metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890

Tetra­chloridobis(di­benzyl sulfoxide-κO)tin(IV)

aDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
*Correspondence e-mail: seikweng@um.edu.my

(Received 20 April 2011; accepted 26 April 2011; online 7 May 2011)

The six-coordinate SnIV atom in the title compound, [SnCl4(C14H14OS)2], exists in a cis-SnCl4O2 octa­hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn—Cl bonds involving these two Cl atoms are longer than the other two Sn—Cl bonds.

Related literature

For the SnCl4(DMSO)2 adduct (DMSO is dimethyl sulfoxide), see: Kisenyi et al. (1985[Kisenyi, J. M., Willey, G. R. & Drew, M. G. B. (1985). Acta Cryst. C41, 700-702.]). For the tetra­hydro­thio­phene-1-oxide adduct, see: Howie et al. (2010[Howie, R. H., Harrison, W. T. A., de Lima, G. M., Wardell, J. L. & Wardell, S. M. S. V. (2010). Z. Kristallogr. 225, 448-455.]).

[Scheme 1]

Experimental

Crystal data
  • [SnCl4(C14H14OS)2]

  • Mr = 721.11

  • Triclinic, [P \overline 1]

  • a = 10.7982 (1) Å

  • b = 11.1469 (1) Å

  • c = 14.9456 (2) Å

  • α = 80.8623 (6)°

  • β = 87.8310 (5)°

  • γ = 61.4279 (6)°

  • V = 1558.31 (3) Å3

  • Z = 2

  • Mo Kα radiation

  • μ = 1.32 mm−1

  • T = 100 K

  • 0.30 × 0.30 × 0.30 mm

Data collection
  • Bruker SMART APEX diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.]) Tmin = 0.693, Tmax = 0.693

  • 14537 measured reflections

  • 7139 independent reflections

  • 6609 reflections with I > 2σ(I)

  • Rint = 0.019

Refinement
  • R[F2 > 2σ(F2)] = 0.028

  • wR(F2) = 0.073

  • S = 1.05

  • 7139 reflections

  • 334 parameters

  • H-atom parameters constrained

  • Δρmax = 0.83 e Å−3

  • Δρmin = −1.02 e Å−3

Data collection: APEX2 (Bruker, 2009[Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2009[Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: X-SEED (Barbour, 2001[Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).

Supporting information


Comment top

The attempted synthesis of the dibenzyl sulfoxide adduct of dibenzyltin chloride resulted in the cleavage both tin-carbon bonds to yield the 1:2 stannic chloride–dibenzyl sulfoxide adduct (Scheme I, Fig. 1). The six-coordinate SnIV atom exists in cis-SnCl4O2 octahedral geometry (Fig. 1). The adduct exists as a discrete molecule and there are no chlorine···chlorine contacts. The corresponding DMSO adduct shows a similar geometry (Kisenyi et al., 1985) as does the tetrahydrothiophenene-1-oxide adduct (Howie et al., 2010).

Related literature top

For the SnCl4(DMSO)2 adduct, see: Kisenyi et al. (1985). For the tetrahydrothiophene-1-oxide adduct, see: Howie et al. (2010).

Experimental top

Dibenzyltin dichloride (0.37 g, 1 mmol) and dibenzylsulfoxide (0.46 g, 2 mmol) were heated in ethanol (100 ml) for an hour. The solution was filtered and then set aside for the growth of colorless crystals.

Refinement top

H-atoms were placed in calculated positions (C—H 0.95 to 0.99 Å) and were included in the refinement in the riding model approximation, with U(H) set to 1.2 times Ueq(C). In the final difference Fourier map, the large peak is in the vicinity of Sn1 and the deepest hole is in the vicinity of the same atom.

Computing details top

Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2010).

