Dimethyl­bis(4-methyl­piperidine-1-dithiocarboxyl­ato-κ²S,S′)tin(IV)

The title compound, [Sn(CH₃)₂(C₇H₁₂NS₂)₂], comprises Sn^IV coordinated by two 4-methyl­piperidine­dithio­carboxyl­ate ligands and two methyl groups. The coordination geometry around Sn is distorted octa­hedral, with the methyl groups adopting an arrangement inter­mediate between a cis and trans configuration. There are two independent complexes in the asymmetric unit, with closely comparable geometries.

Key indicators

• Single-crystal X-ray study
• T = 295 K
• Mean [sigma](C-C) = 0.009 Å
• R factor = 0.058
• wR factor = 0.110
• Data-to-parameter ratio = 26.4

checkCIF/PLATON results

No syntax errors found



Alert level C
RINTA01_ALERT_3_C  The value of Rint is greater than 0.10
            Rint given   0.104
PLAT020_ALERT_3_C The value of Rint is greater than 0.10 .........       0.10
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.33 Ratio
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.05 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.20 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.14 Ratio
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         S2
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        Sn1
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C4
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C13
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        Sn2
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C19
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C29
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...          9

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  14 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   9 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Dimethylbis(4-methylpiperidine-1-dithiocarboxylato-κ²S,S')tin(IV)

Crystal data

[Sn(CH3)2(C7H12NS2)2]	Dx = 1.459 Mg m^−3
Mr = 497.41	Melting point = 415–416 K
Orthorhombic, Pbca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 76764 reflections
a = 19.432 (3) Å	θ = 1.1–28.3°
b = 12.512 (2) Å	µ = 1.50 mm^−1
c = 37.267 (6) Å	T = 295 K
V = 9061 (2) Å^3	Needle, colourless
Z = 16	0.33 × 0.09 × 0.07 mm
F(000) = 4064

Data collection

Bruker SMART APEX CCD area-detector diffractometer	11153 independent reflections
Radiation source: normal-focus sealed tube	5552 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.104
ω scans	θmax = 28.3°, θmin = 1.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −25→25
Tmin = 0.638, Tmax = 0.900	k = −16→16
76764 measured reflections	l = −49→48

