8)—W(2)—C(17) | 78.9 (2) | C(29)—C(30)—C(31) | 121.6 (5) |
C(8)—W(2)—C(18) | 81.9 (2) | C(29)—C(30)—H(30) | 119.2 |
C(8)—W(2)—C(19) | 115.3 (2) | C(31)—C(30)—H(30) | 119.2 |
C(8)—W(2)—C(27) | 121.3 (2) | C(30)—C(31)—C(32) | 120.4 (5) |
C(8)—W(2)—C(28) | 92.1 (2) | C(30)—C(31)—H(31) | 119.8 |
C(15)—W(2)—C(16) | 35.3 (2) | C(32)—C(31)—H(31) | 119.8 |
C(15)—W(2)—C(17) | 59.0 (2) | C(31)—C(32)—C(33) | 119.6 (5) |
C(15)—W(2)—C(18) | 58.6 (2) | C(31)—C(32)—H(32) | 120.2 |
C(15)—W(2)—C(19) | 34.8 (2) | C(33)—C(32)—H(32) | 120.2 |
C(15)—W(2)—C(27) | 97.3 (2) | C(32)—C(33)—C(34) | 120.3 (5) |
C(15)—W(2)—C(28) | 112.1 (2) | C(32)—C(33)—H(33) | 119.9 |
C(16)—W(2)—C(17) | 35.5 (2) | C(34)—C(33)—H(33) | 119.9 |
C(16)—W(2)—C(18) | 59.3 (2) | C(29)—C(34)—C(33) | 121.5 (5) |
C(16)—W(2)—C(19) | 58.7 (2) | C(29)—C(34)—H(34) | 119.3 |
C(16)—W(2)—C(27) | 102.5 (2) | C(33)—C(34)—H(34) | 119.3 |
Ir(1)—Ir(2)—W(1)—C(5) | 35.3 (1) | C(1)—Ir(1)—Ir(2)—C(7) | 137.5 (8) |
Ir(1)—Ir(2)—W(1)—C(7) | 109.4 (2) | C(1)—Ir(1)—Ir(2)—C(8) | −51.5 (8) |
Ir(1)—Ir(2)—W(1)—C(9) | 126.6 (2) | C(1)—Ir(1)—Ir(2)—C(28) | 37.7 (8) |
Ir(1)—Ir(2)—W(1)—C(11) | −120.1 (2) | C(1)—Ir(1)—W(1)—C(5) | 57.0 (2) |
Ir(1)—Ir(2)—W(1)—C(12) | −156.7 (2) | C(1)—Ir(1)—W(1)—C(7) | 138.9 (2) |
Ir(1)—Ir(2)—W(1)—C(13) | 162.9 (1) | C(1)—Ir(1)—W(1)—C(9) | 58.2 (3) |
Ir(1)—Ir(2)—W(1)—C(27) | −52.4 (1) | C(1)—Ir(1)—W(1)—C(10) | 13.0 (2) |
Ir(1)—Ir(2)—W(1)—C(28) | −88.8 (1) | C(1)—Ir(1)—W(1)—C(11) | −30.5 (2) |
Ir(1)—Ir(2)—W(2)—C(6) | −47.6 (1) | C(1)—Ir(1)—W(1)—C(12) | −78.0 (4) |
Ir(1)—Ir(2)—W(2)—C(8) | −133.1 (2) | C(1)—Ir(1)—W(1)—C(13) | 110.2 (5) |
Ir(1)—Ir(2)—W(2)—C(15) | 100.1 (4) | C(1)—Ir(1)—W(1)—C(27) | −76.6 (2) |
Ir(1)—Ir(2)—W(2)—C(16) | 140.8 (2) | C(1)—Ir(1)—W(1)—C(28) | −113.7 (2) |
Ir(1)—Ir(2)—W(2)—C(17) | −176.8 (2) | C(1)—Ir(1)—W(2)—C(6) | −67.3 (2) |
Ir(1)—Ir(2)—W(2)—C(18) | −133.9 (2) | C(1)—Ir(1)—W(2)—C(8) | −147.9 (2) |
Ir(1)—Ir(2)—W(2)—C(19) | −91.0 (5) | C(1)—Ir(1)—W(2)—C(15) | 20.0 (2) |
Ir(1)—Ir(2)—W(2)—C(27) | 53.0 (1) | C(1)—Ir(1)—W(2)—C(16) | 58.5 (3) |
Ir(1)—Ir(2)—W(2)—C(28) | 89.7 (1) | C(1)—Ir(1)—W(2)—C(18) | −60.6 (3) |
Ir(1)—Ir(2)—C(7)—W(1) | −57.0 (1) | C(1)—Ir(1)—W(2)—C(19) | −21.6 (2) |
Ir(1)—Ir(2)—C(7)—O(7) | 121.4 (4) | C(1)—Ir(1)—W(2)—C(27) | 86.8 (2) |
Ir(1)—Ir(2)—C(8)—W(2) | 39.7 (1) | C(1)—Ir(1)—W(2)—C(28) | 123.0 (2) |
Ir(1)—Ir(2)—C(8)—O(8) | −144.6 (5) | C(1)—Ir(1)—C(27)—C(26) | 9.4 (4) |
Ir(1)—Ir(2)—C(28)—W(1) | 66.67 (7) | C(1)—Ir(1)—C(27)—C(28) | −171.2 (3) |
Ir(1)—Ir(2)—C(28)—W(2) | −65.52 (7) | C(2)—Ir(1)—Ir(2)—C(3) | −129.3 (8) |
Ir(1)—Ir(2)—C(28)—C(27) | 1.7 (3) | C(2)—Ir(1)—Ir(2)—C(4) | 3.4 (2) |
Ir(1)—Ir(2)—C(28)—C(29) | −174.9 (4) | C(2)—Ir(1)—Ir(2)—C(7) | −77.7 (2) |
Ir(1)—W(1)—Ir(2)—W(2) | 51.383 (7) | C(2)—Ir(1)—Ir(2)—C(8) | 93.2 (2) |
Ir(1)—W(1)—Ir(2)—C(3) | 177.9 (2) | C(2)—Ir(1)—Ir(2)—C(28) | −177.5 (2) |
Ir(1)—W(1)—Ir(2)—C(4) | −78.1 (2) | C(2)—Ir(1)—W(1)—C(5) | −56.4 (2) |
Ir(1)—W(1)—Ir(2)—C(7) | −109.4 (2) | C(2)—Ir(1)—W(1)—C(7) | 25.5 (2) |
Ir(1)—W(1)—Ir(2)—C(8) | 57.1 (2) | C(2)—Ir(1)—W(1)—C(9) | −55.2 (3) |
Ir(1)—W(1)—Ir(2)—C(28) | 88.8 (1) | C(2)—Ir(1)—W(1)—C(10) | −100.5 (2) |
Ir(1)—W(1)—C(5)—O(5) | 178 (1) | C(2)—Ir(1)—W(1)—C(11) | −143.9 (2) |
Ir(1)—W(1)—C(7)—Ir(2) | 52.65 (8) | C(2)—Ir(1)—W(1)—C(12) | 168.5 (4) |
Ir(1)—W(1)—C(7)—O(7) | −123 (1) | C(2)—Ir(1)—W(1)—C(13) | −3.3 (5) |
Ir(1)—W(1)—C(9)—C(10) | −85.3 (3) | C(2)—Ir(1)—W(1)—C(27) | 170.0 (2) |
Ir(1)—W(1)—C(9)—C(13) | 159.5 (2) | C(2)—Ir(1)—W(1)—C(28) | 132.8 (2) |
Ir(1)—W(1)—C(10)—C(9) | 125.2 (3) | C(2)—Ir(1)—W(2)—C(6) | 40.1 (2) |
Ir(1)—W(1)—C(10)—C(11) | −118.5 (3) | C(2)—Ir(1)—W(2)—C(8) | −40.5 (2) |
Ir(1)—W(1)—C(11)—C(10) | 89.5 (3) | C(2)—Ir(1)—W(2)—C(15) | 127.4 (2) |
Ir(1)—W(1)—C(11)—C(12) | −154.4 (2) | C(2)—Ir(1)—W(2)—C(16) | 165.9 (3) |
Ir(1)—W(1)—C(12)—C(11) | 67.0 (5) | C(2)—Ir(1)—W(2)—C(18) | 46.7 (3) |
Ir(1)—W(1)—C(12)—C(13) | −176.3 (3) | C(2)—Ir(1)—W(2)—C(19) | 85.8 (2) |
Ir(1)—W(1)—C(13)—C(9) | −67.9 (6) | C(2)—Ir(1)—W(2)—C(27) | −165.8 (2) |
Ir(1)—W(1)—C(13)—C(12) | 175.1 (4) | C(2)—Ir(1)—W(2)—C(28) | −129.6 (2) |
Ir(1)—W(1)—C(13)—C(14) | 52.5 (8) | C(2)—Ir(1)—C(27)—C(26) | −160.0 (8) |
Ir(1)—W(1)—C(27)—W(2) | −63.0 (2) | C(2)—Ir(1)—C(27)—C(28) | 20 (1) |
Ir(1)—W(1)—C(27)—C(26) | 122.7 (4) | C(3)—Ir(2)—Ir(1)—C(5) | −39.6 (8) |
Ir(1)—W(1)—C(27)—C(28) | −111.6 (3) | C(3)—Ir(2)—Ir(1)—C(6) | 145.4 (8) |
Ir(1)—W(1)—C(28)—Ir(2) | −65.18 (9) | C(3)—Ir(2)—Ir(1)—C(27) | 47.0 (8) |
Ir(1)—W(1)—C(28)—W(2) | −1.5 (2) | C(3)—Ir(2)—W(1)—C(5) | −146.8 (2) |
