[Rh(C7H8)(PPh3)Cl]: an experimental charge-density study

Sparkes, H.A.; Brayshaw, S.K.; Weller, A.S.; Howard, J.A.K.

doi:10.1107/S0108768108026384

[Rh(C₇H₈)(PPh₃)Cl]: an experimental charge-density study

H. A. Sparkes, S. K. Brayshaw, A. S. Weller and J. A. K. Howard

In order to gain a deeper understanding into the bonding situation in rhodium complexes containing rhodium–carbon interactions, the experimental charge-density analysis for [Rh(C₇H₈)(PPh₃)Cl] (1) is reported. Accurate, high-resolution (sin θ/λ = 1.08 Å⁻¹), single-crystal data were obtained at 100 K. The results from the investigation were interesting in relation to the interactions between the rhodium metal centre and the norbornadiene fragment and illustrate the importance of such analyses in studying bonding in organometallic complexes.

Keywords: charge density; X-ray diffraction; organometallic; bonding; rhodium complexes.

Read article Similar articles

Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S0108768108026384/bs5064sup1.cif Contains datablocks publication_text, 1
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108026384/bs50641sup2.hkl Contains datablock 1
	Portable Document Format (PDF) file https://doi.org/10.1107/S0108768108026384/bs5064sup3.pdf Extra figures and tables

CCDC reference: 705576

Computing details top

Data collection: Collect (Nonius BV, 1997-2000); cell refinement: HKL SCALEPACK (Otwinowski & Minor 1997); data reduction: HKL DENZO and SCALEPACK (Otwinowski & Minor 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: Volkov et al., (2006); molecular graphics: Volkov et al., (2006); software used to prepare material for publication: Volkov et al., (2006).

Figures top

(1) top

Crystal data top

C₂₅H₂₃ClPRh	V = 1026.01 (2) Å³
M_r = 492.76	Z = 2
Triclinic, P1	F(000) = 500
Hall symbol: -P 1	D_x = 1.595 Mg m⁻³
a = 10.2430 (1) Å	Mo Kα radiation, λ = 0.71073 Å
b = 10.4042 (1) Å	µ = 1.05 mm⁻¹
c = 11.4078 (1) Å	T = 100 K
α = 99.213 (1)°	Block, orange
β = 103.131 (1)°	× × mm
γ = 115.080 (1)°

Data collection top

Nonius Kappa CCD diffractometer	19920 reflections with I > 3 σ(I)
Radiation source: fine-focus sealed tube	R_int = 0.038
Graphite monochromator	θ_max = 50.2°, θ_min = 2.3°
CCD scans	h = −22→22
370693 measured reflections	k = −22→22
21647 independent reflections	l = −24→24

Refinement top

Refinement on F	0 restraints
Least-squares matrix: full	Only H-atom displacement parameters refined
R[F² > 2σ(F²)] = 0.012	w1 = 1/[s²(F_o)]
wR(F²) = 0.012	(Δ/σ)_max < 0.001
S = 1.35	Δρ_max = 0.20 e Å⁻³
19920 reflections	Δρ_min = −0.21 e Å⁻³
514 parameters

Crystal data top

C₂₅H₂₃ClPRh	γ = 115.080 (1)°
M_r = 492.76	V = 1026.01 (2) Å³
Triclinic, P1	Z = 2
a = 10.2430 (1) Å	Mo Kα radiation
b = 10.4042 (1) Å	µ = 1.05 mm⁻¹
c = 11.4078 (1) Å	T = 100 K
α = 99.213 (1)°	× × mm
β = 103.131 (1)°

Data collection top

Nonius Kappa CCD diffractometer	19920 reflections with I > 3 σ(I)
370693 measured reflections	R_int = 0.038
21647 independent reflections

Refinement top

R[F² > 2σ(F²)] = 0.012	0 restraints
wR(F²) = 0.012	Only H-atom displacement parameters refined
S = 1.35	Δρ_max = 0.20 e Å⁻³
19920 reflections	Δρ_min = −0.21 e Å⁻³
514 parameters

Special details top

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
RH(1)	0.787155 (2)	0.772452 (2)	0.723188 (2)	0.009
CL(1)	0.703751 (7)	0.524121 (7)	0.726514 (6)	0.014
P(1)	1.038951 (7)	0.833909 (7)	0.753578 (5)	0.009
C(1)	0.57359 (3)	0.76988 (4)	0.73741 (3)	0.014
C(2)	0.55919 (4)	0.73356 (4)	0.61128 (3)	0.015
C(3)	0.62251 (4)	0.88065 (4)	0.57771 (3)	0.016
C(4)	0.79460 (4)	0.94849 (4)	0.65042 (3)	0.015
C(5)	0.80950 (4)	0.98571 (3)	0.77949 (3)	0.014
C(6)	0.64693 (4)	0.93992 (4)	0.78397 (3)	0.015
C(7)	0.57716 (4)	0.97283 (4)	0.66465 (3)	0.017
C(8)	1.16740 (3)	1.03313 (3)	0.79144 (2)	0.011
C(9)	1.18870 (3)	1.12563 (3)	0.90621 (2)	0.013
C(10)	1.28192 (3)	1.27875 (3)	0.93910 (2)	0.015
C(11)	1.35652 (3)	1.34086 (3)	0.85797 (3)	0.017
C(12)	1.33788 (3)	1.24985 (3)	0.74471 (3)	0.016
C(13)	1.24307 (3)	1.09672 (3)	0.71121 (2)	0.013
C(14)	1.05684 (3)	0.75315 (3)	0.60731 (2)	0.011
C(15)	0.96550 (3)	0.75167 (3)	0.49451 (2)	0.016
C(16)	0.97714 (4)	0.69701 (4)	0.37963 (2)	0.019
C(17)	1.07786 (4)	0.64058 (3)	0.37567 (3)	0.017
C(18)	1.16620 (3)	0.63821 (3)	0.48670 (2)	0.016
C(19)	1.15592 (3)	0.69400 (3)	0.60186 (2)	0.014
C(20)	1.14490 (3)	0.78763 (3)	0.87592 (2)	0.011
C(21)	1.30128 (3)	0.83458 (3)	0.89884 (2)	0.013
C(22)	1.38014 (3)	0.79347 (3)	0.98835 (2)	0.016
C(23)	1.30540 (4)	0.70980 (3)	1.05982 (3)	0.018
C(24)	1.15240 (3)	0.66861 (3)	1.04128 (3)	0.018
C(25)	1.07137 (3)	0.70535 (3)	0.94857 (2)	0.014
H(1)	0.538368	0.691836	0.792889	0.037
H(2)	0.493344	0.623047	0.542096	0.025
H(3)	0.589356	0.869806	0.476452	0.026
H(4)	0.887016	0.999483	0.611813	0.02
H(5)	0.911195	1.070806	0.857875	0.024
H(6)	0.642067	0.991658	0.873724	0.027
H(7B)	0.631184	1.090811	0.668612	0.025
H(7A)	0.452523	0.926975	0.637468	0.024
H(9)	1.131536	1.074026	0.967816	0.02
H(10)	1.296051	1.349127	1.026725	0.023
H(11)	1.427987	1.459179	0.880588	0.034
H(12)	1.400042	1.297166	0.684227	0.027
H(13)	1.227628	1.02814	0.622107	0.021
H(15)	0.881561	0.788878	0.492818	0.029
H(16)	0.903517	0.691546	0.292418	0.026
H(17)	1.083195	0.597283	0.285309	0.029
H(18)	1.245579	0.596059	0.483222	0.026
H(19)	1.225312	0.694502	0.688933	0.033
H(21)	1.359091	0.902062	0.845263	0.026
H(22)	1.499848	0.829394	1.003835	0.019
H(23)	1.367037	0.679622	1.130575	0.033
H(24)	1.093755	0.603139	1.095603	0.032
H(25)	0.950536	0.665982	0.929523	0.022
DUM0	0	0	0	0	0

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
RH(1)	0.008013 (7)	0.010441 (7)	0.010231 (6)	0.004524 (6)	0.003436 (5)	0.003240 (5)
CL(1)	0.01341 (2)	0.01133 (2)	0.01681 (2)	0.005118 (19)	0.005363 (19)	0.004116 (18)
P(1)	0.00831 (2)	0.01039 (2)	0.00942 (2)	0.004648 (18)	0.003331 (17)	0.003571 (17)
C(1)	0.01169 (10)	0.01670 (11)	0.01700 (11)	0.00732 (9)	0.00685 (9)	0.00595 (9)
C(2)	0.01180 (10)	0.01664 (11)	0.01502 (11)	0.00714 (9)	0.00201 (9)	0.00216 (9)
C(3)	0.01654 (12)	0.02171 (13)	0.01417 (10)	0.01218 (11)	0.00473 (9)	0.00725 (10)
C(4)	0.01433 (11)	0.01683 (11)	0.01708 (11)	0.00906 (9)	0.00763 (9)	0.00846 (9)
C(5)	0.01207 (10)	0.01326 (10)	0.01579 (10)	0.00653 (9)	0.00394 (9)	0.00311 (8)
C(6)	0.01430 (11)	0.01710 (11)	0.01524 (10)	0.00972 (10)	0.00604 (9)	0.00388 (9)
C(7)	0.01634 (12)	0.02027 (13)	0.02076 (12)	0.01269 (11)	0.00607 (10)	0.00753 (10)
C(8)	0.01028 (8)	0.01086 (8)	0.01108 (8)	0.00462 (7)	0.00399 (6)	0.00371 (6)
C(9)	0.01256 (9)	0.01307 (8)	0.01154 (8)	0.00490 (7)	0.00398 (7)	0.00250 (7)
C(10)	0.01443 (9)	0.01288 (9)	0.01430 (9)	0.00486 (8)	0.00258 (7)	0.00110 (7)
C(11)	0.01543 (10)	0.01152 (9)	0.01769 (10)	0.00337 (8)	0.00313 (8)	0.00378 (8)
C(12)	0.01547 (10)	0.01331 (9)	0.01658 (9)	0.00362 (8)	0.00600 (8)	0.00621 (8)
C(13)	0.01376 (9)	0.01248 (8)	0.01322 (8)	0.00474 (7)	0.00616 (7)	0.00500 (7)
C(14)	0.01118 (8)	0.01242 (8)	0.01033 (7)	0.00627 (7)	0.00386 (7)	0.00322 (6)
C(15)	0.02070 (11)	0.02233 (11)	0.01075 (8)	0.01520 (10)	0.00463 (8)	0.00495 (8)
C(16)	0.02748 (13)	0.02632 (13)	0.01080 (8)	0.01838 (11)	0.00624 (9)	0.00573 (8)
C(17)	0.02089 (12)	0.02098 (11)	0.01265 (9)	0.01151 (10)	0.00756 (9)	0.00341 (8)
C(18)	0.01442 (10)	0.02081 (11)	0.01433 (9)	0.01002 (9)	0.00496 (8)	0.00080 (8)
C(19)	0.01257 (9)	0.01814 (10)	0.01237 (8)	0.00930 (8)	0.00323 (7)	0.00158 (7)
C(20)	0.00996 (8)	0.01226 (8)	0.01072 (7)	0.00534 (7)	0.00307 (6)	0.00459 (6)
C(21)	0.01011 (8)	0.01530 (9)	0.01288 (8)	0.00621 (7)	0.00298 (7)	0.00476 (7)
C(22)	0.01289 (9)	0.01745 (10)	0.01582 (9)	0.00848 (8)	0.00139 (7)	0.00479 (8)
C(23)	0.01759 (11)	0.01691 (10)	0.01667 (10)	0.00808 (9)	0.00010 (9)	0.00720 (8)
C(24)	0.01675 (11)	0.01733 (10)	0.01529 (9)	0.00500 (9)	0.00219 (8)	0.00927 (8)
C(25)	0.01232 (9)	0.01572 (9)	0.01273 (8)	0.00475 (8)	0.00376 (7)	0.00708 (7)

