metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

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ISSN: 2056-9890

Di-μ-chlorido-bis­­{bis­­[3,5-di­methyl­pyrazol-1-yl-κN2)methane]iron(II)} bis­­[tetra­chloridoferrate(III)]

aCollege of Chemistry and Chemical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, People's Republic of China
*Correspondence e-mail: hyxia-jx@163.com

(Received 11 October 2008; accepted 28 October 2008; online 8 November 2008)

In the title complex, [Fe2Cl2(C11H16N4)4][FeCl4]2, the asymmetric unit is composed of one and a half units of [Fe(bdmpm)2Cl]2(FeCl4)2(bdmpm = bis(bis(3,5-dimethyl­pyrazol-1-yl)methane). The three independent FeII atom have a distorted octa­hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis­(3,5-dimethyl­pyrazol-1-yl)methane ligands. The FeIII atom has a tetra­hedral coordination geometry comprising four chloride anions.

Related literature

For information on the coordination chemistry of poly-(pyrazol­yl)methane ligands, see: Anderson et al. (2000[Anderson, P. A., Astley, T., Hitchman, M. A., Keene, F. R., Moubaraki, B., Murray, K. S., Skelton, B. W., Tiekink, E. R. T., Toftlund, H. & White, A. H. (2000). J. Chem. Soc. Dalton Trans. pp. 3505-3512.]); Edwards et al. (2006[Edwards, P. G., Harrison, A., Newman, P. D. & Zhang, W. J. (2006). Inorg. Chim. Acta, 359, 3549-3556.]); Higgs et al. (1999[Higgs, T. C., Ji, D., Czernuscewicz, R. S. & Carrano, C. J. (1999). Inorg. Chim. Acta, 286, 80-92.]); Moubaraki et al. (2003[Moubaraki, B., Murray, K. S. & Tiekink, E. R. T. (2003). Z. Kristallogr. New Cryst. Struct. 218, 349-350.]); Pettinari & Pettinari (2005[Pettinari, C. & Pettinari, R. (2005). Coord. Chem. Rev. 249, 525-543663-691.]); Reger et al. (2004[Reger, D. L., Elgin, J. D., Smith, M. D., Grandjean, F., Rebbouh, L. & Long, G. J. (2004). Eur. J. Inorg. Chem. pp. 3345-3352.]). For information on binuclear complexes, see: Moubaraki et al. (2003[Moubaraki, B., Murray, K. S. & Tiekink, E. R. T. (2003). Z. Kristallogr. New Cryst. Struct. 218, 349-350.]); Batten et al. (2004[Batten, S. R., Bjernemose, J. K., Jensen, P., Leita, B. A., Murray, K. S., Moubaraki, B., Smith, J. P. & Toftlund, H. (2004). Dalton Trans. pp. 3370-3375.]); Gu et al. (2006[Gu, Z. G., Yang, Q. F., Liu, W., Song, Y., Li, Y.-Z., Zuo, J.-L. & You, X.-Z. (2006). Inorg. Chem. 45, 8895-8901.]).

[Scheme 1]

Experimental

Crystal data
  • [Fe2Cl2(C11H16N4)4][FeCl4]2

  • Mr = 1395.01

  • Triclinic, [P \overline 1]

  • a = 14.100 (3) Å

  • b = 18.244 (4) Å

  • c = 19.969 (4) Å

  • α = 85.58 (3)°

  • β = 71.23 (3)°

  • γ = 68.20 (3)°

  • V = 4511 (2) Å3

  • Z = 3

  • Mo Kα radiation

  • μ = 1.44 mm−1

  • T = 293 (2) K

  • 0.18 × 0.15 × 0.12 mm

Data collection
  • Rigaku Mercury diffractometer

  • Absorption correction: multi-scan (Jacobson, 1998[Jacobson, R. (1998). Private communication to the Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.782, Tmax = 0.847

  • 44634 measured reflections

  • 16405 independent reflections

  • 10865 reflections with I > 2σ(I)

  • Rint = 0.096

Refinement
  • R[F2 > 2σ(F2)] = 0.093

  • wR(F2) = 0.209

  • S = 1.08

  • 16405 reflections

  • 1022 parameters

  • H-atom parameters constrained

  • Δρmax = 0.76 e Å−3

  • Δρmin = −0.95 e Å−3

Data collection: CrystalClear (Rigaku/MSC, 2001[Rigaku/MSC (2001). CrystalClear. Rigaku/MSC, The Woodlands, Texas, USA.]); cell refinement: CrystalClear; data reduction: CrystalStructure (Rigaku/MSC, 2004[Rigaku/MSC (2004). CrystalStructure. Rigaku/MSC, The Woodlands, Texas, USA.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXL97.

Supporting information


Comment top

The various unsubstituted and methyl-substituted poly-(pyrazolyl)methane ligands have become very important in coordination chemistry (Pettinari, et al., 2005; Reger, et al., 2004; Higgs, et al., 1999; Anderson, et al., 2000; Edwards, et al., 2006). But most of them are coordinated with iron to form single nuclear coordination complexes, only few examples are binuclear coordination complexes (Gu, et al., 2006; Batten, et al., 2004; Moubaraki, et al., 2003). In the crystal of the title complex, the asymmetric unit is composed of one and a half units of [Fe(bdmpm)2Cl]2 2FeCl4 (bdmpm = bis(bis(3,5-dimethylpyrazol-1-yl)methane). One of [Fe(bdmpm)2Cl]2 complexes has a crystallographic center of symmetry, the other has an approximate center of symmetry but it is not crystallographic. The reason for this difference is that the bond length and bond angles around Fe(2) and Fe(3) are slightly different. Each binuclear cations with a pair of bridging chloride ligands and the two bmmpm ligands results in six-coordination about each of the metal atoms; the environments of the complex are octahedron geometry (Fig. 1).

Related literature top

For information on the coordination chemistry of poly-(pyrazolyl)methane ligands, see: Anderson et al. (2000); Edwards et al. (2006); Higgs et al. (1999); Moubaraki et al. (2003); Pettinari et al. (2005); Reger et al. (2004). For information on binuclear complexes, see: Moubaraki et al. (2003); Batten et al. (2004); Gu et al. (2006).

Experimental top

The reaction of FeCl2.4H2O (20 mg, 0.1 mmol) with bdmpm (44 mg, 0.22 mmol) in EtOH (15 ml) was carried out at ambient temperature for 20 minutes, the mixture was filtered and the filtrate was then left for crystallization.

Refinement top

In this structrue, the C-H distance was constrained to 0.93 Å for C-H, 0.96 Å for C-H3 and 0.97 for C-H2. The ratio of the Uiso values 1.2 for H atoms of C-H and C-H2, 1.5 for H atoms of C-H3.