Ir(1)—W(1)—C(28)—C(27) | 47.8 (2) | C(3)—Ir(2)—W(1)—C(7) | −72.8 (2) |
Ir(1)—W(1)—C(28)—C(29) | 171.6 (4) | C(3)—Ir(2)—W(1)—C(9) | −55.5 (3) |
Ir(1)—W(2)—Ir(2)—W(1) | −52.043 (7) | C(3)—Ir(2)—W(1)—C(11) | 57.7 (3) |
Ir(1)—W(2)—Ir(2)—C(3) | −167.2 (2) | C(3)—Ir(2)—W(1)—C(12) | 21.1 (2) |
Ir(1)—W(2)—Ir(2)—C(4) | 78.3 (2) | C(3)—Ir(2)—W(1)—C(13) | −19.2 (2) |
Ir(1)—W(2)—Ir(2)—C(7) | −32.7 (2) | C(3)—Ir(2)—W(1)—C(27) | 125.5 (2) |
Ir(1)—W(2)—Ir(2)—C(8) | 133.1 (2) | C(3)—Ir(2)—W(1)—C(28) | 89.1 (2) |
Ir(1)—W(2)—Ir(2)—C(28) | −89.7 (1) | C(3)—Ir(2)—W(2)—C(6) | 145.2 (2) |
Ir(1)—W(2)—C(6)—O(6) | 177 (1) | C(3)—Ir(2)—W(2)—C(8) | 59.7 (2) |
Ir(1)—W(2)—C(8)—Ir(2) | −38.6 (1) | C(3)—Ir(2)—W(2)—C(15) | −67.1 (4) |
Ir(1)—W(2)—C(8)—O(8) | 149.0 (9) | C(3)—Ir(2)—W(2)—C(16) | −26.5 (3) |
Ir(1)—W(2)—C(15)—C(16) | 144.7 (3) | C(3)—Ir(2)—W(2)—C(17) | 16.0 (2) |
Ir(1)—W(2)—C(15)—C(19) | −98.1 (3) | C(3)—Ir(2)—W(2)—C(18) | 58.8 (3) |
Ir(1)—W(2)—C(16)—C(15) | −64.0 (4) | C(3)—Ir(2)—W(2)—C(19) | 101.8 (5) |
Ir(1)—W(2)—C(16)—C(17) | 179.7 (3) | C(3)—Ir(2)—W(2)—C(27) | −114.2 (2) |
Ir(1)—W(2)—C(18)—C(17) | −175.2 (3) | C(3)—Ir(2)—W(2)—C(28) | −77.6 (2) |
Ir(1)—W(2)—C(18)—C(19) | 68.9 (4) | C(3)—Ir(2)—C(28)—C(27) | −169.8 (3) |
Ir(1)—W(2)—C(19)—C(15) | 104.9 (3) | C(3)—Ir(2)—C(28)—C(29) | 13.6 (4) |
Ir(1)—W(2)—C(19)—C(18) | −138.2 (3) | C(4)—Ir(2)—Ir(1)—C(5) | 93.0 (2) |
Ir(1)—W(2)—C(19)—C(20) | −16.6 (6) | C(4)—Ir(2)—Ir(1)—C(6) | −81.9 (2) |
Ir(1)—W(2)—C(27)—W(1) | 63.9 (2) | C(4)—Ir(2)—Ir(1)—C(27) | 179.7 (2) |
Ir(1)—W(2)—C(27)—C(26) | −122.0 (4) | C(4)—Ir(2)—W(1)—C(5) | −42.8 (2) |
Ir(1)—W(2)—C(27)—C(28) | 113.1 (3) | C(4)—Ir(2)—W(1)—C(7) | 31.3 (2) |
Ir(1)—W(2)—C(28)—Ir(2) | 64.98 (8) | C(4)—Ir(2)—W(1)—C(9) | 48.5 (3) |
Ir(1)—W(2)—C(28)—W(1) | 1.5 (2) | C(4)—Ir(2)—W(1)—C(11) | 161.8 (3) |
Ir(1)—W(2)—C(28)—C(27) | −47.1 (2) | C(4)—Ir(2)—W(1)—C(12) | 125.2 (2) |
Ir(1)—W(2)—C(28)—C(29) | −172.1 (3) | C(4)—Ir(2)—W(1)—C(13) | 84.8 (2) |
Ir(1)—C(5)—W(1)—Ir(2) | −36.5 (1) | C(4)—Ir(2)—W(1)—C(27) | −130.5 (2) |
Ir(1)—C(5)—W(1)—C(7) | −92.8 (2) | C(4)—Ir(2)—W(1)—C(28) | −166.9 (2) |
Ir(1)—C(5)—W(1)—C(9) | −179.1 (2) | C(4)—Ir(2)—W(2)—C(6) | 30.7 (2) |
Ir(1)—C(5)—W(1)—C(10) | 144.2 (2) | C(4)—Ir(2)—W(2)—C(8) | −54.7 (3) |
Ir(1)—C(5)—W(1)—C(11) | 128.4 (2) | C(4)—Ir(2)—W(2)—C(15) | 178.4 (4) |
Ir(1)—C(5)—W(1)—C(12) | 159.0 (2) | C(4)—Ir(2)—W(2)—C(16) | −140.9 (2) |
Ir(1)—C(5)—W(1)—C(13) | −166.8 (1) | C(4)—Ir(2)—W(2)—C(17) | −98.5 (2) |
Ir(1)—C(5)—W(1)—C(27) | 32.4 (2) | C(4)—Ir(2)—W(2)—C(18) | −55.6 (3) |
Ir(1)—C(5)—W(1)—C(28) | 10.2 (2) | C(4)—Ir(2)—W(2)—C(19) | −12.7 (5) |
Ir(1)—C(6)—W(2)—Ir(2) | 48.9 (1) | C(4)—Ir(2)—W(2)—C(27) | 131.3 (2) |
Ir(1)—C(6)—W(2)—C(8) | 102.1 (2) | C(4)—Ir(2)—W(2)—C(28) | 168.0 (2) |
Ir(1)—C(6)—W(2)—C(15) | −120.0 (2) | C(4)—Ir(2)—C(28)—C(27) | 6 (1) |
Ir(1)—C(6)—W(2)—C(16) | −140.3 (2) | C(4)—Ir(2)—C(28)—C(29) | −170.8 (8) |
Ir(1)—C(6)—W(2)—C(17) | 176.8 (2) | C(5)—Ir(1)—Ir(2)—C(7) | 12.0 (2) |
Ir(1)—C(6)—W(2)—C(18) | −175.9 (2) | C(5)—Ir(1)—Ir(2)—C(8) | −177.1 (2) |
Ir(1)—C(6)—W(2)—C(19) | −141.4 (2) | C(5)—Ir(1)—Ir(2)—C(28) | −87.8 (2) |
Ir(1)—C(6)—W(2)—C(27) | −19.2 (2) | C(5)—Ir(1)—W(1)—C(7) | 82.0 (2) |
Ir(1)—C(6)—W(2)—C(28) | 11.6 (2) | C(5)—Ir(1)—W(1)—C(9) | 1.3 (3) |
Ir(1)—C(27)—W(1)—Ir(2) | 64.44 (9) | C(5)—Ir(1)—W(1)—C(10) | −44.0 (2) |
Ir(1)—C(27)—W(1)—C(5) | −36.3 (2) | C(5)—Ir(1)—W(1)—C(11) | −87.5 (3) |
Ir(1)—C(27)—W(1)—C(7) | 45.3 (2) | C(5)—Ir(1)—W(1)—C(12) | −135.0 (4) |
Ir(1)—C(27)—W(1)—C(9) | −114.4 (3) | C(5)—Ir(1)—W(1)—C(13) | 53.2 (5) |
Ir(1)—C(27)—W(1)—C(10) | −116.7 (2) | C(5)—Ir(1)—W(1)—C(27) | −133.6 (2) |
Ir(1)—C(27)—W(1)—C(11) | −148.2 (2) | C(5)—Ir(1)—W(1)—C(28) | −170.7 (2) |
Ir(1)—C(27)—W(1)—C(12) | 179.5 (2) | C(5)—Ir(1)—W(2)—C(6) | 177.6 (3) |
Ir(1)—C(27)—W(1)—C(13) | 176.8 (2) | C(5)—Ir(1)—W(2)—C(8) | 97.1 (2) |
Ir(1)—C(27)—W(1)—C(28) | 111.6 (3) | C(5)—Ir(1)—W(2)—C(15) | −95.1 (2) |
Ir(1)—C(27)—W(2)—Ir(2) | −65.33 (9) | C(5)—Ir(1)—W(2)—C(16) | −56.5 (3) |
Ir(1)—C(27)—W(2)—C(6) | 21.5 (2) | C(5)—Ir(1)—W(2)—C(18) | −175.7 (3) |
Ir(1)—C(27)—W(2)—C(8) | −71.0 (2) | C(5)—Ir(1)—W(2)—C(19) | −136.6 (2) |
Ir(1)—C(27)—W(2)—C(15) | 129.4 (2) | C(5)—Ir(1)—W(2)—C(27) | −28.2 (2) |
Ir(1)—C(27)—W(2)—C(16) | 165.0 (2) | C(5)—Ir(1)—W(2)—C(28) | 8.0 (2) |
Ir(1)—C(27)—W(2)—C(17) | −177.7 (2) | C(5)—Ir(1)—C(27)—C(26) | −81.8 (4) |
Ir(1)—C(27)—W(2)—C(18) | 126.7 (4) | C(5)—Ir(1)—C(27)—C(28) | 97.7 (3) |
Ir(1)—C(27)—W(2)—C(19) | 104.3 (2) | C(5)—W(1)—Ir(1)—C(6) | −175.6 (3) |
Ir(1)—C(27)—W(2)—C(28) | −113.1 (3) | C(5)—W(1)—Ir(1)—C(27) | 133.6 (2) |
