Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807028966/bt2389sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536807028966/bt2389Isup2.hkl |
CCDC reference: 654993
The title compound was synthesized by a photo-induced reaction between α,α,α-trifluoroacetophenone (0.05M) and an excess amount of 1-phenyl-2-trimethyl-silylacetylene (0.2M) in a acetonitrile solution. The title compound was isolated using silica gel column chromatography. Single crystal suitable for X-ray diffraction analysis were obtained by slow evaporation of the solvents from a petroleum ether-ethyl acetate solution (V:V = 2:1).
The H atoms on C10 were located in a difference map and refined isotropically. The remaining H atoms were positional geometrically and refined as riding, with C—H = 0.93 Å and Uiso(H) = 1.2 Ueq(C). The ratio of the refined occupancies for the major and minor components of the disordered linkage of C7B/C8B/O1B and C7A/C8A/O1A are 0.614 (4): 0.386 (4).
The photochemistry of α,α,α-trifluoroacetophenone is of continuing research interest (van Alem et al., 2005). In continuation of our recent work on photoinduced reactions of ketones with alkynes, the title compound, (I), was obtained by the reaction of photoexcited α,α,α-trifluoroacetophenone with trimethylsilylphenylethyne. A crystallographic analysis of (I) was carried out to elucidate its structure.
Bond lengths and angles in (I) display normal values (Allen et al., 1987). The dihedral angle between the C1—C6 and C11—C16 benzene rings is 4.66 (12)°. The torsion angle of C9—C7A—C8A—C10 and C9—C7B—C8B—C10 are 176.1 (3) and -175.5 (2)°, respectively. The linkage between the two phenyl rings is disordered over two positions.
In the crystal structure, the molecules are interconnected into columns along the b axis by intermolecular C13—H13A···O1B and C5—H5A···O1B interactions (Figure 2 and Table 1) together with intermolecular C12—H12A···O1A interactions (Table 1) and short O1A···O1A (-x, y, 1/2 - z) contacts [2.525 (8) Å] (Figure 3). In addition, the crystal structure is further stabilized by C—H···π interactions involving the C1—C6 (centroid Cg1) and C11—C16 (centroid Cg2) ring (Table 1).
For related literature on values of bond lengths, see: Allen et al. (1987). For a related structure, see: van Alem et al. (2005)
Data collection: APEX2 (Bruker, 2005); cell refinement: APEX2; data reduction: SAINT (Bruker, 2005); program(s) used to solve structure: SHELXTL (Sheldrick, 1998); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL, PARST (Nardelli, 1995) and PLATON (Spek, 2003).
C16H11F3O | F(000) = 1136 |
Mr = 276.25 | Dx = 1.434 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 6048 reflections |
a = 29.1818 (8) Å | θ = 1.7–29.7° |
b = 5.8972 (2) Å | µ = 0.12 mm−1 |
c = 17.8356 (6) Å | T = 100 K |