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.058	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.110	H-atom parameters constrained
S = 1.00	w = 1/[σ^2(Fo^2) + (0.0381P)^2 + 1.2271P] where P = (Fo^2 + 2Fc^2)/3
11153 reflections	(Δ/σ)max = 0.001
423 parameters	Δρmax = 0.37 e Å^−3
0 restraints	Δρmin = −0.32 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Sn1	0.727329 (18)	0.03531 (3)	0.209371 (9)	0.05864 (12)
S1	0.58759 (8)	−0.02888 (11)	0.22835 (5)	0.0802 (5)
S2	0.64528 (8)	0.18793 (10)	0.22010 (4)	0.0764 (4)
S3	0.86322 (7)	−0.03895 (10)	0.18739 (4)	0.0689 (4)
S4	0.81385 (7)	0.18276 (10)	0.19729 (4)	0.0705 (4)
N1	0.5127 (2)	0.1467 (4)	0.22439 (12)	0.0709 (12)
N2	0.9345 (2)	0.1331 (3)	0.16839 (12)	0.0651 (12)
C1	0.5738 (3)	0.1050 (4)	0.22453 (13)	0.0605 (14)
C2	0.4989 (3)	0.2619 (4)	0.22096 (17)	0.0879 (19)
H2A	0.5420	0.3008	0.2197	0.105*
H2B	0.4737	0.2868	0.2418	0.105*
C3	0.4573 (3)	0.2829 (5)	0.18756 (19)	0.103 (2)
H3A	0.4855	0.2672	0.1667	0.124*
H3B	0.4455	0.3581	0.1867	0.124*
C4	0.3913 (4)	0.2173 (6)	0.1852 (2)	0.112 (2)
H4	0.3627	0.2375	0.2058	0.134*
C5	0.3517 (4)	0.2428 (8)	0.1525 (3)	0.194 (5)
H5A	0.3770	0.2199	0.1318	0.291*
H5B	0.3442	0.3185	0.1513	0.291*
H5C	0.3082	0.2066	0.1533	0.291*
C6	0.4103 (3)	0.1015 (6)	0.1900 (2)	0.104 (2)
H6A	0.3687	0.0588	0.1902	0.125*
H6B	0.4380	0.0786	0.1698	0.125*
C7	0.4492 (3)	0.0821 (5)	0.22377 (19)	0.098 (2)
H7A	0.4207	0.1005	0.2442	0.117*
H7B	0.4608	0.0069	0.2255	0.117*
C8	0.6953 (3)	−0.0155 (4)	0.15799 (13)	0.0781 (17)
H8A	0.7008	−0.0915	0.1561	0.117*
H8B	0.7228	0.0191	0.1400	0.117*
H8C	0.6478	0.0029	0.1545	0.117*
C9	0.7517 (3)	−0.0329 (5)	0.25969 (14)	0.0921 (19)
H9A	0.7232	−0.0015	0.2779	0.138*
H9B	0.7992	−0.0195	0.2652	0.138*
H9C	0.7438	−0.1086	0.2589	0.138*
C10	0.8774 (3)	0.0951 (4)	0.18230 (13)	0.0582 (13)
C11	0.9875 (3)	0.0647 (4)	0.15238 (15)	0.0759 (17)
H11A	0.9849	0.0701	0.1265	0.091*
H11B	0.9786	−0.0091	0.1589	0.091*
C12	1.0586 (3)	0.0951 (4)	0.16450 (15)	0.0766 (16)
H12A	1.0922	0.0505	0.1524	0.092*
H12B	1.0629	0.0826	0.1901	0.092*
C13	1.0736 (3)	0.2129 (5)	0.15637 (15)	0.0760 (17)
H13	1.0710	0.2227	0.1303	0.091*
C14	1.1456 (3)	0.2449 (6)	0.16844 (19)	0.126 (3)
H14A	1.1557	0.3158	0.1600	0.189*
H14B	1.1786	0.1957	0.1587	0.189*
H14C	1.1480	0.2435	0.1942	0.189*
Sn2	0.554720 (19)	0.84599 (3)	0.042907 (10)	0.06318 (12)
S5	0.49893 (7)	0.66309 (11)	0.04465 (4)	0.0750 (4)
S6	0.40204 (9)	0.83614 (13)	0.02547 (5)	0.0984 (6)
S7	0.65688 (7)	0.74664 (10)	0.06668 (4)	0.0723 (4)
S8	0.67770 (8)	0.97487 (10)	0.04916 (4)	0.0708 (4)
N3	0.3674 (2)	0.6313 (4)	0.02967 (12)	0.0802 (14)
N4	0.7722 (2)	0.8525 (3)	0.08012 (12)	0.0676 (12)
C15	1.0182 (3)	0.2805 (4)	0.17333 (15)	0.0772 (16)
H15A	1.0258	0.3547	0.1670	0.093*
H15B	1.0217	0.2747	0.1992	0.093*
C16	0.9464 (3)	0.2484 (4)	0.16183 (16)	0.0755 (16)
H16A	0.9129	0.2900	0.1751	0.091*
H16B	0.9405	0.2636	0.1365	0.091*
C17	0.2947 (3)	0.6604 (5)	0.02556 (19)	0.105 (2)
H17A	0.2761	0.6277	0.0040	0.125*
H17B	0.2903	0.7373	0.0233	0.125*
C18	0.2552 (3)	0.6217 (7)	0.0582 (2)	0.116 (3)
H18A	0.2706	0.6616	0.0790	0.139*
H18B	0.2068	0.6372	0.0547	0.139*
C19	0.2632 (4)	0.5042 (7)	0.06579 (19)	0.113 (3)
H19	0.2435	0.4654	0.0454	0.136*
C20	0.2244 (4)	0.4687 (8)	0.0990 (2)	0.174 (4)
H20A	0.2280	0.3926	0.1015	0.261*
H20B	0.1768	0.4884	0.0968	0.261*
H20C	0.2438	0.5027	0.1198	0.261*
C21	0.3394 (3)	0.4775 (5)	0.06712 (18)	0.103 (2)
H21A	0.3593	0.5095	0.0884	0.123*
H21B	0.3448	0.4006	0.0691	0.123*
C22	0.3781 (3)	0.5162 (5)	0.03468 (17)	0.093 (2)
H22A	0.4268	0.5018	0.0377	0.112*
H22B	0.3624	0.4780	0.0136	0.112*
C23	0.4162 (3)	0.7050 (4)	0.03284 (14)	0.0689 (15)
C24	0.5167 (3)	0.9382 (4)	0.08611 (14)	0.0773 (16)
H24A	0.5022	1.0068	0.0774	0.116*
H24B	0.5524	0.9476	0.1037	0.116*
H24C	0.4783	0.9021	0.0969	0.116*
C25	0.5657 (3)	0.8733 (5)	−0.01257 (14)	0.099 (2)
H25A	0.5216	0.8673	−0.0240	0.149*
H25B	0.5966	0.8214	−0.0225	0.149*
H25C	0.5838	0.9437	−0.0164	0.149*
C26	0.7099 (3)	0.8601 (3)	0.06691 (13)	0.0569 (13)
C27	0.7992 (3)	0.7557 (4)	0.09834 (18)	0.0873 (19)
H27A	0.7976	0.7662	0.1241	0.105*
H27B	0.7702	0.6950	0.0925	0.105*
C28	0.8701 (3)	0.7326 (4)	0.08748 (18)	0.0883 (19)
H28A	0.8702	0.7109	0.0625	0.106*
H28B	0.8871	0.6730	0.1016	0.106*
C29	0.9184 (3)	0.8260 (4)	0.09202 (15)	0.0691 (15)
H29	0.9193	0.8443	0.1176	0.083*
C30	0.9912 (3)	0.8030 (5)	0.08055 (18)	0.110 (2)
H30A	1.0056	0.7356	0.0904	0.166*
H30B	1.0210	0.8586	0.0891	0.166*
H30C	0.9935	0.8000	0.0548	0.166*
C31	0.8885 (3)	0.9203 (4)	0.07213 (15)	0.0794 (17)
H31A	0.9175	0.9822	0.0762	0.095*
H31B	0.8891	0.9051	0.0466	0.095*
C32	0.8174 (3)	0.9469 (4)	0.08287 (17)	0.0798 (17)
H32A	0.8172	0.9729	0.1074	0.096*
H32B	0.7998	1.0033	0.0675	0.096*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Sn1	0.0660 (2)	0.0455 (2)	0.0643 (2)	−0.00482 (18)	−0.00411 (19)	0.00438 (18)
S1	0.0795 (11)	0.0485 (8)	0.1127 (12)	−0.0081 (8)	0.0157 (9)	0.0131 (8)
S2	0.0713 (10)	0.0446 (7)	0.1133 (12)	−0.0066 (7)	0.0026 (9)	−0.0061 (8)
S3	0.0710 (9)	0.0444 (7)	0.0914 (11)	−0.0031 (7)	−0.0032 (8)	0.0026 (7)
S4	0.0635 (9)	0.0431 (7)	0.1047 (11)	−0.0026 (7)	0.0026 (8)	0.0032 (7)
N1	0.064 (3)	0.064 (3)	0.084 (3)	0.000 (3)	0.018 (3)	0.003 (2)
N2	0.061 (3)	0.046 (3)	0.088 (3)	−0.004 (2)	0.001 (3)	0.002 (2)
C1	0.066 (4)	0.054 (3)	0.061 (3)	−0.003 (3)	0.016 (3)	−0.002 (3)
C2	0.092 (5)	0.063 (4)	0.108 (5)	0.024 (3)	0.014 (4)	−0.012 (3)
C3	0.094 (5)	0.079 (4)	0.137 (6)	0.001 (4)	−0.009 (5)	0.034 (4)
C4	0.079 (5)	0.122 (6)	0.135 (7)	−0.020 (5)	−0.001 (5)	0.030 (5)
C5	0.129 (8)	0.228 (11)	0.224 (11)	−0.037 (8)	−0.070 (8)	0.093 (9)
C6	0.073 (5)	0.112 (6)	0.127 (6)	−0.030 (4)	0.011 (4)	0.015 (5)
C7	0.072 (4)	0.094 (5)	0.127 (6)	0.004 (4)	0.036 (4)	0.026 (4)
C8	0.077 (4)	0.088 (4)	0.069 (4)	−0.008 (3)	−0.007 (3)	−0.004 (3)
C9	0.099 (5)	0.109 (5)	0.068 (4)	−0.013 (4)	−0.014 (3)	0.019 (4)
C10	0.068 (4)	0.045 (3)	0.062 (3)	−0.001 (3)	−0.013 (3)	0.002 (2)
C11	0.078 (4)	0.059 (3)	0.091 (4)	−0.003 (3)	0.018 (3)	−0.006 (3)
C12	0.068 (4)	0.081 (4)	0.080 (4)	0.003 (3)	0.019 (3)	0.001 (3)
C13	0.065 (4)	0.095 (5)	0.068 (4)	−0.016 (3)	0.006 (3)	0.001 (3)
C14	0.080 (5)	0.158 (7)	0.140 (7)	−0.026 (5)	0.021 (5)	−0.005 (5)
Sn2	0.0691 (3)	0.0528 (2)	0.0677 (2)	0.00510 (19)	−0.0073 (2)	0.00538 (18)
S5	0.0627 (9)	0.0607 (8)	0.1016 (11)	−0.0012 (7)	−0.0115 (8)	0.0107 (8)
S6	0.0851 (12)	0.0766 (11)	0.1335 (15)	0.0090 (9)	−0.0349 (11)	0.0113 (10)
S7	0.0597 (9)	0.0426 (7)	0.1146 (13)	−0.0029 (6)	−0.0111 (9)	0.0103 (7)
S8	0.0749 (10)	0.0440 (7)	0.0935 (11)	0.0030 (7)	−0.0071 (8)	0.0094 (7)
N3	0.066 (3)	0.081 (4)	0.093 (4)	−0.013 (3)	−0.017 (3)	0.005 (3)
N4	0.058 (3)	0.043 (2)	0.102 (4)	−0.003 (2)	−0.010 (3)	0.005 (2)
C15	0.079 (4)	0.067 (4)	0.085 (4)	−0.016 (3)	0.012 (3)	−0.004 (3)
C16	0.070 (4)	0.054 (3)	0.103 (5)	−0.008 (3)	0.007 (4)	0.009 (3)
C17	0.072 (5)	0.117 (6)	0.125 (6)	−0.010 (4)	−0.037 (4)	0.011 (5)
C18	0.063 (5)	0.169 (9)	0.117 (6)	−0.012 (5)	−0.009 (4)	−0.003 (6)
C19	0.108 (7)	0.139 (7)	0.093 (6)	−0.053 (5)	−0.005 (5)	0.002 (5)
C20	0.148 (8)	0.244 (11)	0.131 (7)	−0.036 (8)	0.040 (6)	0.039 (7)
C21	0.095 (6)	0.109 (5)	0.104 (5)	−0.032 (4)	−0.020 (4)	0.017 (4)
C22	0.087 (5)	0.085 (5)	0.107 (5)	−0.017 (4)	−0.013 (4)	−0.006 (4)
C23	0.066 (4)	0.076 (4)	0.065 (4)	−0.005 (3)	−0.010 (3)	0.003 (3)
C24	0.085 (4)	0.070 (4)	0.077 (4)	0.014 (3)	0.002 (3)	0.000 (3)
C25	0.123 (6)	0.106 (5)	0.069 (4)	−0.025 (4)	−0.006 (4)	0.004 (4)
C26	0.060 (3)	0.041 (3)	0.070 (4)	−0.003 (2)	0.003 (3)	−0.003 (2)
C27	0.066 (4)	0.053 (3)	0.142 (6)	0.000 (3)	−0.018 (4)	0.022 (4)
C28	0.078 (4)	0.056 (4)	0.131 (6)	0.006 (3)	−0.026 (4)	−0.007 (3)
C29	0.064 (4)	0.065 (4)	0.079 (4)	−0.006 (3)	−0.005 (3)	−0.014 (3)
C30	0.081 (5)	0.114 (6)	0.137 (6)	0.008 (4)	−0.002 (4)	−0.035 (5)
C31	0.074 (4)	0.079 (4)	0.085 (4)	−0.019 (3)	−0.007 (3)	−0.001 (3)
C32	0.072 (4)	0.048 (3)	0.119 (5)	−0.003 (3)	−0.004 (4)	−0.004 (3)

Geometric parameters (Å, º)

Sn1—C8	2.111 (5)	Sn2—S6	3.0397 (17)
Sn1—C9	2.114 (5)	S5—C23	1.747 (6)
Sn1—S2	2.5196 (15)	S6—C23	1.687 (6)
Sn1—S4	2.5364 (14)	S7—C26	1.754 (5)
Sn1—S3	2.9167 (15)	S8—C26	1.700 (5)
Sn1—S1	2.9187 (16)	N3—C23	1.328 (6)
S1—C1	1.702 (5)	N3—C17	1.467 (7)
S2—C1	1.742 (5)	N3—C22	1.467 (7)
S3—C10	1.710 (5)	N4—C26	1.311 (6)
S4—C10	1.743 (5)	N4—C32	1.475 (6)
N1—C1	1.296 (6)	N4—C27	1.484 (6)
N1—C2	1.472 (6)	C15—C16	1.514 (7)
N1—C7	1.476 (7)	C15—H15A	0.970
N2—C10	1.314 (6)	C15—H15B	0.970
N2—C11	1.465 (6)	C16—H16A	0.970
N2—C16	1.481 (6)	C16—H16B	0.970
C2—C3	1.507 (8)	C17—C18	1.516 (8)
C2—H2A	0.970	C17—H17A	0.970
C2—H2B	0.970	C17—H17B	0.970
C3—C4	1.524 (8)	C18—C19	1.505 (9)
C3—H3A	0.970	C18—H18A	0.970
C3—H3B	0.970	C18—H18B	0.970
C4—C5	1.476 (9)	C19—C20	1.516 (9)
C4—C6	1.506 (9)	C19—C21	1.519 (9)
C4—H4	0.980	C19—H19	0.980
C5—H5A	0.960	C20—H20A	0.960
C5—H5B	0.960	C20—H20B	0.960
C5—H5C	0.960	C20—H20C	0.960
C6—C7	1.487 (8)	C21—C22	1.504 (8)
C6—H6A	0.970	C21—H21A	0.970
C6—H6B	0.970	C21—H21B	0.970
C7—H7A	0.970	C22—H22A	0.970
C7—H7B	0.970	C22—H22B	0.970
C8—H8A	0.960	C24—H24A	0.960
C8—H8B	0.960	C24—H24B	0.960
C8—H8C	0.960	C24—H24C	0.960
C9—H9A	0.960	C25—H25A	0.960
C9—H9B	0.960	C25—H25B	0.960
C9—H9C	0.960	C25—H25C	0.960
C11—C12	1.504 (7)	C27—C28	1.465 (7)
C11—H11A	0.970	C27—H27A	0.970
C11—H11B	0.970	C27—H27B	0.970
C12—C13	1.533 (7)	C28—C29	1.508 (7)
C12—H12A	0.970	C28—H28A	0.970
C12—H12B	0.970	C28—H28B	0.970
C13—C15	1.508 (7)	C29—C30	1.507 (7)
C13—C14	1.523 (7)	C29—C31	1.510 (7)
C13—H13	0.980	C29—H29	0.980
C14—H14A	0.960	C30—H30A	0.960
C14—H14B	0.960	C30—H30B	0.960
C14—H14C	0.960	C30—H30C	0.960
Sn2—C25	2.106 (5)	C31—C32	1.476 (7)
Sn2—C24	2.114 (5)	C31—H31A	0.970
Sn2—S7	2.5043 (14)	C31—H31B	0.970
Sn2—S5	2.5330 (15)	C32—H32A	0.970
Sn2—S8	2.8923 (15)	C32—H32B	0.970
C8—Sn1—C9	138.5 (2)	S7—Sn2—S6	146.02 (4)
C8—Sn1—S2	100.70 (16)	S5—Sn2—S6	63.33 (4)
C9—Sn1—S2	107.86 (17)	S8—Sn2—S6	147.81 (4)
C8—Sn1—S4	104.66 (15)	C23—S5—Sn2	96.68 (19)
C9—Sn1—S4	107.62 (16)	C23—S6—Sn2	81.1 (2)
S2—Sn1—S4	84.05 (5)	C26—S7—Sn2	93.75 (17)
C8—Sn1—S3	85.19 (15)	C26—S8—Sn2	82.21 (17)
C9—Sn1—S3	85.29 (17)	C23—N3—C17	121.7 (5)
S2—Sn1—S3	149.19 (4)	C23—N3—C22	124.7 (5)
S4—Sn1—S3	65.27 (4)	C17—N3—C22	113.2 (5)
C8—Sn1—S1	82.13 (15)	C26—N4—C32	121.2 (4)
C9—Sn1—S1	83.24 (16)	C26—N4—C27	123.9 (4)
S2—Sn1—S1	65.25 (4)	C32—N4—C27	114.3 (4)
S4—Sn1—S1	149.30 (4)	C13—C15—C16	113.0 (5)
S3—Sn1—S1	145.36 (4)	C13—C15—H15A	109.0
C1—S1—Sn1	81.71 (18)	C16—C15—H15A	109.0
C1—S2—Sn1	93.91 (18)	C13—C15—H15B	109.0
C10—S3—Sn1	82.20 (19)	C16—C15—H15B	109.0
C10—S4—Sn1	93.94 (17)	H15A—C15—H15B	107.8
C1—N1—C2	124.2 (5)	N2—C16—C15	110.9 (4)
C1—N1—C7	123.0 (5)	N2—C16—H16A	109.5
C2—N1—C7	112.5 (5)	C15—C16—H16A	109.5
C10—N2—C11	122.9 (4)	N2—C16—H16B	109.5
C10—N2—C16	123.3 (4)	C15—C16—H16B	109.5
C11—N2—C16	113.0 (4)	H16A—C16—H16B	108.1
N1—C1—S1	122.8 (4)	N3—C17—C18	109.0 (5)
N1—C1—S2	119.3 (4)	N3—C17—H17A	109.9
S1—C1—S2	117.9 (3)	C18—C17—H17A	109.9
N1—C2—C3	109.9 (5)	N3—C17—H17B	109.9
N1—C2—H2A	109.7	C18—C17—H17B	109.9
C3—C2—H2A	109.7	H17A—C17—H17B	108.3
N1—C2—H2B	109.7	C19—C18—C17	114.3 (7)
C3—C2—H2B	109.7	C19—C18—H18A	108.7
H2A—C2—H2B	108.2	C17—C18—H18A	108.7
C2—C3—C4	113.9 (6)	C19—C18—H18B	108.7
C2—C3—H3A	108.8	C17—C18—H18B	108.7
C4—C3—H3A	108.8	H18A—C18—H18B	107.6
C2—C3—H3B	108.8	C18—C19—C20	112.9 (8)
C4—C3—H3B	108.8	C18—C19—C21	108.7 (6)
H3A—C3—H3B	107.7	C20—C19—C21	113.2 (7)
C5—C4—C6	115.7 (7)	C18—C19—H19	107.2
C5—C4—C3	111.7 (6)	C20—C19—H19	107.2
C6—C4—C3	107.8 (6)	C21—C19—H19	107.2
C5—C4—H4	107.1	C19—C20—H20A	109.5
C6—C4—H4	107.1	C19—C20—H20B	109.5
C3—C4—H4	107.1	H20A—C20—H20B	109.5
C4—C5—H5A	109.5	C19—C20—H20C	109.5
C4—C5—H5B	109.5	H20A—C20—H20C	109.5
H5A—C5—H5B	109.5	H20B—C20—H20C	109.5
C4—C5—H5C	109.5	C22—C21—C19	113.0 (6)
H5A—C5—H5C	109.5	C22—C21—H21A	109.0
H5B—C5—H5C	109.5	C19—C21—H21A	109.0
C7—C6—C4	112.5 (6)	C22—C21—H21B	109.0
C7—C6—H6A	109.1	C19—C21—H21B	109.0
C4—C6—H6A	109.1	H21A—C21—H21B	107.8
C7—C6—H6B	109.1	N3—C22—C21	110.3 (5)
C4—C6—H6B	109.1	N3—C22—H22A	109.6
H6A—C6—H6B	107.8	C21—C22—H22A	109.6
N1—C7—C6	110.4 (5)	N3—C22—H22B	109.6
N1—C7—H7A	109.6	C21—C22—H22B	109.6
C6—C7—H7A	109.6	H22A—C22—H22B	108.1
N1—C7—H7B	109.6	N3—C23—S6	123.0 (4)
C6—C7—H7B	109.6	N3—C23—S5	118.1 (4)
H7A—C7—H7B	108.1	S6—C23—S5	118.9 (3)
Sn1—C8—H8A	109.5	Sn2—C24—H24A	109.5
Sn1—C8—H8B	109.5	Sn2—C24—H24B	109.5
H8A—C8—H8B	109.5	H24A—C24—H24B	109.5
Sn1—C8—H8C	109.5	Sn2—C24—H24C	109.5
H8A—C8—H8C	109.5	H24A—C24—H24C	109.5
H8B—C8—H8C	109.5	H24B—C24—H24C	109.5
Sn1—C9—H9A	109.5	Sn2—C25—H25A	109.5
Sn1—C9—H9B	109.5	Sn2—C25—H25B	109.5
H9A—C9—H9B	109.5	H25A—C25—H25B	109.5
Sn1—C9—H9C	109.5	Sn2—C25—H25C	109.5
H9A—C9—H9C	109.5	H25A—C25—H25C	109.5
H9B—C9—H9C	109.5	H25B—C25—H25C	109.5
N2—C10—S3	122.3 (4)	N4—C26—S8	123.2 (4)
N2—C10—S4	119.8 (4)	N4—C26—S7	119.1 (3)
S3—C10—S4	117.9 (3)	S8—C26—S7	117.8 (3)
N2—C11—C12	112.1 (4)	C28—C27—N4	111.5 (5)
N2—C11—H11A	109.2	C28—C27—H27A	109.3
C12—C11—H11A	109.2	N4—C27—H27A	109.3
N2—C11—H11B	109.2	C28—C27—H27B	109.3
C12—C11—H11B	109.2	N4—C27—H27B	109.3
H11A—C11—H11B	107.9	H27A—C27—H27B	108.0
C11—C12—C13	111.0 (5)	C27—C28—C29	113.7 (5)
C11—C12—H12A	109.4	C27—C28—H28A	108.8
C13—C12—H12A	109.4	C29—C28—H28A	108.8
C11—C12—H12B	109.4	C27—C28—H28B	108.8
C13—C12—H12B	109.4	C29—C28—H28B	108.8
H12A—C12—H12B	108.0	H28A—C28—H28B	107.7
C15—C13—C14	112.6 (5)	C30—C29—C28	113.9 (5)
C15—C13—C12	108.7 (4)	C30—C29—C31	111.8 (5)
C14—C13—C12	111.7 (5)	C28—C29—C31	108.2 (4)
C15—C13—H13	107.9	C30—C29—H29	107.6
C14—C13—H13	107.9	C28—C29—H29	107.6
C12—C13—H13	107.9	C31—C29—H29	107.6
C13—C14—H14A	109.5	C29—C30—H30A	109.5
C13—C14—H14B	109.5	C29—C30—H30B	109.5
H14A—C14—H14B	109.5	H30A—C30—H30B	109.5
C13—C14—H14C	109.5	C29—C30—H30C	109.5
H14A—C14—H14C	109.5	H30A—C30—H30C	109.5
H14B—C14—H14C	109.5	H30B—C30—H30C	109.5
C25—Sn2—C24	134.0 (2)	C32—C31—C29	113.8 (5)
C25—Sn2—S7	110.36 (18)	C32—C31—H31A	108.8
C24—Sn2—S7	106.16 (15)	C29—C31—H31A	108.8
C25—Sn2—S5	102.41 (17)	C32—C31—H31B	108.8
C24—Sn2—S5	108.91 (15)	C29—C31—H31B	108.8
S7—Sn2—S5	83.21 (4)	H31A—C31—H31B	107.7
C25—Sn2—S8	84.56 (16)	N4—C32—C31	110.9 (4)
C24—Sn2—S8	85.57 (15)	N4—C32—H32A	109.5
S7—Sn2—S8	66.00 (4)	C31—C32—H32A	109.4
S5—Sn2—S8	148.79 (4)	N4—C32—H32B	109.4
C25—Sn2—S6	83.99 (17)	C31—C32—H32B	109.5
C24—Sn2—S6	81.03 (15)	H32A—C32—H32B	108.0