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The title compound, heptamolybdenum(VI) tetragadolin­ate(III), a novel phase in the the Gd2O3–MoO3 system, has been prepared by pyrolysis of [Gd2(H2O)12Mo8O27]·8H2O at 1023 K for 2 h in air. The compound can be described as a layer structure consisting of {MoO4}-, {Mo3O11}- and {Gd}-containing layers, which are stacked along the a direction. The {Mo3O11} group is composed of trigonal bipyramidal MoO5 connected to two MoO4 tetrahedra, with corner-sharing. The coordination polyhedra of square-antiprismatic GdO8 and monocapped trigonal prismatic GdO7 are dimerized to give {Gd2On} (n = 12 and 13) groups which possess short Gd...Gd separations [3.6345 (4)–3.6404 (4) Å].

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802010334/br6055sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536802010334/br6055Isup2.hkl
Contains datablock I

Key indicators

  • Single-crystal X-ray study
  • T = 296 K
  • Mean [sigma](Mo-O) = 0.005 Å
  • R factor = 0.039
  • wR factor = 0.108
  • Data-to-parameter ratio = 19.7

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry








Computing details top

Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO (Rigaku, 1998); data reduction: TEXSAN (Molecular Structure Corporation, 2000; program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: TEXSAN (Molecular Structure Corporation, 2000; software used to prepare material for publication: TEXSAN (Molecular Structure Corporation, 2000.

(I) top
Crystal data top
Gd4Mo7O27F(000) = 6128.0
Mr = 1732.56Dx = 4.908 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.7107 Å
Hall symbol: -C 2ycCell parameters from 15047 reflections
a = 23.034 (2) Åθ = 2.8–30.0°
b = 14.677 (2) ŵ = 14.88 mm1
c = 14.348 (1) ÅT = 296 K
β = 104.816 (3)°Block, colorless
V = 4689.4 (8) Å30.15 × 0.11 × 0.11 mm
Z = 8
Data collection top
Rigaku RAXIS-RAPID Imaging Plate
diffractometer
5944 reflections with F2 > 2σ(F2)
Detector resolution: 10.00 pixels mm-1Rint = 0.048
ω scansθmax = 30.0°
Absorption correction: numerical
(Higashi, 1999)
h = 032
Tmin = 0.101, Tmax = 0.197k = 020
24606 measured reflectionsl = 2019
6779 independent reflections
Refinement top
Refinement on F2 w = 1/[σ2(Fo2) + (0.05(Max(Fo2,0) + 2Fc2)/3)2]