β = 123.485 (3)° | Neddle, colourless |
V = 2559.92 (17) Å3 | 0.53 × 0.11 × 0.08 mm |
Z = 8 |
Bruker SMART APEX II CCD area-detector diffractometer | 3611 independent reflections |
Radiation source: fine-focus sealed tube | 2817 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.035 |
Detector resolution: 8.33 pixels mm-1 | θmax = 29.7°, θmin = 1.7° |
ω scans | h = −40→40 |
Absorption correction: multi-scan (SADABS; Bruker, 2005) | k = −8→8 |
Tmin = 0.851, Tmax = 0.991 | l = −24→24 |
24392 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.074 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.199 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.07 | w = 1/[σ2(Fo2) + (0.077P)2 + 6.0256P] where P = (Fo2 + 2Fc2)/3 |
3611 reflections | (Δ/σ)max < 0.001 |
217 parameters | Δρmax = 0.53 e Å−3 |
0 restraints | Δρmin = −0.56 e Å−3 |
C16H11F3O | V = 2559.92 (17) Å3 |
Mr = 276.25 | Z = 8 |
Monoclinic, C2/c | Mo Kα radiation |
a = 29.1818 (8) Å | µ = 0.12 mm−1 |
b = 5.8972 (2) Å | T = 100 K |
c = 17.8356 (6) Å | 0.53 × 0.11 × 0.08 mm |
β = 123.485 (3)° |
Bruker SMART APEX II CCD area-detector diffractometer | 3611 independent reflections |
Absorption correction: multi-scan (SADABS; Bruker, 2005) | 2817 reflections with I > 2σ(I) |
Tmin = 0.851, Tmax = 0.991 | Rint = 0.035 |
24392 measured reflections |
R[F2 > 2σ(F2)] = 0.074 | 0 restraints |
wR(F2) = 0.199 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.07 | Δρmax = 0.53 e Å−3 |
3611 reflections | Δρmin = −0.56 e Å−3 |
217 parameters |
Experimental. The data was collected with the Oxford Cyrosystem Cobra low-temperature attachment. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
C1 | 0.18069 (11) | 0.9487 (5) | 0.23530 (19) | 0.0464 (7) | |
H1A | 0.1880 | 1.0725 | 0.2726 | 0.056* | |
C2 | 0.20283 (8) | 0.9398 (4) | 0.18402 (14) | 0.0290 (4) | |
H2A | 0.2253 | 1.0566 | 0.1872 | 0.035* | |
C3 | 0.19152 (8) | 0.7565 (4) | 0.12787 (12) | 0.0265 (4) | |
H3A | 0.2062 | 0.7511 | 0.0929 | 0.032* | |
C4 | 0.15853 (8) | 0.5809 (4) | 0.12336 (13) | 0.0267 (4) | |
H4A | 0.1510 | 0.4581 | 0.0855 | 0.032* | |
C5 | 0.13670 (9) | 0.5889 (4) | 0.17546 (15) | 0.0349 (5) | |
H5A | 0.1148 | 0.4709 | 0.1731 | 0.042* | |
C6 | 0.14771 (11) | 0.7744 (5) | 0.23137 (18) | 0.0509 (8) | |
C7A | 0.1405 (2) | 0.7075 (8) | 0.3129 (3) | 0.0206 (11) | 0.386 (4) |
C8A | 0.0984 (2) | 0.8206 (8) | 0.3060 (3) | 0.0211 (11) | 0.386 (4) |
C7B | 0.12592 (13) | 0.7038 (5) | 0.3454 (2) | 0.0219 (7) | 0.614 (4) |
C8B | 0.11472 (13) | 0.8185 (5) | 0.2723 (2) | 0.0211 (7) | 0.614 (4) |
C9 | 0.17483 (9) | 0.5436 (4) | 0.39318 (14) | 0.0302 (4) | |
F1 | 0.21769 (8) | 0.5581 (4) | 0.38942 (15) | 0.0710 (6) | |
F2 | 0.15724 (7) | 0.3293 (3) | 0.37303 (13) | 0.0622 (5) | |
F3 | 0.19211 (10) | 0.5757 (4) | 0.47726 (12) | 0.0731 (6) | |
