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The title complex, [Cu2(C16H10NO2)4(H2O)2], has a centrosymmetric wheel-shaped dinuclear structure in which two symmetry-related CuII centers are bridged by four carboxyl­ate groups of distinct 2-phenylquinoline-4-carboxyl­ate (phqc) ligands, the Cu—Cu separation being 2.6507 (12) Å. Each CuII center is five-coordinated by four O atoms of carboxyl­ate groups in the basal plane and one O atom of a water mol­ecule in the apical position. In addition, the dinuclear mol­ecules are linked by inter­molecular O—H...N hydrogen bonds to form a one-dimensional supramolecular chain.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805034793/br6220sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805034793/br6220Isup2.hkl
Contains datablock I

CCDC reference: 289644

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.005 Å
  • R factor = 0.046
  • wR factor = 0.123
  • Data-to-parameter ratio = 13.1

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT420_ALERT_2_B D-H Without Acceptor O1W - H1 ... ?
Alert level C PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 2.20 PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent ..... ? PLAT199_ALERT_1_C Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_C Check the Reported _diffrn_ambient_temperature . 293 K PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.77 Ratio PLAT230_ALERT_2_C Hirshfeld Test Diff for O1 - C1 .. 5.34 su
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 6 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 4 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: RAPID-AUTO (Rigaku Corporation, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXL97; software used to prepare material for publication: SHELXL97.

Diaquatetrakis(µ-2-phenylquinoline-4-carboxylato- κ2O:O')dicopper(II)(Cu—Cu) top
Crystal data top
[Cu2(C16H10NO2)4(H2O)2]Z = 1
Mr = 1156.11F(000) = 594
Triclinic, P1Dx = 1.488 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 8.2800 (17) ÅCell parameters from 10366 reflections
b = 10.668 (2) Åθ = 3.1–27.5°
c = 15.501 (3) ŵ = 0.89 mm1
α = 86.62 (3)°T = 293 K
β = 85.99 (3)°Block, blue
γ = 70.92 (3)°0.14 × 0.10 × 0.10 mm
V = 1289.9 (4) Å3
Data collection top
Rigaku R-AXIS RAPID
diffractometer
