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In the title compounds, the cation distributions correspond to a normal garnet structure for Ca3[8]Fe2[6]Ge3[4]O12 and Ca3[8]Y2[6]Ge3[4]O12, and to an inverse garnet structure for (MgY2)[8]Mg2[6]Ge3[4]O12.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks Ca3Fe2Ge3O12, Ca3Y2Ge3O12, Mg3Y2Ge3O12, global

hkl

Structure factor file (CIF format)
Contains datablock ca3fe2ge3o12

hkl

Structure factor file (CIF format)
Contains datablock ca3y2ge3o12

hkl

Structure factor file (CIF format)
Contains datablock mg3y2ge3o12

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