Geometric parameters (Å, º) top

RH(1)—CL(1)	2.3625 (1)	C(10)—H(10)	1.0800 (3)
RH(1)—P(1)	2.3034 (1)	C(10)—H(11)	2.1638 (3)
RH(1)—C(1)	2.2193 (3)	C(11)—C(12)	1.3948 (4)
RH(1)—C(2)	2.2192 (3)	C(11)—H(10)	2.1520 (3)
RH(1)—C(4)	2.1087 (3)	C(11)—H(11)	1.0800 (3)
RH(1)—C(5)	2.1058 (3)	C(11)—H(12)	2.1491 (3)
P(1)—C(8)	1.8322 (2)	C(12)—C(13)	1.3972 (4)
P(1)—C(14)	1.8287 (2)	C(12)—H(11)	2.1361 (3)
P(1)—C(20)	1.8242 (2)	C(12)—H(12)	1.0800 (3)
C(1)—C(2)	1.3845 (4)	C(12)—H(13)	2.1432 (3)
C(1)—C(3)	2.3443 (4)	C(13)—H(12)	2.1488 (2)
C(1)—C(5)	2.3748 (4)	C(13)—H(13)	1.0800 (2)
C(1)—C(6)	1.5386 (4)	C(14)—C(15)	1.4021 (3)
C(1)—C(7)	2.3788 (5)	C(14)—C(19)	1.3995 (3)
C(1)—H(1)	1.1000 (3)	C(14)—H(15)	2.1733 (2)
C(1)—H(2)	2.2332 (3)	C(14)—H(19)	2.1358 (2)
C(1)—H(6)	2.2843 (3)	C(15)—C(16)	1.3947 (4)
C(2)—C(3)	1.5390 (5)	C(15)—H(15)	1.0800 (3)
C(2)—C(4)	2.3736 (5)	C(15)—H(16)	2.1554 (2)
C(2)—C(6)	2.3459 (4)	C(16)—C(17)	1.3918 (4)
C(2)—C(7)	2.3827 (5)	C(16)—H(15)	2.1241 (3)
C(2)—H(1)	2.2218 (3)	C(16)—H(16)	1.0800 (3)
C(2)—H(2)	1.1000 (3)	C(16)—H(17)	2.1315 (3)
C(2)—H(3)	2.2391 (3)	C(17)—C(18)	1.3899 (4)
C(3)—C(4)	1.5449 (5)	C(17)—H(16)	2.1367 (3)
C(3)—C(5)	2.3617 (5)	C(17)—H(17)	1.0800 (3)
C(3)—C(6)	2.2619 (4)	C(17)—H(18)	2.1378 (3)
C(3)—C(7)	1.5497 (4)	C(18)—C(19)	1.3944 (3)
C(3)—H(2)	2.3452 (4)	C(18)—H(17)	2.1621 (3)
C(3)—H(3)	1.1000 (3)	C(18)—H(18)	1.0800 (3)
C(3)—H(4)	2.3554 (3)	C(18)—H(19)	2.1596 (3)
C(3)—H(7B)	2.2207 (3)	C(19)—H(18)	2.1517 (2)
C(3)—H(7A)	2.2078 (3)	C(19)—H(19)	1.0800 (3)
C(4)—C(5)	1.4164 (4)	C(20)—C(21)	1.4065 (3)
C(4)—C(6)	2.3650 (4)	C(20)—C(25)	1.3968 (3)
C(4)—C(7)	2.3834 (4)	C(20)—H(21)	2.1496 (2)
C(4)—H(3)	2.2702 (3)	C(20)—H(25)	2.1458 (2)
C(4)—H(4)	1.1000 (3)	C(21)—C(22)	1.3915 (4)
C(4)—H(5)	2.2604 (3)	C(21)—H(19)	2.3533 (2)
C(5)—C(6)	1.5416 (4)	C(21)—H(21)	1.0800 (2)
C(5)—C(7)	2.3780 (4)	C(21)—H(22)	2.1404 (2)
C(5)—H(4)	2.2341 (3)	C(22)—C(23)	1.3980 (4)
C(5)—H(5)	1.1000 (3)	C(22)—H(21)	2.1505 (3)
C(5)—H(6)	2.2377 (3)	C(22)—H(22)	1.0800 (3)
C(6)—C(7)	1.5478 (5)	C(22)—H(23)	2.1524 (3)
C(6)—H(1)	2.3688 (3)	C(23)—C(24)	1.3911 (4)
C(6)—H(5)	2.3158 (3)	C(23)—H(22)	2.1575 (3)
C(6)—H(6)	1.1000 (3)	C(23)—H(23)	1.0800 (3)
C(6)—H(7B)	2.2366 (3)	C(23)—H(24)	2.1460 (3)
C(6)—H(7A)	2.2282 (3)	C(24)—C(25)	1.3976 (4)
C(7)—H(3)	2.2961 (3)	C(24)—H(23)	2.1484 (3)
C(7)—H(6)	2.2779 (3)	C(24)—H(24)	1.0800 (3)
C(7)—H(7B)	1.1000 (4)	C(24)—H(25)	2.1552 (3)
C(7)—H(7A)	1.1000 (3)	C(25)—H(24)	2.1448 (2)
C(8)—C(9)	1.4059 (3)	C(25)—H(25)	1.0800 (3)
C(8)—C(13)	1.3991 (3)	H(2)—H(18)ⁱ	2.3520
C(8)—H(9)	2.1351 (2)	H(3)—H(12)ⁱⁱ	2.3707
C(8)—H(13)	2.1567 (2)	H(3)—H(13)ⁱⁱ	2.3576
C(9)—C(10)	1.3952 (4)	H(4)—H(15)	2.3572
C(9)—H(9)	1.0800 (2)	H(5)—H(9)	2.3031
C(9)—H(10)	2.1513 (2)	H(7B)—H(7A)	1.8019
C(10)—C(11)	1.3972 (4)	H(17)—H(24)ⁱⁱⁱ	2.2004
C(10)—H(9)	2.1652 (3)	H(19)—H(21)	2.2067