Ir(1)—C(27)—C(26)—C(21) | −141.4 (4) | C(5)—W(1)—Ir(2)—C(7) | −74.0 (2) |
Ir(1)—C(27)—C(26)—C(25) | 35.3 (6) | C(5)—W(1)—Ir(2)—C(8) | 92.4 (3) |
Ir(1)—C(27)—C(28)—Ir(2) | −2.1 (3) | C(5)—W(1)—Ir(2)—C(28) | 124.1 (2) |
Ir(1)—C(27)—C(28)—W(1) | −71.5 (2) | C(5)—W(1)—C(9)—C(10) | −84.3 (3) |
Ir(1)—C(27)—C(28)—W(2) | 68.6 (2) | C(5)—W(1)—C(9)—C(13) | 160.5 (3) |
Ir(1)—C(27)—C(28)—C(29) | 174.3 (4) | C(5)—W(1)—C(10)—C(9) | 90.0 (3) |
Ir(2)—Ir(1)—W(1)—C(5) | −136.0 (2) | C(5)—W(1)—C(10)—C(11) | −153.7 (4) |
Ir(2)—Ir(1)—W(1)—C(7) | −54.0 (1) | C(5)—W(1)—C(11)—C(10) | 28.0 (4) |
Ir(2)—Ir(1)—W(1)—C(9) | −134.7 (2) | C(5)—W(1)—C(11)—C(12) | 144.1 (3) |
Ir(2)—Ir(1)—W(1)—C(10) | 180.0 (2) | C(5)—W(1)—C(12)—C(11) | −54.0 (4) |
Ir(2)—Ir(1)—W(1)—C(11) | 136.5 (2) | C(5)—W(1)—C(12)—C(13) | 62.7 (4) |
Ir(2)—Ir(1)—W(1)—C(12) | 89.0 (4) | C(5)—W(1)—C(13)—C(9) | −21.5 (4) |
Ir(2)—Ir(1)—W(1)—C(13) | −82.8 (5) | C(5)—W(1)—C(13)—C(12) | −138.4 (3) |
Ir(2)—Ir(1)—W(1)—C(27) | 90.4 (1) | C(5)—W(1)—C(13)—C(14) | 99.0 (5) |
Ir(2)—Ir(1)—W(1)—C(28) | 53.3 (1) | C(5)—W(1)—C(27)—C(26) | 86.3 (3) |
Ir(2)—Ir(1)—W(2)—C(6) | 116.8 (2) | C(5)—W(1)—C(27)—C(28) | −147.9 (3) |
Ir(2)—Ir(1)—W(2)—C(8) | 36.3 (1) | C(5)—W(1)—C(28)—C(27) | 38.8 (3) |
Ir(2)—Ir(1)—W(2)—C(15) | −155.9 (2) | C(5)—W(1)—C(28)—C(29) | 162.7 (3) |
Ir(2)—Ir(1)—W(2)—C(16) | −117.3 (3) | C(6)—Ir(1)—Ir(2)—C(7) | −163.0 (2) |
Ir(2)—Ir(1)—W(2)—C(18) | 123.5 (2) | C(6)—Ir(1)—Ir(2)—C(8) | 8.0 (2) |
Ir(2)—Ir(1)—W(2)—C(19) | 162.6 (2) | C(6)—Ir(1)—Ir(2)—C(28) | 97.2 (2) |
Ir(2)—Ir(1)—W(2)—C(27) | −89.0 (1) | C(6)—Ir(1)—W(1)—C(7) | −93.7 (2) |
Ir(2)—Ir(1)—W(2)—C(28) | −52.8 (1) | C(6)—Ir(1)—W(1)—C(9) | −174.4 (3) |
Ir(2)—Ir(1)—C(5)—W(1) | 37.6 (1) | C(6)—Ir(1)—W(1)—C(10) | 140.3 (3) |
Ir(2)—Ir(1)—C(5)—O(5) | −141.1 (4) | C(6)—Ir(1)—W(1)—C(11) | 96.9 (3) |
Ir(2)—Ir(1)—C(6)—W(2) | −51.9 (1) | C(6)—Ir(1)—W(1)—C(12) | 49.3 (4) |
Ir(2)—Ir(1)—C(6)—O(6) | 129.6 (4) | C(6)—Ir(1)—W(1)—C(13) | −122.5 (5) |
Ir(2)—Ir(1)—C(27)—W(1) | −65.68 (8) | C(6)—Ir(1)—W(1)—C(27) | 50.8 (2) |
Ir(2)—Ir(1)—C(27)—W(2) | 66.48 (7) | C(6)—Ir(1)—W(1)—C(28) | 13.6 (2) |
Ir(2)—Ir(1)—C(27)—C(26) | −177.8 (4) | C(6)—Ir(1)—W(2)—C(8) | −80.6 (2) |
Ir(2)—Ir(1)—C(27)—C(28) | 1.7 (3) | C(6)—Ir(1)—W(2)—C(15) | 87.3 (2) |
Ir(2)—W(1)—Ir(1)—W(2) | −52.238 (7) | C(6)—Ir(1)—W(2)—C(16) | 125.9 (3) |
Ir(2)—W(1)—Ir(1)—C(1) | −167.0 (2) | C(6)—Ir(1)—W(2)—C(18) | 6.7 (3) |
Ir(2)—W(1)—Ir(1)—C(2) | 79.5 (2) | C(6)—Ir(1)—W(2)—C(19) | 45.8 (2) |
Ir(2)—W(1)—Ir(1)—C(5) | 136.0 (2) | C(6)—Ir(1)—W(2)—C(27) | 154.2 (2) |
Ir(2)—W(1)—Ir(1)—C(6) | −39.6 (2) | C(6)—Ir(1)—W(2)—C(28) | −169.6 (2) |
Ir(2)—W(1)—Ir(1)—C(27) | −90.4 (1) | C(6)—Ir(1)—C(27)—C(26) | 97.7 (4) |
Ir(2)—W(1)—C(5)—O(5) | 141 (1) | C(6)—Ir(1)—C(27)—C(28) | −82.8 (3) |
Ir(2)—W(1)—C(7)—O(7) | −176 (1) | C(6)—W(2)—Ir(1)—C(27) | −154.2 (2) |
Ir(2)—W(1)—C(9)—C(10) | 178.2 (2) | C(6)—W(2)—Ir(2)—C(7) | −80.3 (2) |
Ir(2)—W(1)—C(9)—C(13) | 63.0 (4) | C(6)—W(2)—Ir(2)—C(8) | 85.4 (2) |
Ir(2)—W(1)—C(11)—C(10) | −178.1 (2) | C(6)—W(2)—Ir(2)—C(28) | −137.3 (2) |
Ir(2)—W(1)—C(11)—C(12) | −61.9 (4) | C(6)—W(2)—C(15)—C(16) | −155.9 (3) |
Ir(2)—W(1)—C(12)—C(11) | 143.7 (3) | C(6)—W(2)—C(15)—C(19) | −38.7 (4) |
Ir(2)—W(1)—C(12)—C(13) | −99.6 (3) | C(6)—W(2)—C(16)—C(15) | 35.3 (5) |
Ir(2)—W(1)—C(13)—C(9) | −141.9 (3) | C(6)—W(2)—C(16)—C(17) | −81.1 (4) |
Ir(2)—W(1)—C(13)—C(12) | 101.2 (3) | C(6)—W(2)—C(17)—C(16) | 127.4 (3) |
Ir(2)—W(1)—C(13)—C(14) | −21.4 (5) | C(6)—W(2)—C(17)—C(18) | 12.3 (4) |
Ir(2)—W(1)—C(27)—W(2) | 1.4 (2) | C(6)—W(2)—C(18)—C(17) | −169.6 (3) |
Ir(2)—W(1)—C(27)—C(26) | −172.9 (3) | C(6)—W(2)—C(18)—C(19) | 74.4 (3) |
Ir(2)—W(1)—C(27)—C(28) | −47.2 (2) | C(6)—W(2)—C(19)—C(15) | 142.2 (3) |
Ir(2)—W(1)—C(28)—W(2) | 63.7 (2) | C(6)—W(2)—C(19)—C(18) | −101.0 (4) |
Ir(2)—W(1)—C(28)—C(27) | 113.0 (3) | C(6)—W(2)—C(19)—C(20) | 20.7 (5) |
Ir(2)—W(1)—C(28)—C(29) | −123.2 (4) | C(6)—W(2)—C(27)—C(26) | −100.5 (4) |
Ir(2)—W(2)—Ir(1)—W(1) | 51.774 (7) | C(6)—W(2)—C(27)—C(28) | 134.6 (3) |
Ir(2)—W(2)—Ir(1)—C(1) | 175.8 (2) | C(6)—W(2)—C(28)—C(27) | −57.4 (3) |
Ir(2)—W(2)—Ir(1)—C(2) | −76.8 (2) | C(6)—W(2)—C(28)—C(29) | 177.6 (3) |
Ir(2)—W(2)—Ir(1)—C(5) | 60.8 (2) | C(7)—Ir(2)—Ir(1)—C(27) | 98.6 (2) |
Ir(2)—W(2)—Ir(1)—C(6) | −116.8 (2) | C(7)—Ir(2)—W(1)—C(9) | 17.3 (3) |
Ir(2)—W(2)—Ir(1)—C(27) | 89.0 (1) | C(7)—Ir(2)—W(1)—C(11) | 130.5 (3) |
Ir(2)—W(2)—C(6)—O(6) | −134 (1) | C(7)—Ir(2)—W(1)—C(12) | 93.9 (2) |
Ir(2)—W(2)—C(8)—O(8) | −172 (1) | C(7)—Ir(2)—W(1)—C(13) | 53.6 (2) |
Ir(2)—W(2)—C(15)—C(16) | 57.9 (5) | C(7)—Ir(2)—W(1)—C(27) | −161.7 (2) |