Figures top
[Figure 1] Fig. 1. Anisotropic displacement ellipsoid plot (Barbour, 2001) of SnCl4(C14H14OS)2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
Tetrachloridobis(dibenzyl sulfoxide-κO)tin(IV) top
Crystal data top
[SnCl4(C14H14OS)2]Z = 2
Mr = 721.11F(000) = 724
Triclinic, P1Dx = 1.537 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 10.7982 (1) ÅCell parameters from 9933 reflections
b = 11.1469 (1) Åθ = 2.3–28.3°
c = 14.9456 (2) ŵ = 1.32 mm1
α = 80.8623 (6)°T = 100 K
β = 87.8310 (5)°Cuboic, colorless
γ = 61.4279 (6)°0.30 × 0.30 × 0.30 mm
V = 1558.31 (3) Å3
Data collection top
Bruker SMART APEX
diffractometer
7139 independent reflections
Radiation source: fine-focus sealed tube6609 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.019
ω scansθmax = 27.5°, θmin = 1.4°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1414
Tmin = 0.693, Tmax = 0.693k = 1414
14537 measured reflectionsl = 1919
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.028Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.073H-atom parameters constrained
S = 1.05 w = 1/[σ2(Fo2) + (0.0353P)2 + 1.7363P]
where P = (Fo2 + 2Fc2)/3
7139 reflections(Δ/σ)max = 0.001
334 parametersΔρmax = 0.83 e Å3
0 restraintsΔρmin = 1.02 e Å3
Crystal data top
[SnCl4(C14H14OS)2]γ = 61.4279 (6)°
Mr = 721.11V = 1558.31 (3) Å3
Triclinic, P1Z = 2
a = 10.7982 (1) ÅMo Kα radiation
b = 11.1469 (1) ŵ = 1.32 mm1
c = 14.9456 (2) ÅT = 100 K
α = 80.8623 (6)°0.30 × 0.30 × 0.30 mm
β = 87.8310 (5)°
Data collection top
Bruker SMART APEX
diffractometer
7139 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
6609 reflections with I > 2σ(I)
Tmin = 0.693, Tmax = 0.693Rint = 0.019
14537 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0280 restraints
wR(F2) = 0.073H-atom parameters constrained
S = 1.05Δρmax = 0.83 e Å3
7139 reflectionsΔρmin = 1.02 e Å3
334 parameters
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.596648 (15)0.444875 (15)0.252840 (10)0.01653 (5)
Cl10.38718 (6)0.50368 (6)0.34078 (4)0.02255 (12)
Cl20.73128 (6)0.23980 (6)0.35805 (4)0.02240 (12)
Cl30.79172 (6)0.41742 (6)0.16256 (4)0.02173 (11)
Cl40.51422 (7)0.34402 (7)0.15481 (4)0.02784 (13)
S10.46614 (6)0.65868 (6)0.06715 (4)0.01692 (11)
S20.63003 (5)0.55337 (5)0.43151 (4)0.01626 (11)
O10.47446 (16)0.64050 (16)0.17213 (10)0.0186 (3)
O20.63931 (16)0.56674 (16)0.32657 (10)0.0180 (3)
C10.4837 (2)0.8131 (2)0.03527 (16)0.0220 (5)
H1A0.45050.85340.02870.026*
H1B0.42540.88280.07390.026*
C20.6361 (2)0.7760 (2)0.04695 (17)0.0230 (5)
C30.7306 (3)0.7160 (3)0.01962 (17)0.0261 (5)
H30.69700.70400.07360.031*
C40.8721 (3)0.6743 (3)0.0072 (2)0.0336 (6)
H40.93590.63320.05240.040*
C50.9213 (3)0.6923 (3)0.0710 (2)0.0390 (7)
H51.01880.66340.07950.047*
C60.8287 (3)0.7522 (3)0.1369 (2)0.0375 (6)
H60.86270.76550.19030.045*
C70.6863 (3)0.7931 (3)0.12542 (19)0.0294 (5)
H70.62320.83280.17130.035*