Computing details top

Data collection: CrystalClear (Rigaku/MSC, 2001); cell refinement: CrystalClear (Rigaku/MSC, 2001); data reduction: CrystalStructure (Rigaku/MSC, 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure with displacement ellipsoids drawn at the 50% probability level. Atoms labeled with the suffix A are related by the (1 - x, 1 - y, 1 - z) symmetry operator.
Di-µ-chlorido-bis{bis[3,5-dimethylpyrazol-1-yl-κN2)methane]iron(II)} bis[tetrachloridoiron(II)] top
Crystal data top
[Fe2Cl2(C11H16N4)4][FeCl4]2Z = 3
Mr = 1395.01F(000) = 2142
Triclinic, P1Dx = 1.541 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 14.100 (3) ÅCell parameters from 12389 reflections
b = 18.244 (4) Åθ = 3.1–25.4°
c = 19.969 (4) ŵ = 1.44 mm1
α = 85.58 (3)°T = 293 K
β = 71.23 (3)°Prism, yellow
γ = 68.20 (3)°0.18 × 0.15 × 0.12 mm
V = 4511 (2) Å3
Data collection top
Rigaku Mercury
diffractometer
16405 independent reflections
Radiation source: fine-focus sealed tube10865 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.096
ω scansθmax = 25.4°, θmin = 3.1°
Absorption correction: multi-scan
(Jacobson, 1998)
h = 1416
Tmin = 0.782, Tmax = 0.847k = 2121
44634 measured reflectionsl = 2224
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.093Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.209H-atom parameters constrained
S = 1.08 w = 1/[σ2(Fo2) + (0.0667P)2 + 17.766P]
where P = (Fo2 + 2Fc2)/3
16405 reflections(Δ/σ)max = 0.001
1022 parametersΔρmax = 0.76 e Å3
0 restraintsΔρmin = 0.95 e Å3
Crystal data top
[Fe2Cl2(C11H16N4)4][FeCl4]2γ = 68.20 (3)°
Mr = 1395.01V = 4511 (2) Å3
Triclinic, P1Z = 3
a = 14.100 (3) ÅMo Kα radiation
b = 18.244 (4) ŵ = 1.44 mm1
c = 19.969 (4) ÅT = 293 K
α = 85.58 (3)°0.18 × 0.15 × 0.12 mm
β = 71.23 (3)°
Data collection top
Rigaku Mercury
diffractometer
16405 independent reflections
Absorption correction: multi-scan
(Jacobson, 1998)
10865 reflections with I > 2σ(I)
Tmin = 0.782, Tmax = 0.847Rint = 0.096
44634 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0930 restraints
wR(F2) = 0.209H-atom parameters constrained
S = 1.08 w = 1/[σ2(Fo2) + (0.0667P)2 + 17.766P]
where P = (Fo2 + 2Fc2)/3
16405 reflectionsΔρmax = 0.76 e Å3
1022 parametersΔρmin = 0.95 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Fe10.62332 (8)0.51099 (6)0.50914 (5)0.0247 (2)
Fe20.74539 (9)0.16729 (6)0.16291 (5)0.0257 (3)
Fe30.99665 (9)0.17009 (6)0.18208 (5)0.0282 (3)
Fe40.63770 (10)0.63582 (7)0.06660 (6)0.0422 (3)
Fe50.99828 (10)0.69688 (7)0.26964 (6)0.0370 (3)
Fe61.32478 (10)0.03970 (7)0.40487 (6)0.0354 (3)
Cl10.57354 (17)0.41434 (12)0.46044 (11)0.0410 (5)
Cl20.80653 (18)0.25535 (13)0.21295 (12)0.0477 (5)
Cl30.93390 (19)0.08437 (14)0.13036 (12)0.0514 (6)
Cl40.7281 (2)0.52573 (14)0.10930 (12)0.0573 (6)
Cl50.7239 (2)0.64291 (16)0.04497 (12)0.0610 (7)
Cl60.6167 (2)0.73748 (16)0.12761 (16)0.0754 (8)
Cl70.4792 (2)0.63502 (19)0.07611 (13)0.0707 (8)
Cl81.0250 (2)0.80953 (13)0.24793 (12)0.0587 (7)
Cl90.8800 (2)0.70590 (15)0.37419 (12)0.0602 (7)
Cl101.1519 (2)0.60330 (17)0.26359 (17)0.0781 (8)
Cl110.9354 (3)0.67382 (17)0.19135 (15)0.0774 (9)
Cl121.31887 (19)0.15580 (13)0.44282 (12)0.0499 (6)
Cl131.18150 (19)0.05457 (13)0.46825 (13)0.0533 (6)
Cl141.3308 (2)0.03182 (17)0.29382 (12)0.0652 (7)
Cl151.46816 (19)0.03050 (15)0.41644 (14)0.0567 (6)
N10.7937 (5)0.4304 (3)0.4892 (3)0.0261 (14)
N20.8140 (5)0.3594 (3)0.5215 (3)0.0293 (14)
N30.6535 (5)0.3821 (3)0.6202 (3)0.0312 (15)
N40.5976 (5)0.4607 (3)0.6133 (3)0.0275 (14)
N50.6583 (5)0.6072 (3)0.5454 (3)0.0268 (14)
N60.6305 (5)0.6792 (3)0.5136 (3)0.0276 (14)
N70.6583 (5)0.5625 (3)0.4070 (3)0.0260 (13)
N80.6266 (5)0.6434 (3)0.4021 (3)0.0284 (14)
N90.5806 (5)0.2555 (3)0.1851 (3)0.0302 (15)
N100.5666 (5)0.3242 (3)0.1493 (3)0.0300 (14)
N110.7731 (5)0.2163 (3)0.0589 (3)0.0285 (14)
N120.7309 (5)0.2976 (3)0.0525 (3)0.0289 (14)
N130.6936 (5)0.0789 (4)0.1283 (3)0.0326 (15)
N140.7025 (5)0.0118 (4)0.1674 (3)0.0352 (16)
N150.7092 (5)0.1155 (3)0.2663 (3)0.0262 (14)
N160.7415 (5)0.0349 (3)0.2707 (3)0.0314 (15)
N171.0463 (5)0.2590 (4)0.2160 (3)0.0335 (15)
N181.0214 (5)0.3315 (3)0.1877 (3)0.0354 (16)
N191.0364 (5)0.2189 (3)0.0794 (3)0.0331 (15)
N201.0169 (6)0.2978 (4)0.0749 (3)0.0395 (17)
N211.1602 (5)0.0799 (3)0.1588 (3)0.0306 (14)
N221.1697 (5)0.0043 (3)0.1781 (3)0.0304 (14)
N230.9701 (5)0.1183 (3)0.2847 (3)0.0286 (14)
N241.0253 (5)0.0387 (3)0.2891 (3)0.0310 (15)
C10.9188 (7)0.3241 (4)0.5144 (4)0.037 (2)
C20.9694 (7)0.3718 (5)0.4769 (4)0.041 (2)
H2A1.04260.36230.46360.049*
C30.8891 (6)0.4383 (4)0.4623 (4)0.0307 (17)
C40.9045 (6)0.5082 (5)0.4232 (4)0.0370 (19)
H4A0.93010.49580.37310.055*
H4B0.95620.52160.43610.055*
H4C0.83710.55220.43500.055*
C50.9646 (8)0.2436 (5)0.5413 (5)0.059 (3)
H5A0.93690.24600.59200.088*
H5B1.04170.22650.52650.088*
H5C0.94440.20680.52240.088*
C60.7271 (7)0.3339 (4)0.5571 (4)0.037 (2)