Ir(2)—W(2)—C(15)—C(19) | 175.1 (3) | C(7)—Ir(2)—W(1)—C(28) | 161.9 (2) |
Ir(2)—W(2)—C(16)—C(15) | −157.1 (2) | C(7)—Ir(2)—W(2)—C(8) | −165.7 (3) |
Ir(2)—W(2)—C(16)—C(17) | 86.6 (3) | C(7)—Ir(2)—W(2)—C(15) | 67.4 (4) |
Ir(2)—W(2)—C(17)—C(16) | −119.2 (3) | C(7)—Ir(2)—W(2)—C(16) | 108.1 (2) |
Ir(2)—W(2)—C(17)—C(18) | 125.7 (3) | C(7)—Ir(2)—W(2)—C(17) | 150.5 (2) |
Ir(2)—W(2)—C(18)—C(17) | −81.6 (4) | C(7)—Ir(2)—W(2)—C(18) | −166.6 (3) |
Ir(2)—W(2)—C(18)—C(19) | 162.4 (2) | C(7)—Ir(2)—W(2)—C(19) | −123.6 (5) |
Ir(2)—W(2)—C(19)—C(15) | −173.3 (4) | C(7)—Ir(2)—W(2)—C(27) | 20.4 (2) |
Ir(2)—W(2)—C(19)—C(18) | −56.5 (7) | C(7)—Ir(2)—W(2)—C(28) | 57.0 (2) |
Ir(2)—W(2)—C(19)—C(20) | 65.2 (8) | C(7)—Ir(2)—C(28)—C(27) | −77.5 (3) |
Ir(2)—W(2)—C(27)—W(1) | −1.4 (2) | C(7)—Ir(2)—C(28)—C(29) | 105.9 (4) |
Ir(2)—W(2)—C(27)—C(26) | 172.7 (4) | C(7)—W(1)—Ir(1)—C(27) | −144.4 (2) |
Ir(2)—W(2)—C(27)—C(28) | 47.8 (2) | C(7)—W(1)—Ir(2)—C(8) | 166.4 (3) |
Ir(2)—W(2)—C(28)—W(1) | −63.4 (2) | C(7)—W(1)—Ir(2)—C(28) | −161.9 (2) |
Ir(2)—W(2)—C(28)—C(27) | −112.1 (3) | C(7)—W(1)—C(9)—C(10) | −167.0 (3) |
Ir(2)—W(2)—C(28)—C(29) | 123.0 (3) | C(7)—W(1)—C(9)—C(13) | 77.8 (3) |
Ir(2)—C(7)—W(1)—C(5) | 107.5 (2) | C(7)—W(1)—C(10)—C(9) | 15.1 (4) |
Ir(2)—C(7)—W(1)—C(9) | −169.7 (2) | C(7)—W(1)—C(10)—C(11) | 131.4 (3) |
Ir(2)—C(7)—W(1)—C(10) | −178.6 (2) | C(7)—W(1)—C(11)—C(10) | −74.7 (4) |
Ir(2)—C(7)—W(1)—C(11) | −138.8 (2) | C(7)—W(1)—C(11)—C(12) | 41.4 (4) |
Ir(2)—C(7)—W(1)—C(12) | −114.8 (2) | C(7)—W(1)—C(12)—C(11) | −152.2 (3) |
Ir(2)—C(7)—W(1)—C(13) | −134.6 (2) | C(7)—W(1)—C(12)—C(13) | −35.5 (4) |
Ir(2)—C(7)—W(1)—C(27) | 21.0 (2) | C(7)—W(1)—C(13)—C(9) | −97.3 (3) |
Ir(2)—C(7)—W(1)—C(28) | −13.9 (2) | C(7)—W(1)—C(13)—C(12) | 145.8 (3) |
Ir(2)—C(8)—W(2)—C(6) | −93.4 (2) | C(7)—W(1)—C(13)—C(14) | 23.2 (5) |
Ir(2)—C(8)—W(2)—C(15) | 156.2 (2) | C(7)—W(1)—C(27)—C(26) | 167.9 (3) |
Ir(2)—C(8)—W(2)—C(16) | 126.7 (2) | C(7)—W(1)—C(27)—C(28) | −66.4 (3) |
Ir(2)—C(8)—W(2)—C(17) | 142.7 (2) | C(7)—W(1)—C(28)—C(27) | 129.1 (3) |
Ir(2)—C(8)—W(2)—C(18) | 179.4 (2) | C(7)—W(1)—C(28)—C(29) | −107.1 (4) |
Ir(2)—C(8)—W(2)—C(19) | −169.1 (2) | C(8)—Ir(2)—Ir(1)—C(27) | −90.5 (2) |
Ir(2)—C(8)—W(2)—C(27) | 6.6 (2) | C(8)—Ir(2)—W(1)—C(9) | −176.3 (3) |
Ir(2)—C(8)—W(2)—C(28) | 30.3 (2) | C(8)—Ir(2)—W(1)—C(11) | −63.1 (3) |
Ir(2)—C(28)—W(1)—C(5) | −74.1 (2) | C(8)—Ir(2)—W(1)—C(12) | −99.6 (3) |
Ir(2)—C(28)—W(1)—C(7) | 16.1 (2) | C(8)—Ir(2)—W(1)—C(13) | −140.0 (3) |
Ir(2)—C(28)—W(1)—C(9) | 127.3 (3) | C(8)—Ir(2)—W(1)—C(27) | 4.7 (2) |
Ir(2)—C(28)—W(1)—C(10) | 178.3 (2) | C(8)—Ir(2)—W(1)—C(28) | −31.7 (3) |
Ir(2)—C(28)—W(1)—C(11) | 162.2 (2) | C(8)—Ir(2)—W(2)—C(15) | −126.9 (4) |
Ir(2)—C(28)—W(1)—C(12) | 126.4 (2) | C(8)—Ir(2)—W(2)—C(16) | −86.2 (3) |
Ir(2)—C(28)—W(1)—C(13) | 102.6 (2) | C(8)—Ir(2)—W(2)—C(17) | −43.8 (3) |
Ir(2)—C(28)—W(1)—C(27) | −113.0 (3) | C(8)—Ir(2)—W(2)—C(18) | −0.9 (3) |
Ir(2)—C(28)—W(2)—C(6) | 54.7 (2) | C(8)—Ir(2)—W(2)—C(19) | 42.1 (5) |
Ir(2)—C(28)—W(2)—C(8) | −32.9 (2) | C(8)—Ir(2)—W(2)—C(27) | −173.9 (2) |
Ir(2)—C(28)—W(2)—C(15) | −176.1 (2) | C(8)—Ir(2)—W(2)—C(28) | −137.3 (2) |
Ir(2)—C(28)—W(2)—C(16) | −144.0 (2) | C(8)—Ir(2)—C(28)—C(27) | 95.7 (3) |
Ir(2)—C(28)—W(2)—C(17) | −111.8 (2) | C(8)—Ir(2)—C(28)—C(29) | −80.9 (4) |
Ir(2)—C(28)—W(2)—C(18) | −110.7 (3) | C(8)—W(2)—Ir(1)—C(27) | 125.3 (2) |
Ir(2)—C(28)—W(2)—C(19) | −179.7 (2) | C(8)—W(2)—Ir(2)—C(28) | 137.3 (2) |
Ir(2)—C(28)—W(2)—C(27) | 112.1 (3) | C(8)—W(2)—C(15)—C(16) | −52.9 (4) |
Ir(2)—C(28)—C(27)—W(1) | 69.4 (2) | C(8)—W(2)—C(15)—C(19) | 64.2 (4) |
Ir(2)—C(28)—C(27)—W(2) | −70.7 (2) | C(8)—W(2)—C(16)—C(15) | 144.2 (3) |
Ir(2)—C(28)—C(27)—C(26) | 177.3 (4) | C(8)—W(2)—C(16)—C(17) | 27.8 (4) |
Ir(2)—C(28)—C(29)—C(30) | 32.7 (6) | C(8)—W(2)—C(17)—C(16) | −153.6 (4) |
Ir(2)—C(28)—C(29)—C(34) | −148.8 (4) | C(8)—W(2)—C(17)—C(18) | 91.3 (3) |
W(1)—Ir(1)—Ir(2)—W(2) | −117.028 (8) | C(8)—W(2)—C(18)—C(17) | −82.3 (4) |
W(1)—Ir(1)—Ir(2)—C(3) | −10.5 (8) | C(8)—W(2)—C(18)—C(19) | 161.7 (4) |
W(1)—Ir(1)—Ir(2)—C(4) | 122.1 (1) | C(8)—W(2)—C(19)—C(15) | −136.9 (3) |
W(1)—Ir(1)—Ir(2)—C(7) | 41.1 (1) | C(8)—W(2)—C(19)—C(18) | −20.1 (4) |
W(1)—Ir(1)—Ir(2)—C(8) | −148.0 (1) | C(8)—W(2)—C(19)—C(20) | 101.6 (5) |
W(1)—Ir(1)—Ir(2)—C(28) | −58.7 (1) | C(8)—W(2)—C(27)—C(26) | 167.0 (3) |
W(1)—Ir(1)—W(2)—C(6) | 168.6 (2) | C(8)—W(2)—C(27)—C(28) | 42.1 (3) |
W(1)—Ir(1)—W(2)—C(8) | 88.0 (1) | C(8)—W(2)—C(28)—C(27) | −145.0 (3) |
W(1)—Ir(1)—W(2)—C(15) | −104.1 (2) | C(8)—W(2)—C(28)—C(29) | 90.0 (3) |