CL(1)—RH(1)—P(1)	96.346 (2)	C(5)—C(7)—C(6)	39.576 (16)
CL(1)—RH(1)—C(1)	93.758 (8)	C(5)—C(7)—H(3)	91.996 (13)
CL(1)—RH(1)—C(2)	95.090 (9)	C(5)—C(7)—H(6)	57.403 (11)
CL(1)—RH(1)—C(4)	157.369 (9)	C(5)—C(7)—H(7B)	93.87 (2)
CL(1)—RH(1)—C(5)	154.088 (9)	C(5)—C(7)—H(7A)	151.57 (3)
P(1)—RH(1)—C(1)	164.189 (9)	C(6)—C(7)—H(3)	118.53 (2)
P(1)—RH(1)—C(2)	153.217 (9)	C(6)—C(7)—H(6)	25.313 (12)
P(1)—RH(1)—C(4)	95.663 (9)	C(6)—C(7)—H(7B)	114.22 (3)
P(1)—RH(1)—C(5)	99.964 (8)	C(6)—C(7)—H(7A)	113.53 (3)
C(1)—RH(1)—C(2)	36.352 (11)	H(3)—C(7)—H(6)	143.836 (15)
C(1)—RH(1)—C(4)	79.135 (12)	H(3)—C(7)—H(7B)	100.47 (2)
C(1)—RH(1)—C(5)	66.548 (12)	H(3)—C(7)—H(7A)	98.38 (2)
C(2)—RH(1)—C(4)	66.464 (13)	H(6)—C(7)—H(7B)	100.40 (2)
C(2)—RH(1)—C(5)	79.078 (12)	H(6)—C(7)—H(7A)	101.76 (2)
C(4)—RH(1)—C(5)	39.276 (12)	H(7B)—C(7)—H(7A)	109.98 (3)
RH(1)—P(1)—C(8)	114.197 (8)	P(1)—C(8)—C(9)	117.895 (18)
RH(1)—P(1)—C(14)	109.506 (8)	P(1)—C(8)—C(13)	123.135 (18)
RH(1)—P(1)—C(20)	121.381 (8)	P(1)—C(8)—H(9)	91.327 (10)
C(8)—P(1)—C(14)	104.183 (11)	P(1)—C(8)—H(13)	97.534 (10)
C(8)—P(1)—C(20)	100.444 (11)	C(9)—C(8)—C(13)	118.97 (2)
C(14)—P(1)—C(20)	105.455 (11)	C(9)—C(8)—H(9)	26.584 (11)
RH(1)—C(1)—C(2)	71.819 (17)	C(9)—C(8)—H(13)	144.565 (18)
RH(1)—C(1)—C(3)	75.419 (12)	C(13)—C(8)—H(9)	145.537 (19)
RH(1)—C(1)—C(5)	54.435 (10)	C(13)—C(8)—H(13)	25.600 (11)
RH(1)—C(1)—C(6)	93.981 (18)	H(9)—C(8)—H(13)	171.133 (13)
RH(1)—C(1)—C(7)	103.305 (14)	C(8)—C(9)—C(10)	120.70 (2)
RH(1)—C(1)—H(1)	102.015 (19)	C(8)—C(9)—H(9)	117.78 (2)
RH(1)—C(1)—H(2)	78.416 (10)	C(8)—C(9)—H(10)	146.415 (19)
RH(1)—C(1)—H(6)	107.179 (13)	C(10)—C(9)—H(9)	121.51 (2)
C(2)—C(1)—C(3)	39.009 (18)	C(10)—C(9)—H(10)	25.719 (12)
C(2)—C(1)—C(5)	90.27 (2)	H(9)—C(9)—H(10)	95.800 (14)
C(2)—C(1)—C(6)	106.63 (3)	C(9)—C(10)—C(11)	119.74 (2)
C(2)—C(1)—C(7)	73.25 (2)	C(9)—C(10)—H(9)	25.167 (11)
C(2)—C(1)—H(1)	126.44 (3)	C(9)—C(10)—H(10)	120.18 (2)
C(2)—C(1)—H(2)	22.957 (15)	C(9)—C(10)—H(11)	145.011 (19)
C(2)—C(1)—H(6)	130.39 (2)	C(11)—C(10)—H(9)	144.90 (2)
C(3)—C(1)—C(5)	60.057 (14)	C(11)—C(10)—H(10)	120.07 (2)
C(3)—C(1)—C(6)	67.620 (18)	C(11)—C(10)—H(11)	25.273 (13)
C(3)—C(1)—C(7)	38.299 (12)	H(9)—C(10)—H(10)	95.025 (17)
C(3)—C(1)—H(1)	165.44 (3)	H(9)—C(10)—H(11)	170.171 (13)
C(3)—C(1)—H(2)	61.581 (12)	H(10)—C(10)—H(11)	94.802 (16)
C(3)—C(1)—H(6)	91.665 (14)	C(10)—C(11)—C(12)	120.01 (2)
C(5)—C(1)—C(6)	39.603 (15)	C(10)—C(11)—H(10)	25.741 (12)
C(5)—C(1)—C(7)	60.033 (13)	C(10)—C(11)—H(11)	121.20 (3)
C(5)—C(1)—H(1)	130.30 (2)	C(10)—C(11)—H(12)	145.74 (2)
C(5)—C(1)—H(2)	111.083 (14)	C(12)—C(11)—H(10)	145.75 (2)
C(5)—C(1)—H(6)	57.368 (10)	C(12)—C(11)—H(11)	118.79 (3)
C(6)—C(1)—C(7)	39.722 (16)	C(12)—C(11)—H(12)	25.796 (12)
C(6)—C(1)—H(1)	126.93 (3)	H(10)—C(11)—H(11)	95.460 (18)
C(6)—C(1)—H(2)	128.96 (2)	H(10)—C(11)—H(12)	171.410 (15)
C(6)—C(1)—H(6)	24.912 (12)	H(11)—C(11)—H(12)	93.045 (18)
C(7)—C(1)—H(1)	152.11 (2)	C(11)—C(12)—C(13)	120.18 (2)
C(7)—C(1)—H(2)	92.517 (14)	C(11)—C(12)—H(11)	26.302 (13)
C(7)—C(1)—H(6)	58.441 (11)	C(11)—C(12)—H(12)	120.01 (2)
H(1)—C(1)—H(2)	103.87 (2)	C(11)—C(12)—H(13)	146.25 (2)
H(1)—C(1)—H(6)	102.72 (2)	C(13)—C(12)—H(11)	146.47 (2)
H(2)—C(1)—H(6)	150.947 (16)	C(13)—C(12)—H(12)	119.77 (2)
RH(1)—C(2)—C(1)	71.829 (18)	C(13)—C(12)—H(13)	26.084 (11)
RH(1)—C(2)—C(3)	94.267 (19)	H(11)—C(12)—H(12)	93.758 (16)
RH(1)—C(2)—C(4)	54.536 (10)	H(11)—C(12)—H(13)	172.420 (14)
RH(1)—C(2)—C(6)	75.191 (12)	H(12)—C(12)—H(13)	93.734 (17)
RH(1)—C(2)—C(7)	103.183 (15)	C(8)—C(13)—C(12)	120.39 (2)
RH(1)—C(2)—H(1)	74.054 (10)	C(8)—C(13)—H(12)	146.203 (19)
RH(1)—C(2)—H(2)	111.47 (2)	C(8)—C(13)—H(13)	120.36 (2)
RH(1)—C(2)—H(3)	108.641 (14)	C(12)—C(13)—H(12)	25.867 (12)
C(1)—C(2)—C(3)	106.50 (3)	C(12)—C(13)—H(13)	119.25 (2)
C(1)—C(2)—C(4)	90.49 (2)	H(12)—C(13)—H(13)	93.427 (14)
C(1)—C(2)—C(6)	38.935 (18)	P(1)—C(14)—C(15)	117.357 (18)
C(1)—C(2)—C(7)	72.94 (2)	P(1)—C(14)—C(19)	123.988 (18)
C(1)—C(2)—H(1)	23.472 (15)	P(1)—C(14)—H(15)	92.410 (10)
C(1)—C(2)—H(2)	127.64 (3)	P(1)—C(14)—H(19)	97.574 (10)
C(1)—C(2)—H(3)	131.47 (2)	C(15)—C(14)—C(19)	118.65 (2)
C(3)—C(2)—C(4)	39.767 (16)	C(15)—C(14)—H(15)	25.015 (11)
C(3)—C(2)—C(6)	67.566 (18)	C(15)—C(14)—H(19)	145.068 (18)
C(3)—C(2)—C(7)	39.682 (16)	C(19)—C(14)—H(15)	143.569 (18)
C(3)—C(2)—H(1)	129.97 (2)	C(19)—C(14)—H(19)	26.415 (11)
C(3)—C(2)—H(2)	124.57 (3)	H(15)—C(14)—H(19)	169.814 (12)
C(3)—C(2)—H(3)	26.421 (13)	C(14)—C(15)—C(16)	120.58 (2)
C(4)—C(2)—C(6)	60.143 (13)	C(14)—C(15)—H(15)	121.69 (2)
C(4)—C(2)—C(7)	60.145 (14)	C(14)—C(15)—H(16)	146.080 (19)
C(4)—C(2)—H(1)	109.244 (15)	C(16)—C(15)—H(15)	117.70 (2)
C(4)—C(2)—H(2)	135.74 (2)	C(16)—C(15)—H(16)	25.544 (13)
C(4)—C(2)—H(3)	58.878 (11)	H(15)—C(15)—H(16)	92.161 (15)
C(6)—C(2)—C(7)	38.203 (12)	C(15)—C(16)—C(17)	120.17 (3)
C(6)—C(2)—H(1)	62.406 (11)	C(15)—C(16)—H(15)	26.753 (12)
C(6)—C(2)—H(2)	164.02 (3)	C(15)—C(16)—H(16)	120.62 (3)
C(6)—C(2)—H(3)	92.977 (14)	C(15)—C(16)—H(17)	146.57 (2)
C(7)—C(2)—H(1)	94.771 (14)	C(17)—C(16)—H(15)	146.86 (2)
C(7)—C(2)—H(2)	143.71 (2)	C(17)—C(16)—H(16)	119.10 (2)
C(7)—C(2)—H(3)	59.482 (12)	C(17)—C(16)—H(17)	26.408 (12)
H(1)—C(2)—H(2)	104.56 (2)	H(15)—C(16)—H(16)	93.867 (18)
H(1)—C(2)—H(3)	154.227 (16)	H(15)—C(16)—H(17)	173.023 (15)
H(2)—C(2)—H(3)	98.23 (2)	H(16)—C(16)—H(17)	92.719 (16)
C(1)—C(3)—C(2)	34.491 (15)	C(16)—C(17)—C(18)	119.69 (2)
C(1)—C(3)—C(4)	87.826 (19)	C(16)—C(17)—H(16)	26.209 (13)
C(1)—C(3)—C(5)	60.613 (13)	C(16)—C(17)—H(17)	118.62 (3)
C(1)—C(3)—C(6)	38.975 (12)	C(16)—C(17)—H(18)	145.81 (2)
C(1)—C(3)—C(7)	72.054 (19)	C(18)—C(17)—H(16)	145.80 (2)
C(1)—C(3)—H(2)	56.877 (11)	C(18)—C(17)—H(17)	121.67 (3)
C(1)—C(3)—H(3)	147.10 (3)	C(18)—C(17)—H(18)	26.122 (12)
C(1)—C(3)—H(4)	109.614 (14)	H(16)—C(17)—H(17)	92.438 (18)
C(1)—C(3)—H(7B)	95.873 (14)	H(16)—C(17)—H(18)	171.848 (14)
C(1)—C(3)—H(7A)	72.061 (12)	H(17)—C(17)—H(18)	95.572 (18)
C(2)—C(3)—C(4)	100.65 (2)	C(17)—C(18)—C(19)	120.32 (2)
C(2)—C(3)—C(5)	87.178 (19)	C(17)—C(18)—H(17)	25.158 (12)
C(2)—C(3)—C(6)	73.465 (19)	C(17)—C(18)—H(18)	119.36 (2)
C(2)—C(3)—C(7)	100.96 (3)	C(17)—C(18)—H(19)	145.68 (2)
C(2)—C(3)—H(2)	22.719 (13)	C(19)—C(18)—H(17)	145.47 (2)
C(2)—C(3)—H(3)	115.08 (3)	C(19)—C(18)—H(18)	120.29 (3)
C(2)—C(3)—H(4)	115.52 (2)	C(19)—C(18)—H(19)	25.368 (12)
C(2)—C(3)—H(7B)	127.55 (2)	H(17)—C(18)—H(18)	94.225 (15)
C(2)—C(3)—H(7A)	89.239 (19)	H(17)—C(18)—H(19)	170.833 (14)
C(4)—C(3)—C(5)	35.264 (15)	H(18)—C(18)—H(19)	94.927 (17)
C(4)—C(3)—C(6)	74.140 (18)	C(14)—C(19)—C(18)	120.56 (2)
C(4)—C(3)—C(7)	100.74 (3)	C(14)—C(19)—H(18)	146.218 (19)
C(4)—C(3)—H(2)	111.85 (2)	C(14)—C(19)—H(19)	118.38 (2)
C(4)—C(3)—H(3)	117.26 (3)	C(18)—C(19)—H(18)	25.684 (13)
C(4)—C(3)—H(4)	22.484 (13)	C(18)—C(19)—H(19)	121.05 (2)
C(4)—C(3)—H(7B)	89.00 (2)	H(18)—C(19)—H(19)	95.369 (15)
C(4)—C(3)—H(7A)	127.76 (2)	P(1)—C(20)—C(21)	120.675 (18)
C(5)—C(3)—C(6)	38.877 (12)	P(1)—C(20)—C(25)	120.184 (19)
C(5)—C(3)—C(7)	71.484 (19)	P(1)—C(20)—H(21)	94.642 (10)
C(5)—C(3)—H(2)	107.684 (14)	P(1)—C(20)—H(25)	94.226 (10)
C(5)—C(3)—H(3)	150.44 (3)	C(21)—C(20)—C(25)	119.14 (2)
C(5)—C(3)—H(4)	56.537 (11)	C(21)—C(20)—H(21)	26.050 (11)
C(5)—C(3)—H(7B)	71.713 (12)	C(21)—C(20)—H(25)	145.093 (18)
C(5)—C(3)—H(7A)	95.576 (14)	C(25)—C(20)—H(21)	145.153 (19)
C(6)—C(3)—C(7)	43.059 (16)	C(25)—C(20)—H(25)	25.974 (12)
C(6)—C(3)—H(2)	95.728 (15)	H(21)—C(20)—H(25)	171.127 (12)
C(6)—C(3)—H(3)	162.13 (3)	C(20)—C(21)—C(22)	120.50 (2)
C(6)—C(3)—H(4)	94.937 (15)	C(20)—C(21)—H(19)	85.357 (14)
C(6)—C(3)—H(7B)	59.852 (11)	C(20)—C(21)—H(21)	119.07 (2)
C(6)—C(3)—H(7A)	59.789 (11)	C(20)—C(21)—H(22)	146.558 (19)
C(7)—C(3)—H(2)	116.22 (2)	C(22)—C(21)—H(19)	115.279 (18)
C(7)—C(3)—H(3)	119.15 (3)	C(22)—C(21)—H(21)	120.43 (2)
C(7)—C(3)—H(4)	112.05 (2)	C(22)—C(21)—H(22)	26.059 (13)
C(7)—C(3)—H(7B)	27.175 (15)	H(19)—C(21)—H(21)	68.839 (12)
C(7)—C(3)—H(7A)	27.569 (15)	H(19)—C(21)—H(22)	108.001 (10)
H(2)—C(3)—H(3)	92.43 (2)	H(21)—C(21)—H(22)	94.367 (15)
H(2)—C(3)—H(4)	118.912 (13)	C(21)—C(22)—C(23)	119.98 (2)
H(2)—C(3)—H(7B)	143.104 (16)	C(21)—C(22)—H(21)	25.661 (12)
H(2)—C(3)—H(7A)	96.708 (13)	C(21)—C(22)—H(22)	119.47 (3)
H(3)—C(3)—H(4)	94.98 (2)	C(21)—C(22)—H(23)	145.71 (2)
H(3)—C(3)—H(7B)	104.93 (2)	C(23)—C(22)—H(21)	145.62 (2)
H(3)—C(3)—H(7A)	103.51 (2)	C(23)—C(22)—H(22)	120.53 (2)
H(4)—C(3)—H(7B)	92.168 (13)	C(23)—C(22)—H(23)	25.742 (13)
H(4)—C(3)—H(7A)	139.059 (17)	H(21)—C(22)—H(22)	93.809 (17)
H(7B)—C(3)—H(7A)	48.019 (7)	H(21)—C(22)—H(23)	171.262 (14)
RH(1)—C(4)—C(2)	59.000 (11)	H(22)—C(22)—H(23)	94.787 (16)
RH(1)—C(4)—C(3)	98.54 (2)	C(22)—C(23)—C(24)	119.68 (2)
RH(1)—C(4)—C(5)	70.250 (17)	C(22)—C(23)—H(22)	25.544 (12)
RH(1)—C(4)—C(6)	76.828 (12)	C(22)—C(23)—H(23)	120.05 (3)