R[F2 > 2σ(F2)] = 0.039(Δ/σ)max = 0.002
wR(F2) = 0.108Δρmax = 4.62 e Å3
S = 1.38Δρmin = 3.57 e Å3
6778 reflectionsExtinction correction: Zachariasen (1967) type 2 Gaussian isotropic
344 parametersExtinction coefficient: 0.00217 (4)
Special details top

Refinement. Refinement using reflections with F2 > -10.0 σ(F2). The weighted R-factor (wR) and goodness of fit (S) are based on F2. R-factor (gt) are based on F. The threshold expression of F2 > 2.0 σ(F2) is used only for calculating R-factor (gt).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Gd(1)0.11465 (1)0.94156 (2)0.14469 (2)0.00925 (7)
Gd(2)0.62225 (1)0.80732 (2)0.06296 (2)0.00899 (7)
Gd(3)0.61114 (1)0.94038 (2)0.14541 (2)0.00921 (7)
Gd(4)0.38042 (1)0.69462 (2)0.06521 (2)0.00984 (7)
Mo(1)0.25560 (2)0.80117 (3)0.16578 (4)0.0099 (1)
Mo(2)0.22995 (2)0.88003 (3)0.38708 (4)0.0106 (1)
Mo(3)0.23504 (2)0.59750 (3)0.29825 (4)0.0107 (1)
Mo(4)0.56999 (2)1.05445 (3)0.10012 (4)0.0097 (1)
Mo(5)0.06886 (2)0.94988 (3)0.10152 (4)0.0098 (1)
Mo(6)0.06131 (2)0.69567 (3)0.14512 (4)0.0094 (1)
Mo(7)0.56210 (2)0.69421 (3)0.14586 (4)0.0097 (1)
O(1)0.5791 (2)0.9741 (3)0.2866 (3)0.020 (1)
O(2)0.5900 (2)0.7855 (3)0.0866 (3)0.016 (1)
O(3)0.5899 (2)0.9543 (3)0.0254 (3)0.0115 (9)
O(4)0.6002 (2)0.7932 (4)0.2341 (4)0.024 (1)
O(5)0.6005 (2)0.6541 (3)0.0587 (4)0.019 (1)
O(6)0.1990 (2)0.8789 (3)0.2568 (3)0.0147 (10)
O(7)0.3847 (2)0.8488 (3)0.0598 (3)0.016 (1)
O(8)0.4001 (3)0.6987 (4)0.2320 (4)0.027 (1)
O(9)0.0747 (2)1.0873 (3)0.1023 (4)0.020 (1)
O(10)0.0868 (2)0.9721 (4)0.2896 (3)0.024 (1)
O(11)0.0870 (2)0.7878 (3)0.0820 (3)0.016 (1)
O(12)0.1952 (2)1.0459 (3)0.1563 (4)0.019 (1)
O(13)0.0079 (2)0.9342 (3)0.1207 (4)0.019 (1)
O(14)0.2459 (2)0.7153 (3)0.2609 (4)0.020 (1)
O(15)0.7034 (2)0.7161 (3)0.0662 (4)0.019 (1)
O(16)0.6947 (2)0.9030 (3)0.1151 (4)0.021 (1)
O(17)0.5163 (2)0.7981 (3)0.1277 (4)0.022 (1)
O(18)0.6888 (2)0.8735 (3)0.0817 (3)0.0152 (10)
O(19)0.5052 (2)0.9183 (3)0.1124 (4)0.018 (1)
O(20)0.5768 (2)1.0886 (3)0.1027 (4)0.020 (1)
O(21)0.4845 (2)0.7071 (3)0.1282 (4)0.022 (1)
O(22)0.6955 (2)1.0383 (3)0.1964 (4)0.022 (1)
O(23)0.6866 (2)0.8761 (3)0.2853 (3)0.016 (1)
O(24)0.2860 (2)0.7268 (3)0.0976 (3)0.0157 (10)
O(25)0.1948 (2)0.8495 (3)0.0776 (3)0.017 (1)
O(26)0.0931 (2)0.9504 (3)0.0246 (3)0.0124 (10)