H6A0.75610.27960.56990.045*
H6B0.68760.33510.52490.045*
C70.6286 (7)0.3620 (4)0.6881 (4)0.039 (2)
C80.5552 (7)0.4292 (5)0.7274 (4)0.039 (2)
H8A0.52240.43360.77620.047*
C90.5391 (6)0.4899 (4)0.6802 (4)0.0303 (17)
C100.6762 (9)0.2811 (5)0.7122 (5)0.060 (3)
H10A0.66380.24380.68800.090*
H10B0.64320.28000.76230.090*
H10C0.75230.26730.70190.090*
C110.4729 (7)0.5744 (5)0.6969 (4)0.041 (2)
H11A0.51040.59920.71420.062*
H11B0.40570.57990.73260.062*
H11C0.45950.59920.65500.062*
C120.6665 (6)0.7291 (4)0.5355 (4)0.0317 (18)
C130.7196 (6)0.6896 (4)0.5815 (4)0.0314 (18)
H13A0.75320.70870.60530.038*
C140.7132 (6)0.6144 (4)0.5854 (4)0.0285 (17)
C150.6445 (8)0.8130 (4)0.5129 (5)0.048 (2)
H15A0.66930.81310.46210.072*
H15B0.68180.83640.53200.072*
H15C0.56860.84290.53020.072*
C160.7610 (7)0.5477 (5)0.6277 (4)0.0364 (19)
H16A0.71770.55760.67660.055*
H16B0.83280.54340.62310.055*
H16C0.76320.49920.61050.055*
C170.5678 (6)0.6935 (4)0.4663 (4)0.0299 (17)
H17A0.54790.74850.45400.036*
H17B0.50210.68390.49010.036*
C180.6542 (7)0.6650 (5)0.3351 (4)0.0335 (18)
C190.7084 (6)0.5961 (4)0.2934 (4)0.0325 (18)
H19A0.73780.59160.24430.039*
C200.7103 (6)0.5347 (4)0.3391 (4)0.0302 (17)
C210.6302 (8)0.7493 (5)0.3150 (5)0.051 (2)
H21A0.59050.78370.35670.077*
H21B0.58810.76090.28330.077*
H21C0.69640.75740.29180.077*
C220.7658 (7)0.4472 (4)0.3209 (4)0.038 (2)
H22A0.75330.41860.36320.057*
H22B0.84180.43470.29940.057*
H22C0.73770.43250.28830.057*
C230.4612 (7)0.3631 (5)0.1552 (4)0.040 (2)
C240.4075 (7)0.3191 (5)0.1935 (4)0.044 (2)
H24A0.33390.33040.20530.053*
C250.4811 (7)0.2538 (5)0.2124 (4)0.0358 (19)
C260.4232 (8)0.4413 (5)0.1214 (5)0.057 (3)
H26A0.34630.46020.13250.086*
H26B0.45630.43410.07100.086*
H26C0.44290.47900.13920.086*
C270.4616 (7)0.1858 (5)0.2536 (5)0.047 (2)
H27A0.43060.16120.23020.070*
H27B0.41310.20460.30040.070*
H27C0.52860.14790.25680.070*
C280.6579 (7)0.3472 (4)0.1162 (4)0.0356 (19)
H28A0.69660.34300.14950.043*
H28B0.63280.40200.10370.043*
C290.7608 (7)0.3186 (5)0.0149 (4)0.0341 (18)
C300.8243 (7)0.2482 (5)0.0549 (4)0.038 (2)
H30A0.85820.24280.10360.045*
C310.8275 (6)0.1868 (4)0.0076 (4)0.0283 (17)
C320.7313 (8)0.4014 (5)0.0373 (4)0.049 (2)
H32A0.65440.42590.02500.073*
H32B0.76310.40170.08770.073*
H32C0.75740.43010.01390.073*
C330.8799 (6)0.1007 (5)0.0257 (4)0.0366 (19)
H33A0.89650.07340.01460.055*
H33B0.94500.09050.06470.055*
H33C0.83200.08260.03850.055*
C340.6352 (7)0.0221 (5)0.1630 (5)0.044 (2)
C350.5815 (8)0.0232 (5)0.1197 (4)0.046 (2)
H35A0.52870.01480.10650.055*
C360.6196 (7)0.0847 (5)0.0986 (4)0.042 (2)
C370.6298 (9)0.0956 (6)0.2013 (5)0.065 (3)
H37A0.69910.13750.18580.097*
H37B0.57750.11100.19120.097*
H37C0.60920.08520.25140.097*
C380.5838 (7)0.1494 (5)0.0528 (4)0.042 (2)
H38A0.51100.18320.07660.063*
H38B0.58740.12770.00940.063*
H38C0.62970.17940.04270.063*
C390.7792 (7)0.0124 (4)0.2052 (4)0.037 (2)
H39A0.84610.00800.17520.045*
H39B0.79380.06740.21620.045*
C400.7230 (6)0.0123 (5)0.3382 (4)0.0361 (19)
C410.6764 (6)0.0800 (5)0.3797 (4)0.0340 (18)
H41A0.65460.08390.42890.041*
C420.6674 (6)0.1431 (4)0.3340 (4)0.0289 (17)
C430.7498 (7)0.0714 (5)0.3587 (5)0.046 (2)
H43A0.71260.09560.34040.069*
H43B0.72800.07310.40940.069*
H43C0.82600.09960.33950.069*
C440.6167 (7)0.2287 (4)0.3534 (4)0.039 (2)
H44A0.64810.25700.31590.059*
H44B0.62830.23850.39610.059*
H44C0.54080.24610.36080.059*
C451.0586 (7)0.3788 (5)0.2121 (4)0.043 (2)
C461.1065 (8)0.3363 (6)0.2584 (5)0.055 (3)
H46A1.13840.35360.28480.065*
C471.1000 (7)0.2623 (5)0.2598 (4)0.038 (2)
C481.0394 (9)0.4629 (5)0.1916 (5)0.062 (3)
H48A1.07130.46390.14140.093*
H48B1.07120.48590.21580.093*
H48C0.96330.49250.20460.093*
C491.1465 (7)0.1917 (5)0.2990 (5)0.048 (2)
H49A1.10560.20030.34840.073*
H49B1.22000.18380.29310.073*
H49C1.14380.14570.28060.073*
C500.9607 (8)0.3492 (4)0.1381 (4)0.044 (2)
H50A0.89190.34370.16110.052*
H50B0.94670.40360.12500.052*
C511.0533 (7)0.3169 (5)0.0074 (4)0.0365 (19)
C521.0996 (7)0.2488 (5)0.0330 (4)0.039 (2)
H52A1.13170.24360.08190.047*
C531.0903 (6)0.1880 (4)0.0121 (4)0.0314 (17)
C541.0374 (9)0.4006 (5)0.0139 (5)0.055 (3)
H54A0.96180.43110.00290.082*
H54B1.07230.40070.06380.082*
H54C1.06800.42330.01150.082*
C551.1312 (7)0.1023 (4)0.0065 (4)0.043 (2)
H55A1.10410.07540.03400.064*
H55B1.20850.08170.02120.064*
H55C1.10760.09430.04450.064*
C561.2710 (7)0.0487 (4)0.1468 (4)0.0361 (19)
C571.3278 (6)0.0050 (4)0.1076 (4)0.0355 (19)
H57A1.39970.02450.07950.043*
C581.2595 (6)0.0729 (5)0.1173 (4)0.0331 (18)
C591.3022 (7)0.1345 (4)0.1588 (4)0.044 (2)
H59A1.28890.14260.20850.067*
H59B1.37740.16120.13400.067*
H59C1.26050.15530.14170.067*
C601.2860 (7)0.1434 (5)0.0887 (5)0.045 (2)
H60A1.22160.18990.10130.068*
H60B1.31640.13690.03810.068*
H60C1.33710.14870.10840.068*
C611.0760 (6)0.0108 (4)0.2252 (4)0.0312 (18)
H61A1.02410.00180.20040.037*
H61B1.09830.06570.23740.037*