RH(1)—C(4)—C(7)	106.690 (15)	C(22)—C(23)—H(24)	145.51 (2)
RH(1)—C(4)—H(3)	111.537 (14)	C(24)—C(23)—H(22)	145.20 (2)
RH(1)—C(4)—H(4)	116.73 (2)	C(24)—C(23)—H(23)	120.26 (3)
RH(1)—C(4)—H(5)	79.709 (10)	C(24)—C(23)—H(24)	25.831 (12)
C(2)—C(4)—C(3)	39.583 (16)	H(22)—C(23)—H(23)	94.51 (2)
C(2)—C(4)—C(5)	89.56 (2)	H(22)—C(23)—H(24)	171.013 (14)
C(2)—C(4)—C(6)	59.348 (13)	H(23)—C(23)—H(24)	94.441 (19)
C(2)—C(4)—C(7)	60.116 (14)	C(23)—C(24)—C(25)	120.54 (2)
C(2)—C(4)—H(3)	57.602 (11)	C(23)—C(24)—H(23)	25.735 (13)
C(2)—C(4)—H(4)	143.46 (3)	C(23)—C(24)—H(24)	120.03 (3)
C(2)—C(4)—H(5)	111.812 (14)	C(23)—C(24)—H(25)	146.03 (2)
C(3)—C(4)—C(5)	105.71 (2)	C(25)—C(24)—H(23)	146.26 (2)
C(3)—C(4)—C(6)	66.928 (18)	C(25)—C(24)—H(24)	119.37 (3)
C(3)—C(4)—C(7)	39.704 (16)	C(25)—C(24)—H(25)	25.625 (12)
C(3)—C(4)—H(3)	25.514 (13)	H(23)—C(24)—H(24)	94.306 (17)
C(3)—C(4)—H(4)	125.03 (3)	H(23)—C(24)—H(25)	171.447 (15)
C(3)—C(4)—H(5)	125.93 (2)	H(24)—C(24)—H(25)	93.756 (18)
C(5)—C(4)—C(6)	38.778 (16)	C(20)—C(25)—C(24)	120.07 (2)
C(5)—C(4)—C(7)	72.486 (19)	C(20)—C(25)—H(24)	146.09 (2)
C(5)—C(4)—H(3)	130.16 (2)	C(20)—C(25)—H(25)	119.52 (2)
C(5)—C(4)—H(4)	124.72 (3)	C(24)—C(25)—H(24)	26.029 (13)
C(5)—C(4)—H(5)	22.738 (14)	C(24)—C(25)—H(25)	120.34 (2)
C(6)—C(4)—C(7)	38.045 (12)	H(24)—C(25)—H(25)	94.326 (15)
C(6)—C(4)—H(3)	91.685 (14)	C(1)—H(1)—C(2)	30.088 (19)
C(6)—C(4)—H(4)	156.68 (3)	C(1)—H(1)—C(6)	31.280 (18)
C(6)—C(4)—H(5)	60.038 (11)	C(2)—H(1)—C(6)	61.367 (11)
C(7)—C(4)—H(3)	59.071 (11)	C(1)—H(2)—C(2)	29.402 (19)
C(7)—C(4)—H(4)	136.44 (2)	C(1)—H(2)—C(3)	61.542 (11)
C(7)—C(4)—H(5)	88.468 (14)	C(1)—H(2)—H(18)ⁱ	96.512 (7)
H(3)—C(4)—H(4)	99.723 (19)	C(2)—H(2)—C(3)	32.707 (19)
H(3)—C(4)—H(5)	147.286 (14)	C(2)—H(2)—H(18)ⁱ	101.831 (16)
H(4)—C(4)—H(5)	101.99 (2)	C(3)—H(2)—H(18)ⁱ	96.244 (8)
RH(1)—C(5)—C(1)	59.018 (11)	C(2)—H(3)—C(3)	38.50 (2)
RH(1)—C(5)—C(3)	77.160 (13)	C(2)—H(3)—C(4)	63.520 (11)
RH(1)—C(5)—C(4)	70.473 (17)	C(2)—H(3)—C(7)	63.372 (12)
RH(1)—C(5)—C(6)	98.468 (19)	C(2)—H(3)—H(12)ⁱⁱ	97.659 (8)
RH(1)—C(5)—C(7)	106.980 (15)	C(2)—H(3)—H(13)ⁱⁱ	136.024 (8)
RH(1)—C(5)—H(4)	79.701 (10)	C(3)—H(3)—C(4)	37.226 (19)
RH(1)—C(5)—H(5)	118.47 (2)	C(3)—H(3)—C(7)	36.117 (18)
RH(1)—C(5)—H(6)	113.093 (14)	C(3)—H(3)—H(12)ⁱⁱ	126.862 (17)
C(1)—C(5)—C(3)	59.330 (14)	C(3)—H(3)—H(13)ⁱⁱ	121.788 (18)
C(1)—C(5)—C(4)	89.67 (2)	C(4)—H(3)—C(7)	62.923 (11)
C(1)—C(5)—C(6)	39.511 (15)	C(4)—H(3)—H(12)ⁱⁱ	108.442 (8)
C(1)—C(5)—C(7)	60.065 (14)	C(4)—H(3)—H(13)ⁱⁱ	84.812 (8)
C(1)—C(5)—H(4)	112.846 (15)	C(7)—H(3)—H(12)ⁱⁱ	160.956 (8)
C(1)—C(5)—H(5)	141.42 (2)	C(7)—H(3)—H(13)ⁱⁱ	129.231 (9)
C(1)—C(5)—H(6)	59.281 (11)	H(12)ⁱⁱ—H(3)—H(13)ⁱⁱ	62.7546
C(3)—C(5)—C(4)	39.030 (17)	C(3)—H(4)—C(4)	32.488 (18)
C(3)—C(5)—C(6)	67.062 (18)	C(3)—H(4)—C(5)	61.876 (11)
C(3)—C(5)—C(7)	38.166 (12)	C(3)—H(4)—H(15)	94.161 (8)
C(3)—C(5)—H(4)	61.587 (11)	C(4)—H(4)—C(5)	31.408 (19)
C(3)—C(5)—H(5)	157.68 (2)	C(4)—H(4)—H(15)	101.601 (16)
C(3)—C(5)—H(6)	92.384 (13)	C(5)—H(4)—H(15)	119.083 (7)
C(4)—C(5)—C(6)	106.09 (3)	C(4)—H(5)—C(5)	29.848 (18)
C(4)—C(5)—C(7)	72.902 (19)	C(4)—H(5)—C(6)	62.222 (11)
C(4)—C(5)—H(4)	23.873 (15)	C(4)—H(5)—H(9)	120.597 (8)
C(4)—C(5)—H(5)	127.41 (3)	C(5)—H(5)—C(6)	34.546 (17)
C(4)—C(5)—H(6)	130.96 (2)	C(5)—H(5)—H(9)	132.225 (15)
C(6)—C(5)—C(7)	39.766 (16)	C(6)—H(5)—H(9)	145.388 (8)
C(6)—C(5)—H(4)	127.71 (2)	C(1)—H(6)—C(5)	63.351 (11)
C(6)—C(5)—H(5)	121.59 (3)	C(1)—H(6)—C(6)	36.099 (19)
C(6)—C(5)—H(6)	26.511 (13)	C(1)—H(6)—C(7)	62.855 (12)
C(7)—C(5)—H(4)	90.239 (14)	C(5)—H(6)—C(6)	38.725 (18)
C(7)—C(5)—H(5)	134.04 (2)	C(5)—H(6)—C(7)	63.548 (11)
C(7)—C(5)—H(6)	59.049 (11)	C(6)—H(6)—C(7)	36.985 (18)
H(4)—C(5)—H(5)	103.55 (2)	C(3)—H(7B)—C(6)	60.990 (11)
H(4)—C(5)—H(6)	148.682 (15)	C(3)—H(7B)—C(7)	40.047 (19)
H(5)—C(5)—H(6)	95.157 (18)	C(3)—H(7B)—H(7A)	65.614 (9)
C(1)—C(6)—C(2)	34.437 (15)	C(6)—H(7B)—C(7)	39.13 (2)
C(1)—C(6)—C(3)	73.405 (19)	C(6)—H(7B)—H(7A)	65.955 (8)
C(1)—C(6)—C(4)	87.221 (18)	C(7)—H(7B)—H(7A)	35.009 (17)
C(1)—C(6)—C(5)	100.89 (2)	C(3)—H(7A)—C(6)	61.314 (11)
C(1)—C(6)—C(7)	100.84 (3)	C(3)—H(7A)—C(7)	40.69 (2)
C(1)—C(6)—H(1)	21.790 (13)	C(3)—H(7A)—H(7B)	66.367 (9)
C(1)—C(6)—H(5)	116.714 (19)	C(6)—H(7A)—C(7)	39.56 (2)
C(1)—C(6)—H(6)	118.99 (3)	C(6)—H(7A)—H(7B)	66.441 (8)
C(1)—C(6)—H(7B)	126.80 (2)	C(7)—H(7A)—H(7B)	35.010 (18)
C(1)—C(6)—H(7A)	88.741 (19)	C(8)—H(9)—C(9)	35.631 (14)
C(2)—C(6)—C(3)	38.968 (13)	C(8)—H(9)—C(10)	68.954 (9)
C(2)—C(6)—C(4)	60.509 (13)	C(8)—H(9)—H(5)	86.694 (6)
C(2)—C(6)—C(5)	87.689 (18)	C(9)—H(9)—C(10)	33.324 (15)
C(2)—C(6)—C(7)	72.183 (19)	C(9)—H(9)—H(5)	90.590 (13)
C(2)—C(6)—H(1)	56.227 (11)	C(10)—H(9)—H(5)	94.376 (7)
C(2)—C(6)—H(5)	110.832 (14)	C(9)—H(10)—C(10)	34.098 (16)
C(2)—C(6)—H(6)	151.13 (3)	C(9)—H(10)—C(11)	68.283 (10)
C(2)—C(6)—H(7B)	95.249 (14)	C(10)—H(10)—C(11)	34.185 (16)
C(2)—C(6)—H(7A)	71.507 (12)	C(10)—H(11)—C(11)	33.527 (17)
C(3)—C(6)—C(4)	38.931 (12)	C(10)—H(11)—C(12)	68.433 (10)
C(3)—C(6)—C(5)	74.061 (18)	C(11)—H(11)—C(12)	34.908 (17)
C(3)—C(6)—C(7)	43.125 (16)	C(11)—H(12)—C(12)	34.195 (16)
C(3)—C(6)—H(1)	95.194 (15)	C(11)—H(12)—C(13)	68.543 (10)
C(3)—C(6)—H(5)	96.108 (14)	C(11)—H(12)—H(3)ⁱⁱ	149.067 (7)
C(3)—C(6)—H(6)	160.76 (2)	C(12)—H(12)—C(13)	34.364 (16)
C(3)—C(6)—H(7B)	59.158 (12)	C(12)—H(12)—H(3)ⁱⁱ	116.929 (15)
C(3)—C(6)—H(7A)	58.897 (11)	C(13)—H(12)—H(3)ⁱⁱ	83.321 (6)
C(4)—C(6)—C(5)	35.130 (15)	C(8)—H(13)—C(12)	68.707 (9)
C(4)—C(6)—C(7)	71.620 (18)	C(8)—H(13)—C(13)	34.039 (14)
C(4)—C(6)—H(1)	104.696 (13)	C(8)—H(13)—H(3)ⁱⁱ	148.518 (6)
C(4)—C(6)—H(5)	57.739 (11)	C(12)—H(13)—C(13)	34.670 (14)
C(4)—C(6)—H(6)	147.04 (3)	C(12)—H(13)—H(3)ⁱⁱ	84.060 (7)
C(4)—C(6)—H(7B)	71.268 (12)	C(13)—H(13)—H(3)ⁱⁱ	117.200 (13)
C(4)—C(6)—H(7A)	94.791 (14)	C(14)—H(15)—C(15)	33.297 (14)
C(5)—C(6)—C(7)	100.66 (2)	C(14)—H(15)—C(16)	68.827 (10)
C(5)—C(6)—H(1)	107.870 (18)	C(14)—H(15)—H(4)	107.583 (6)
C(5)—C(6)—H(5)	23.867 (13)	C(15)—H(15)—C(16)	35.542 (15)
C(5)—C(6)—H(6)	114.76 (3)	C(15)—H(15)—H(4)	133.468 (15)
C(5)—C(6)—H(7B)	88.662 (18)	C(16)—H(15)—H(4)	149.271 (9)
C(5)—C(6)—H(7A)	126.89 (2)	C(15)—H(16)—C(16)	33.837 (16)
C(7)—C(6)—H(1)	118.40 (2)	C(15)—H(16)—C(17)	68.484 (10)
C(7)—C(6)—H(5)	112.50 (2)	C(16)—H(16)—C(17)	34.690 (16)
C(7)—C(6)—H(6)	117.70 (3)	C(16)—H(17)—C(17)	34.970 (18)
C(7)—C(6)—H(7B)	26.651 (15)	C(16)—H(17)—C(18)	68.133 (11)
C(7)—C(6)—H(7A)	26.912 (14)	C(16)—H(17)—H(24)ⁱⁱⁱ	123.868 (7)
H(1)—C(6)—H(5)	115.470 (13)	C(17)—H(17)—C(18)	33.168 (18)
H(1)—C(6)—H(6)	97.865 (19)	C(17)—H(17)—H(24)ⁱⁱⁱ	153.937 (16)
H(1)—C(6)—H(7B)	145.027 (15)	C(18)—H(17)—H(24)ⁱⁱⁱ	157.927 (7)
H(1)—C(6)—H(7A)	99.983 (13)	C(17)—H(18)—C(18)	34.515 (16)
H(5)—C(6)—H(6)	90.975 (19)	C(17)—H(18)—C(19)	68.528 (10)
H(5)—C(6)—H(7B)	92.225 (12)	C(17)—H(18)—H(2)^iv	150.425 (8)
H(5)—C(6)—H(7A)	138.873 (15)	C(18)—H(18)—C(19)	34.025 (16)
H(6)—C(6)—H(7B)	102.814 (19)	C(18)—H(18)—H(2)^iv	151.700 (15)
H(6)—C(6)—H(7A)	104.716 (19)	C(19)—H(18)—H(2)^iv	125.422 (7)
H(7B)—C(6)—H(7A)	47.604 (6)	C(14)—H(19)—C(18)	68.781 (9)
C(1)—C(7)—C(2)	33.809 (11)	C(14)—H(19)—C(19)	35.203 (14)
C(1)—C(7)—C(3)	69.647 (18)	C(14)—H(19)—C(21)	98.371 (9)
C(1)—C(7)—C(4)	70.789 (13)	C(14)—H(19)—H(21)	94.205 (6)
C(1)—C(7)—C(5)	59.902 (13)	C(18)—H(19)—C(19)	33.582 (14)
C(1)—C(7)—C(6)	39.440 (16)	C(18)—H(19)—C(21)	160.199 (10)
C(1)—C(7)—H(3)	90.554 (14)	C(18)—H(19)—H(21)	135.276 (8)
C(1)—C(7)—H(6)	58.704 (11)	C(19)—H(19)—C(21)	132.057 (14)
C(1)—C(7)—H(7B)	152.08 (3)	C(19)—H(19)—H(21)	119.155 (14)
C(1)—C(7)—H(7A)	93.43 (2)	C(21)—H(19)—H(21)	27.157 (6)
C(2)—C(7)—C(3)	39.355 (17)	C(20)—H(21)—C(21)	34.883 (14)
C(2)—C(7)—C(4)	59.740 (13)	C(20)—H(21)—C(22)	68.795 (10)
C(2)—C(7)—C(5)	70.710 (13)	C(20)—H(21)—H(19)	74.659 (6)
C(2)—C(7)—C(6)	69.614 (18)	C(21)—H(21)—C(22)	33.913 (15)
C(2)—C(7)—H(3)	57.147 (11)	C(21)—H(21)—H(19)	84.004 (13)
C(2)—C(7)—H(6)	91.940 (14)	C(22)—H(21)—H(19)	94.693 (7)
C(2)—C(7)—H(7B)	150.87 (3)	C(21)—H(22)—C(22)	34.471 (16)
C(2)—C(7)—H(7A)	92.90 (2)	C(21)—H(22)—C(23)	68.390 (10)
C(3)—C(7)—C(4)	39.559 (17)	C(22)—H(22)—C(23)	33.929 (16)
C(3)—C(7)—C(5)	70.349 (18)	C(22)—H(23)—C(23)	34.209 (19)
C(3)—C(7)—C(6)	93.82 (2)	C(22)—H(23)—C(24)	68.210 (10)
C(3)—C(7)—H(3)	24.733 (13)	C(23)—H(23)—C(24)	34.007 (19)
C(3)—C(7)—H(6)	119.11 (2)	C(23)—H(24)—C(24)	34.142 (17)
C(3)—C(7)—H(7B)	112.78 (3)	C(23)—H(24)—C(25)	68.716 (10)
C(3)—C(7)—H(7A)	111.74 (3)	C(23)—H(24)—H(17)^v	122.583 (7)
C(4)—C(7)—C(5)	34.612 (11)	C(24)—H(24)—C(25)	34.601 (17)
C(4)—C(7)—C(6)	70.335 (17)	C(24)—H(24)—H(17)^v	145.291 (15)
C(4)—C(7)—H(3)	58.006 (11)	C(25)—H(24)—H(17)^v	146.610 (7)
C(4)—C(7)—H(6)	91.582 (14)	C(20)—H(25)—C(24)	68.507 (9)
C(4)—C(7)—H(7B)	93.36 (2)	C(20)—H(25)—C(25)	34.502 (14)
C(4)—C(7)—H(7A)	150.16 (3)	C(24)—H(25)—C(25)	34.031 (15)