O(27)0.2052 (2)0.9758 (3)0.4309 (4)0.023 (1)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Gd(1)0.0084 (1)0.0099 (1)0.0090 (1)0.00012 (8)0.0015 (1)0.00032 (9)
Gd(2)0.0077 (1)0.0096 (1)0.0097 (1)0.00016 (8)0.0025 (1)0.00106 (9)
Gd(3)0.0083 (1)0.0098 (1)0.0095 (1)0.00081 (8)0.0022 (1)0.00027 (9)
Gd(4)0.0092 (1)0.0107 (1)0.0095 (2)0.00068 (9)0.0021 (1)0.00091 (9)
Mo(1)0.0074 (2)0.0121 (2)0.0099 (2)0.0009 (2)0.0016 (2)0.0006 (2)
Mo(2)0.0069 (2)0.0139 (2)0.0106 (2)0.0005 (2)0.0014 (2)0.0010 (2)
Mo(3)0.0093 (2)0.0096 (2)0.0135 (2)0.0005 (2)0.0034 (2)0.0007 (2)
Mo(4)0.0085 (2)0.0097 (2)0.0107 (2)0.0008 (2)0.0023 (2)0.0014 (2)
Mo(5)0.0092 (2)0.0101 (2)0.0101 (2)0.0005 (2)0.0023 (2)0.0013 (2)
Mo(6)0.0079 (2)0.0105 (2)0.0097 (2)0.0002 (2)0.0023 (2)0.0004 (2)
Mo(7)0.0081 (2)0.0112 (2)0.0098 (2)0.0003 (2)0.0022 (2)0.0002 (2)
O(1)0.019 (2)0.026 (2)0.015 (2)0.003 (2)0.007 (2)0.000 (2)
O(2)0.018 (2)0.013 (2)0.019 (2)0.000 (2)0.008 (2)0.002 (2)
O(3)0.017 (2)0.010 (2)0.008 (2)0.003 (2)0.004 (2)0.000 (1)
O(4)0.023 (3)0.038 (3)0.012 (2)0.002 (2)0.003 (2)0.003 (2)
O(5)0.014 (2)0.013 (2)0.028 (3)0.002 (2)0.003 (2)0.000 (2)
O(6)0.014 (2)0.018 (2)0.010 (2)0.002 (2)0.001 (2)0.002 (2)
O(7)0.016 (2)0.013 (2)0.021 (2)0.001 (2)0.005 (2)0.001 (2)
O(8)0.023 (3)0.046 (3)0.013 (2)0.006 (2)0.004 (2)0.000 (2)
O(9)0.022 (2)0.014 (2)0.026 (3)0.003 (2)0.008 (2)0.005 (2)
O(10)0.023 (2)0.037 (3)0.012 (2)0.001 (2)0.005 (2)0.003 (2)
O(11)0.024 (2)0.014 (2)0.014 (2)0.002 (2)0.008 (2)0.001 (2)
O(12)0.015 (2)0.021 (2)0.022 (2)0.003 (2)0.006 (2)0.001 (2)
O(13)0.010 (2)0.025 (2)0.023 (2)0.001 (2)0.004 (2)0.000 (2)
O(14)0.021 (2)0.015 (2)0.028 (3)0.000 (2)0.012 (2)0.000 (2)
O(15)0.010 (2)0.024 (2)0.024 (2)0.001 (2)0.006 (2)0.009 (2)
O(16)0.026 (2)0.017 (2)0.027 (3)0.006 (2)0.019 (2)0.003 (2)
O(17)0.009 (2)0.025 (2)0.030 (3)0.003 (2)0.002 (2)0.003 (2)
O(18)0.006 (2)0.020 (2)0.018 (2)0.001 (2)0.002 (2)0.002 (2)
O(19)0.010 (2)0.020 (2)0.022 (2)0.001 (2)0.004 (2)0.001 (2)
O(20)0.025 (2)0.014 (2)0.022 (2)0.004 (2)0.008 (2)0.003 (2)
O(21)0.009 (2)0.024 (2)0.032 (3)0.002 (2)0.003 (2)0.002 (2)
O(22)0.024 (2)0.022 (2)0.019 (2)0.007 (2)0.005 (2)0.001 (2)
O(23)0.012 (2)0.023 (2)0.015 (2)0.004 (2)0.004 (2)0.002 (2)
O(24)0.008 (2)0.023 (2)0.017 (2)0.003 (2)0.005 (2)0.005 (2)
O(25)0.013 (2)0.019 (2)0.015 (2)0.003 (2)0.000 (2)0.002 (2)