C621.0109 (6)0.0187 (5)0.3568 (4)0.0337 (18)
C630.9459 (7)0.0861 (5)0.3978 (4)0.0380 (19)
H63A0.92160.09040.44700.046*
C640.9228 (6)0.1473 (5)0.3524 (4)0.0314 (18)
C651.0595 (7)0.0641 (5)0.3771 (5)0.047 (2)
H65A1.03050.09730.36160.071*
H65B1.04310.06520.42760.071*
H65C1.13620.08320.35510.071*
C660.8590 (7)0.2325 (5)0.3715 (4)0.042 (2)
H66A0.90270.25670.38220.062*
H66B0.79720.23810.41220.062*
H66C0.83590.25770.33250.062*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Fe10.0325 (6)0.0166 (5)0.0198 (5)0.0057 (5)0.0057 (4)0.0023 (4)
Fe20.0330 (6)0.0174 (5)0.0225 (5)0.0082 (5)0.0053 (5)0.0036 (4)
Fe30.0371 (7)0.0172 (5)0.0250 (6)0.0074 (5)0.0066 (5)0.0036 (4)
Fe40.0518 (8)0.0402 (7)0.0364 (7)0.0215 (6)0.0093 (6)0.0052 (5)
Fe50.0518 (8)0.0269 (6)0.0343 (6)0.0156 (6)0.0157 (6)0.0054 (5)
Fe60.0405 (7)0.0314 (7)0.0330 (6)0.0088 (5)0.0145 (5)0.0018 (5)
Cl10.0454 (12)0.0432 (12)0.0421 (11)0.0224 (10)0.0191 (10)0.0132 (9)
Cl20.0463 (13)0.0519 (14)0.0517 (13)0.0225 (11)0.0226 (11)0.0182 (10)
Cl30.0502 (14)0.0557 (15)0.0560 (14)0.0252 (12)0.0239 (11)0.0191 (11)
Cl40.0776 (18)0.0479 (14)0.0466 (13)0.0239 (13)0.0195 (12)0.0035 (10)
Cl50.0685 (17)0.0799 (19)0.0388 (13)0.0368 (15)0.0125 (12)0.0089 (12)
Cl60.083 (2)0.0571 (17)0.090 (2)0.0209 (15)0.0305 (16)0.0304 (15)
Cl70.0692 (18)0.113 (2)0.0486 (14)0.0567 (18)0.0141 (13)0.0005 (14)
Cl80.0803 (18)0.0387 (13)0.0496 (14)0.0338 (13)0.0047 (12)0.0043 (10)
Cl90.0774 (18)0.0578 (16)0.0436 (13)0.0367 (14)0.0048 (12)0.0104 (11)
Cl100.0682 (19)0.0559 (17)0.094 (2)0.0004 (14)0.0334 (16)0.0099 (15)
Cl110.131 (3)0.0736 (19)0.0648 (17)0.0565 (19)0.0611 (18)0.0231 (14)
Cl120.0556 (14)0.0343 (12)0.0626 (14)0.0162 (11)0.0227 (12)0.0035 (10)
Cl130.0453 (13)0.0405 (13)0.0596 (14)0.0010 (11)0.0122 (11)0.0106 (10)
Cl140.0726 (18)0.086 (2)0.0361 (12)0.0237 (15)0.0222 (12)0.0028 (12)
Cl150.0464 (14)0.0592 (16)0.0727 (17)0.0207 (12)0.0265 (12)0.0040 (12)
N10.039 (4)0.012 (3)0.026 (3)0.007 (3)0.012 (3)0.004 (2)
N20.039 (4)0.013 (3)0.029 (3)0.004 (3)0.009 (3)0.001 (2)
N30.046 (4)0.015 (3)0.019 (3)0.001 (3)0.006 (3)0.003 (2)
N40.040 (4)0.020 (3)0.020 (3)0.009 (3)0.007 (3)0.001 (2)
N50.030 (3)0.016 (3)0.028 (3)0.005 (3)0.007 (3)0.004 (2)
N60.030 (4)0.017 (3)0.030 (3)0.005 (3)0.005 (3)0.001 (2)
N70.030 (3)0.016 (3)0.027 (3)0.009 (3)0.003 (3)0.005 (2)
N80.043 (4)0.021 (3)0.019 (3)0.012 (3)0.007 (3)0.005 (2)
N90.045 (4)0.023 (3)0.020 (3)0.011 (3)0.009 (3)0.001 (2)
N100.042 (4)0.019 (3)0.025 (3)0.009 (3)0.008 (3)0.002 (2)
N110.039 (4)0.017 (3)0.023 (3)0.007 (3)0.006 (3)0.006 (2)
N120.042 (4)0.020 (3)0.022 (3)0.007 (3)0.012 (3)0.003 (2)
N130.042 (4)0.025 (4)0.029 (3)0.015 (3)0.005 (3)0.001 (3)
N140.046 (4)0.019 (3)0.036 (4)0.012 (3)0.007 (3)0.002 (3)
N150.040 (4)0.014 (3)0.023 (3)0.011 (3)0.006 (3)0.001 (2)
N160.041 (4)0.024 (3)0.023 (3)0.012 (3)0.002 (3)0.006 (3)
N170.038 (4)0.024 (4)0.037 (4)0.015 (3)0.007 (3)0.005 (3)
N180.042 (4)0.018 (3)0.039 (4)0.009 (3)0.005 (3)0.004 (3)
N190.050 (4)0.013 (3)0.029 (3)0.009 (3)0.006 (3)0.006 (2)
N200.056 (5)0.021 (3)0.031 (4)0.013 (3)0.002 (3)0.005 (3)
N210.034 (4)0.017 (3)0.039 (4)0.006 (3)0.013 (3)0.002 (3)
N220.038 (4)0.020 (3)0.026 (3)0.006 (3)0.006 (3)0.004 (3)
N230.036 (4)0.019 (3)0.028 (3)0.005 (3)0.012 (3)0.006 (2)
N240.044 (4)0.017 (3)0.027 (3)0.009 (3)0.008 (3)0.002 (2)
C10.039 (5)0.022 (4)0.042 (5)0.006 (4)0.022 (4)0.004 (3)
C20.036 (5)0.034 (5)0.049 (5)0.006 (4)0.014 (4)0.005 (4)
C30.021 (4)0.021 (4)0.038 (4)0.002 (3)0.001 (3)0.000 (3)
C40.026 (4)0.040 (5)0.042 (5)0.013 (4)0.005 (4)0.003 (4)
C50.068 (7)0.031 (5)0.068 (6)0.007 (5)0.040 (6)0.005 (4)
C60.059 (6)0.013 (4)0.026 (4)0.006 (4)0.003 (4)0.002 (3)
C70.059 (6)0.024 (4)0.029 (4)0.013 (4)0.011 (4)0.012 (3)
C80.054 (6)0.043 (5)0.024 (4)0.025 (5)0.010 (4)0.008 (4)
C90.026 (4)0.035 (5)0.024 (4)0.011 (4)0.002 (3)0.001 (3)
C100.106 (9)0.028 (5)0.036 (5)0.014 (5)0.027 (5)0.021 (4)
C110.042 (5)0.033 (5)0.031 (4)0.005 (4)0.005 (4)0.015 (4)
C120.040 (5)0.015 (4)0.031 (4)0.009 (3)0.000 (4)0.006 (3)
C130.028 (4)0.020 (4)0.039 (4)0.006 (3)0.003 (4)0.008 (3)
C140.027 (4)0.024 (4)0.026 (4)0.000 (3)0.008 (3)0.001 (3)
C150.073 (7)0.020 (4)0.049 (5)0.022 (4)0.011 (5)0.006 (4)
C160.041 (5)0.035 (5)0.040 (5)0.015 (4)0.022 (4)0.003 (4)
C170.045 (5)0.019 (4)0.025 (4)0.011 (4)0.012 (4)0.004 (3)
C180.046 (5)0.032 (4)0.030 (4)0.021 (4)0.016 (4)0.012 (3)
C190.042 (5)0.033 (4)0.020 (4)0.018 (4)0.000 (3)0.004 (3)
C200.036 (4)0.024 (4)0.028 (4)0.013 (4)0.002 (3)0.007 (3)
C210.078 (7)0.039 (5)0.040 (5)0.027 (5)0.021 (5)0.018 (4)
C220.050 (5)0.035 (5)0.026 (4)0.020 (4)0.001 (4)0.007 (3)
C230.045 (5)0.030 (5)0.035 (5)0.005 (4)0.021 (4)0.005 (4)
C240.040 (5)0.047 (6)0.042 (5)0.009 (5)0.014 (4)0.004 (4)
C250.035 (5)0.037 (5)0.032 (4)0.009 (4)0.009 (4)0.007 (3)
C260.069 (7)0.039 (5)0.050 (6)0.007 (5)0.029 (5)0.008 (4)