Symmetry codes: (i) x−1, y, z; (ii) −x+2, −y+2, −z+1; (iii) x, y, z−1; (iv) x+1, y, z; (v) x, y, z+1.

Experimental details

Crystal data
Chemical formula	C₂₅H₂₃ClPRh
M_r	492.76
Crystal system, space group	Triclinic, P1
Temperature (K)	100
a, b, c (Å)	10.2430 (1), 10.4042 (1), 11.4078 (1)
α, β, γ (°)	99.213 (1), 103.131 (1), 115.080 (1)
V (Å³)	1026.01 (2)
Z	2
Radiation type	Mo Kα
µ (mm⁻¹)	1.05
Crystal size (mm)	× ×

Data collection
Diffractometer	Nonius Kappa CCD diffractometer
Absorption correction	–
No. of measured, independent and observed [I > 3 σ(I)] reflections	370693, 21647, 19920
R_int	0.038
(sin θ/λ)_max (Å⁻¹)	1.080

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.012, 0.012, 1.35
No. of reflections	19920
No. of parameters	514
H-atom treatment	Only H-atom displacement parameters refined
Δρ_max, Δρ_min (e Å⁻³)	0.20, −0.21

Computer programs: Collect (Nonius BV, 1997-2000), HKL SCALEPACK (Otwinowski & Minor 1997), HKL DENZO and SCALEPACK (Otwinowski & Minor 1997), SHELXS97 (Sheldrick, 1990), Volkov et al., (2006).

Selected geometric parameters (Å, º) top

RH(1)—CL(1)	2.3625 (1)	C(10)—H(10)	1.0800 (3)
RH(1)—P(1)	2.3034 (1)	C(10)—H(11)	2.1638 (3)
RH(1)—C(1)	2.2193 (3)	C(11)—C(12)	1.3948 (4)
RH(1)—C(2)	2.2192 (3)	C(11)—H(10)	2.1520 (3)
RH(1)—C(4)	2.1087 (3)	C(11)—H(11)	1.0800 (3)
RH(1)—C(5)	2.1058 (3)	C(11)—H(12)	2.1491 (3)
P(1)—C(8)	1.8322 (2)	C(12)—C(13)	1.3972 (4)
P(1)—C(14)	1.8287 (2)	C(12)—H(11)	2.1361 (3)
P(1)—C(20)	1.8242 (2)	C(12)—H(12)	1.0800 (3)
C(1)—C(2)	1.3845 (4)	C(12)—H(13)	2.1432 (3)
C(1)—C(3)	2.3443 (4)	C(13)—H(12)	2.1488 (2)
C(1)—C(5)	2.3748 (4)	C(13)—H(13)	1.0800 (2)
C(1)—C(6)	1.5386 (4)	C(14)—C(15)	1.4021 (3)
C(1)—C(7)	2.3788 (5)	C(14)—C(19)	1.3995 (3)
C(1)—H(1)	1.1000 (3)	C(14)—H(15)	2.1733 (2)
C(1)—H(2)	2.2332 (3)	C(14)—H(19)	2.1358 (2)
C(1)—H(6)	2.2843 (3)	C(15)—C(16)	1.3947 (4)
C(2)—C(3)	1.5390 (5)	C(15)—H(15)	1.0800 (3)
C(2)—C(4)	2.3736 (5)	C(15)—H(16)	2.1554 (2)
C(2)—C(6)	2.3459 (4)	C(16)—C(17)	1.3918 (4)
C(2)—C(7)	2.3827 (5)	C(16)—H(15)	2.1241 (3)
C(2)—H(1)	2.2218 (3)	C(16)—H(16)	1.0800 (3)
C(2)—H(2)	1.1000 (3)	C(16)—H(17)	2.1315 (3)
C(2)—H(3)	2.2391 (3)	C(17)—C(18)	1.3899 (4)
C(3)—C(4)	1.5449 (5)	C(17)—H(16)	2.1367 (3)
C(3)—C(5)	2.3617 (5)	C(17)—H(17)	1.0800 (3)
C(3)—C(6)	2.2619 (4)	C(17)—H(18)	2.1378 (3)
C(3)—C(7)	1.5497 (4)	C(18)—C(19)	1.3944 (3)
C(3)—H(2)	2.3452 (4)	C(18)—H(17)	2.1621 (3)
C(3)—H(3)	1.1000 (3)	C(18)—H(18)	1.0800 (3)
C(3)—H(4)	2.3554 (3)	C(18)—H(19)	2.1596 (3)
C(3)—H(7B)	2.2207 (3)	C(19)—H(18)	2.1517 (2)
C(3)—H(7A)	2.2078 (3)	C(19)—H(19)	1.0800 (3)
C(4)—C(5)	1.4164 (4)	C(20)—C(21)	1.4065 (3)
C(4)—C(6)	2.3650 (4)	C(20)—C(25)	1.3968 (3)
C(4)—C(7)	2.3834 (4)	C(20)—H(21)	2.1496 (2)
C(4)—H(3)	2.2702 (3)	C(20)—H(25)	2.1458 (2)
C(4)—H(4)	1.1000 (3)	C(21)—C(22)	1.3915 (4)
C(4)—H(5)	2.2604 (3)	C(21)—H(19)	2.3533 (2)
C(5)—C(6)	1.5416 (4)	C(21)—H(21)	1.0800 (2)
C(5)—C(7)	2.3780 (4)	C(21)—H(22)	2.1404 (2)
C(5)—H(4)	2.2341 (3)	C(22)—C(23)	1.3980 (4)
C(5)—H(5)	1.1000 (3)	C(22)—H(21)	2.1505 (3)
C(5)—H(6)	2.2377 (3)	C(22)—H(22)	1.0800 (3)
C(6)—C(7)	1.5478 (5)	C(22)—H(23)	2.1524 (3)
C(6)—H(1)	2.3688 (3)	C(23)—C(24)	1.3911 (4)
C(6)—H(5)	2.3158 (3)	C(23)—H(22)	2.1575 (3)
C(6)—H(6)	1.1000 (3)	C(23)—H(23)	1.0800 (3)
C(6)—H(7B)	2.2366 (3)	C(23)—H(24)	2.1460 (3)
C(6)—H(7A)	2.2282 (3)	C(24)—C(25)	1.3976 (4)
C(7)—H(3)	2.2961 (3)	C(24)—H(23)	2.1484 (3)
C(7)—H(6)	2.2779 (3)	C(24)—H(24)	1.0800 (3)
C(7)—H(7B)	1.1000 (4)	C(24)—H(25)	2.1552 (3)
C(7)—H(7A)	1.1000 (3)	C(25)—H(24)	2.1448 (2)
C(8)—C(9)	1.4059 (3)	C(25)—H(25)	1.0800 (3)
C(8)—C(13)	1.3991 (3)	H(2)—H(18)ⁱ	2.3520
C(8)—H(9)	2.1351 (2)	H(3)—H(12)ⁱⁱ	2.3707
C(8)—H(13)	2.1567 (2)	H(3)—H(13)ⁱⁱ	2.3576
C(9)—C(10)	1.3952 (4)	H(4)—H(15)	2.3572
C(9)—H(9)	1.0800 (2)	H(5)—H(9)	2.3031
C(9)—H(10)	2.1513 (2)	H(7B)—H(7A)	1.8019
C(10)—C(11)	1.3972 (4)	H(17)—H(24)ⁱⁱⁱ	2.2004
C(10)—H(9)	2.1652 (3)	H(19)—H(21)	2.2067