C10 | 0.06815 (8) | 0.9881 (4) | 0.23205 (13) | 0.0256 (4) | |
H10A | 0.070 (3) | 1.000 (13) | 0.174 (4) | 0.023 (16)* | 0.386 (4) |
H10B | 0.0408 (14) | 0.983 (7) | 0.252 (2) | 0.013 (8)* | 0.614 (4) |
O1A | 0.03311 (17) | 1.1142 (8) | 0.2254 (3) | 0.0326 (11) | 0.386 (4) |
O1B | 0.06237 (11) | 1.1301 (5) | 0.17911 (18) | 0.0350 (7) | 0.614 (4) |
C11 | 0.08796 (12) | 0.7462 (6) | 0.37994 (18) | 0.0550 (9) | |
C12 | 0.05262 (9) | 0.5710 (4) | 0.36590 (15) | 0.0345 (5) | |
H12A | 0.0471 | 0.4526 | 0.3273 | 0.041* | |
C13 | 0.02536 (8) | 0.5724 (4) | 0.40948 (14) | 0.0288 (4) | |
H13A | 0.0016 | 0.4546 | 0.4002 | 0.035* | |
C14 | 0.03350 (8) | 0.7491 (4) | 0.46699 (13) | 0.0296 (4) | |
H14A | 0.0153 | 0.7487 | 0.4964 | 0.036* | |
C15 | 0.06837 (9) | 0.9249 (4) | 0.48076 (14) | 0.0320 (5) | |
H15A | 0.0737 | 1.0434 | 0.5192 | 0.038* | |
C16 | 0.09546 (13) | 0.9235 (5) | 0.43669 (18) | 0.0527 (8) | |
H16A | 0.1188 | 1.0425 | 0.4453 | 0.063* |
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.0506 (14) | 0.0514 (16) | 0.0622 (15) | −0.0278 (12) | 0.0469 (13) | −0.0355 (13) |
C2 | 0.0296 (9) | 0.0292 (11) | 0.0369 (10) | −0.0059 (8) | 0.0239 (9) | −0.0039 (8) |
C3 | 0.0277 (9) | 0.0340 (11) | 0.0241 (8) | 0.0014 (8) | 0.0183 (8) | 0.0018 (8) |
C4 | 0.0313 (10) | 0.0286 (10) | 0.0240 (9) | −0.0014 (8) | 0.0177 (8) | −0.0035 (7) |
C5 | 0.0420 (12) | 0.0402 (13) | 0.0352 (10) | −0.0185 (10) | 0.0293 (10) | −0.0141 (9) |
C6 | 0.0582 (15) | 0.0696 (19) | 0.0547 (14) | −0.0396 (14) | 0.0500 (13) | −0.0387 (14) |
C7A | 0.027 (2) | 0.018 (2) | 0.021 (2) | 0.0024 (19) | 0.016 (2) | 0.0051 (18) |
C8A | 0.029 (2) | 0.018 (2) | 0.020 (2) | −0.005 (2) | 0.016 (2) | −0.0026 (18) |
C7B | 0.0271 (15) | 0.0206 (15) | 0.0241 (14) | 0.0004 (12) | 0.0181 (13) | −0.0006 (12) |
C8B | 0.0265 (15) | 0.0179 (15) | 0.0251 (14) | −0.0057 (12) | 0.0181 (13) | −0.0045 (12) |
C9 | 0.0357 (11) | 0.0296 (11) | 0.0329 (10) | 0.0063 (8) | 0.0236 (9) | 0.0053 (8) |
F1 | 0.0742 (12) | 0.0783 (14) | 0.1068 (16) | 0.0048 (10) | 0.0791 (13) | 0.0040 (11) |
F2 | 0.0612 (10) | 0.0260 (8) | 0.0837 (13) | 0.0030 (7) | 0.0300 (9) | 0.0034 (8) |
F3 | 0.1158 (16) | 0.0815 (14) | 0.0529 (10) | −0.0030 (12) | 0.0660 (12) | −0.0016 (9) |
C10 | 0.0293 (9) | 0.0258 (10) | 0.0268 (9) | −0.0001 (8) | 0.0186 (8) | 0.0001 (7) |
O1A | 0.039 (2) | 0.032 (2) | 0.032 (2) | 0.0098 (17) | 0.0223 (18) | 0.0025 (17) |
O1B | 0.0350 (14) | 0.0308 (16) | 0.0430 (15) | 0.0028 (11) | 0.0239 (12) | 0.0114 (11) |
C11 | 0.0686 (17) | 0.077 (2) | 0.0508 (14) | −0.0466 (16) | 0.0525 (14) | −0.0370 (14) |
C12 | 0.0376 (11) | 0.0403 (13) | 0.0352 (10) | −0.0130 (9) | 0.0260 (9) | −0.0144 (9) |
C13 | 0.0293 (9) | 0.0304 (11) | 0.0320 (10) | −0.0040 (8) | 0.0201 (8) | 0.0028 (8) |