O(26)0.017 (2)0.010 (2)0.010 (2)0.004 (2)0.005 (2)0.001 (1)
O(27)0.023 (2)0.025 (2)0.022 (2)0.007 (2)0.006 (2)0.007 (2)
Geometric parameters (Å, º) top
Gd(1)—O(9)2.346 (4)Gd(4)—O(11)i2.428 (5)
Gd(1)—O(26)2.355 (4)Mo(1)—O(24)1.729 (4)
Gd(1)—O(6)2.368 (4)Mo(1)—O(23)ii1.732 (4)
Gd(1)—O(10)2.371 (5)Mo(1)—O(25)1.777 (4)
Gd(1)—O(12)2.379 (4)Mo(1)—O(14)1.913 (5)
Gd(1)—O(13)2.396 (5)Mo(1)—O(6)2.362 (4)
Gd(1)—O(11)2.452 (4)Mo(2)—O(27)1.697 (4)
Gd(1)—O(25)2.659 (4)Mo(2)—O(15)iii1.738 (4)
Gd(2)—O(5)2.309 (4)Mo(2)—O(18)ii1.811 (4)
Gd(2)—O(15)2.310 (4)Mo(2)—O(6)1.823 (4)
Gd(2)—O(17)2.383 (5)Mo(3)—O(16)iii1.732 (4)
Gd(2)—O(4)2.386 (5)Mo(3)—O(22)iv1.743 (5)
Gd(2)—O(3)2.388 (4)Mo(3)—O(12)v1.745 (4)
Gd(2)—O(16)2.441 (4)Mo(3)—O(14)1.845 (5)
Gd(2)—O(18)2.444 (4)Mo(4)—O(1)vi1.742 (5)
Gd(2)—O(2)2.464 (5)Mo(4)—O(19)vii1.743 (4)
Gd(3)—O(20)2.342 (4)Mo(4)—O(7)vii1.769 (4)
Gd(3)—O(22)2.377 (5)Mo(4)—O(3)1.808 (4)
Gd(3)—O(1)2.378 (5)Mo(5)—O(5)i1.734 (4)
Gd(3)—O(3)2.382 (4)Mo(5)—O(13)1.734 (5)
Gd(3)—O(19)2.385 (4)Mo(5)—O(10)viii1.745 (5)
Gd(3)—O(18)2.417 (4)Mo(5)—O(26)ix1.832 (4)
Gd(3)—O(2)2.431 (4)Mo(6)—O(17)i1.743 (5)
Gd(3)—O(23)2.481 (4)Mo(6)—O(4)iii1.743 (5)
Gd(4)—O(7)2.268 (4)Mo(6)—O(20)iv1.755 (5)
Gd(4)—O(8)2.320 (6)Mo(6)—O(11)1.810 (4)
Gd(4)—O(26)i2.329 (4)Mo(7)—O(9)x1.741 (5)
Gd(4)—O(21)2.343 (5)Mo(7)—O(8)ii1.747 (6)
Gd(4)—O(24)2.384 (4)Mo(7)—O(21)1.750 (5)
Gd(4)—O(25)i2.409 (4)Mo(7)—O(2)1.792 (5)
O(9)—Gd(1)—O(26)73.6 (2)O(26)i—Gd(4)—O(24)122.7 (2)
O(9)—Gd(1)—O(6)136.8 (2)O(26)i—Gd(4)—O(25)i73.7 (2)
O(9)—Gd(1)—O(10)83.0 (2)O(26)i—Gd(4)—O(11)i73.8 (2)
O(9)—Gd(1)—O(12)71.2 (2)O(21)—Gd(4)—O(24)143.5 (2)
O(9)—Gd(1)—O(13)71.6 (2)O(21)—Gd(4)—O(25)i142.3 (2)
O(9)—Gd(1)—O(11)134.1 (2)O(21)—Gd(4)—O(11)i79.3 (2)
O(9)—Gd(1)—O(25)129.2 (2)O(24)—Gd(4)—O(25)i74.1 (2)
O(26)—Gd(1)—O(6)129.9 (2)O(24)—Gd(4)—O(11)i130.4 (2)
O(26)—Gd(1)—O(10)149.5 (2)O(25)i—Gd(4)—O(11)i66.7 (2)
O(26)—Gd(1)—O(12)89.5 (2)O(24)—Mo(1)—O(23)ii104.4 (2)
O(26)—Gd(1)—O(13)85.2 (2)O(24)—Mo(1)—O(25)102.0 (2)
O(26)—Gd(1)—O(11)72.9 (1)O(24)—Mo(1)—O(14)97.2 (2)
O(26)—Gd(1)—O(25)68.7 (1)O(24)—Mo(1)—O(6)168.1 (2)
O(6)—Gd(1)—O(10)80.6 (2)O(23)ii—Mo(1)—O(25)114.8 (2)
O(6)—Gd(1)—O(12)73.3 (2)O(23)ii—Mo(1)—O(14)110.4 (2)
O(6)—Gd(1)—O(13)135.5 (2)O(23)ii—Mo(1)—O(6)86.9 (2)
O(6)—Gd(1)—O(11)89.0 (2)O(25)—Mo(1)—O(14)123.8 (2)
