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A triclinic modification of triphenylphosphine, C18H15P, is reported. Two of the four unique molecules are in virtually the same conformation and are related by a local inversion centre; the other two molecules each have a different conformation. The structure contains a number of short C—H...π contacts.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, shelxl

fcf

Structure factor file (CIF format)
Contains datablock shelxl

CCDC reference: 130547

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