C270.036 (5)0.052 (6)0.050 (5)0.019 (4)0.004 (4)0.006 (4)
C280.059 (6)0.018 (4)0.024 (4)0.009 (4)0.013 (4)0.001 (3)
C290.048 (5)0.033 (5)0.027 (4)0.020 (4)0.016 (4)0.014 (3)
C300.049 (5)0.040 (5)0.023 (4)0.021 (4)0.005 (4)0.003 (3)
C310.028 (4)0.027 (4)0.026 (4)0.008 (3)0.006 (3)0.002 (3)
C320.075 (7)0.038 (5)0.037 (5)0.025 (5)0.020 (5)0.012 (4)
C330.035 (5)0.037 (5)0.025 (4)0.004 (4)0.002 (3)0.007 (3)
C340.056 (6)0.024 (4)0.043 (5)0.021 (4)0.007 (4)0.011 (4)
C350.063 (6)0.051 (6)0.036 (5)0.039 (5)0.007 (4)0.008 (4)
C360.047 (5)0.036 (5)0.040 (5)0.008 (4)0.014 (4)0.009 (4)
C370.087 (8)0.046 (6)0.055 (6)0.040 (6)0.008 (6)0.003 (5)
C380.042 (5)0.045 (5)0.044 (5)0.017 (4)0.017 (4)0.009 (4)
C390.050 (5)0.012 (4)0.028 (4)0.004 (4)0.005 (4)0.004 (3)
C400.037 (5)0.038 (5)0.032 (4)0.014 (4)0.011 (4)0.014 (4)
C410.033 (4)0.049 (5)0.019 (4)0.017 (4)0.007 (3)0.010 (3)
C420.030 (4)0.023 (4)0.026 (4)0.005 (3)0.005 (3)0.000 (3)
C430.046 (5)0.037 (5)0.048 (5)0.010 (4)0.016 (4)0.020 (4)
C440.042 (5)0.031 (5)0.036 (4)0.009 (4)0.004 (4)0.011 (3)
C450.057 (6)0.032 (5)0.033 (5)0.024 (4)0.006 (4)0.004 (4)
C460.053 (6)0.057 (6)0.051 (6)0.032 (5)0.004 (5)0.019 (5)
C470.034 (5)0.033 (5)0.043 (5)0.014 (4)0.004 (4)0.003 (4)
C480.079 (8)0.030 (5)0.064 (7)0.028 (5)0.003 (6)0.003 (4)
C490.046 (6)0.061 (6)0.048 (5)0.020 (5)0.026 (4)0.010 (4)
C500.062 (6)0.016 (4)0.037 (5)0.003 (4)0.007 (4)0.002 (3)
C510.039 (5)0.032 (5)0.038 (5)0.017 (4)0.010 (4)0.013 (4)
C520.052 (5)0.037 (5)0.027 (4)0.024 (4)0.003 (4)0.006 (3)
C530.036 (5)0.033 (4)0.023 (4)0.013 (4)0.006 (3)0.001 (3)
C540.089 (8)0.040 (5)0.045 (5)0.034 (5)0.028 (5)0.024 (4)
C550.050 (5)0.026 (4)0.036 (5)0.007 (4)0.002 (4)0.005 (3)
C560.053 (5)0.020 (4)0.030 (4)0.002 (4)0.020 (4)0.001 (3)
C570.024 (4)0.030 (4)0.049 (5)0.005 (4)0.012 (4)0.002 (4)
C580.023 (4)0.030 (4)0.043 (5)0.008 (4)0.010 (4)0.004 (3)
C590.059 (6)0.021 (4)0.041 (5)0.001 (4)0.016 (4)0.004 (3)
C600.037 (5)0.029 (5)0.057 (6)0.012 (4)0.001 (4)0.005 (4)
C610.042 (5)0.009 (3)0.033 (4)0.011 (3)0.001 (4)0.002 (3)
C620.041 (5)0.033 (5)0.027 (4)0.016 (4)0.011 (4)0.015 (3)
C630.039 (5)0.045 (5)0.031 (4)0.015 (4)0.014 (4)0.003 (4)
C640.032 (4)0.041 (5)0.022 (4)0.015 (4)0.007 (3)0.002 (3)
C650.053 (6)0.043 (5)0.042 (5)0.016 (5)0.015 (4)0.015 (4)
C660.046 (5)0.042 (5)0.034 (4)0.010 (4)0.012 (4)0.010 (4)
Geometric parameters (Å, º) top
Fe1—N72.165 (6)C16—H16A0.9600
Fe1—N42.184 (6)C16—H16B0.9600
Fe1—N52.218 (6)C16—H16C0.9600
Fe1—N12.223 (6)C17—H17A0.9700
Fe1—Cl1i2.483 (3)C17—H17B0.9700
Fe1—Cl12.484 (2)C18—C191.378 (10)
Fe1—Fe1i3.777 (2)C18—C211.499 (10)
Fe2—N112.171 (6)C19—C201.386 (10)
Fe2—N152.191 (6)C19—H19A0.9300
Fe2—N92.204 (7)C20—C221.509 (10)
Fe2—N132.233 (6)C21—H21A0.9600
Fe2—Cl32.414 (3)C21—H21B0.9600
Fe2—Cl22.481 (3)C21—H21C0.9600
Fe2—Fe33.7028 (17)C22—H22A0.9600
Fe3—N192.158 (6)C22—H22B0.9600
Fe3—N232.170 (6)C22—H22C0.9600
Fe3—N212.202 (6)C23—C241.337 (12)
Fe3—N172.213 (6)C23—C261.514 (11)
Fe3—Cl22.444 (3)C24—C251.380 (11)
Fe3—Cl32.482 (3)C24—H24A0.9300
Fe4—Cl62.173 (3)C25—C271.498 (11)
Fe4—Cl72.187 (3)C26—H26A0.9600
Fe4—Cl52.188 (3)C26—H26B0.9600
Fe4—Cl42.218 (3)C26—H26C0.9600
Fe5—Cl112.163 (3)C27—H27A0.9600
Fe5—Cl102.177 (3)C27—H27B0.9600
Fe5—Cl92.186 (3)C27—H27C0.9600
Fe5—Cl82.210 (2)C28—H28A0.9700
Fe6—Cl152.174 (3)C28—H28B0.9700
Fe6—Cl132.180 (3)C29—C301.390 (11)
Fe6—Cl142.187 (3)C29—C321.485 (10)
Fe6—Cl122.216 (3)C30—C311.406 (10)
Cl1—Fe1i2.483 (3)C30—H30A0.9300
N1—C31.336 (9)C31—C331.482 (10)
N1—N21.376 (8)C32—H32A0.9600
N2—C11.339 (10)C32—H32B0.9600
N2—C61.427 (10)C32—H32C0.9600
N3—C71.344 (9)C33—H33A0.9600
N3—N41.377 (8)C33—H33B0.9600
N3—C61.446 (9)C33—H33C0.9600
N4—C91.349 (9)C34—C351.360 (13)
N5—C141.321 (9)C34—C371.507 (12)
N5—N61.389 (8)C35—C361.398 (12)
N6—C121.352 (9)C35—H35A0.9300
N6—C171.440 (9)C36—C381.473 (12)
N7—C201.350 (9)C37—H37A0.9600
N7—N81.380 (8)C37—H37B0.9600
N8—C181.339 (9)C37—H37C0.9600
N8—C171.448 (9)C38—H38A0.9600
N9—C251.343 (10)C38—H38B0.9600
N9—N101.374 (8)C38—H38C0.9600
N10—C231.358 (10)C39—H39A0.9700
N10—C281.444 (10)C39—H39B0.9700
N11—C311.338 (9)C40—C411.362 (11)
N11—N121.392 (8)C40—C431.489 (11)
N12—C291.346 (9)C41—C421.407 (10)
N12—C281.462 (9)C41—H41A0.9300
N13—C361.325 (10)C42—C441.478 (10)
N13—N141.388 (8)C43—H43A0.9600
N14—C341.338 (10)C43—H43B0.9600
N14—C391.432 (10)C43—H43C0.9600
N15—C421.340 (9)C44—H44A0.9600
N15—N161.373 (8)C44—H44B0.9600
N16—C401.350 (9)C44—H44C0.9600
N16—C391.457 (9)C45—C461.346 (13)
N17—C471.345 (10)C45—C481.503 (11)
N17—N181.364 (8)C46—C471.385 (12)
N18—C451.351 (10)C46—H46A0.9300
N18—C501.451 (11)C47—C491.500 (11)
N19—C531.358 (9)C48—H48A0.9600
N19—N201.363 (8)C48—H48B0.9600
N20—C511.348 (10)C48—H48C0.9600
N20—C501.445 (10)C49—H49A0.9600
N21—C581.342 (9)C49—H49B0.9600
N21—N221.373 (8)C49—H49C0.9600
N22—C561.364 (10)C50—H50A0.9700
N22—C611.461 (9)C50—H50B0.9700