O(6)—Gd(1)—O(25)61.5 (1)O(25)—Mo(1)—O(6)75.8 (2)
O(10)—Gd(1)—O(12)101.4 (2)O(14)—Mo(1)—O(6)75.0 (2)
O(10)—Gd(1)—O(13)68.7 (2)O(27)—Mo(2)—O(15)iii110.2 (2)
O(10)—Gd(1)—O(11)113.2 (2)O(27)—Mo(2)—O(18)ii112.1 (2)
O(10)—Gd(1)—O(25)141.5 (2)O(27)—Mo(2)—O(6)107.9 (2)
O(12)—Gd(1)—O(13)142.4 (2)O(15)iii—Mo(2)—O(18)ii107.7 (2)
O(12)—Gd(1)—O(11)138.0 (2)O(15)iii—Mo(2)—O(6)107.7 (2)
O(12)—Gd(1)—O(25)75.6 (2)O(18)ii—Mo(2)—O(6)111.2 (2)
O(13)—Gd(1)—O(11)75.3 (2)O(16)iii—Mo(3)—O(22)iv109.8 (2)
O(13)—Gd(1)—O(25)135.0 (2)O(16)iii—Mo(3)—O(12)v110.0 (2)
O(11)—Gd(1)—O(25)62.5 (1)O(16)iii—Mo(3)—O(14)110.5 (2)
O(5)—Gd(2)—O(15)67.6 (2)O(22)iv—Mo(3)—O(12)v109.3 (2)
O(5)—Gd(2)—O(17)75.4 (2)O(22)iv—Mo(3)—O(14)107.7 (2)
O(5)—Gd(2)—O(4)87.2 (2)O(12)v—Mo(3)—O(14)109.6 (2)
O(5)—Gd(2)—O(3)142.3 (2)O(1)vi—Mo(4)—O(19)vii108.4 (2)
O(5)—Gd(2)—O(16)137.6 (2)O(1)vi—Mo(4)—O(7)vii107.2 (2)
O(5)—Gd(2)—O(18)117.3 (2)O(1)vi—Mo(4)—O(3)106.5 (2)
O(5)—Gd(2)—O(2)74.6 (2)O(19)vii—Mo(4)—O(7)vii109.7 (2)
O(15)—Gd(2)—O(17)135.5 (2)O(19)vii—Mo(4)—O(3)109.9 (2)
O(15)—Gd(2)—O(4)83.6 (2)O(7)vii—Mo(4)—O(3)114.8 (2)
O(15)—Gd(2)—O(3)146.0 (2)O(5)i—Mo(5)—O(13)105.0 (2)
O(15)—Gd(2)—O(16)72.9 (2)O(5)i—Mo(5)—O(10)viii107.9 (2)
O(15)—Gd(2)—O(18)85.0 (2)O(5)i—Mo(5)—O(26)ix117.0 (2)
O(15)—Gd(2)—O(2)111.6 (2)O(13)—Mo(5)—O(10)viii110.4 (2)
O(17)—Gd(2)—O(4)70.5 (2)O(13)—Mo(5)—O(26)ix110.1 (2)
O(17)—Gd(2)—O(3)78.0 (2)O(10)viii—Mo(5)—O(26)ix106.5 (2)
O(17)—Gd(2)—O(16)128.7 (2)O(17)i—Mo(6)—O(4)iii112.7 (3)
O(17)—Gd(2)—O(18)135.4 (2)O(17)i—Mo(6)—O(20)iv106.8 (2)
O(17)—Gd(2)—O(2)79.9 (2)O(17)i—Mo(6)—O(11)110.2 (2)
O(4)—Gd(2)—O(3)108.3 (2)O(4)iii—Mo(6)—O(20)iv109.3 (2)
O(4)—Gd(2)—O(16)73.5 (2)O(4)iii—Mo(6)—O(11)106.0 (2)
O(4)—Gd(2)—O(18)146.2 (2)O(20)iv—Mo(6)—O(11)112.0 (2)
O(4)—Gd(2)—O(2)148.5 (2)O(9)x—Mo(7)—O(8)ii107.9 (3)
O(3)—Gd(2)—O(16)80.0 (2)O(9)x—Mo(7)—O(21)107.7 (2)
O(3)—Gd(2)—O(18)67.3 (1)O(9)x—Mo(7)—O(2)113.0 (2)
O(3)—Gd(2)—O(2)74.9 (1)O(8)ii—Mo(7)—O(21)111.7 (3)
O(16)—Gd(2)—O(18)72.7 (2)O(8)ii—Mo(7)—O(2)107.5 (2)
O(16)—Gd(2)—O(2)136.4 (2)O(21)—Mo(7)—O(2)109.1 (2)
O(18)—Gd(2)—O(2)64.9 (2)Mo(4)xi—O(1)—Gd(3)151.9 (3)
O(20)—Gd(3)—O(22)73.4 (2)Mo(7)—O(2)—Gd(3)126.8 (2)
O(20)—Gd(3)—O(1)82.7 (2)Mo(7)—O(2)—Gd(2)137.3 (2)
O(20)—Gd(3)—O(3)71.6 (2)Gd(3)—O(2)—Gd(2)95.9 (2)
O(20)—Gd(3)—O(19)79.3 (2)Mo(4)—O(3)—Gd(3)129.3 (2)
