metal-organic compounds
In the title compound, [Ni(C14H9N3O6)(C6H7N)3], the coordination polyhedron around NiII is a slightly distorted octahedron, with one N atom from the tridentate ligand and three N atoms from three monodentate ligands forming the equatorial plane. The apical positions are occupied by the two O atoms of the tridentate ligand. The Ni-O distances are 2.013 (2) and 2.008 (2) Å and the Ni-N distances range from 2.043 (2) to 2.168 (3) Å. The cis bond angles at NiII range from 82.75 (9) to 96.2 (1)°. There are intramolecular as well as intermolecular hydrogen bonds in the structure.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129928