N23—C641.348 (9)C51—C521.354 (11)
N23—N241.381 (8)C51—C541.506 (11)
N24—C621.342 (9)C52—C531.391 (10)
N24—C611.438 (9)C52—H52A0.9300
C1—C21.357 (12)C53—C551.483 (10)
C1—C51.503 (11)C54—H54A0.9600
C2—C31.406 (11)C54—H54B0.9600
C2—H2A0.9300C54—H54C0.9600
C3—C41.493 (10)C55—H55A0.9600
C4—H4A0.9600C55—H55B0.9600
C4—H4B0.9600C55—H55C0.9600
C4—H4C0.9600C56—C571.364 (11)
C5—H5A0.9600C56—C591.485 (10)
C5—H5B0.9600C57—C581.376 (10)
C5—H5C0.9600C57—H57A0.9300
C6—H6A0.9700C58—C601.491 (10)
C6—H6B0.9700C59—H59A0.9600
C7—C81.369 (11)C59—H59B0.9600
C7—C101.493 (10)C59—H59C0.9600
C8—C91.400 (10)C60—H60A0.9600
C8—H8A0.9300C60—H60B0.9600
C9—C111.473 (10)C60—H60C0.9600
C10—H10A0.9600C61—H61A0.9700
C10—H10B0.9600C61—H61B0.9700
C10—H10C0.9600C62—C631.364 (11)
C11—H11A0.9600C62—C651.494 (11)
C11—H11B0.9600C63—C641.393 (11)
C11—H11C0.9600C63—H63A0.9300
C12—C131.364 (11)C64—C661.484 (11)
C12—C151.508 (10)C65—H65A0.9600
C13—C141.404 (10)C65—H65B0.9600
C13—H13A0.9300C65—H65C0.9600
C14—C161.499 (10)C66—H66A0.9600
C15—H15A0.9600C66—H66B0.9600
C15—H15B0.9600C66—H66C0.9600
C15—H15C0.9600
N7—Fe1—N4175.9 (2)C14—C16—H16C109.5
N7—Fe1—N584.3 (2)H16A—C16—H16C109.5
N4—Fe1—N592.5 (2)H16B—C16—H16C109.5
N7—Fe1—N193.0 (2)N6—C17—N8111.7 (6)
N4—Fe1—N184.4 (2)N6—C17—H17A109.3
N5—Fe1—N190.3 (2)N8—C17—H17A109.3
N7—Fe1—Cl1i93.18 (17)N6—C17—H17B109.3
N4—Fe1—Cl1i89.69 (17)N8—C17—H17B109.3
N5—Fe1—Cl1i95.11 (16)H17A—C17—H17B107.9
N1—Fe1—Cl1i172.16 (16)N8—C18—C19106.3 (6)
N7—Fe1—Cl190.80 (16)N8—C18—C21123.6 (7)
N4—Fe1—Cl192.58 (16)C19—C18—C21130.1 (7)
N5—Fe1—Cl1173.57 (16)C18—C19—C20106.4 (6)
N1—Fe1—Cl194.09 (16)C18—C19—H19A126.8
Cl1i—Fe1—Cl181.01 (9)C20—C19—H19A126.8
N7—Fe1—Fe1i92.62 (17)N7—C20—C19111.1 (6)
N4—Fe1—Fe1i91.49 (17)N7—C20—C22121.1 (6)
N5—Fe1—Fe1i135.41 (16)C19—C20—C22127.7 (6)
N1—Fe1—Fe1i134.28 (15)C18—C21—H21A109.5
Cl1i—Fe1—Fe1i40.52 (5)C18—C21—H21B109.5
Cl1—Fe1—Fe1i40.49 (6)H21A—C21—H21B109.5
N11—Fe2—N15176.1 (2)C18—C21—H21C109.5
N11—Fe2—N984.6 (2)H21A—C21—H21C109.5
N15—Fe2—N993.6 (2)H21B—C21—H21C109.5
N11—Fe2—N1391.8 (2)C20—C22—H22A109.5
N15—Fe2—N1384.7 (2)C20—C22—H22B109.5
N9—Fe2—N1389.8 (2)H22A—C22—H22B109.5
N11—Fe2—Cl389.59 (18)C20—C22—H22C109.5
N15—Fe2—Cl392.54 (17)H22A—C22—H22C109.5
N9—Fe2—Cl3172.30 (17)H22B—C22—H22C109.5
N13—Fe2—Cl395.43 (18)C24—C23—N10106.9 (7)
N11—Fe2—Cl294.50 (17)C24—C23—C26131.4 (9)
N15—Fe2—Cl289.04 (16)N10—C23—C26121.7 (8)
N9—Fe2—Cl293.04 (17)C23—C24—C25107.5 (8)
N13—Fe2—Cl2173.29 (17)C23—C24—H24A126.3
Cl3—Fe2—Cl282.42 (9)C25—C24—H24A126.3
N11—Fe2—Fe393.45 (17)N9—C25—C24110.4 (8)
N15—Fe2—Fe390.32 (17)N9—C25—C27121.4 (7)
N9—Fe2—Fe3133.71 (16)C24—C25—C27128.1 (8)
N13—Fe2—Fe3136.52 (17)C23—C26—H26A109.5
Cl3—Fe2—Fe341.56 (6)C23—C26—H26B109.5
Cl2—Fe2—Fe340.88 (6)H26A—C26—H26B109.5
N19—Fe3—N23175.4 (2)C23—C26—H26C109.5
N19—Fe3—N2192.1 (2)H26A—C26—H26C109.5
N23—Fe3—N2183.9 (2)H26B—C26—H26C109.5
N19—Fe3—N1784.4 (2)C25—C27—H27A109.5
N23—Fe3—N1793.5 (2)C25—C27—H27B109.5
N21—Fe3—N1791.8 (2)H27A—C27—H27B109.5
N19—Fe3—Cl292.93 (19)C25—C27—H27C109.5
N23—Fe3—Cl291.30 (17)H27A—C27—H27C109.5
N21—Fe3—Cl2172.22 (17)H27B—C27—H27C109.5
N17—Fe3—Cl294.60 (18)N10—C28—N12111.5 (6)
N19—Fe3—Cl388.04 (18)N10—C28—H28A109.3
N23—Fe3—Cl394.39 (17)N12—C28—H28A109.3
N21—Fe3—Cl392.45 (17)N10—C28—H28B109.3
N17—Fe3—Cl3171.44 (18)N12—C28—H28B109.3
Cl2—Fe3—Cl381.80 (9)H28A—C28—H28B108.0
N19—Fe3—Fe291.30 (19)N12—C29—C30105.6 (6)
N23—Fe3—Fe293.09 (17)N12—C29—C32124.5 (7)
N21—Fe3—Fe2132.33 (16)C30—C29—C32129.9 (7)
N17—Fe3—Fe2135.84 (17)C29—C30—C31106.8 (7)
Cl2—Fe3—Fe241.62 (6)C29—C30—H30A126.6
Cl3—Fe3—Fe240.19 (6)C31—C30—H30A126.6
Cl6—Fe4—Cl7108.90 (13)N11—C31—C30110.4 (6)
Cl6—Fe4—Cl5110.04 (13)N11—C31—C33122.6 (6)
Cl7—Fe4—Cl5109.23 (11)C30—C31—C33127.0 (7)
Cl6—Fe4—Cl4109.57 (12)C29—C32—H32A109.5
Cl7—Fe4—Cl4108.78 (12)C29—C32—H32B109.5
Cl5—Fe4—Cl4110.28 (12)H32A—C32—H32B109.5
Cl11—Fe5—Cl10110.33 (14)C29—C32—H32C109.5
Cl11—Fe5—Cl9108.39 (13)H32A—C32—H32C109.5
Cl10—Fe5—Cl9111.11 (13)H32B—C32—H32C109.5
Cl11—Fe5—Cl8108.99 (11)C31—C33—H33A109.5
Cl10—Fe5—Cl8108.23 (13)C31—C33—H33B109.5
Cl9—Fe5—Cl8109.77 (10)H33A—C33—H33B109.5
Cl15—Fe6—Cl13109.96 (11)C31—C33—H33C109.5
Cl15—Fe6—Cl14110.51 (12)H33A—C33—H33C109.5
Cl13—Fe6—Cl14109.46 (11)H33B—C33—H33C109.5
Cl15—Fe6—Cl12107.95 (11)N14—C34—C35105.5 (7)
Cl13—Fe6—Cl12109.50 (11)N14—C34—C37121.9 (9)
Cl14—Fe6—Cl12109.43 (11)C35—C34—C37132.5 (9)
Fe1i—Cl1—Fe198.99 (9)C34—C35—C36108.0 (8)
Fe3—Cl2—Fe297.50 (9)C34—C35—H35A126.0
Fe2—Cl3—Fe398.25 (10)C36—C35—H35A126.0
C3—N1—N2105.4 (6)N13—C36—C35109.5 (8)
C3—N1—Fe1135.0 (5)N13—C36—C38122.8 (8)
N2—N1—Fe1118.3 (4)C35—C36—C38127.6 (8)
C1—N2—N1111.1 (6)C34—C37—H37A109.5
C1—N2—C6129.3 (7)C34—C37—H37B109.5
N1—N2—C6119.5 (6)H37A—C37—H37B109.5
C7—N3—N4111.8 (6)C34—C37—H37C109.5
C7—N3—C6129.6 (6)H37A—C37—H37C109.5
N4—N3—C6118.5 (5)H37B—C37—H37C109.5
C9—N4—N3104.8 (5)C36—C38—H38A109.5