C14 | 0.0303 (10) | 0.0387 (12) | 0.0294 (9) | 0.0043 (9) | 0.0224 (8) | 0.0060 (8) |
C15 | 0.0421 (11) | 0.0327 (11) | 0.0278 (9) | −0.0030 (9) | 0.0235 (9) | −0.0039 (8) |
C16 | 0.0775 (19) | 0.0587 (18) | 0.0482 (14) | −0.0445 (15) | 0.0514 (15) | −0.0287 (13) |
C1—C2 | 1.382 (3) | C9—F1 | 1.292 (2) |
C1—C6 | 1.383 (3) | C9—F3 | 1.306 (3) |
C1—H1A | 0.9300 | C9—F2 | 1.337 (3) |
C2—C3 | 1.384 (3) | C10—O1B | 1.202 (3) |
C2—H2A | 0.9300 | C10—O1A | 1.216 (4) |
C3—C4 | 1.386 (3) | C10—H10A | 1.07 (6) |
C3—H3A | 0.9300 | C10—H10B | 1.04 (3) |
C4—C5 | 1.387 (3) | O1A—H10B | 0.87 (4) |
C4—H4A | 0.9300 | O1B—H10A | 0.82 (7) |
C5—C6 | 1.393 (3) | C11—C12 | 1.382 (3) |
C5—H5A | 0.9300 | C11—C16 | 1.386 (3) |
C6—C8B | 1.517 (3) | C12—C13 | 1.385 (3) |
C6—C7A | 1.629 (5) | C12—H12A | 0.9300 |
C7A—C8A | 1.343 (7) | C13—C14 | 1.387 (3) |
C7A—C9 | 1.551 (5) | C13—H13A | 0.9300 |
C8A—C10 | 1.486 (5) | C14—C15 | 1.376 (3) |
C8A—C11 | 1.571 (5) | C14—H14A | 0.9300 |
C7B—C8B | 1.340 (4) | C15—C16 | 1.389 (3) |
C7B—C9 | 1.521 (4) | C15—H15A | 0.9300 |
C7B—C11 | 1.556 (4) | C16—H16A | 0.9300 |
C8B—C10 | 1.512 (4) | ||
C2—C1—C6 | 120.3 (2) | F1—C9—C7A | 93.6 (2) |
C2—C1—H1A | 119.9 | F3—C9—C7A | 127.8 (3) |
C6—C1—H1A | 119.9 | F2—C9—C7A | 112.6 (2) |
C1—C2—C3 | 119.80 (19) | O1B—C10—O1A | 75.6 (3) |
C1—C2—H2A | 120.1 | O1B—C10—C8A | 156.5 (3) |
C3—C2—H2A | 120.1 | O1A—C10—C8A | 123.3 (3) |
C2—C3—C4 | 120.40 (17) | O1B—C10—C8B | 122.2 (2) |
C2—C3—H3A | 119.8 | O1A—C10—C8B | 159.8 (3) |
C4—C3—H3A | 119.8 | O1A—C10—H10A | 111 (4) |
C3—C4—C5 | 119.80 (18) | C8A—C10—H10A | 126 (4) |
C3—C4—H4A | 120.1 | C8B—C10—H10A | 90 (4) |
C5—C4—H4A | 120.1 | O1B—C10—H10B | 119 (2) |
C4—C5—C6 | 119.76 (19) | C8A—C10—H10B | 83 (2) |
C4—C5—H5A | 120.1 | C8B—C10—H10B | 119 (2) |
C6—C5—H5A | 120.1 | H10A—C10—H10B | 142 (4) |
C1—C6—C5 | 119.94 (19) | C10—O1A—H10B | 57 (2) |
C1—C6—C8B | 117.2 (2) | C10—O1B—H10A | 60 (4) |
C5—C6—C8B | 121.5 (2) | C12—C11—C16 | 119.9 (2) |
C1—C6—C7A | 124.3 (3) | C12—C11—C7B | 115.5 (2) |
C5—C6—C7A | 110.9 (3) | C16—C11—C7B | 123.4 (2) |
C8A—C7A—C9 | 119.2 (4) | C12—C11—C8A | 121.8 (2) |
C8A—C7A—C6 | 111.1 (4) | C16—C11—C8A | 112.1 (3) |
C9—C7A—C6 | 129.7 (3) | C11—C12—C13 | 119.7 (2) |
C7A—C8A—C10 | 118.5 (4) | C11—C12—H12A | 120.1 |
C7A—C8A—C11 | 112.0 (4) | C13—C12—H12A | 120.1 |
C10—C8A—C11 | 129.5 (4) | C12—C13—C14 | 120.14 (19) |
C8B—C7B—C9 | 120.6 (3) | C12—C13—H13A | 119.9 |
C8B—C7B—C11 | 117.4 (3) | C14—C13—H13A | 119.9 |
C9—C7B—C11 | 122.1 (2) | C15—C14—C13 | 120.37 (17) |
C7B—C8B—C10 | 117.9 (3) | C15—C14—H14A | 119.8 |
C7B—C8B—C6 | 120.2 (3) | C13—C14—H14A | 119.8 |
C10—C8B—C6 | 121.9 (3) | C14—C15—C16 | 119.4 (2) |
F1—C9—F3 | 106.2 (2) | C14—C15—H15A | 120.3 |
F1—C9—F2 | 106.72 (19) | C16—C15—H15A | 120.3 |
F3—C9—F2 | 107.1 (2) | C11—C16—C15 | 120.5 (2) |