4730 independent reflections
Radiation source: fine-focus sealed tube3963 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.034
Detector resolution: 10.00 pixels mm-1θmax = 25.5°, θmin = 3.1°
ω scansh = 1010
Absorption correction: multi-scan
(ABSCOR; Higashi, 1995)
k = 1211
Tmin = 0.885, Tmax = 0.916l = 1818
10554 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.046Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.123H-atom parameters constrained
S = 1.06 w = 1/[σ2(Fo2) + (0.0735P)2 + 0.2379P]
where P = (Fo2 + 2Fc2)/3
4730 reflections(Δ/σ)max = 0.001
361 parametersΔρmax = 1.04 e Å3
0 restraintsΔρmin = 0.47 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Cu10.35053 (4)0.57927 (3)0.03088 (2)0.02788 (14)
N10.2023 (3)0.0251 (2)0.05574 (16)0.0323 (5)
N20.7388 (4)0.3508 (3)0.41677 (17)0.0441 (7)
C10.3682 (4)0.3182 (3)0.01931 (19)0.0339 (7)
C20.3060 (4)0.1994 (3)0.0301 (2)0.0334 (6)
C30.3049 (4)0.1239 (3)0.04222 (19)0.0333 (7)
C40.3536 (5)0.1528 (3)0.1278 (2)0.0457 (8)
H4A0.39320.22460.13950.055*
C50.3437 (5)0.0774 (4)0.1940 (2)0.0539 (9)
H5A0.37820.09700.25020.065*
C60.2813 (5)0.0300 (4)0.1774 (2)0.0496 (9)
H6A0.27170.07940.22310.060*
C70.2352 (4)0.0627 (3)0.0958 (2)0.0388 (7)
H7A0.19610.13490.08580.047*
C80.2463 (4)0.0128 (3)0.02581 (19)0.0321 (6)
C90.2075 (4)0.0459 (3)0.1222 (2)0.0345 (7)
C100.1684 (4)0.0016 (3)0.2096 (2)0.0395 (7)
C110.2256 (5)0.1376 (3)0.2316 (2)0.0460 (8)
H11A0.28680.19790.19050.055*
C120.1913 (6)0.1827 (4)0.3142 (3)0.0609 (11)
H12A0.23150.27300.32880.073*
C130.0980 (6)0.0943 (5)0.3748 (3)0.0683 (13)
H13A0.07410.12500.43000.082*
C140.0402 (6)0.0393 (5)0.3538 (3)0.0619 (11)
H14A0.02400.09890.39460.074*
C150.0772 (5)0.0853 (4)0.2722 (2)0.0503 (9)
H15A0.04020.17610.25910.060*
C160.2550 (4)0.1629 (3)0.1097 (2)0.0363 (7)
H16A0.25090.21450.15660.044*
C170.5961 (4)0.4535 (3)0.15281 (19)0.0331 (7)
C180.6535 (4)0.4176 (3)0.24328 (19)0.0358 (7)
C190.8013 (4)0.4379 (3)0.27233 (19)0.0379 (7)
C200.9123 (5)0.4905 (4)0.2201 (2)0.0484 (8)
H20A0.89280.51060.16180.058*
C211.0478 (5)0.5121 (4)0.2544 (3)0.0588 (10)
H21A1.11880.54820.21960.071*
C221.0806 (5)0.4798 (4)0.3424 (3)0.0585 (10)
H22A1.17300.49510.36530.070*
C230.9784 (5)0.4266 (4)0.3941 (2)0.0514 (9)
H23A1.00220.40500.45190.062*
C240.8370 (4)0.4037 (3)0.3610 (2)0.0404 (7)