C9—N4—Fe1134.9 (5)C36—C38—H38B109.5
N3—N4—Fe1120.2 (4)H38A—C38—H38B109.5
C14—N5—N6104.7 (6)C36—C38—H38C109.5
C14—N5—Fe1137.0 (5)H38A—C38—H38C109.5
N6—N5—Fe1117.7 (4)H38B—C38—H38C109.5
C12—N6—N5111.1 (6)N14—C39—N16112.4 (6)
C12—N6—C17128.5 (6)N14—C39—H39A109.1
N5—N6—C17120.4 (6)N16—C39—H39A109.1
C20—N7—N8103.5 (5)N14—C39—H39B109.1
C20—N7—Fe1135.9 (5)N16—C39—H39B109.1
N8—N7—Fe1120.6 (4)H39A—C39—H39B107.9
C18—N8—N7112.6 (6)N16—C40—C41106.0 (7)
C18—N8—C17128.4 (6)N16—C40—C43124.3 (7)
N7—N8—C17119.0 (5)C41—C40—C43129.7 (7)
C25—N9—N10104.4 (6)C40—C41—C42106.8 (6)
C25—N9—Fe2135.2 (5)C40—C41—H41A126.6
N10—N9—Fe2118.0 (5)C42—C41—H41A126.6
C23—N10—N9110.8 (6)N15—C42—C41110.3 (6)
C23—N10—C28129.7 (7)N15—C42—C44122.0 (6)
N9—N10—C28119.3 (6)C41—C42—C44127.7 (7)
C31—N11—N12104.5 (5)C40—C43—H43A109.5
C31—N11—Fe2135.4 (5)C40—C43—H43B109.5
N12—N11—Fe2120.0 (4)H43A—C43—H43B109.5
C29—N12—N11112.6 (6)C40—C43—H43C109.5
C29—N12—C28129.1 (6)H43A—C43—H43C109.5
N11—N12—C28118.2 (5)H43B—C43—H43C109.5
C36—N13—N14104.9 (6)C42—C44—H44A109.5
C36—N13—Fe2133.4 (5)C42—C44—H44B109.5
N14—N13—Fe2115.9 (5)H44A—C44—H44B109.5
C34—N14—N13112.1 (7)C42—C44—H44C109.5
C34—N14—C39129.0 (7)H44A—C44—H44C109.5
N13—N14—C39118.9 (6)H44B—C44—H44C109.5
C42—N15—N16104.3 (5)C46—C45—N18105.8 (7)
C42—N15—Fe2135.5 (5)C46—C45—C48130.8 (9)
N16—N15—Fe2120.0 (4)N18—C45—C48123.3 (9)
C40—N16—N15112.6 (6)C45—C46—C47108.1 (8)
C40—N16—C39129.4 (6)C45—C46—H46A125.9
N15—N16—C39117.6 (5)C47—C46—H46A125.9
C47—N17—N18104.8 (6)N17—C47—C46109.3 (8)
C47—N17—Fe3136.7 (5)N17—C47—C49121.3 (7)
N18—N17—Fe3118.5 (5)C46—C47—C49129.3 (9)
C45—N18—N17111.9 (7)C45—C48—H48A109.5
C45—N18—C50128.5 (7)C45—C48—H48B109.5
N17—N18—C50119.6 (6)H48A—C48—H48B109.5
C53—N19—N20105.1 (6)C45—C48—H48C109.5
C53—N19—Fe3134.9 (5)H48A—C48—H48C109.5
N20—N19—Fe3119.6 (4)H48B—C48—H48C109.5
C51—N20—N19111.5 (6)C47—C49—H49A109.5
C51—N20—C50128.7 (7)C47—C49—H49B109.5
N19—N20—C50119.8 (6)H49A—C49—H49B109.5
C58—N21—N22104.3 (6)C47—C49—H49C109.5
C58—N21—Fe3136.6 (5)H49A—C49—H49C109.5
N22—N21—Fe3117.6 (5)H49B—C49—H49C109.5
C56—N22—N21111.7 (6)N20—C50—N18112.3 (7)
C56—N22—C61128.5 (6)N20—C50—H50A109.1
N21—N22—C61119.8 (6)N18—C50—H50A109.1
C64—N23—N24105.1 (6)N20—C50—H50B109.1
C64—N23—Fe3134.8 (5)N18—C50—H50B109.1
N24—N23—Fe3119.1 (4)H50A—C50—H50B107.9
C62—N24—N23111.3 (6)N20—C51—C52106.8 (7)
C62—N24—C61129.7 (6)N20—C51—C54123.1 (7)
N23—N24—C61118.4 (6)C52—C51—C54130.1 (8)
N2—C1—C2107.5 (7)C51—C52—C53107.4 (7)
N2—C1—C5122.4 (8)C51—C52—H52A126.3
C2—C1—C5130.0 (8)C53—C52—H52A126.3
C1—C2—C3106.4 (7)N19—C53—C52109.1 (7)
C1—C2—H2A126.8N19—C53—C55122.9 (6)
C3—C2—H2A126.8C52—C53—C55128.0 (7)
N1—C3—C2109.7 (7)C51—C54—H54A109.5
N1—C3—C4123.6 (6)C51—C54—H54B109.5
C2—C3—C4126.7 (7)H54A—C54—H54B109.5
C3—C4—H4A109.5C51—C54—H54C109.5
C3—C4—H4B109.5H54A—C54—H54C109.5
H4A—C4—H4B109.5H54B—C54—H54C109.5
C3—C4—H4C109.5C53—C55—H55A109.5
H4A—C4—H4C109.5C53—C55—H55B109.5
H4B—C4—H4C109.5H55A—C55—H55B109.5
C1—C5—H5A109.5C53—C55—H55C109.5
C1—C5—H5B109.5H55A—C55—H55C109.5
H5A—C5—H5B109.5H55B—C55—H55C109.5
C1—C5—H5C109.5C57—C56—N22105.5 (6)
H5A—C5—H5C109.5C57—C56—C59132.1 (8)
H5B—C5—H5C109.5N22—C56—C59122.3 (8)
N2—C6—N3113.0 (6)C56—C57—C58107.6 (7)
N2—C6—H6A109.0C56—C57—H57A126.2
N3—C6—H6A109.0C58—C57—H57A126.2
N2—C6—H6B109.0N21—C58—C57110.8 (7)
N3—C6—H6B109.0N21—C58—C60121.6 (7)
H6A—C6—H6B107.8C57—C58—C60127.6 (7)
N3—C7—C8106.6 (6)C56—C59—H59A109.5
N3—C7—C10124.3 (7)C56—C59—H59B109.5
C8—C7—C10129.1 (7)H59A—C59—H59B109.5
C7—C8—C9106.9 (7)C56—C59—H59C109.5
C7—C8—H8A126.6H59A—C59—H59C109.5
C9—C8—H8A126.6H59B—C59—H59C109.5
N4—C9—C8109.7 (7)C58—C60—H60A109.5
N4—C9—C11122.4 (7)C58—C60—H60B109.5
C8—C9—C11127.9 (7)H60A—C60—H60B109.5
C7—C10—H10A109.5C58—C60—H60C109.5
C7—C10—H10B109.5H60A—C60—H60C109.5
H10A—C10—H10B109.5H60B—C60—H60C109.5
C7—C10—H10C109.5N24—C61—N22112.5 (6)
H10A—C10—H10C109.5N24—C61—H61A109.1
H10B—C10—H10C109.5N22—C61—H61A109.1
C9—C11—H11A109.5N24—C61—H61B109.1
C9—C11—H11B109.5N22—C61—H61B109.1
H11A—C11—H11B109.5H61A—C61—H61B107.8
C9—C11—H11C109.5N24—C62—C63106.8 (7)
H11A—C11—H11C109.5N24—C62—C65122.7 (7)
H11B—C11—H11C109.5C63—C62—C65130.5 (7)
N6—C12—C13107.0 (6)C62—C63—C64107.3 (7)
N6—C12—C15123.5 (7)C62—C63—H63A126.3
C13—C12—C15129.5 (7)C64—C63—H63A126.3
C12—C13—C14106.0 (7)N23—C64—C63109.4 (7)
C12—C13—H13A127.0N23—C64—C66122.8 (7)
C14—C13—H13A127.0C63—C64—C66127.8 (7)
N5—C14—C13111.3 (6)C62—C65—H65A109.5
N5—C14—C16121.6 (7)C62—C65—H65B109.5
C13—C14—C16127.1 (7)H65A—C65—H65B109.5
C12—C15—H15A109.5C62—C65—H65C109.5
C12—C15—H15B109.5H65A—C65—H65C109.5
H15A—C15—H15B109.5H65B—C65—H65C109.5
C12—C15—H15C109.5C64—C66—H66A109.5
H15A—C15—H15C109.5C64—C66—H66B109.5
H15B—C15—H15C109.5H66A—C66—H66B109.5
C14—C16—H16A109.5C64—C66—H66C109.5
C14—C16—H16B109.5H66A—C66—H66C109.5
H16A—C16—H16B109.5H66B—C66—H66C109.5
Symmetry code: (i) x+1, y+1, z+1.