O(20)—Gd(3)—O(18)120.8 (2)Mo(4)—O(3)—Gd(2)130.3 (2)
O(20)—Gd(3)—O(2)138.9 (2)Gd(3)—O(3)—Gd(2)99.3 (2)
O(20)—Gd(3)—O(23)133.2 (2)Mo(6)xii—O(4)—Gd(2)159.2 (3)
O(22)—Gd(3)—O(1)91.1 (2)Mo(5)i—O(5)—Gd(2)157.3 (3)
O(22)—Gd(3)—O(3)101.6 (2)Mo(2)—O(6)—Mo(1)116.4 (2)
O(22)—Gd(3)—O(19)149.0 (2)Mo(2)—O(6)—Gd(1)137.0 (2)
O(22)—Gd(3)—O(18)74.7 (2)Mo(1)—O(6)—Gd(1)106.6 (2)
O(22)—Gd(3)—O(2)138.4 (2)Mo(4)vii—O(7)—Gd(4)144.8 (2)
O(22)—Gd(3)—O(23)68.4 (2)Mo(7)ii—O(8)—Gd(4)161.7 (3)
O(1)—Gd(3)—O(3)146.3 (2)Mo(7)xiii—O(9)—Gd(1)145.0 (3)
O(1)—Gd(3)—O(19)70.9 (2)Mo(5)viii—O(10)—Gd(1)158.2 (3)
O(1)—Gd(3)—O(18)145.9 (2)Mo(6)—O(11)—Gd(4)i136.7 (2)
O(1)—Gd(3)—O(2)114.3 (2)Mo(6)—O(11)—Gd(1)126.2 (2)
O(1)—Gd(3)—O(23)72.2 (2)Gd(4)i—O(11)—Gd(1)96.5 (2)
O(3)—Gd(3)—O(19)82.9 (2)Mo(3)xiv—O(12)—Gd(1)158.9 (3)
O(3)—Gd(3)—O(18)67.8 (2)Mo(5)—O(13)—Gd(1)169.7 (3)
O(3)—Gd(3)—O(2)75.7 (2)Mo(3)—O(14)—Mo(1)150.9 (3)
O(3)—Gd(3)—O(23)141.5 (1)Mo(2)xii—O(15)—Gd(2)147.6 (3)
O(19)—Gd(3)—O(18)133.5 (2)Mo(3)xii—O(16)—Gd(2)138.8 (2)
O(19)—Gd(3)—O(2)72.5 (2)Mo(6)i—O(17)—Gd(2)164.5 (3)
O(19)—Gd(3)—O(23)125.3 (2)Mo(2)ii—O(18)—Gd(3)134.6 (2)
O(18)—Gd(3)—O(2)65.8 (1)Mo(2)ii—O(18)—Gd(2)128.0 (2)
O(18)—Gd(3)—O(23)73.7 (1)Gd(3)—O(18)—Gd(2)96.8 (1)
O(2)—Gd(3)—O(23)87.8 (2)Mo(4)vii—O(19)—Gd(3)158.3 (3)
O(7)—Gd(4)—O(8)90.6 (2)Mo(6)xv—O(20)—Gd(3)145.7 (3)
O(7)—Gd(4)—O(26)i152.5 (2)Mo(7)—O(21)—Gd(4)162.5 (3)
O(7)—Gd(4)—O(21)83.4 (2)Mo(3)xv—O(22)—Gd(3)140.4 (3)
O(7)—Gd(4)—O(24)81.9 (2)Mo(1)ii—O(23)—Gd(3)151.2 (2)
O(7)—Gd(4)—O(25)i105.5 (2)Mo(1)—O(24)—Gd(4)139.2 (2)
O(7)—Gd(4)—O(11)i80.7 (2)Mo(1)—O(25)—Gd(4)i139.7 (2)
O(8)—Gd(4)—O(26)i106.7 (2)Mo(1)—O(25)—Gd(1)116.0 (2)
O(8)—Gd(4)—O(21)71.9 (2)Gd(4)i—O(25)—Gd(1)91.7 (1)
O(8)—Gd(4)—O(24)75.0 (2)Mo(5)ix—O(26)—Gd(4)i129.6 (2)
O(8)—Gd(4)—O(25)i142.4 (2)Mo(5)ix—O(26)—Gd(1)128.1 (2)
O(8)—Gd(4)—O(11)i150.7 (2)Gd(4)i—O(26)—Gd(1)102.0 (2)
O(26)i—Gd(4)—O(21)82.0 (2)
Symmetry codes: (i) x+1/2, y+3/2, z; (ii) x+1, y, z+1/2; (iii) x1/2, y+3/2, z+1/2; (iv) x1/2, y1/2, z; (v) x+1/2, y1/2, z+1/2; (vi) x, y+2, z1/2; (vii) x+1, y+2, z; (viii) x, y, z+1/2; (ix) x, y+2, z; (x) x+1/2, y1/2, z; (xi) x, y+2, z+1/2; (xii) x+1/2, y+3/2, z1/2; (xiii) x1/2, y+1/2, z; (xiv) x+1/2, y+1/2, z+1/2; (xv) x+1/2, y+1/2, z.
 

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