C250.6043 (4)0.3306 (3)0.3869 (2)0.0414 (7)
C260.4987 (5)0.2749 (3)0.4495 (2)0.0453 (8)
C270.4772 (6)0.3113 (4)0.5342 (2)0.0602 (10)
H27A0.53200.36800.55220.072*
C280.3745 (7)0.2644 (5)0.5933 (3)0.0750 (13)
H28A0.35680.29250.64990.090*
C290.2991 (6)0.1763 (6)0.5680 (3)0.0807 (15)
H29A0.23280.14280.60790.097*
C300.3216 (7)0.1382 (6)0.4849 (3)0.0888 (18)
H30A0.27040.07860.46790.107*
C310.4207 (6)0.1875 (5)0.4249 (3)0.0707 (13)
H31A0.43450.16140.36790.085*
C320.5560 (5)0.3651 (3)0.3009 (2)0.0419 (8)
H32A0.45780.35230.28300.050*
O10.2677 (3)0.4262 (2)0.04389 (15)0.0426 (5)
O20.5172 (3)0.29631 (19)0.01271 (15)0.0402 (5)
O30.4461 (3)0.5301 (2)0.14534 (13)0.0435 (5)
O40.7001 (3)0.4007 (2)0.09265 (13)0.0415 (5)
O1W0.1156 (3)0.73465 (18)0.06693 (13)0.0358 (5)
H10.01450.75220.07620.043*
H20.12970.80870.06830.043*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cu10.0352 (2)0.0254 (2)0.0282 (2)0.01726 (15)0.00477 (14)0.00434 (13)
N10.0367 (14)0.0270 (12)0.0373 (14)0.0164 (10)0.0034 (11)0.0035 (10)
N20.0516 (18)0.0504 (16)0.0339 (14)0.0217 (13)0.0081 (12)0.0069 (12)
C10.0414 (18)0.0346 (16)0.0343 (15)0.0246 (14)0.0086 (13)0.0100 (13)
C20.0357 (16)0.0247 (14)0.0448 (17)0.0171 (12)0.0051 (13)0.0058 (12)
C30.0350 (16)0.0315 (15)0.0391 (16)0.0192 (12)0.0067 (13)0.0088 (12)
C40.062 (2)0.0435 (18)0.0430 (19)0.0336 (16)0.0144 (16)0.0137 (15)
C50.077 (3)0.062 (2)0.0355 (18)0.043 (2)0.0062 (17)0.0098 (16)
C60.069 (2)0.053 (2)0.0379 (18)0.0319 (18)0.0138 (17)0.0006 (15)
C70.0446 (18)0.0343 (16)0.0442 (18)0.0214 (14)0.0097 (14)0.0029 (13)
C80.0337 (16)0.0252 (14)0.0406 (16)0.0143 (12)0.0080 (13)0.0070 (12)
C90.0364 (17)0.0297 (15)0.0421 (17)0.0177 (12)0.0029 (13)0.0036 (13)
C100.0443 (19)0.0411 (17)0.0440 (18)0.0289 (14)0.0038 (14)0.0026 (14)
C110.065 (2)0.0409 (18)0.0408 (18)0.0299 (17)0.0052 (16)0.0052 (14)
C120.089 (3)0.058 (2)0.050 (2)0.045 (2)0.012 (2)0.0164 (19)
C130.090 (3)0.097 (3)0.040 (2)0.064 (3)0.009 (2)0.018 (2)
C140.067 (3)0.082 (3)0.044 (2)0.035 (2)0.0049 (19)0.0067 (19)
C150.060 (2)0.049 (2)0.047 (2)0.0251 (17)0.0007 (17)0.0026 (16)
C160.0458 (18)0.0324 (15)0.0382 (17)0.0235 (13)0.0021 (14)0.0010 (13)
C170.0436 (18)0.0338 (15)0.0302 (15)0.0237 (13)0.0069 (13)0.0040 (12)
C180.0453 (18)0.0340 (15)0.0297 (15)0.0151 (13)0.0068 (13)0.0046 (12)