CL(1)—RH(1)—P(1)	96.346 (2)	C(5)—C(7)—C(6)	39.576 (16)
CL(1)—RH(1)—C(1)	93.758 (8)	C(5)—C(7)—H(3)	91.996 (13)
CL(1)—RH(1)—C(2)	95.090 (9)	C(5)—C(7)—H(6)	57.403 (11)
CL(1)—RH(1)—C(4)	157.369 (9)	C(5)—C(7)—H(7B)	93.87 (2)
CL(1)—RH(1)—C(5)	154.088 (9)	C(5)—C(7)—H(7A)	151.57 (3)
P(1)—RH(1)—C(1)	164.189 (9)	C(6)—C(7)—H(3)	118.53 (2)
P(1)—RH(1)—C(2)	153.217 (9)	C(6)—C(7)—H(6)	25.313 (12)
P(1)—RH(1)—C(4)	95.663 (9)	C(6)—C(7)—H(7B)	114.22 (3)
P(1)—RH(1)—C(5)	99.964 (8)	C(6)—C(7)—H(7A)	113.53 (3)
C(1)—RH(1)—C(2)	36.352 (11)	H(3)—C(7)—H(6)	143.836 (15)
C(1)—RH(1)—C(4)	79.135 (12)	H(3)—C(7)—H(7B)	100.47 (2)
C(1)—RH(1)—C(5)	66.548 (12)	H(3)—C(7)—H(7A)	98.38 (2)
C(2)—RH(1)—C(4)	66.464 (13)	H(6)—C(7)—H(7B)	100.40 (2)
C(2)—RH(1)—C(5)	79.078 (12)	H(6)—C(7)—H(7A)	101.76 (2)
C(4)—RH(1)—C(5)	39.276 (12)	H(7B)—C(7)—H(7A)	109.98 (3)
RH(1)—P(1)—C(8)	114.197 (8)	P(1)—C(8)—C(9)	117.895 (18)
RH(1)—P(1)—C(14)	109.506 (8)	P(1)—C(8)—C(13)	123.135 (18)
RH(1)—P(1)—C(20)	121.381 (8)	P(1)—C(8)—H(9)	91.327 (10)
C(8)—P(1)—C(14)	104.183 (11)	P(1)—C(8)—H(13)	97.534 (10)
C(8)—P(1)—C(20)	100.444 (11)	C(9)—C(8)—C(13)	118.97 (2)
C(14)—P(1)—C(20)	105.455 (11)	C(9)—C(8)—H(9)	26.584 (11)
RH(1)—C(1)—C(2)	71.819 (17)	C(9)—C(8)—H(13)	144.565 (18)
RH(1)—C(1)—C(3)	75.419 (12)	C(13)—C(8)—H(9)	145.537 (19)
RH(1)—C(1)—C(5)	54.435 (10)	C(13)—C(8)—H(13)	25.600 (11)
RH(1)—C(1)—C(6)	93.981 (18)	H(9)—C(8)—H(13)	171.133 (13)
RH(1)—C(1)—C(7)	103.305 (14)	C(8)—C(9)—C(10)	120.70 (2)
RH(1)—C(1)—H(1)	102.015 (19)	C(8)—C(9)—H(9)	117.78 (2)
RH(1)—C(1)—H(2)	78.416 (10)	C(8)—C(9)—H(10)	146.415 (19)
RH(1)—C(1)—H(6)	107.179 (13)	C(10)—C(9)—H(9)	121.51 (2)
C(2)—C(1)—C(3)	39.009 (18)	C(10)—C(9)—H(10)	25.719 (12)
C(2)—C(1)—C(5)	90.27 (2)	H(9)—C(9)—H(10)	95.800 (14)
C(2)—C(1)—C(6)	106.63 (3)	C(9)—C(10)—C(11)	119.74 (2)
C(2)—C(1)—C(7)	73.25 (2)	C(9)—C(10)—H(9)	25.167 (11)
C(2)—C(1)—H(1)	126.44 (3)	C(9)—C(10)—H(10)	120.18 (2)
C(2)—C(1)—H(2)	22.957 (15)	C(9)—C(10)—H(11)	145.011 (19)
C(2)—C(1)—H(6)	130.39 (2)	C(11)—C(10)—H(9)	144.90 (2)
C(3)—C(1)—C(5)	60.057 (14)	C(11)—C(10)—H(10)	120.07 (2)
C(3)—C(1)—C(6)	67.620 (18)	C(11)—C(10)—H(11)	25.273 (13)
C(3)—C(1)—C(7)	38.299 (12)	H(9)—C(10)—H(10)	95.025 (17)
C(3)—C(1)—H(1)	165.44 (3)	H(9)—C(10)—H(11)	170.171 (13)
C(3)—C(1)—H(2)	61.581 (12)	H(10)—C(10)—H(11)	94.802 (16)
C(3)—C(1)—H(6)	91.665 (14)	C(10)—C(11)—C(12)	120.01 (2)
C(5)—C(1)—C(6)	39.603 (15)	C(10)—C(11)—H(10)	25.741 (12)
C(5)—C(1)—C(7)	60.033 (13)	C(10)—C(11)—H(11)	121.20 (3)
C(5)—C(1)—H(1)	130.30 (2)	C(10)—C(11)—H(12)	145.74 (2)
C(5)—C(1)—H(2)	111.083 (14)	C(12)—C(11)—H(10)	145.75 (2)
C(5)—C(1)—H(6)	57.368 (10)	C(12)—C(11)—H(11)	118.79 (3)
C(6)—C(1)—C(7)	39.722 (16)	C(12)—C(11)—H(12)	25.796 (12)
C(6)—C(1)—H(1)	126.93 (3)	H(10)—C(11)—H(11)	95.460 (18)
C(6)—C(1)—H(2)	128.96 (2)	H(10)—C(11)—H(12)	171.410 (15)
C(6)—C(1)—H(6)	24.912 (12)	H(11)—C(11)—H(12)	93.045 (18)
C(7)—C(1)—H(1)	152.11 (2)	C(11)—C(12)—C(13)	120.18 (2)
C(7)—C(1)—H(2)	92.517 (14)	C(11)—C(12)—H(11)	26.302 (13)
C(7)—C(1)—H(6)	58.441 (11)	C(11)—C(12)—H(12)	120.01 (2)
H(1)—C(1)—H(2)	103.87 (2)	C(11)—C(12)—H(13)	146.25 (2)
H(1)—C(1)—H(6)	102.72 (2)	C(13)—C(12)—H(11)	146.47 (2)
H(2)—C(1)—H(6)	150.947 (16)	C(13)—C(12)—H(12)	119.77 (2)
RH(1)—C(2)—C(1)	71.829 (18)	C(13)—C(12)—H(13)	26.084 (11)
RH(1)—C(2)—C(3)	94.267 (19)	H(11)—C(12)—H(12)	93.758 (16)
RH(1)—C(2)—C(4)	54.536 (10)	H(11)—C(12)—H(13)	172.420 (14)
RH(1)—C(2)—C(6)	75.191 (12)	H(12)—C(12)—H(13)	93.734 (17)
RH(1)—C(2)—C(7)	103.183 (15)	C(8)—C(13)—C(12)	120.39 (2)
RH(1)—C(2)—H(1)	74.054 (10)	C(8)—C(13)—H(12)	146.203 (19)
RH(1)—C(2)—H(2)	111.47 (2)	C(8)—C(13)—H(13)	120.36 (2)
RH(1)—C(2)—H(3)	108.641 (14)	C(12)—C(13)—H(12)	25.867 (12)
C(1)—C(2)—C(3)	106.50 (3)	C(12)—C(13)—H(13)	119.25 (2)
C(1)—C(2)—C(4)	90.49 (2)	H(12)—C(13)—H(13)	93.427 (14)
C(1)—C(2)—C(6)	38.935 (18)	P(1)—C(14)—C(15)	117.357 (18)
C(1)—C(2)—C(7)	72.94 (2)	P(1)—C(14)—C(19)	123.988 (18)
C(1)—C(2)—H(1)	23.472 (15)	P(1)—C(14)—H(15)	92.410 (10)
C(1)—C(2)—H(2)	127.64 (3)	P(1)—C(14)—H(19)	97.574 (10)
C(1)—C(2)—H(3)	131.47 (2)	C(15)—C(14)—C(19)	118.65 (2)
C(3)—C(2)—C(4)	39.767 (16)	C(15)—C(14)—H(15)	25.015 (11)
C(3)—C(2)—C(6)	67.566 (18)	C(15)—C(14)—H(19)	145.068 (18)
C(3)—C(2)—C(7)	39.682 (16)	C(19)—C(14)—H(15)	143.569 (18)
C(3)—C(2)—H(1)	129.97 (2)	C(19)—C(14)—H(19)	26.415 (11)
C(3)—C(2)—H(2)	124.57 (3)	H(15)—C(14)—H(19)	169.814 (12)
C(3)—C(2)—H(3)	26.421 (13)	C(14)—C(15)—C(16)	120.58 (2)
C(4)—C(2)—C(6)	60.143 (13)	C(14)—C(15)—H(15)	121.69 (2)
C(4)—C(2)—C(7)	60.145 (14)	C(14)—C(15)—H(16)	146.080 (19)
C(4)—C(2)—H(1)	109.244 (15)	C(16)—C(15)—H(15)	117.70 (2)
C(4)—C(2)—H(2)	135.74 (2)	C(16)—C(15)—H(16)	25.544 (13)
C(4)—C(2)—H(3)	58.878 (11)	H(15)—C(15)—H(16)	92.161 (15)
C(6)—C(2)—C(7)	38.203 (12)	C(15)—C(16)—C(17)	120.17 (3)
C(6)—C(2)—H(1)	62.406 (11)	C(15)—C(16)—H(15)	26.753 (12)
C(6)—C(2)—H(2)	164.02 (3)	C(15)—C(16)—H(16)	120.62 (3)
C(6)—C(2)—H(3)	92.977 (14)	C(15)—C(16)—H(17)	146.57 (2)
C(7)—C(2)—H(1)	94.771 (14)	C(17)—C(16)—H(15)	146.86 (2)
C(7)—C(2)—H(2)	143.71 (2)	C(17)—C(16)—H(16)	119.10 (2)
C(7)—C(2)—H(3)	59.482 (12)	C(17)—C(16)—H(17)	26.408 (12)
H(1)—C(2)—H(2)	104.56 (2)	H(15)—C(16)—H(16)	93.867 (18)
H(1)—C(2)—H(3)	154.227 (16)	H(15)—C(16)—H(17)	173.023 (15)
H(2)—C(2)—H(3)	98.23 (2)	H(16)—C(16)—H(17)	92.719 (16)
C(1)—C(3)—C(2)	34.491 (15)	C(16)—C(17)—C(18)	119.69 (2)
C(1)—C(3)—C(4)	87.826 (19)	C(16)—C(17)—H(16)	26.209 (13)
C(1)—C(3)—C(5)	60.613 (13)	C(16)—C(17)—H(17)	118.62 (3)
C(1)—C(3)—C(6)	38.975 (12)	C(16)—C(17)—H(18)	145.81 (2)
C(1)—C(3)—C(7)	72.054 (19)	C(18)—C(17)—H(16)	145.80 (2)
C(1)—C(3)—H(2)	56.877 (11)	C(18)—C(17)—H(17)	121.67 (3)
C(1)—C(3)—H(3)	147.10 (3)	C(18)—C(17)—H(18)	26.122 (12)
C(1)—C(3)—H(4)	109.614 (14)	H(16)—C(17)—H(17)	92.438 (18)
C(1)—C(3)—H(7B)	95.873 (14)	H(16)—C(17)—H(18)	171.848 (14)
C(1)—C(3)—H(7A)	72.061 (12)	H(17)—C(17)—H(18)	95.572 (18)