C80.2791 (2)0.7253 (3)0.04071 (16)0.0219 (5)
H8A0.25870.76690.02420.026*
H8B0.25800.64710.05020.026*
C90.1836 (2)0.8315 (2)0.09659 (16)0.0211 (5)
C100.1443 (2)0.7906 (3)0.18065 (17)0.0250 (5)
H100.17880.69490.20270.030*
C110.0553 (3)0.8881 (3)0.23263 (18)0.0307 (6)
H110.02950.85890.29020.037*
C120.0036 (3)1.0280 (3)0.2011 (2)0.0334 (6)
H120.05751.09480.23670.040*
C130.0418 (3)1.0697 (3)0.1173 (2)0.0305 (6)
H130.00641.16550.09540.037*
C140.1313 (3)0.9726 (3)0.06500 (18)0.0258 (5)
H140.15721.00220.00760.031*
C150.7840 (2)0.5654 (2)0.46182 (16)0.0207 (4)
H15A0.78770.64330.42190.025*
H15B0.78040.58120.52540.025*
C160.9120 (2)0.4305 (3)0.45052 (17)0.0224 (5)
C170.9583 (3)0.3185 (3)0.52021 (19)0.0289 (5)
H170.91210.32810.57600.035*
C181.0721 (3)0.1923 (3)0.5085 (2)0.0358 (6)
H181.10320.11560.55620.043*
C191.1403 (3)0.1780 (3)0.4276 (2)0.0377 (7)
H191.21880.09180.42000.045*
C201.0945 (3)0.2887 (3)0.3583 (2)0.0397 (7)
H201.14110.27860.30260.048*
C210.9800 (3)0.4155 (3)0.36924 (18)0.0302 (6)
H210.94850.49160.32110.036*
C220.4876 (2)0.7197 (2)0.45106 (16)0.0209 (4)
H22A0.39740.71740.44830.025*
H22B0.50110.73320.51320.025*
C230.4757 (2)0.8415 (2)0.38565 (16)0.0190 (4)
C240.3880 (2)0.8883 (2)0.30771 (16)0.0227 (5)
H240.34030.83970.29480.027*
C250.3701 (3)1.0057 (3)0.24878 (18)0.0310 (6)
H250.30871.03850.19640.037*
C260.4414 (3)1.0743 (3)0.2664 (2)0.0361 (6)
H260.42901.15430.22580.043*
C270.5305 (3)1.0283 (3)0.3421 (2)0.0373 (7)
H270.58051.07560.35310.045*
C280.5472 (3)0.9122 (3)0.40263 (19)0.0281 (5)
H280.60730.88120.45550.034*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.01704 (8)0.01775 (8)0.01609 (8)0.00884 (6)0.00230 (5)0.00479 (6)
Cl10.0173 (2)0.0304 (3)0.0187 (2)0.0110 (2)0.00222 (19)0.0022 (2)
Cl20.0230 (3)0.0175 (2)0.0230 (3)0.0069 (2)0.0030 (2)0.0033 (2)
Cl30.0194 (3)0.0212 (3)0.0227 (3)0.0080 (2)0.0060 (2)0.0054 (2)
Cl40.0408 (3)0.0343 (3)0.0217 (3)0.0275 (3)0.0037 (2)0.0089 (2)
S10.0149 (2)0.0185 (3)0.0168 (2)0.0072 (2)0.00010 (18)0.00387 (19)
S20.0157 (2)0.0143 (2)0.0170 (2)0.0053 (2)0.00029 (18)0.00397 (19)
O10.0186 (8)0.0201 (8)0.0166 (7)0.0080 (6)0.0013 (6)0.0057 (6)
O20.0187 (8)0.0192 (8)0.0167 (7)0.0091 (6)0.0022 (6)0.0050 (6)
C10.0229 (11)0.0199 (11)0.0238 (11)0.0110 (9)0.0006 (9)0.0024 (9)
C20.0210 (11)0.0222 (11)0.0277 (12)0.0127 (10)0.0005 (9)0.0015 (9)
C30.0250 (12)0.0276 (12)0.0287 (12)0.0150 (10)0.0045 (10)0.0053 (10)
C40.0252 (13)0.0325 (14)0.0443 (16)0.0150 (11)0.0114 (11)0.0076 (12)
C50.0230 (13)0.0426 (17)0.0575 (19)0.0210 (13)0.0022 (12)0.0066 (14)
C60.0311 (14)0.0475 (17)0.0430 (16)0.0254 (13)0.0047 (12)0.0085 (13)
C70.0284 (13)0.0331 (14)0.0331 (13)0.0188 (11)0.0038 (10)0.0094 (11)
C80.0152 (10)0.0269 (12)0.0244 (11)0.0095 (9)0.0021 (8)0.0075 (9)
C90.0120 (10)0.0251 (12)0.0250 (11)0.0072 (9)0.0019 (8)0.0059 (9)
C100.0175 (11)0.0263 (12)0.0287 (12)0.0086 (10)0.0006 (9)0.0039 (10)