C190.0447 (18)0.0378 (16)0.0329 (16)0.0151 (13)0.0066 (13)0.0017 (13)
C200.056 (2)0.056 (2)0.0393 (18)0.0274 (17)0.0077 (16)0.0063 (15)
C210.056 (2)0.077 (3)0.054 (2)0.038 (2)0.0058 (18)0.0089 (19)
C220.054 (2)0.076 (3)0.057 (2)0.036 (2)0.0132 (19)0.001 (2)
C230.059 (2)0.062 (2)0.0405 (19)0.0276 (18)0.0196 (17)0.0031 (16)
C240.0485 (19)0.0410 (17)0.0336 (16)0.0171 (14)0.0075 (14)0.0036 (13)
C250.049 (2)0.0436 (18)0.0342 (17)0.0188 (15)0.0046 (14)0.0061 (14)
C260.048 (2)0.050 (2)0.0393 (18)0.0193 (16)0.0077 (15)0.0154 (15)
C270.085 (3)0.053 (2)0.044 (2)0.027 (2)0.0010 (19)0.0127 (17)
C280.097 (4)0.074 (3)0.048 (2)0.026 (3)0.011 (2)0.016 (2)
C290.069 (3)0.112 (4)0.068 (3)0.046 (3)0.009 (2)0.042 (3)
C300.094 (4)0.121 (4)0.082 (3)0.079 (4)0.034 (3)0.044 (3)
C310.087 (3)0.098 (3)0.048 (2)0.060 (3)0.021 (2)0.024 (2)
C320.049 (2)0.0466 (18)0.0356 (17)0.0234 (15)0.0117 (14)0.0083 (14)
O10.0461 (13)0.0295 (11)0.0571 (14)0.0212 (10)0.0073 (11)0.0014 (10)
O20.0395 (13)0.0290 (11)0.0589 (14)0.0205 (9)0.0050 (11)0.0018 (10)
O30.0475 (14)0.0500 (13)0.0309 (11)0.0133 (11)0.0051 (10)0.0060 (10)
O40.0464 (14)0.0476 (13)0.0310 (11)0.0152 (10)0.0086 (10)0.0010 (10)
O1W0.0452 (13)0.0192 (9)0.0440 (12)0.0128 (8)0.0005 (10)0.0027 (8)
Geometric parameters (Å, º) top
Cu1—O11.962 (2)C14—H14A0.9300
Cu1—O2i1.976 (2)C15—H15A0.9300
Cu1—O31.966 (2)C16—H16A0.9300
Cu1—O4i1.973 (2)C17—O41.250 (4)
Cu1—O1W2.167 (2)C17—O31.253 (4)
Cu1—Cu1i2.6507 (12)C17—C181.500 (4)
N1—C91.325 (4)C18—C321.378 (4)
N1—C81.365 (4)C18—C191.418 (4)
N2—C251.320 (4)C19—C201.412 (5)
N2—C241.367 (4)C19—C241.428 (4)
C1—O11.243 (4)C20—C211.364 (5)
C1—O21.250 (4)C20—H20A0.9300
C1—C21.513 (4)C21—C221.411 (5)
C2—C161.354 (4)C21—H21A0.9300
C2—C31.420 (4)C22—C231.358 (5)
C3—C41.406 (4)C22—H22A0.9300
C3—C81.425 (4)C23—C241.407 (5)
C4—C51.363 (5)C23—H23A0.9300
C4—H4A0.9300C25—C321.411 (4)
C5—C61.408 (5)C25—C261.487 (5)
C5—H5A0.9300C26—C271.375 (5)
C6—C71.354 (5)C26—C311.379 (5)
C6—H6A0.9300C27—C281.389 (6)
C7—C81.414 (4)C27—H27A0.9300
C7—H7A0.9300C28—C291.374 (7)
C9—C161.425 (4)C28—H28A0.9300
C9—C101.471 (4)C29—C301.356 (7)
C10—C151.385 (5)C29—H29A0.9300
C10—C111.400 (5)C30—C311.391 (6)
C11—C121.385 (5)C30—H30A0.9300
C11—H11A0.9300C31—H31A0.9300
C12—C131.377 (6)C32—H32A0.9300
C12—H12A0.9300O2—Cu1i1.976 (2)
C13—C141.374 (6)O4—Cu1i1.973 (2)