W(1)—Ir(1)—W(2)—C(16) | −65.5 (3) | C(9)—W(1)—Ir(1)—C(27) | 134.9 (2) |
W(1)—Ir(1)—W(2)—C(18) | 175.3 (2) | C(9)—W(1)—Ir(2)—C(28) | −144.6 (3) |
W(1)—Ir(1)—W(2)—C(19) | −145.6 (2) | C(9)—W(1)—C(10)—C(11) | 116.2 (5) |
W(1)—Ir(1)—W(2)—C(27) | −37.3 (1) | C(9)—W(1)—C(11)—C(10) | −38.2 (3) |
W(1)—Ir(1)—W(2)—C(28) | −1.0 (1) | C(9)—W(1)—C(11)—C(12) | 78.0 (3) |
W(1)—Ir(1)—C(5)—O(5) | −178.8 (6) | C(9)—W(1)—C(12)—C(11) | −79.6 (3) |
W(1)—Ir(1)—C(6)—W(2) | −17.9 (3) | C(9)—W(1)—C(12)—C(13) | 37.1 (3) |
W(1)—Ir(1)—C(6)—O(6) | 163.6 (3) | C(9)—W(1)—C(13)—C(12) | −117.0 (5) |
W(1)—Ir(1)—C(27)—W(2) | 132.2 (2) | C(9)—W(1)—C(13)—C(14) | 120.5 (6) |
W(1)—Ir(1)—C(27)—C(26) | −112.1 (4) | C(9)—W(1)—C(27)—C(26) | 8.3 (5) |
W(1)—Ir(1)—C(27)—C(28) | 67.4 (3) | C(9)—W(1)—C(27)—C(28) | 134.0 (3) |
W(1)—Ir(2)—Ir(1)—W(2) | 117.028 (8) | C(9)—W(1)—C(28)—C(27) | −119.7 (4) |
W(1)—Ir(2)—Ir(1)—C(1) | 96.5 (8) | C(9)—W(1)—C(28)—C(29) | 4.1 (6) |
W(1)—Ir(2)—Ir(1)—C(2) | −118.8 (2) | C(9)—C(10)—W(1)—C(11) | −116.2 (5) |
W(1)—Ir(2)—Ir(1)—C(5) | −29.1 (1) | C(9)—C(10)—W(1)—C(12) | −78.4 (3) |
W(1)—Ir(2)—Ir(1)—C(6) | 156.0 (1) | C(9)—C(10)—W(1)—C(13) | −37.5 (3) |
W(1)—Ir(2)—Ir(1)—C(27) | 57.6 (1) | C(9)—C(10)—W(1)—C(27) | 178.0 (3) |
W(1)—Ir(2)—W(2)—C(6) | −99.7 (1) | C(9)—C(10)—W(1)—C(28) | −144.8 (3) |
W(1)—Ir(2)—W(2)—C(8) | 174.9 (2) | C(9)—C(10)—C(11)—C(12) | −1.5 (6) |
W(1)—Ir(2)—W(2)—C(15) | 48.0 (4) | C(9)—C(13)—W(1)—C(10) | 38.6 (3) |
W(1)—Ir(2)—W(2)—C(16) | 88.7 (2) | C(9)—C(13)—W(1)—C(11) | 79.4 (3) |
W(1)—Ir(2)—W(2)—C(17) | 131.1 (2) | C(9)—C(13)—W(1)—C(12) | 117.0 (5) |
W(1)—Ir(2)—W(2)—C(18) | 174.0 (2) | C(9)—C(13)—W(1)—C(27) | 121.3 (4) |
W(1)—Ir(2)—W(2)—C(19) | −143.0 (5) | C(9)—C(13)—W(1)—C(28) | 161.5 (3) |
W(1)—Ir(2)—W(2)—C(27) | 1.0 (1) | C(9)—C(13)—C(12)—C(11) | 2.3 (6) |
W(1)—Ir(2)—W(2)—C(28) | 37.6 (1) | C(10)—W(1)—Ir(1)—C(27) | 89.6 (2) |
W(1)—Ir(2)—C(7)—O(7) | 178.4 (5) | C(10)—W(1)—C(9)—C(13) | −115.2 (5) |
W(1)—Ir(2)—C(8)—W(2) | −8.1 (3) | C(10)—W(1)—C(11)—C(12) | 116.1 (4) |
W(1)—Ir(2)—C(8)—O(8) | 167.7 (4) | C(10)—W(1)—C(12)—C(11) | −36.9 (3) |
W(1)—Ir(2)—C(28)—W(2) | −132.2 (1) | C(10)—W(1)—C(12)—C(13) | 79.8 (3) |
W(1)—Ir(2)—C(28)—C(27) | −65.0 (3) | C(10)—W(1)—C(13)—C(12) | −78.4 (3) |
W(1)—Ir(2)—C(28)—C(29) | 118.4 (4) | C(10)—W(1)—C(13)—C(14) | 159.0 (5) |
W(1)—C(5)—Ir(1)—W(2) | −12.9 (3) | C(10)—W(1)—C(27)—C(26) | 6.0 (4) |
W(1)—C(5)—Ir(1)—C(1) | −133.1 (2) | C(10)—W(1)—C(27)—C(28) | 131.7 (3) |
W(1)—C(5)—Ir(1)—C(2) | 132.2 (2) | C(10)—W(1)—C(28)—C(27) | −68.7 (3) |
W(1)—C(5)—Ir(1)—C(27) | −36.0 (2) | C(10)—W(1)—C(28)—C(29) | 55.1 (4) |
W(1)—C(7)—Ir(2)—W(2) | −28.6 (2) | C(10)—C(9)—W(1)—C(11) | 36.6 (3) |
W(1)—C(7)—Ir(2)—C(3) | 114.2 (2) | C(10)—C(9)—W(1)—C(12) | 78.6 (3) |
W(1)—C(7)—Ir(2)—C(4) | −153.1 (2) | C(10)—C(9)—W(1)—C(13) | 115.2 (5) |
W(1)—C(7)—Ir(2)—C(28) | 14.9 (2) | C(10)—C(9)—W(1)—C(27) | −3.5 (5) |
W(1)—C(9)—C(10)—C(11) | −64.3 (4) | C(10)—C(9)—W(1)—C(28) | 77.5 (5) |
W(1)—C(9)—C(13)—C(12) | 62.5 (4) | C(10)—C(9)—C(13)—C(12) | −3.2 (6) |
W(1)—C(9)—C(13)—C(14) | −123.1 (5) | C(10)—C(9)—C(13)—C(14) | 171.2 (5) |
W(1)—C(10)—C(9)—C(13) | 67.2 (4) | C(10)—C(11)—W(1)—C(12) | −116.1 (4) |
W(1)—C(10)—C(11)—C(12) | −64.4 (4) | C(10)—C(11)—W(1)—C(13) | −79.6 (3) |
W(1)—C(11)—C(10)—C(9) | 62.9 (4) | C(10)—C(11)—W(1)—C(27) | 121.8 (3) |
W(1)—C(11)—C(12)—C(13) | −64.4 (4) | C(10)—C(11)—W(1)—C(28) | 158.8 (3) |
W(1)—C(12)—C(11)—C(10) | 64.0 (4) | C(10)—C(11)—C(12)—C(13) | −0.5 (6) |
W(1)—C(12)—C(13)—C(9) | −61.0 (3) | C(11)—W(1)—Ir(1)—C(27) | 46.1 (2) |
W(1)—C(12)—C(13)—C(14) | 124.6 (5) | C(11)—W(1)—Ir(2)—C(28) | −31.3 (3) |
W(1)—C(13)—C(9)—C(10) | −65.7 (3) | C(11)—W(1)—C(9)—C(13) | −78.6 (3) |
W(1)—C(13)—C(12)—C(11) | 63.3 (3) | C(11)—W(1)—C(12)—C(13) | 116.7 (4) |
W(1)—C(27)—Ir(1)—W(2) | −132.2 (2) | C(11)—W(1)—C(13)—C(12) | −37.5 (3) |
W(1)—C(27)—Ir(1)—C(1) | 121.5 (2) | C(11)—W(1)—C(13)—C(14) | −160.1 (5) |
W(1)—C(27)—Ir(1)—C(2) | −48 (1) | C(11)—W(1)—C(27)—C(26) | −25.5 (3) |
W(1)—C(27)—Ir(1)—C(5) | 30.3 (1) | C(11)—W(1)—C(27)—C(28) | 100.2 (3) |
W(1)—C(27)—Ir(1)—C(6) | −150.2 (1) | C(11)—W(1)—C(28)—C(27) | −84.9 (3) |
W(1)—C(27)—W(2)—C(6) | 85.4 (3) | C(11)—W(1)—C(28)—C(29) | 39.0 (4) |
W(1)—C(27)—W(2)—C(8) | −7.1 (3) | C(11)—C(10)—W(1)—C(12) | 37.9 (3) |
W(1)—C(27)—W(2)—C(15) | −166.6 (2) | C(11)—C(10)—W(1)—C(13) | 78.8 (3) |
W(1)—C(27)—W(2)—C(16) | −131.1 (2) | C(11)—C(10)—W(1)—C(27) | −65.8 (3) |
W(1)—C(27)—W(2)—C(17) | −113.8 (3) | C(11)—C(10)—W(1)—C(28) | −28.6 (4) |
W(1)—C(27)—W(2)—C(18) | −169.4 (4) | C(11)—C(10)—C(9)—C(13) | 3.0 (6) |