Experimental details

Crystal data
Chemical formula[Fe2Cl2(C11H16N4)4][FeCl4]2
Mr1395.01
Crystal system, space groupTriclinic, P1
Temperature (K)293
a, b, c (Å)14.100 (3), 18.244 (4), 19.969 (4)
α, β, γ (°)85.58 (3), 71.23 (3), 68.20 (3)
V3)4511 (2)
Z3
Radiation typeMo Kα
µ (mm1)1.44
Crystal size (mm)0.18 × 0.15 × 0.12
Data collection
DiffractometerRigaku Mercury
diffractometer
Absorption correctionMulti-scan
(Jacobson, 1998)
Tmin, Tmax0.782, 0.847
No. of measured, independent and
observed [I > 2σ(I)] reflections
44634, 16405, 10865
Rint0.096
(sin θ/λ)max1)0.602
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.093, 0.209, 1.08
No. of reflections16405
No. of parameters1022
H-atom treatmentH-atom parameters constrained
w = 1/[σ2(Fo2) + (0.0667P)2 + 17.766P]
where P = (Fo2 + 2Fc2)/3
Δρmax, Δρmin (e Å3)0.76, 0.95

Computer programs: CrystalClear (Rigaku/MSC, 2001), CrystalStructure (Rigaku/MSC, 2004), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

 

Acknowledgements

The authors acknowledge Jiangxi Science and Technology Normal University for funding.

References

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First citationBatten, S. R., Bjernemose, J. K., Jensen, P., Leita, B. A., Murray, K. S., Moubaraki, B., Smith, J. P. & Toftlund, H. (2004). Dalton Trans. pp. 3370–3375.  Web of Science CSD CrossRef Google Scholar
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First citationPettinari, C. & Pettinari, R. (2005). Coord. Chem. Rev. 249, 525–543663-691.  Google Scholar
First citationReger, D. L., Elgin, J. D., Smith, M. D., Grandjean, F., Rebbouh, L. & Long, G. J. (2004). Eur. J. Inorg. Chem. pp. 3345–3352.  Web of Science CSD CrossRef Google Scholar
First citationRigaku/MSC (2001). CrystalClear. Rigaku/MSC, The Woodlands, Texas, USA.  Google Scholar
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