C110.0231 (12)0.0369 (15)0.0272 (13)0.0104 (11)0.0055 (10)0.0059 (11)
C120.0240 (13)0.0346 (15)0.0388 (15)0.0092 (11)0.0083 (11)0.0165 (12)
C130.0202 (12)0.0240 (12)0.0442 (15)0.0075 (10)0.0032 (10)0.0082 (11)
C140.0186 (11)0.0268 (12)0.0288 (12)0.0088 (10)0.0003 (9)0.0024 (10)
C150.0179 (10)0.0185 (11)0.0246 (11)0.0067 (9)0.0013 (8)0.0066 (9)
C160.0156 (10)0.0241 (12)0.0268 (12)0.0072 (9)0.0015 (9)0.0094 (9)
C170.0222 (12)0.0270 (13)0.0326 (13)0.0072 (10)0.0005 (10)0.0070 (10)
C180.0272 (14)0.0254 (13)0.0441 (16)0.0041 (11)0.0076 (12)0.0028 (12)
C190.0205 (13)0.0331 (15)0.0479 (17)0.0003 (11)0.0049 (11)0.0187 (13)
C200.0239 (13)0.0480 (18)0.0355 (15)0.0049 (13)0.0027 (11)0.0174 (13)
C210.0240 (12)0.0341 (14)0.0273 (13)0.0087 (11)0.0005 (10)0.0082 (11)
C220.0191 (11)0.0151 (10)0.0226 (11)0.0032 (9)0.0040 (8)0.0051 (9)
C230.0173 (10)0.0158 (10)0.0231 (11)0.0062 (8)0.0042 (8)0.0081 (8)
C240.0207 (11)0.0186 (11)0.0263 (12)0.0062 (9)0.0010 (9)0.0078 (9)
C250.0342 (14)0.0223 (12)0.0239 (12)0.0040 (11)0.0007 (10)0.0022 (10)
C260.0357 (15)0.0210 (12)0.0437 (16)0.0098 (11)0.0121 (12)0.0007 (11)
C270.0305 (14)0.0231 (13)0.065 (2)0.0169 (11)0.0101 (13)0.0136 (13)
C280.0211 (12)0.0222 (12)0.0411 (15)0.0083 (10)0.0038 (10)0.0111 (11)
Geometric parameters (Å, º) top
Sn1—O22.0938 (16)C11—H110.9500
Sn1—O12.1176 (16)C12—C131.383 (4)
Sn1—Cl32.3772 (5)C12—H120.9500
Sn1—Cl22.3800 (6)C13—C141.389 (4)
Sn1—Cl42.4045 (6)C13—H130.9500
Sn1—Cl12.4297 (5)C14—H140.9500
S1—O11.5502 (16)C15—C161.508 (3)
S1—C11.809 (2)C15—H15A0.9900
S1—C81.822 (2)C15—H15B0.9900
S2—O21.5558 (16)C16—C211.386 (4)
S2—C151.810 (2)C16—C171.387 (4)
S2—C221.816 (2)C17—C181.388 (4)
C1—C21.503 (3)C17—H170.9500
C1—H1A0.9900C18—C191.382 (4)
C1—H1B0.9900C18—H180.9500
C2—C71.387 (4)C19—C201.375 (5)
C2—C31.400 (3)C19—H190.9500
C3—C41.379 (4)C20—C211.393 (4)
C3—H30.9500C20—H200.9500
C4—C51.383 (4)C21—H210.9500
C4—H40.9500C22—C231.495 (3)
C5—C61.383 (4)C22—H22A0.9900
C5—H50.9500C22—H22B0.9900
C6—C71.388 (4)C23—C281.393 (3)
C6—H60.9500C23—C241.394 (3)
C7—H70.9500C24—C251.390 (4)
C8—C91.498 (3)C24—H240.9500
C8—H8A0.9900C25—C261.374 (4)
C8—H8B0.9900C25—H250.9500
C9—C101.389 (3)C26—C271.377 (5)
C9—C141.397 (3)C26—H260.9500
C10—C111.386 (4)C27—C281.394 (4)
C10—H100.9500C27—H270.9500
C11—C121.386 (4)C28—H280.9500
O2—Sn1—O181.00 (6)C10—C11—H11119.8
O2—Sn1—Cl388.98 (4)C12—C11—H11119.8
O1—Sn1—Cl388.48 (4)C13—C12—C11119.5 (3)
O2—Sn1—Cl292.70 (4)C13—C12—H12120.3
O1—Sn1—Cl2173.13 (4)C11—C12—H12120.3
Cl3—Sn1—Cl294.17 (2)C12—C13—C14120.5 (3)
O2—Sn1—Cl4169.67 (5)C12—C13—H13119.7
O1—Sn1—Cl488.95 (4)C14—C13—H13119.7
Cl3—Sn1—Cl493.16 (2)C13—C14—C9120.2 (2)
Cl2—Sn1—Cl497.22 (2)C13—C14—H14119.9
O2—Sn1—Cl186.64 (4)C9—C14—H14119.9
O1—Sn1—Cl185.29 (4)C16—C15—S2107.39 (16)
Cl3—Sn1—Cl1172.87 (2)C16—C15—H15A110.2
Cl2—Sn1—Cl191.656 (19)S2—C15—H15A110.2
Cl4—Sn1—Cl190.18 (2)C16—C15—H15B110.2
O1—S1—C1101.73 (10)S2—C15—H15B110.2
