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The isomorphous title compounds are newly discovered double-anion salts containing ZnCl42- and NO3- ions. The structure consists of rows of nitrate ions parallel to a, surrounded by cylinders of cations, which in turn are surrounded by concentric cylinders of tetrachlorozincate ions.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, k3zn2, nh4pnma

fcf

Structure factor file (CIF format)
Contains datablock k3zn2

fcf

Structure factor file (CIF format)
Contains datablock nh4pnma

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