C13—H13A0.9300O1W—H10.8001
C14—C151.380 (5)O1W—H20.8374
O1—Cu1—O1W99.22 (9)C14—C15—H15A119.5
O1—Cu1—O2i167.50 (9)C10—C15—H15A119.5
O1—Cu1—O388.27 (10)C2—C16—C9120.5 (3)
O1—Cu1—O4i89.97 (10)C2—C16—H16A119.7
O2i—Cu1—O1W93.24 (8)C9—C16—H16A119.7
O3—Cu1—O1W99.58 (9)O4—C17—O3126.5 (3)
O3—Cu1—O2i88.61 (10)O4—C17—C18117.0 (3)
O3—Cu1—O4i167.74 (9)O3—C17—C18116.5 (3)
O4i—Cu1—O1W92.67 (9)C32—C18—C19118.8 (3)
O4i—Cu1—O2i90.51 (10)C32—C18—C17118.3 (3)
O1—Cu1—Cu1i89.10 (7)C19—C18—C17122.9 (3)
O3—Cu1—Cu1i85.69 (8)C20—C19—C18124.6 (3)
O4i—Cu1—Cu1i82.15 (8)C20—C19—C24118.7 (3)
O2i—Cu1—Cu1i78.59 (7)C18—C19—C24116.8 (3)
O1W—Cu1—Cu1i170.23 (5)C21—C20—C19120.7 (3)
C9—N1—C8119.7 (2)C21—C20—H20A119.7
C25—N2—C24118.2 (3)C19—C20—H20A119.7
O1—C1—O2127.0 (3)C20—C21—C22120.3 (4)
O1—C1—C2117.1 (3)C20—C21—H21A119.9
O2—C1—C2115.9 (3)C22—C21—H21A119.9
C16—C2—C3119.7 (3)C23—C22—C21120.6 (3)
C16—C2—C1119.6 (3)C23—C22—H22A119.7
C3—C2—C1120.6 (3)C21—C22—H22A119.7
C4—C3—C2124.8 (3)C22—C23—C24120.7 (3)
C4—C3—C8118.4 (3)C22—C23—H23A119.7
C2—C3—C8116.7 (3)C24—C23—H23A119.7
C5—C4—C3121.1 (3)N2—C24—C23117.6 (3)
C5—C4—H4A119.5N2—C24—C19123.3 (3)
C3—C4—H4A119.5C23—C24—C19119.1 (3)
C4—C5—C6120.0 (3)N2—C25—C32122.5 (3)
C4—C5—H5A120.0N2—C25—C26116.8 (3)
C6—C5—H5A120.0C32—C25—C26120.6 (3)
C7—C6—C5121.0 (3)C27—C26—C31118.7 (4)
C7—C6—H6A119.5C27—C26—C25119.5 (3)
C5—C6—H6A119.5C31—C26—C25121.7 (3)
C6—C7—C8120.2 (3)C26—C27—C28120.7 (4)
C6—C7—H7A119.9C26—C27—H27A119.7
C8—C7—H7A119.9C28—C27—H27A119.7
N1—C8—C7118.5 (2)C29—C28—C27119.9 (4)
N1—C8—C3122.2 (3)C29—C28—H28A120.1
C7—C8—C3119.3 (3)C27—C28—H28A120.1
N1—C9—C16120.9 (3)C30—C29—C28119.9 (4)
N1—C9—C10118.2 (2)C30—C29—H29A120.1
C16—C9—C10120.8 (3)C28—C29—H29A120.1
C15—C10—C11118.4 (3)C29—C30—C31120.5 (5)
C15—C10—C9121.6 (3)C29—C30—H30A119.7
C11—C10—C9120.0 (3)C31—C30—H30A119.7
C12—C11—C10120.2 (4)C26—C31—C30120.3 (4)
C12—C11—H11A119.9C26—C31—H31A119.9
C10—C11—H11A119.9C30—C31—H31A119.9
C13—C12—C11120.2 (4)C18—C32—C25120.4 (3)
C13—C12—H12A119.9C18—C32—H32A119.8
C11—C12—H12A119.9C25—C32—H32A119.8
C14—C13—C12120.1 (4)C1—O1—Cu1116.8 (2)
C14—C13—H13A120.0C1—O2—Cu1i128.4 (2)
C12—C13—H13A120.0C17—O3—Cu1120.9 (2)
C13—C14—C15120.0 (4)C17—O4—Cu1i124.7 (2)
C13—C14—H14A120.0Cu1—O1W—H1144.7
C15—C14—H14A120.0Cu1—O1W—H2112.2
C14—C15—C10121.1 (3)H1—O1W—H2102.8