O1—S1—C8103.26 (10)H15A—C15—H15B108.5
C1—S1—C8101.23 (11)C21—C16—C17119.5 (2)
O2—S2—C15100.62 (10)C21—C16—C15120.5 (2)
O2—S2—C22104.75 (10)C17—C16—C15119.9 (2)
C15—S2—C22101.73 (11)C16—C17—C18120.1 (3)
S1—O1—Sn1121.84 (9)C16—C17—H17119.9
S2—O2—Sn1121.81 (9)C18—C17—H17119.9
C2—C1—S1108.98 (16)C19—C18—C17120.2 (3)
C2—C1—H1A109.9C19—C18—H18119.9
S1—C1—H1A109.9C17—C18—H18119.9
C2—C1—H1B109.9C20—C19—C18119.9 (3)
S1—C1—H1B109.9C20—C19—H19120.1
H1A—C1—H1B108.3C18—C19—H19120.1
C7—C2—C3119.4 (2)C19—C20—C21120.3 (3)
C7—C2—C1120.7 (2)C19—C20—H20119.8
C3—C2—C1119.8 (2)C21—C20—H20119.8
C4—C3—C2120.3 (2)C16—C21—C20119.9 (3)
C4—C3—H3119.9C16—C21—H21120.0
C2—C3—H3119.9C20—C21—H21120.0
C3—C4—C5120.0 (3)C23—C22—S2114.98 (16)
C3—C4—H4120.0C23—C22—H22A108.5
C5—C4—H4120.0S2—C22—H22A108.5
C4—C5—C6120.2 (3)C23—C22—H22B108.5
C4—C5—H5119.9S2—C22—H22B108.5
C6—C5—H5119.9H22A—C22—H22B107.5
C5—C6—C7120.2 (3)C28—C23—C24119.2 (2)
C5—C6—H6119.9C28—C23—C22121.2 (2)
C7—C6—H6119.9C24—C23—C22119.6 (2)
C6—C7—C2120.0 (3)C25—C24—C23120.2 (2)
C6—C7—H7120.0C25—C24—H24119.9
C2—C7—H7120.0C23—C24—H24119.9
C9—C8—S1113.76 (16)C26—C25—C24119.9 (3)
C9—C8—H8A108.8C26—C25—H25120.1
S1—C8—H8A108.8C24—C25—H25120.1
C9—C8—H8B108.8C25—C26—C27120.8 (3)
S1—C8—H8B108.8C25—C26—H26119.6
H8A—C8—H8B107.7C27—C26—H26119.6
C10—C9—C14118.9 (2)C26—C27—C28119.8 (3)
C10—C9—C8120.2 (2)C26—C27—H27120.1
C14—C9—C8120.9 (2)C28—C27—H27120.1
C11—C10—C9120.6 (2)C23—C28—C27120.0 (2)
C11—C10—H10119.7C23—C28—H28120.0
C9—C10—H10119.7C27—C28—H28120.0
C10—C11—C12120.3 (2)
C1—S1—O1—Sn1136.20 (11)C9—C10—C11—C120.3 (4)
C8—S1—O1—Sn1119.12 (11)C10—C11—C12—C130.1 (4)
O2—Sn1—O1—S1140.81 (11)C11—C12—C13—C140.2 (4)
Cl3—Sn1—O1—S151.60 (10)C12—C13—C14—C90.2 (4)
Cl4—Sn1—O1—S141.59 (10)C10—C9—C14—C130.1 (4)
Cl1—Sn1—O1—S1131.86 (10)C8—C9—C14—C13179.4 (2)
C15—S2—O2—Sn1138.94 (11)O2—S2—C15—C1673.55 (17)
C22—S2—O2—Sn1115.80 (11)C22—S2—C15—C16178.78 (16)
O1—Sn1—O2—S2132.52 (11)S2—C15—C16—C2192.2 (2)
Cl3—Sn1—O2—S2138.85 (10)S2—C15—C16—C1784.7 (2)
Cl2—Sn1—O2—S244.73 (10)C21—C16—C17—C180.1 (4)
Cl4—Sn1—O2—S2119.0 (2)C15—C16—C17—C18177.0 (2)
Cl1—Sn1—O2—S246.77 (10)C16—C17—C18—C190.4 (4)
O1—S1—C1—C277.36 (18)C17—C18—C19—C200.6 (4)
C8—S1—C1—C2176.37 (17)C18—C19—C20—C210.3 (5)
S1—C1—C2—C796.3 (2)C17—C16—C21—C200.4 (4)
S1—C1—C2—C380.0 (2)C15—C16—C21—C20177.3 (2)
C7—C2—C3—C40.1 (4)C19—C20—C21—C160.2 (4)
C1—C2—C3—C4176.3 (2)O2—S2—C22—C2335.0 (2)
C2—C3—C4—C50.3 (4)C15—S2—C22—C2369.5 (2)
C3—C4—C5—C60.1 (4)S2—C22—C23—C2890.2 (2)
C4—C5—C6—C70.8 (5)S2—C22—C23—C2492.0 (2)
C5—C6—C7—C21.1 (4)C28—C23—C24—C251.3 (4)
C3—C2—C7—C60.6 (4)C22—C23—C24—C25176.6 (2)
C1—C2—C7—C6177.0 (2)C23—C24—C25—C261.4 (4)
O1—S1—C8—C941.3 (2)C24—C25—C26—C270.2 (4)
C1—S1—C8—C963.7 (2)C25—C26—C27—C281.1 (4)
S1—C8—C9—C1086.7 (2)C24—C23—C28—C270.1 (4)
S1—C8—C9—C1494.0 (2)C22—C23—C28—C27177.8 (2)
C14—C9—C10—C110.3 (4)C26—C27—C28—C231.1 (4)
C8—C9—C10—C11179.6 (2)