F1—C9—C7B | 124.5 (2) | C11—C16—H16A | 119.8 |
F3—C9—C7B | 101.7 (2) | C15—C16—H16A | 119.8 |
F2—C9—C7B | 109.5 (2) | ||
C6—C1—C2—C3 | 0.6 (4) | C8A—C7A—C9—F3 | −42.2 (6) |
C1—C2—C3—C4 | −0.6 (3) | C6—C7A—C9—F3 | 136.4 (4) |
C2—C3—C4—C5 | 0.0 (3) | C8A—C7A—C9—F2 | 94.4 (4) |
C3—C4—C5—C6 | 0.6 (4) | C6—C7A—C9—F2 | −87.0 (4) |
C2—C1—C6—C5 | 0.0 (5) | C8A—C7A—C9—C7B | 2.8 (3) |
C2—C1—C6—C8B | −166.5 (3) | C6—C7A—C9—C7B | −178.6 (7) |
C2—C1—C6—C7A | 153.0 (3) | C7A—C8A—C10—O1B | −33.0 (10) |
C4—C5—C6—C1 | −0.5 (4) | C11—C8A—C10—O1B | 148.6 (6) |
C4—C5—C6—C8B | 165.4 (3) | C7A—C8A—C10—O1A | −172.6 (4) |
C4—C5—C6—C7A | −157.0 (3) | C11—C8A—C10—O1A | 8.9 (6) |
C1—C6—C7A—C8A | 90.6 (5) | C7A—C8A—C10—C8B | 1.0 (3) |
C5—C6—C7A—C8A | −114.2 (4) | C11—C8A—C10—C8B | −177.4 (6) |
C8B—C6—C7A—C8A | 1.1 (3) | C7B—C8B—C10—O1B | 164.3 (3) |
C1—C6—C7A—C9 | −88.1 (5) | C6—C8B—C10—O1B | −16.6 (4) |
C5—C6—C7A—C9 | 67.1 (5) | C7B—C8B—C10—O1A | 15.1 (10) |
C8B—C6—C7A—C9 | −177.6 (7) | C6—C8B—C10—O1A | −165.8 (8) |
C9—C7A—C8A—C10 | 176.1 (3) | C7B—C8B—C10—C8A | −0.5 (3) |
C6—C7A—C8A—C10 | −2.7 (6) | C6—C8B—C10—C8A | 178.6 (5) |
C9—C7A—C8A—C11 | −5.2 (6) | C8B—C7B—C11—C12 | 107.9 (3) |
C6—C7A—C8A—C11 | 176.0 (3) | C9—C7B—C11—C12 | −73.6 (4) |
C9—C7B—C8B—C10 | −175.5 (2) | C8B—C7B—C11—C16 | −84.8 (4) |
C11—C7B—C8B—C10 | 3.1 (4) | C9—C7B—C11—C16 | 93.7 (4) |
C9—C7B—C8B—C6 | 5.4 (4) | C8B—C7B—C11—C8A | −1.8 (3) |
C11—C7B—C8B—C6 | −176.1 (2) | C9—C7B—C11—C8A | 176.7 (5) |
C1—C6—C8B—C7B | −113.5 (4) | C7A—C8A—C11—C12 | −90.1 (5) |
C5—C6—C8B—C7B | 80.2 (4) | C10—C8A—C11—C12 | 88.5 (5) |
C7A—C6—C8B—C7B | −1.7 (3) | C7A—C8A—C11—C16 | 117.7 (4) |
C1—C6—C8B—C10 | 67.4 (4) | C10—C8A—C11—C16 | −63.8 (5) |
C5—C6—C8B—C10 | −98.9 (4) | C7A—C8A—C11—C7B | 1.1 (3) |
C7A—C6—C8B—C10 | 179.2 (5) | C10—C8A—C11—C7B | 179.6 (6) |
C8B—C7B—C9—F1 | 24.0 (4) | C16—C11—C12—C13 | −0.7 (5) |
C11—C7B—C9—F1 | −154.5 (2) | C7B—C11—C12—C13 | 167.1 (2) |
C8B—C7B—C9—F3 | 143.1 (3) | C8A—C11—C12—C13 | −150.9 (3) |
C11—C7B—C9—F3 | −35.4 (3) | C11—C12—C13—C14 | 0.0 (4) |
C8B—C7B—C9—F2 | −103.9 (3) | C12—C13—C14—C15 | 0.4 (3) |
C11—C7B—C9—F2 | 77.7 (3) | C13—C14—C15—C16 | −0.2 (3) |
C8B—C7B—C9—C7A | −2.1 (4) | C12—C11—C16—C15 | 1.0 (5) |
C11—C7B—C9—C7A | 179.4 (5) | C7B—C11—C16—C15 | −165.8 (3) |
C8A—C7A—C9—F1 | −155.8 (4) | C8A—C11—C16—C15 | 153.9 (3) |
C6—C7A—C9—F1 | 22.7 (4) | C14—C15—C16—C11 | −0.6 (4) |
D—H···A | D—H | H···A | D···A | D—H···A |
C5—H5A···O1Bi | 0.93 | 2.56 | 3.491 (4) | 175 |
C13—H13A···O1Bii | 0.93 | 2.50 | 3.375 (4) | 158 |
C12—H12A···O1Ai | 0.93 | 2.58 | 3.506 (5) | 178 |
C2—H2A···Cg1iii | 0.93 | 2.92 | 3.668 (3) | 139 |
C4—H4A···Cg2iv | 0.93 | 2.90 | 3.662 (2) | 141 |
C15—H15A···Cg1v | 0.93 | 2.91 | 3.618 (2) | 134 |