O1—C1—C2—C1657.9 (4)C24—C19—C20—C212.0 (5)
O2—C1—C2—C16121.3 (3)C19—C20—C21—C221.1 (6)
O1—C1—C2—C3123.7 (3)C20—C21—C22—C230.2 (6)
O2—C1—C2—C357.1 (4)C21—C22—C23—C240.6 (6)
C16—C2—C3—C4179.5 (3)C25—N2—C24—C23179.1 (3)
C1—C2—C3—C42.2 (5)C25—N2—C24—C190.0 (5)
C16—C2—C3—C80.9 (4)C22—C23—C24—N2179.5 (4)
C1—C2—C3—C8179.2 (3)C22—C23—C24—C190.4 (5)
C2—C3—C4—C5177.9 (3)C20—C19—C24—N2179.3 (3)
C8—C3—C4—C50.6 (5)C18—C19—C24—N21.5 (5)
C3—C4—C5—C61.1 (6)C20—C19—C24—C231.6 (5)
C4—C5—C6—C72.0 (6)C18—C19—C24—C23177.6 (3)
C5—C6—C7—C81.1 (5)C24—N2—C25—C321.9 (5)
C9—N1—C8—C7178.3 (3)C24—N2—C25—C26179.1 (3)
C9—N1—C8—C32.6 (4)N2—C25—C26—C2735.3 (5)
C6—C7—C8—N1178.5 (3)C32—C25—C26—C27141.9 (4)
C6—C7—C8—C30.5 (5)N2—C25—C26—C31144.9 (4)
C4—C3—C8—N1177.6 (3)C32—C25—C26—C3137.8 (5)
C2—C3—C8—N13.7 (4)C31—C26—C27—C282.0 (6)
C4—C3—C8—C71.4 (4)C25—C26—C27—C28177.8 (4)
C2—C3—C8—C7177.2 (3)C26—C27—C28—C292.7 (7)
C8—N1—C9—C161.3 (4)C27—C28—C29—C301.7 (8)
C8—N1—C9—C10176.8 (3)C28—C29—C30—C310.1 (8)
N1—C9—C10—C15142.3 (3)C27—C26—C31—C300.4 (7)
C16—C9—C10—C1539.7 (5)C25—C26—C31—C30179.4 (4)
N1—C9—C10—C1138.6 (4)C29—C30—C31—C260.6 (8)
C16—C9—C10—C11139.5 (3)C19—C18—C32—C250.8 (5)
C15—C10—C11—C120.2 (5)C17—C18—C32—C25179.6 (3)
C9—C10—C11—C12179.0 (3)N2—C25—C32—C182.4 (5)
C10—C11—C12—C131.2 (6)C26—C25—C32—C18179.5 (3)
C11—C12—C13—C140.8 (7)O2—C1—O1—Cu10.2 (4)
C12—C13—C14—C150.7 (7)C2—C1—O1—Cu1179.34 (19)
C13—C14—C15—C101.8 (6)O3—Cu1—O1—C187.7 (2)
C11—C10—C15—C141.3 (6)O4i—Cu1—O1—C180.1 (2)
C9—C10—C15—C14179.5 (3)O2i—Cu1—O1—C112.1 (6)
C3—C2—C16—C92.8 (5)O1W—Cu1—O1—C1172.8 (2)
C1—C2—C16—C9175.5 (3)Cu1i—Cu1—O1—C12.0 (2)
N1—C9—C16—C24.1 (5)O1—C1—O2—Cu1i3.0 (5)
C10—C9—C16—C2173.9 (3)C2—C1—O2—Cu1i176.08 (18)
O4—C17—C18—C32123.5 (3)O4—C17—O3—Cu10.2 (4)
O3—C17—C18—C3254.3 (4)C18—C17—O3—Cu1177.35 (18)
O4—C17—C18—C1957.8 (4)O1—Cu1—O3—C1790.5 (2)
O3—C17—C18—C19124.4 (3)O4i—Cu1—O3—C178.7 (6)
C32—C18—C19—C20179.8 (3)O2i—Cu1—O3—C1777.4 (2)
C17—C18—C19—C201.5 (5)O1W—Cu1—O3—C17170.4 (2)
C32—C18—C19—C241.0 (4)Cu1i—Cu1—O3—C171.3 (2)
C17—C18—C19—C24177.7 (3)O3—C17—O4—Cu1i2.4 (4)
C18—C19—C20—C21177.1 (4)C18—C17—O4—Cu1i175.08 (18)
Symmetry code: (i) x+1, y+1, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H2···N1ii0.842.052.873 (3)169
Symmetry code: (ii) x, y+1, z.
 

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