Experimental details

Crystal data
Chemical formula[SnCl4(C14H14OS)2]
Mr721.11
Crystal system, space groupTriclinic, P1
Temperature (K)100
a, b, c (Å)10.7982 (1), 11.1469 (1), 14.9456 (2)
α, β, γ (°)80.8623 (6), 87.8310 (5), 61.4279 (6)
V3)1558.31 (3)
Z2
Radiation typeMo Kα
µ (mm1)1.32
Crystal size (mm)0.30 × 0.30 × 0.30
Data collection
DiffractometerBruker SMART APEX
diffractometer
Absorption correctionMulti-scan
(SADABS; Sheldrick, 1996)
Tmin, Tmax0.693, 0.693
No. of measured, independent and
observed [I > 2σ(I)] reflections
14537, 7139, 6609
Rint0.019
(sin θ/λ)max1)0.650
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.028, 0.073, 1.05
No. of reflections7139
No. of parameters334
H-atom treatmentH-atom parameters constrained
Δρmax, Δρmin (e Å3)0.83, 1.02

Computer programs: APEX2 (Bruker, 2009), SAINT (Bruker, 2009), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), X-SEED (Barbour, 2001), publCIF (Westrip, 2010).

 

Acknowledgements

We thank the University of Malaya (Ggrant No. RG020/09AFR) for supporting this study.

References

First citationBarbour, L. J. (2001). J. Supramol. Chem. 1, 189–191.  CrossRef CAS Google Scholar
First citationBruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.  Google Scholar
First citationHowie, R. H., Harrison, W. T. A., de Lima, G. M., Wardell, J. L. & Wardell, S. M. S. V. (2010). Z. Kristallogr. 225, 448–455.  CAS Google Scholar
First citationKisenyi, J. M., Willey, G. R. & Drew, M. G. B. (1985). Acta Cryst. C41, 700–702.  CSD CrossRef CAS Web of Science IUCr Journals Google Scholar
First citationSheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.  Google Scholar
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationWestrip, S. P. (2010). J. Appl. Cryst. 43, 920–925.  Web of Science CrossRef CAS IUCr Journals Google Scholar

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds