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The new heterobimetallic complex [{LaEu(oda)3(H2O)3·5H2O}n] (oda = O2CCH2OCH2CO2) has been synthesized and structurally characterized. Three tridentate oda ligands are coordinated to the smaller EuIII cation, whereas six adjacent outer carboxylate O atoms and three metal-bound water O atoms are bonded to the larger LaIII cation. The structure consists of a three-dimensional network with the metal centers bridged by oda carboxylate groups with Eu...La separations of 6.95 (1) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, LaEuODA

fcf

Structure factor file (CIF format)
Contains datablock tmp

CCDC reference: 129927

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