C(2)—C(3)—C(4)	100.65 (2)	C(17)—C(18)—C(19)	120.32 (2)
C(2)—C(3)—C(5)	87.178 (19)	C(17)—C(18)—H(17)	25.158 (12)
C(2)—C(3)—C(6)	73.465 (19)	C(17)—C(18)—H(18)	119.36 (2)
C(2)—C(3)—C(7)	100.96 (3)	C(17)—C(18)—H(19)	145.68 (2)
C(2)—C(3)—H(2)	22.719 (13)	C(19)—C(18)—H(17)	145.47 (2)
C(2)—C(3)—H(3)	115.08 (3)	C(19)—C(18)—H(18)	120.29 (3)
C(2)—C(3)—H(4)	115.52 (2)	C(19)—C(18)—H(19)	25.368 (12)
C(2)—C(3)—H(7B)	127.55 (2)	H(17)—C(18)—H(18)	94.225 (15)
C(2)—C(3)—H(7A)	89.239 (19)	H(17)—C(18)—H(19)	170.833 (14)
C(4)—C(3)—C(5)	35.264 (15)	H(18)—C(18)—H(19)	94.927 (17)
C(4)—C(3)—C(6)	74.140 (18)	C(14)—C(19)—C(18)	120.56 (2)
C(4)—C(3)—C(7)	100.74 (3)	C(14)—C(19)—H(18)	146.218 (19)
C(4)—C(3)—H(2)	111.85 (2)	C(14)—C(19)—H(19)	118.38 (2)
C(4)—C(3)—H(3)	117.26 (3)	C(18)—C(19)—H(18)	25.684 (13)
C(4)—C(3)—H(4)	22.484 (13)	C(18)—C(19)—H(19)	121.05 (2)
C(4)—C(3)—H(7B)	89.00 (2)	H(18)—C(19)—H(19)	95.369 (15)
C(4)—C(3)—H(7A)	127.76 (2)	P(1)—C(20)—C(21)	120.675 (18)
C(5)—C(3)—C(6)	38.877 (12)	P(1)—C(20)—C(25)	120.184 (19)
C(5)—C(3)—C(7)	71.484 (19)	P(1)—C(20)—H(21)	94.642 (10)
C(5)—C(3)—H(2)	107.684 (14)	P(1)—C(20)—H(25)	94.226 (10)
C(5)—C(3)—H(3)	150.44 (3)	C(21)—C(20)—C(25)	119.14 (2)
C(5)—C(3)—H(4)	56.537 (11)	C(21)—C(20)—H(21)	26.050 (11)
C(5)—C(3)—H(7B)	71.713 (12)	C(21)—C(20)—H(25)	145.093 (18)
C(5)—C(3)—H(7A)	95.576 (14)	C(25)—C(20)—H(21)	145.153 (19)
C(6)—C(3)—C(7)	43.059 (16)	C(25)—C(20)—H(25)	25.974 (12)
C(6)—C(3)—H(2)	95.728 (15)	H(21)—C(20)—H(25)	171.127 (12)
C(6)—C(3)—H(3)	162.13 (3)	C(20)—C(21)—C(22)	120.50 (2)
C(6)—C(3)—H(4)	94.937 (15)	C(20)—C(21)—H(19)	85.357 (14)
C(6)—C(3)—H(7B)	59.852 (11)	C(20)—C(21)—H(21)	119.07 (2)
C(6)—C(3)—H(7A)	59.789 (11)	C(20)—C(21)—H(22)	146.558 (19)
C(7)—C(3)—H(2)	116.22 (2)	C(22)—C(21)—H(19)	115.279 (18)
C(7)—C(3)—H(3)	119.15 (3)	C(22)—C(21)—H(21)	120.43 (2)
C(7)—C(3)—H(4)	112.05 (2)	C(22)—C(21)—H(22)	26.059 (13)
C(7)—C(3)—H(7B)	27.175 (15)	H(19)—C(21)—H(21)	68.839 (12)
C(7)—C(3)—H(7A)	27.569 (15)	H(19)—C(21)—H(22)	108.001 (10)
H(2)—C(3)—H(3)	92.43 (2)	H(21)—C(21)—H(22)	94.367 (15)
H(2)—C(3)—H(4)	118.912 (13)	C(21)—C(22)—C(23)	119.98 (2)
H(2)—C(3)—H(7B)	143.104 (16)	C(21)—C(22)—H(21)	25.661 (12)
H(2)—C(3)—H(7A)	96.708 (13)	C(21)—C(22)—H(22)	119.47 (3)
H(3)—C(3)—H(4)	94.98 (2)	C(21)—C(22)—H(23)	145.71 (2)
H(3)—C(3)—H(7B)	104.93 (2)	C(23)—C(22)—H(21)	145.62 (2)
H(3)—C(3)—H(7A)	103.51 (2)	C(23)—C(22)—H(22)	120.53 (2)
H(4)—C(3)—H(7B)	92.168 (13)	C(23)—C(22)—H(23)	25.742 (13)
H(4)—C(3)—H(7A)	139.059 (17)	H(21)—C(22)—H(22)	93.809 (17)
H(7B)—C(3)—H(7A)	48.019 (7)	H(21)—C(22)—H(23)	171.262 (14)
RH(1)—C(4)—C(2)	59.000 (11)	H(22)—C(22)—H(23)	94.787 (16)
RH(1)—C(4)—C(3)	98.54 (2)	C(22)—C(23)—C(24)	119.68 (2)
RH(1)—C(4)—C(5)	70.250 (17)	C(22)—C(23)—H(22)	25.544 (12)
RH(1)—C(4)—C(6)	76.828 (12)	C(22)—C(23)—H(23)	120.05 (3)
RH(1)—C(4)—C(7)	106.690 (15)	C(22)—C(23)—H(24)	145.51 (2)
RH(1)—C(4)—H(3)	111.537 (14)	C(24)—C(23)—H(22)	145.20 (2)
RH(1)—C(4)—H(4)	116.73 (2)	C(24)—C(23)—H(23)	120.26 (3)
RH(1)—C(4)—H(5)	79.709 (10)	C(24)—C(23)—H(24)	25.831 (12)
C(2)—C(4)—C(3)	39.583 (16)	H(22)—C(23)—H(23)	94.51 (2)
C(2)—C(4)—C(5)	89.56 (2)	H(22)—C(23)—H(24)	171.013 (14)
C(2)—C(4)—C(6)	59.348 (13)	H(23)—C(23)—H(24)	94.441 (19)
C(2)—C(4)—C(7)	60.116 (14)	C(23)—C(24)—C(25)	120.54 (2)
C(2)—C(4)—H(3)	57.602 (11)	C(23)—C(24)—H(23)	25.735 (13)
C(2)—C(4)—H(4)	143.46 (3)	C(23)—C(24)—H(24)	120.03 (3)
C(2)—C(4)—H(5)	111.812 (14)	C(23)—C(24)—H(25)	146.03 (2)
C(3)—C(4)—C(5)	105.71 (2)	C(25)—C(24)—H(23)	146.26 (2)
C(3)—C(4)—C(6)	66.928 (18)	C(25)—C(24)—H(24)	119.37 (3)
C(3)—C(4)—C(7)	39.704 (16)	C(25)—C(24)—H(25)	25.625 (12)
C(3)—C(4)—H(3)	25.514 (13)	H(23)—C(24)—H(24)	94.306 (17)
C(3)—C(4)—H(4)	125.03 (3)	H(23)—C(24)—H(25)	171.447 (15)
C(3)—C(4)—H(5)	125.93 (2)	H(24)—C(24)—H(25)	93.756 (18)
C(5)—C(4)—C(6)	38.778 (16)	C(20)—C(25)—C(24)	120.07 (2)
C(5)—C(4)—C(7)	72.486 (19)	C(20)—C(25)—H(24)	146.09 (2)
C(5)—C(4)—H(3)	130.16 (2)	C(20)—C(25)—H(25)	119.52 (2)
C(5)—C(4)—H(4)	124.72 (3)	C(24)—C(25)—H(24)	26.029 (13)
C(5)—C(4)—H(5)	22.738 (14)	C(24)—C(25)—H(25)	120.34 (2)
C(6)—C(4)—C(7)	38.045 (12)	H(24)—C(25)—H(25)	94.326 (15)
C(6)—C(4)—H(3)	91.685 (14)	C(1)—H(1)—C(2)	30.088 (19)
C(6)—C(4)—H(4)	156.68 (3)	C(1)—H(1)—C(6)	31.280 (18)
C(6)—C(4)—H(5)	60.038 (11)	C(2)—H(1)—C(6)	61.367 (11)
C(7)—C(4)—H(3)	59.071 (11)	C(1)—H(2)—C(2)	29.402 (19)
C(7)—C(4)—H(4)	136.44 (2)	C(1)—H(2)—C(3)	61.542 (11)
C(7)—C(4)—H(5)	88.468 (14)	C(1)—H(2)—H(18)ⁱ	96.512 (7)
H(3)—C(4)—H(4)	99.723 (19)	C(2)—H(2)—C(3)	32.707 (19)
H(3)—C(4)—H(5)	147.286 (14)	C(2)—H(2)—H(18)ⁱ	101.831 (16)
H(4)—C(4)—H(5)	101.99 (2)	C(3)—H(2)—H(18)ⁱ	96.244 (8)
RH(1)—C(5)—C(1)	59.018 (11)	C(2)—H(3)—C(3)	38.50 (2)
RH(1)—C(5)—C(3)	77.160 (13)	C(2)—H(3)—C(4)	63.520 (11)
RH(1)—C(5)—C(4)	70.473 (17)	C(2)—H(3)—C(7)	63.372 (12)
RH(1)—C(5)—C(6)	98.468 (19)	C(2)—H(3)—H(12)ⁱⁱ	97.659 (8)
RH(1)—C(5)—C(7)	106.980 (15)	C(2)—H(3)—H(13)ⁱⁱ	136.024 (8)
RH(1)—C(5)—H(4)	79.701 (10)	C(3)—H(3)—C(4)	37.226 (19)
RH(1)—C(5)—H(5)	118.47 (2)	C(3)—H(3)—C(7)	36.117 (18)
RH(1)—C(5)—H(6)	113.093 (14)	C(3)—H(3)—H(12)ⁱⁱ	126.862 (17)
C(1)—C(5)—C(3)	59.330 (14)	C(3)—H(3)—H(13)ⁱⁱ	121.788 (18)
C(1)—C(5)—C(4)	89.67 (2)	C(4)—H(3)—C(7)	62.923 (11)
C(1)—C(5)—C(6)	39.511 (15)	C(4)—H(3)—H(12)ⁱⁱ	108.442 (8)
C(1)—C(5)—C(7)	60.065 (14)	C(4)—H(3)—H(13)ⁱⁱ	84.812 (8)
C(1)—C(5)—H(4)	112.846 (15)	C(7)—H(3)—H(12)ⁱⁱ	160.956 (8)
C(1)—C(5)—H(5)	141.42 (2)	C(7)—H(3)—H(13)ⁱⁱ	129.231 (9)
C(1)—C(5)—H(6)	59.281 (11)	H(12)ⁱⁱ—H(3)—H(13)ⁱⁱ	62.7546
C(3)—C(5)—C(4)	39.030 (17)	C(3)—H(4)—C(4)	32.488 (18)
C(3)—C(5)—C(6)	67.062 (18)	C(3)—H(4)—C(5)	61.876 (11)
C(3)—C(5)—C(7)	38.166 (12)	C(3)—H(4)—H(15)	94.161 (8)
C(3)—C(5)—H(4)	61.587 (11)	C(4)—H(4)—C(5)	31.408 (19)
C(3)—C(5)—H(5)	157.68 (2)	C(4)—H(4)—H(15)	101.601 (16)
C(3)—C(5)—H(6)	92.384 (13)	C(5)—H(4)—H(15)	119.083 (7)
C(4)—C(5)—C(6)	106.09 (3)	C(4)—H(5)—C(5)	29.848 (18)