Symmetry codes: (i) x, y−1, z; (ii) −x, y−1, −z+1/2; (iii) −x+1/2, y+1/2, −z+1/2; (iv) x, −y+1, z−1/2; (v) x, −y+2, z+1/2. |
Experimental details
Crystal data | |
Chemical formula | C16H11F3O |
Mr | 276.25 |
Crystal system, space group | Monoclinic, C2/c |
Temperature (K) | 100 |
a, b, c (Å) | 29.1818 (8), 5.8972 (2), 17.8356 (6) |
β (°) | 123.485 (3) |
V (Å3) | 2559.92 (17) |
Z | 8 |
Radiation type | Mo Kα |
µ (mm−1) | 0.12 |
Crystal size (mm) | 0.53 × 0.11 × 0.08 |
Data collection | |
Diffractometer | Bruker SMART APEX II CCD area-detector |
Absorption correction | Multi-scan (SADABS; Bruker, 2005) |
Tmin, Tmax | 0.851, 0.991 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 24392, 3611, 2817 |
Rint | 0.035 |
(sin θ/λ)max (Å−1) | 0.696 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.074, 0.199, 1.07 |
No. of reflections | 3611 |
No. of parameters | 217 |
H-atom treatment | H atoms treated by a mixture of independent and constrained refinement |
Δρmax, Δρmin (e Å−3) | 0.53, −0.56 |
Computer programs: APEX2 (Bruker, 2005), APEX2, SAINT (Bruker, 2005), SHELXTL (Sheldrick, 1998), SHELXTL, PARST (Nardelli, 1995) and PLATON (Spek, 2003).
D—H···A | D—H | H···A | D···A | D—H···A |
C5—H5A···O1Bi | 0.93 | 2.56 | 3.491 (4) | 175 |
C13—H13A···O1Bii | 0.93 | 2.50 | 3.375 (4) | 158 |
C12—H12A···O1Ai | 0.93 | 2.58 | 3.506 (5) | 178 |
C2—H2A···Cg1iii | 0.93 | 2.92 | 3.668 (3) | 139 |
C4—H4A···Cg2iv | 0.93 | 2.90 | 3.662 (2) | 141 |
C15—H15A···Cg1v | 0.93 | 2.91 | 3.618 (2) | 134 |
Symmetry codes: (i) x, y−1, z; (ii) −x, y−1, −z+1/2; (iii) −x+1/2, y+1/2, −z+1/2; (iv) x, −y+1, z−1/2; (v) x, −y+2, z+1/2. |
The photochemistry of α,α,α-trifluoroacetophenone is of continuing research interest (van Alem et al., 2005). In continuation of our recent work on photoinduced reactions of ketones with alkynes, the title compound, (I), was obtained by the reaction of photoexcited α,α,α-trifluoroacetophenone with trimethylsilylphenylethyne. A crystallographic analysis of (I) was carried out to elucidate its structure.
Bond lengths and angles in (I) display normal values (Allen et al., 1987). The dihedral angle between the C1—C6 and C11—C16 benzene rings is 4.66 (12)°. The torsion angle of C9—C7A—C8A—C10 and C9—C7B—C8B—C10 are 176.1 (3) and -175.5 (2)°, respectively. The linkage between the two phenyl rings is disordered over two positions.
In the crystal structure, the molecules are interconnected into columns along the b axis by intermolecular C13—H13A···O1B and C5—H5A···O1B interactions (Figure 2 and Table 1) together with intermolecular C12—H12A···O1A interactions (Table 1) and short O1A···O1A (-x, y, 1/2 - z) contacts [2.525 (8) Å] (Figure 3). In addition, the crystal structure is further stabilized by C—H···π interactions involving the C1—C6 (centroid Cg1) and C11—C16 (centroid Cg2) ring (Table 1).