W(1)—C(27)—W(2)—C(19) | 168.2 (2) | C(11)—C(12)—W(1)—C(13) | −116.7 (4) |
W(1)—C(27)—W(2)—C(28) | −49.2 (2) | C(11)—C(12)—W(1)—C(27) | 65.9 (3) |
W(1)—C(27)—C(26)—C(21) | 126.1 (4) | C(11)—C(12)—W(1)—C(28) | 99.9 (3) |
W(1)—C(27)—C(26)—C(25) | −57.2 (5) | C(11)—C(12)—C(13)—C(14) | −172.1 (5) |
W(1)—C(27)—C(28)—W(2) | 140.1 (1) | C(12)—W(1)—Ir(1)—C(27) | −1.4 (4) |
W(1)—C(27)—C(28)—C(29) | −114.2 (5) | C(12)—W(1)—Ir(2)—C(28) | −67.9 (2) |
W(1)—C(28)—Ir(2)—W(2) | 132.2 (1) | C(12)—W(1)—C(9)—C(13) | −36.6 (3) |
W(1)—C(28)—Ir(2)—C(3) | −104.8 (2) | C(12)—W(1)—C(13)—C(14) | −122.6 (6) |
W(1)—C(28)—Ir(2)—C(4) | 70.8 (9) | C(12)—W(1)—C(27)—C(26) | −57.9 (4) |
W(1)—C(28)—Ir(2)—C(7) | −12.5 (1) | C(12)—W(1)—C(27)—C(28) | 67.9 (3) |
W(1)—C(28)—Ir(2)—C(8) | 160.7 (2) | C(12)—W(1)—C(28)—C(27) | −120.6 (3) |
W(1)—C(28)—W(2)—C(6) | −8.8 (3) | C(12)—W(1)—C(28)—C(29) | 3.2 (4) |
W(1)—C(28)—W(2)—C(8) | −96.4 (3) | C(12)—C(11)—W(1)—C(13) | 36.6 (3) |
W(1)—C(28)—W(2)—C(15) | 120.4 (2) | C(12)—C(11)—W(1)—C(27) | −122.1 (3) |
W(1)—C(28)—W(2)—C(16) | 152.5 (2) | C(12)—C(11)—W(1)—C(28) | −85.1 (3) |
W(1)—C(28)—W(2)—C(17) | −175.3 (2) | C(12)—C(13)—W(1)—C(27) | 4.3 (5) |
W(1)—C(28)—W(2)—C(18) | −174.2 (3) | C(12)—C(13)—W(1)—C(28) | 44.6 (4) |
W(1)—C(28)—W(2)—C(19) | 116.9 (3) | C(13)—W(1)—Ir(1)—C(27) | −173.2 (5) |
W(1)—C(28)—W(2)—C(27) | 48.6 (2) | C(13)—W(1)—Ir(2)—C(28) | −108.3 (2) |
W(1)—C(28)—C(27)—W(2) | −140.1 (1) | C(13)—W(1)—C(27)—C(26) | −60.5 (5) |
W(1)—C(28)—C(27)—C(26) | 108.0 (5) | C(13)—W(1)—C(27)—C(28) | 65.2 (4) |
W(1)—C(28)—C(29)—C(30) | 128.1 (4) | C(13)—W(1)—C(28)—C(27) | −144.4 (3) |
W(1)—C(28)—C(29)—C(34) | −53.4 (6) | C(13)—W(1)—C(28)—C(29) | −20.5 (4) |
W(2)—Ir(1)—Ir(2)—C(3) | 106.5 (8) | C(13)—C(9)—W(1)—C(27) | −118.8 (4) |
W(2)—Ir(1)—Ir(2)—C(4) | −120.8 (1) | C(13)—C(9)—W(1)—C(28) | −37.7 (5) |
W(2)—Ir(1)—Ir(2)—C(7) | 158.1 (1) | C(13)—C(12)—W(1)—C(27) | −177.5 (3) |
W(2)—Ir(1)—Ir(2)—C(8) | −31.0 (1) | C(13)—C(12)—W(1)—C(28) | −143.4 (3) |
W(2)—Ir(1)—Ir(2)—C(28) | 58.3 (1) | C(14)—C(13)—W(1)—C(27) | −118.3 (5) |
W(2)—Ir(1)—W(1)—C(5) | 171.8 (2) | C(14)—C(13)—W(1)—C(28) | −78.0 (5) |
W(2)—Ir(1)—W(1)—C(7) | −106.3 (1) | C(15)—W(2)—Ir(1)—C(27) | −66.9 (2) |
W(2)—Ir(1)—W(1)—C(9) | 173.0 (2) | C(15)—W(2)—Ir(2)—C(28) | 10.4 (4) |
W(2)—Ir(1)—W(1)—C(10) | 127.7 (2) | C(15)—W(2)—C(16)—C(17) | −116.4 (5) |
W(2)—Ir(1)—W(1)—C(11) | 84.3 (2) | C(15)—W(2)—C(17)—C(16) | 37.2 (3) |
W(2)—Ir(1)—W(1)—C(12) | 36.7 (4) | C(15)—W(2)—C(17)—C(18) | −77.9 (3) |
W(2)—Ir(1)—W(1)—C(13) | −135.1 (5) | C(15)—W(2)—C(18)—C(17) | 79.2 (4) |
W(2)—Ir(1)—W(1)—C(27) | 38.2 (1) | C(15)—W(2)—C(18)—C(19) | −36.7 (3) |
W(2)—Ir(1)—W(1)—C(28) | 1.0 (1) | C(15)—W(2)—C(19)—C(18) | 116.9 (5) |
W(2)—Ir(1)—C(5)—O(5) | 168.3 (3) | C(15)—W(2)—C(19)—C(20) | −121.5 (6) |
W(2)—Ir(1)—C(6)—O(6) | −178.4 (5) | C(15)—W(2)—C(27)—C(26) | 7.5 (4) |
W(2)—Ir(1)—C(27)—C(26) | 115.7 (4) | C(15)—W(2)—C(27)—C(28) | −117.4 (3) |
W(2)—Ir(1)—C(27)—C(28) | −64.8 (3) | C(15)—W(2)—C(28)—C(27) | 71.8 (3) |
W(2)—Ir(2)—Ir(1)—C(1) | −20.6 (8) | C(15)—W(2)—C(28)—C(29) | −53.2 (3) |
W(2)—Ir(2)—Ir(1)—C(2) | 124.2 (2) | C(15)—C(16)—W(2)—C(17) | 116.4 (5) |
W(2)—Ir(2)—Ir(1)—C(5) | −146.1 (1) | C(15)—C(16)—W(2)—C(18) | 77.8 (3) |
W(2)—Ir(2)—Ir(1)—C(6) | 38.9 (1) | C(15)—C(16)—W(2)—C(19) | 36.5 (3) |
W(2)—Ir(2)—Ir(1)—C(27) | −59.5 (1) | C(15)—C(16)—W(2)—C(27) | −85.1 (3) |
W(2)—Ir(2)—W(1)—C(5) | 86.7 (1) | C(15)—C(16)—W(2)—C(28) | −121.6 (3) |
W(2)—Ir(2)—W(1)—C(7) | 160.7 (2) | C(15)—C(16)—C(17)—C(18) | −0.5 (6) |
W(2)—Ir(2)—W(1)—C(9) | 178.0 (2) | C(15)—C(19)—W(2)—C(16) | −37.0 (3) |
W(2)—Ir(2)—W(1)—C(11) | −68.7 (2) | C(15)—C(19)—W(2)—C(17) | −78.7 (3) |
W(2)—Ir(2)—W(1)—C(12) | −105.3 (2) | C(15)—C(19)—W(2)—C(18) | −116.9 (5) |
W(2)—Ir(2)—W(1)—C(13) | −145.7 (1) | C(15)—C(19)—W(2)—C(27) | 47.5 (4) |
W(2)—Ir(2)—W(1)—C(27) | −1.0 (1) | C(15)—C(19)—W(2)—C(28) | 5.8 (5) |
W(2)—Ir(2)—W(1)—C(28) | −37.4 (1) | C(15)—C(19)—C(18)—C(17) | −2.8 (6) |
W(2)—Ir(2)—C(7)—O(7) | 149.8 (4) | C(16)—W(2)—Ir(1)—C(27) | −28.3 (3) |
W(2)—Ir(2)—C(8)—O(8) | 175.7 (6) | C(16)—W(2)—Ir(2)—C(28) | 51.1 (2) |
W(2)—Ir(2)—C(28)—C(27) | 67.2 (3) | C(16)—W(2)—C(15)—C(19) | 117.1 (5) |
W(2)—Ir(2)—C(28)—C(29) | −109.4 (4) | C(16)—W(2)—C(17)—C(18) | −115.1 (5) |
W(2)—C(6)—Ir(1)—C(1) | 118.3 (2) | C(16)—W(2)—C(18)—C(17) | 37.8 (3) |
W(2)—C(6)—Ir(1)—C(2) | −146.9 (2) | C(16)—W(2)—C(18)—C(19) | −78.2 (3) |
W(2)—C(6)—Ir(1)—C(27) | 21.3 (2) | C(16)—W(2)—C(19)—C(18) | 79.8 (4) |
W(2)—C(8)—Ir(2)—C(3) | −132.7 (2) | C(16)—W(2)—C(19)—C(20) | −158.5 (6) |