C(4)—C(5)—C(7)	72.902 (19)	C(4)—H(5)—C(6)	62.222 (11)
C(4)—C(5)—H(4)	23.873 (15)	C(4)—H(5)—H(9)	120.597 (8)
C(4)—C(5)—H(5)	127.41 (3)	C(5)—H(5)—C(6)	34.546 (17)
C(4)—C(5)—H(6)	130.96 (2)	C(5)—H(5)—H(9)	132.225 (15)
C(6)—C(5)—C(7)	39.766 (16)	C(6)—H(5)—H(9)	145.388 (8)
C(6)—C(5)—H(4)	127.71 (2)	C(1)—H(6)—C(5)	63.351 (11)
C(6)—C(5)—H(5)	121.59 (3)	C(1)—H(6)—C(6)	36.099 (19)
C(6)—C(5)—H(6)	26.511 (13)	C(1)—H(6)—C(7)	62.855 (12)
C(7)—C(5)—H(4)	90.239 (14)	C(5)—H(6)—C(6)	38.725 (18)
C(7)—C(5)—H(5)	134.04 (2)	C(5)—H(6)—C(7)	63.548 (11)
C(7)—C(5)—H(6)	59.049 (11)	C(6)—H(6)—C(7)	36.985 (18)
H(4)—C(5)—H(5)	103.55 (2)	C(3)—H(7B)—C(6)	60.990 (11)
H(4)—C(5)—H(6)	148.682 (15)	C(3)—H(7B)—C(7)	40.047 (19)
H(5)—C(5)—H(6)	95.157 (18)	C(3)—H(7B)—H(7A)	65.614 (9)
C(1)—C(6)—C(2)	34.437 (15)	C(6)—H(7B)—C(7)	39.13 (2)
C(1)—C(6)—C(3)	73.405 (19)	C(6)—H(7B)—H(7A)	65.955 (8)
C(1)—C(6)—C(4)	87.221 (18)	C(7)—H(7B)—H(7A)	35.009 (17)
C(1)—C(6)—C(5)	100.89 (2)	C(3)—H(7A)—C(6)	61.314 (11)
C(1)—C(6)—C(7)	100.84 (3)	C(3)—H(7A)—C(7)	40.69 (2)
C(1)—C(6)—H(1)	21.790 (13)	C(3)—H(7A)—H(7B)	66.367 (9)
C(1)—C(6)—H(5)	116.714 (19)	C(6)—H(7A)—C(7)	39.56 (2)
C(1)—C(6)—H(6)	118.99 (3)	C(6)—H(7A)—H(7B)	66.441 (8)
C(1)—C(6)—H(7B)	126.80 (2)	C(7)—H(7A)—H(7B)	35.010 (18)
C(1)—C(6)—H(7A)	88.741 (19)	C(8)—H(9)—C(9)	35.631 (14)
C(2)—C(6)—C(3)	38.968 (13)	C(8)—H(9)—C(10)	68.954 (9)
C(2)—C(6)—C(4)	60.509 (13)	C(8)—H(9)—H(5)	86.694 (6)
C(2)—C(6)—C(5)	87.689 (18)	C(9)—H(9)—C(10)	33.324 (15)
C(2)—C(6)—C(7)	72.183 (19)	C(9)—H(9)—H(5)	90.590 (13)
C(2)—C(6)—H(1)	56.227 (11)	C(10)—H(9)—H(5)	94.376 (7)
C(2)—C(6)—H(5)	110.832 (14)	C(9)—H(10)—C(10)	34.098 (16)
C(2)—C(6)—H(6)	151.13 (3)	C(9)—H(10)—C(11)	68.283 (10)
C(2)—C(6)—H(7B)	95.249 (14)	C(10)—H(10)—C(11)	34.185 (16)
C(2)—C(6)—H(7A)	71.507 (12)	C(10)—H(11)—C(11)	33.527 (17)
C(3)—C(6)—C(4)	38.931 (12)	C(10)—H(11)—C(12)	68.433 (10)
C(3)—C(6)—C(5)	74.061 (18)	C(11)—H(11)—C(12)	34.908 (17)
C(3)—C(6)—C(7)	43.125 (16)	C(11)—H(12)—C(12)	34.195 (16)
C(3)—C(6)—H(1)	95.194 (15)	C(11)—H(12)—C(13)	68.543 (10)
C(3)—C(6)—H(5)	96.108 (14)	C(11)—H(12)—H(3)ⁱⁱ	149.067 (7)
C(3)—C(6)—H(6)	160.76 (2)	C(12)—H(12)—C(13)	34.364 (16)
C(3)—C(6)—H(7B)	59.158 (12)	C(12)—H(12)—H(3)ⁱⁱ	116.929 (15)
C(3)—C(6)—H(7A)	58.897 (11)	C(13)—H(12)—H(3)ⁱⁱ	83.321 (6)
C(4)—C(6)—C(5)	35.130 (15)	C(8)—H(13)—C(12)	68.707 (9)
C(4)—C(6)—C(7)	71.620 (18)	C(8)—H(13)—C(13)	34.039 (14)
C(4)—C(6)—H(1)	104.696 (13)	C(8)—H(13)—H(3)ⁱⁱ	148.518 (6)
C(4)—C(6)—H(5)	57.739 (11)	C(12)—H(13)—C(13)	34.670 (14)
C(4)—C(6)—H(6)	147.04 (3)	C(12)—H(13)—H(3)ⁱⁱ	84.060 (7)
C(4)—C(6)—H(7B)	71.268 (12)	C(13)—H(13)—H(3)ⁱⁱ	117.200 (13)
C(4)—C(6)—H(7A)	94.791 (14)	C(14)—H(15)—C(15)	33.297 (14)
C(5)—C(6)—C(7)	100.66 (2)	C(14)—H(15)—C(16)	68.827 (10)
C(5)—C(6)—H(1)	107.870 (18)	C(14)—H(15)—H(4)	107.583 (6)
C(5)—C(6)—H(5)	23.867 (13)	C(15)—H(15)—C(16)	35.542 (15)
C(5)—C(6)—H(6)	114.76 (3)	C(15)—H(15)—H(4)	133.468 (15)
C(5)—C(6)—H(7B)	88.662 (18)	C(16)—H(15)—H(4)	149.271 (9)
C(5)—C(6)—H(7A)	126.89 (2)	C(15)—H(16)—C(16)	33.837 (16)
C(7)—C(6)—H(1)	118.40 (2)	C(15)—H(16)—C(17)	68.484 (10)
C(7)—C(6)—H(5)	112.50 (2)	C(16)—H(16)—C(17)	34.690 (16)
C(7)—C(6)—H(6)	117.70 (3)	C(16)—H(17)—C(17)	34.970 (18)
C(7)—C(6)—H(7B)	26.651 (15)	C(16)—H(17)—C(18)	68.133 (11)
C(7)—C(6)—H(7A)	26.912 (14)	C(16)—H(17)—H(24)ⁱⁱⁱ	123.868 (7)
H(1)—C(6)—H(5)	115.470 (13)	C(17)—H(17)—C(18)	33.168 (18)
H(1)—C(6)—H(6)	97.865 (19)	C(17)—H(17)—H(24)ⁱⁱⁱ	153.937 (16)
H(1)—C(6)—H(7B)	145.027 (15)	C(18)—H(17)—H(24)ⁱⁱⁱ	157.927 (7)
H(1)—C(6)—H(7A)	99.983 (13)	C(17)—H(18)—C(18)	34.515 (16)
H(5)—C(6)—H(6)	90.975 (19)	C(17)—H(18)—C(19)	68.528 (10)
H(5)—C(6)—H(7B)	92.225 (12)	C(17)—H(18)—H(2)^iv	150.425 (8)
H(5)—C(6)—H(7A)	138.873 (15)	C(18)—H(18)—C(19)	34.025 (16)
H(6)—C(6)—H(7B)	102.814 (19)	C(18)—H(18)—H(2)^iv	151.700 (15)
H(6)—C(6)—H(7A)	104.716 (19)	C(19)—H(18)—H(2)^iv	125.422 (7)
H(7B)—C(6)—H(7A)	47.604 (6)	C(14)—H(19)—C(18)	68.781 (9)
C(1)—C(7)—C(2)	33.809 (11)	C(14)—H(19)—C(19)	35.203 (14)
C(1)—C(7)—C(3)	69.647 (18)	C(14)—H(19)—C(21)	98.371 (9)
C(1)—C(7)—C(4)	70.789 (13)	C(14)—H(19)—H(21)	94.205 (6)
C(1)—C(7)—C(5)	59.902 (13)	C(18)—H(19)—C(19)	33.582 (14)
C(1)—C(7)—C(6)	39.440 (16)	C(18)—H(19)—C(21)	160.199 (10)
C(1)—C(7)—H(3)	90.554 (14)	C(18)—H(19)—H(21)	135.276 (8)
C(1)—C(7)—H(6)	58.704 (11)	C(19)—H(19)—C(21)	132.057 (14)
C(1)—C(7)—H(7B)	152.08 (3)	C(19)—H(19)—H(21)	119.155 (14)
C(1)—C(7)—H(7A)	93.43 (2)	C(21)—H(19)—H(21)	27.157 (6)
C(2)—C(7)—C(3)	39.355 (17)	C(20)—H(21)—C(21)	34.883 (14)
C(2)—C(7)—C(4)	59.740 (13)	C(20)—H(21)—C(22)	68.795 (10)
C(2)—C(7)—C(5)	70.710 (13)	C(20)—H(21)—H(19)	74.659 (6)
C(2)—C(7)—C(6)	69.614 (18)	C(21)—H(21)—C(22)	33.913 (15)
C(2)—C(7)—H(3)	57.147 (11)	C(21)—H(21)—H(19)	84.004 (13)
C(2)—C(7)—H(6)	91.940 (14)	C(22)—H(21)—H(19)	94.693 (7)
C(2)—C(7)—H(7B)	150.87 (3)	C(21)—H(22)—C(22)	34.471 (16)
C(2)—C(7)—H(7A)	92.90 (2)	C(21)—H(22)—C(23)	68.390 (10)
C(3)—C(7)—C(4)	39.559 (17)	C(22)—H(22)—C(23)	33.929 (16)
C(3)—C(7)—C(5)	70.349 (18)	C(22)—H(23)—C(23)	34.209 (19)
C(3)—C(7)—C(6)	93.82 (2)	C(22)—H(23)—C(24)	68.210 (10)
C(3)—C(7)—H(3)	24.733 (13)	C(23)—H(23)—C(24)	34.007 (19)
C(3)—C(7)—H(6)	119.11 (2)	C(23)—H(24)—C(24)	34.142 (17)
C(3)—C(7)—H(7B)	112.78 (3)	C(23)—H(24)—C(25)	68.716 (10)
C(3)—C(7)—H(7A)	111.74 (3)	C(23)—H(24)—H(17)^v	122.583 (7)
C(4)—C(7)—C(5)	34.612 (11)	C(24)—H(24)—C(25)	34.601 (17)
C(4)—C(7)—C(6)	70.335 (17)	C(24)—H(24)—H(17)^v	145.291 (15)
C(4)—C(7)—H(3)	58.006 (11)	C(25)—H(24)—H(17)^v	146.610 (7)
C(4)—C(7)—H(6)	91.582 (14)	C(20)—H(25)—C(24)	68.507 (9)
C(4)—C(7)—H(7B)	93.36 (2)	C(20)—H(25)—C(25)	34.502 (14)
C(4)—C(7)—H(7A)	150.16 (3)	C(24)—H(25)—C(25)	34.031 (15)

Symmetry codes: (i) x−1, y, z; (ii) −x+2, −y+2, −z+1; (iii) x, y, z−1; (iv) x+1, y, z; (v) x, y, z+1.

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page