W(2)—C(8)—Ir(2)—C(4) | 134.5 (2) | C(16)—W(2)—C(27)—C(26) | 43.0 (4) |
W(2)—C(8)—Ir(2)—C(28) | −33.5 (2) | C(16)—W(2)—C(27)—C(28) | −81.9 (3) |
W(2)—C(15)—C(16)—C(17) | 63.2 (4) | C(16)—W(2)—C(28)—C(27) | 103.9 (3) |
W(2)—C(15)—C(19)—C(18) | −60.3 (3) | C(16)—W(2)—C(28)—C(29) | −21.1 (3) |
W(2)—C(15)—C(19)—C(20) | 126.4 (5) | C(16)—C(15)—W(2)—C(17) | −37.4 (3) |
W(2)—C(16)—C(15)—C(19) | −64.5 (4) | C(16)—C(15)—W(2)—C(18) | −80.1 (3) |
W(2)—C(16)—C(17)—C(18) | 64.3 (3) | C(16)—C(15)—W(2)—C(19) | −117.1 (5) |
W(2)—C(17)—C(16)—C(15) | −64.8 (4) | C(16)—C(15)—W(2)—C(27) | 101.3 (3) |
W(2)—C(17)—C(18)—C(19) | 67.3 (4) | C(16)—C(15)—W(2)—C(28) | 66.3 (3) |
W(2)—C(18)—C(17)—C(16) | −65.3 (4) | C(16)—C(15)—C(19)—C(18) | 2.5 (6) |
W(2)—C(18)—C(19)—C(15) | 62.0 (4) | C(16)—C(15)—C(19)—C(20) | −170.8 (5) |
W(2)—C(18)—C(19)—C(20) | −124.9 (5) | C(16)—C(17)—W(2)—C(18) | 115.1 (5) |
W(2)—C(19)—C(15)—C(16) | 62.8 (4) | C(16)—C(17)—W(2)—C(19) | 78.0 (3) |
W(2)—C(19)—C(18)—C(17) | −64.8 (3) | C(16)—C(17)—W(2)—C(27) | −30.2 (4) |
W(2)—C(27)—Ir(1)—C(1) | −106.4 (2) | C(16)—C(17)—W(2)—C(28) | −65.9 (3) |
W(2)—C(27)—Ir(1)—C(2) | 84.3 (9) | C(16)—C(17)—C(18)—C(19) | 2.1 (6) |
W(2)—C(27)—Ir(1)—C(5) | 162.5 (1) | C(17)—W(2)—Ir(2)—C(28) | 93.5 (2) |
W(2)—C(27)—Ir(1)—C(6) | −18.0 (2) | C(17)—W(2)—C(15)—C(19) | 79.8 (3) |
W(2)—C(27)—W(1)—C(5) | −99.3 (3) | C(17)—W(2)—C(18)—C(19) | −115.9 (5) |
W(2)—C(27)—W(1)—C(7) | −17.8 (3) | C(17)—W(2)—C(19)—C(18) | 38.2 (3) |
W(2)—C(27)—W(1)—C(9) | −177.4 (3) | C(17)—W(2)—C(19)—C(20) | 159.8 (6) |
W(2)—C(27)—W(1)—C(10) | −179.7 (2) | C(17)—W(2)—C(27)—C(26) | 60.4 (4) |
W(2)—C(27)—W(1)—C(11) | 148.8 (2) | C(17)—W(2)—C(27)—C(28) | −64.5 (3) |
W(2)—C(27)—W(1)—C(12) | 116.5 (2) | C(17)—W(2)—C(28)—C(27) | 136.1 (3) |
W(2)—C(27)—W(1)—C(13) | 113.8 (3) | C(17)—W(2)—C(28)—C(29) | 11.1 (4) |
W(2)—C(27)—W(1)—C(28) | 48.6 (2) | C(17)—C(16)—W(2)—C(18) | −38.5 (3) |
W(2)—C(27)—C(26)—C(21) | −48.6 (6) | C(17)—C(16)—W(2)—C(19) | −79.9 (4) |
W(2)—C(27)—C(26)—C(25) | 128.0 (4) | C(17)—C(16)—W(2)—C(27) | 158.6 (3) |
W(2)—C(27)—C(28)—C(29) | 105.8 (5) | C(17)—C(16)—W(2)—C(28) | 122.0 (3) |
W(2)—C(28)—Ir(2)—C(3) | 123.0 (2) | C(17)—C(16)—C(15)—C(19) | −1.2 (6) |
W(2)—C(28)—Ir(2)—C(4) | −61.4 (9) | C(17)—C(18)—W(2)—C(19) | 115.9 (5) |
W(2)—C(28)—Ir(2)—C(7) | −144.7 (1) | C(17)—C(18)—W(2)—C(27) | 82.4 (5) |
W(2)—C(28)—Ir(2)—C(8) | 28.5 (2) | C(17)—C(18)—W(2)—C(28) | −1.8 (5) |
W(2)—C(28)—W(1)—C(5) | −10.5 (3) | C(17)—C(18)—C(19)—C(20) | 170.3 (5) |
W(2)—C(28)—W(1)—C(7) | 79.7 (3) | C(18)—W(2)—Ir(1)—C(27) | −147.5 (3) |
W(2)—C(28)—W(1)—C(9) | −169.0 (3) | C(18)—W(2)—Ir(2)—C(28) | 136.4 (2) |
W(2)—C(28)—W(1)—C(10) | −118.1 (3) | C(18)—W(2)—C(15)—C(19) | 37.1 (3) |
W(2)—C(28)—W(1)—C(11) | −134.2 (2) | C(18)—W(2)—C(19)—C(20) | 121.6 (7) |
W(2)—C(28)—W(1)—C(12) | −170.0 (2) | C(18)—W(2)—C(27)—C(26) | 4.7 (6) |
W(2)—C(28)—W(1)—C(13) | 166.3 (2) | C(18)—W(2)—C(27)—C(28) | −120.2 (4) |
W(2)—C(28)—W(1)—C(27) | −49.3 (2) | C(18)—W(2)—C(28)—C(27) | 137.2 (3) |
W(2)—C(28)—C(27)—C(26) | −112.0 (5) | C(18)—W(2)—C(28)—C(29) | 12.2 (5) |
W(2)—C(28)—C(29)—C(30) | −57.9 (5) | C(18)—C(17)—W(2)—C(19) | −37.1 (3) |
W(2)—C(28)—C(29)—C(34) | 120.6 (4) | C(18)—C(17)—W(2)—C(27) | −145.2 (3) |
O(5)—C(5)—Ir(1)—C(1) | 48.1 (5) | C(18)—C(17)—W(2)—C(28) | 179.0 (3) |
O(5)—C(5)—Ir(1)—C(2) | −46.5 (5) | C(18)—C(19)—W(2)—C(27) | 164.3 (3) |
O(5)—C(5)—Ir(1)—C(27) | 145.3 (5) | C(18)—C(19)—W(2)—C(28) | 122.6 (4) |
O(5)—C(5)—W(1)—C(7) | 85 (1) | C(19)—W(2)—Ir(1)—C(27) | −108.4 (2) |
O(5)—C(5)—W(1)—C(9) | −2 (1) | C(19)—W(2)—Ir(2)—C(28) | 179.4 (5) |
O(5)—C(5)—W(1)—C(10) | −38 (1) | C(19)—W(2)—C(27)—C(26) | −17.7 (4) |
O(5)—C(5)—W(1)—C(11) | −54 (1) | C(19)—W(2)—C(27)—C(28) | −142.6 (3) |
O(5)—C(5)—W(1)—C(12) | −23 (1) | C(19)—W(2)—C(28)—C(27) | 68.2 (4) |
O(5)—C(5)—W(1)—C(13) | 11 (1) | C(19)—W(2)—C(28)—C(29) | −56.7 (5) |
O(5)—C(5)—W(1)—C(27) | −150 (1) | C(19)—C(15)—W(2)—C(27) | −141.6 (3) |
O(5)—C(5)—W(1)—C(28) | −172 (1) | C(19)—C(15)—W(2)—C(28) | −176.6 (3) |
O(6)—C(6)—Ir(1)—C(1) | −60.1 (5) | C(19)—C(18)—W(2)—C(27) | −33.5 (6) |
O(6)—C(6)—Ir(1)—C(2) | 34.7 (5) | C(19)—C(18)—W(2)—C(28) | −117.7 (4) |
O(6)—C(6)—Ir(1)—C(27) | −157.1 (4) | C(20)—C(19)—W(2)—C(27) | −74.0 (5) |
O(6)—C(6)—W(2)—C(8) | −81 (1) | C(20)—C(19)—W(2)—C(28) | −115.7 (5) |
O(6)—C(6)—W(2)—C(15) | 57 (1) | C(21)—C(22)—C(23)—C(24) | 4.0 (9) |
O(6)—C(6)—W(2)—C(16) | 36 (1) | C(21)—C(26)—C(25)—C(24) | 3.6 (7) |
O(6)—C(6)—W(2)—C(17) | −7 (1) | C(21)—C(26)—C(27)—C(28) | 39.3 (7) |
O(6)—C(6)—W(2)—C(18) | 1 (1) | C(22)—C(21)—C(26)—C(25) | −2.6 (7) |
O(6)—C(6)—W(2)—C(19) | 35 (1) | C(22)—C(21)—C(26)—C(27) | 174.1 (5) |
O(6)—C(6)—W(2)—C(27) | 157 (1) | C(22)—C(23)—C(24)—C(25) | −3.1 (9) |
O(6)—C(6)—W(2)—C(28) | −172 (1) | C(23)—C(22)—C(21)—C(26) | −1.1 (8) |
O(7)—C(7)—Ir(2)—C(3) | −67.4 (5) | C(23)—C(24)—C(25)—C(26) | −0.8 (8) |
O(7)—C(7)—Ir(2)—C(4) | 25.2 (4) | C(24)—C(25)—C(26)—C(27) | −173.4 (5) |
O(7)—C(7)—Ir(2)—C(28) | −166.7 (4) | C(25)—C(26)—C(27)—C(28) | −144.1 (5) |
O(7)—C(7)—W(1)—C(5) | −69 (1) | C(26)—C(27)—W(1)—C(28) | −125.7 (4) |
O(7)—C(7)—W(1)—C(9) | 14 (1) | C(26)—C(27)—W(2)—C(28) | 124.9 (4) |
O(7)—C(7)—W(1)—C(10) | 5 (1) | C(26)—C(27)—C(28)—C(29) | −6.2 (8) |
O(7)—C(7)—W(1)—C(11) | 45 (1) | C(27)—Ir(1)—Ir(2)—C(28) | −1.2 (2) |
O(7)—C(7)—W(1)—C(12) | 69 (1) | C(27)—Ir(1)—W(1)—C(28) | −37.1 (2) |
O(7)—C(7)—W(1)—C(13) | 49 (1) | C(27)—Ir(1)—W(2)—C(28) | 36.2 (2) |
O(7)—C(7)—W(1)—C(27) | −155 (1) | C(27)—W(1)—Ir(2)—C(28) | 36.4 (2) |
O(7)—C(7)—W(1)—C(28) | 170 (1) | C(27)—W(1)—C(28)—C(29) | 123.8 (4) |
O(8)—C(8)—Ir(2)—C(3) | 43.0 (5) | C(27)—W(2)—Ir(2)—C(28) | −36.7 (2) |
O(8)—C(8)—Ir(2)—C(4) | −49.8 (5) | C(27)—W(2)—C(28)—C(29) | −125.0 (4) |
O(8)—C(8)—Ir(2)—C(28) | 142.2 (5) | C(27)—C(28)—C(29)—C(30) | −143.2 (5) |
O(8)—C(8)—W(2)—C(6) | 94 (1) | C(27)—C(28)—C(29)—C(34) | 35.3 (7) |
O(8)—C(8)—W(2)—C(15) | −16 (1) | C(28)—C(29)—C(30)—C(31) | 178.7 (5) |
O(8)—C(8)—W(2)—C(16) | −46 (1) | C(28)—C(29)—C(34)—C(33) | −177.7 (5) |
O(8)—C(8)—W(2)—C(17) | −29.7 (9) | C(29)—C(30)—C(31)—C(32) | −1.5 (9) |
O(8)—C(8)—W(2)—C(18) | 7.0 (9) | C(29)—C(34)—C(33)—C(32) | −0.6 (9) |
O(8)—C(8)—W(2)—C(19) | 19 (1) | C(30)—C(29)—C(34)—C(33) | 0.9 (7) |
O(8)—C(8)—W(2)—C(27) | −165.8 (9) | C(30)—C(31)—C(32)—C(33) | 1.7 (9) |
O(8)—C(8)—W(2)—C(28) | −142 (1) | C(31)—C(30)—C(29)—C(34) | 0.2 (8) |
C(1)—Ir(1)—Ir(2)—C(3) | 86 (1) | C(31)—C(32)—C(33)—C(34) | −0.7 (9) |
C(1)—Ir(1)—Ir(2)—C(4) | −141.4 (8) |
Symmetry codes: (i) x, −y+1/2, z−1/2; (ii) −x, −y, −z; (iii) −x, −y+1, −z; (iv) x, y−1, z; (v) −x, y−1/2, −z+1/2; (vi) x, −y+1/2, z+1/2; (vii) −x+1, −y, −z. |
Experimental details
Crystal data | |
Chemical formula | [W2Ir2(C6H7)2(C14H10)(CO)10] |
Mr | 1312.70 |
Crystal system, space group | Monoclinic, P21/c |
Temperature (K) | 200 |
a, b, c (Å) | 16.8073 (1), 9.5849 (1), 19.0626 (2) |
β (°) | 90.8932 (6) |
V (Å3) | 3070.54 (4) |
Z | 4 |
Radiation type | Mo Kα |
µ (mm−1) | 16.20 |
Crystal size (mm) | 0.30 × 0.25 × 0.10 |
Data collection | |
Diffractometer | Nonius KappaCCD diffractometer |
Absorption correction | Integration [Gaussian (Coppens, 1970) implemented in maXus (1999)] |
Tmin, Tmax | 0.050, 0.327 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 90662, 8980, 7429 |
Rint | 0.077 |
(sin θ/λ)max (Å−1) | 0.704 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.026, 0.030, 0.82 |
No. of reflections | 7429 |
No. of parameters | 415 |
H-atom treatment | H-atom parameters not refined |
Δρmax, Δρmin (e Å−3) | 1.36, −2.33 |
Computer programs: KappaCCD Software (Nonius, 1999), HKL SCALEPACK (Otwinowski & Minor 1997), DENZO and SCALEPACK (Otwinowski & Minor, 1997), PATTY in DIRDIF92 (Beurskens et al., 1992), TEXSAN (Molecular Structure Corporation, 1997), TEXSAN.
Ir(1)—Ir(2) | 2.6951 (2) | Ir(2)—C(28) | 2.138 (4) |
Ir(1)—W(1) | 2.8145 (2) | W(1)—C(27) | 2.331 (4) |
Ir(1)—W(2) | 2.7804 (2) | W(1)—C(28) | 2.353 (4) |
Ir(1)—C(27) | 2.125 (4) | W(2)—C(27) | 2.369 (4) |
Ir(2)—W(1) | 2.8018 (2) | W(2)—C(28) | 2.345 (4) |
Ir(2)—W(2) | 2.8109 (3) | C(27)—C(28) | 1.487 (6) |
Ir(2)—Ir(1)—C(27) | 73.9 (1) | Ir(1)—C(27)—C(28) | 106.3 (3) |
Ir(1)—Ir(2)—C(28) | 73.2 (1) | Ir(2)—C(28)—C(27) | 106.6 (3) |
The chemistry of the cyclopentadienyl-ligated tetrahedral mixed-metal cluster W2Ir2(CO)10(η5-C5H5)2 with alkynes has been examined in order to enhance understanding of how alumina-supported bimetallic W–Ir particles behave; in particular, diphenylacetylene reacts with this ditungstendiiridium cluster to afford W2Ir2(µ4-η2-C2Ph2)(CO)8(η-C5H5)2 (Shapley et al., 1984). We have now investigated the reaction of the methylcyclopentadienyl-ligated cluster analogue W2Ir2(CO)10(η5-C5H4Me)2 (Lucas et al., 2001) with diphenylacetylene, and structurally characterized the product, (I). The alkyne formally inserts into the W—W bond of the precursor tetrahedral W2Ir2 cluster to afford a closo-octahedral W2Ir2C2 cluster. The W2Ir2C2 core bond distances in the title complex are essentially identical to those of the phenylacetylene-containing analogue W2Ir2(µ4-η2-PhC2H)(µ-CO)4(CO)4(η-C5H5)2 (Waterman et al., 1998).