Bis[tris­(1,10-phenanthroline-κ2N,N′)manganese(II)] dodeca­tungstogermanate dihydrate

Zhou, D.-P.; Guo, G.-L.

doi:10.1107/S1600536807012196

Bis[tris(1,10-phenanthroline-κ²N,N′)manganese(II)] dodecatungstogermanate dihydrate

The title compound, [Mn(C₁₂H₈N₂)₃]₂[GeW₁₂O₄₀]·2H₂O, which was prepared under hydrothermal conditions, consists of one Keggin [GeW₁₂O₄₀]⁴⁻ anion disordered over an inversion centre, two isolated [Mn(phen)₃]²⁺ cations (phen is 1,10-phenanthroline) and two solvent water molecules. In each [Mn(phen)₃]²⁺ cation, the Mn^II ion is coordinated by six N atoms from three phen ligands, completing a distorted octahedral geometry.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807012196/bh2076sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536807012196/bh2076Isup2.hkl Contains datablock I

CCDC reference: 642910

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.028 Å
H-atom completeness 93%
Disorder in main residue
R factor = 0.069
wR factor = 0.163
Data-to-parameter ratio = 11.7

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    O     Ueq(max)/Ueq(min) ...       3.97 Ratio
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        O17
PLAT342_ALERT_3_B Low Bond Precision on C-C bonds (x 1000) Ang ...         28
PLAT430_ALERT_2_B Short Inter D...A Contact  O1     ..  O1W     ..       2.72 Ang.
PLAT430_ALERT_2_B Short Inter D...A Contact  O1W    ..  O3      ..       2.78 Ang.
PLAT430_ALERT_2_B Short Inter D...A Contact  O2     ..  O2W     ..       2.74 Ang.
PLAT432_ALERT_2_B Short Inter X...Y Contact  O5     ..  C14     ..       2.82 Ang.

Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)...          ?
PLAT180_ALERT_3_C Check Cell Rounding: # of Values Ending with 0 =          3
PLAT213_ALERT_2_C Atom C16     has ADP max/min Ratio .............       3.40 oblat
PLAT213_ALERT_2_C Atom O13     has ADP max/min Ratio .............       3.10 prola
PLAT213_ALERT_2_C Atom O17     has ADP max/min Ratio .............       3.10 prola
PLAT216_ALERT_3_C Disordered O2W     (An/Solv) ADP max/min Ratio         5.80
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.76 Ratio
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C15
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C18
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C31
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         O8
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         O9
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        Mn1
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C32
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         W4
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         W5
PLAT301_ALERT_3_C Main Residue  Disorder .........................       4.00 Perc.
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      50.00 Perc.
PLAT432_ALERT_2_C Short Inter X...Y Contact  O5     ..  C13     ..       2.95 Ang.
PLAT432_ALERT_2_C Short Inter X...Y Contact  O13    ..  C35     ..       3.01 Ang.
PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of .      45.00 A   3 
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.399(10) ......       3.00 su-Ra
              C1   -C2      1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.39(3), Rep   1.393(10) ......       3.00 su-Ra
              C2   -C3      1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.41(3), Rep   1.406(10) ......       3.00 su-Ra
              C4   -C6      1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.400(10) ......       3.00 su-Ra
              C6   -C7      1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.395(10) ......       3.00 su-Ra
              C10  -C11     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.39(3), Rep   1.393(10) ......       3.00 su-Ra
              C11  -C12     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.404(10) ......       3.00 su-Ra
              C13  -C14     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.398(10) ......       3.00 su-Ra
              C14  -C15     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.400(10) ......       3.00 su-Ra
              C15  -C16     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.398(10) ......       3.00 su-Ra
              C16  -C18     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.402(10) ......       3.00 su-Ra
              C16  -C17     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.39(3), Rep   1.394(10) ......       3.00 su-Ra
              C18  -C19     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.399(10) ......       3.00 su-Ra
              C19  -C20     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.397(10) ......       3.00 su-Ra
              C20  -C22     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.39(3), Rep   1.394(10) ......       3.00 su-Ra
              C22  -C23     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.396(10) ......       3.00 su-Ra
              C23  -C24     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.400(10) ......       3.00 su-Ra
              C25  -C26     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.39(3), Rep   1.393(10) ......       3.00 su-Ra
              C26  -C27     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.400(10) ......       3.00 su-Ra
              C27  -C28     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.401(10) ......       3.00 su-Ra
              C28  -C29     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.41(3), Rep   1.406(10) ......       3.00 su-Ra
              C28  -C30     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.395(10) ......       3.00 su-Ra
              C30  -C31     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.402(10) ......       3.00 su-Ra
              C31  -C32     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.398(10) ......       3.00 su-Ra
              C32  -C33     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.398(10) ......       3.00 su-Ra
              C34  -C35     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.40(3), Rep   1.399(10) ......       3.00 su-Ra
              C35  -C36     1.555   1.555
PLAT764_ALERT_4_C Overcomplete CIF Bond List Detected (Rep/Expd) .       1.12 Ratio
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          1
              C36 H24 Mn N6
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          3
              O
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          4
              O

Alert level G
FORMU01_ALERT_2_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and the formula from the _atom_site* data.
            Atom count from _chemical_formula_sum:C72 H52 Ge1 Mn2 N12 O42 W12
            Atom count from the _atom_site data:  C72 H48 Ge1 Mn2 N12 O42 W12
CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected.
CELLZ01_ALERT_1_G WARNING: H atoms missing from atom site list. Is this intentional?
           From the CIF: _cell_formula_units_Z    1
           From the CIF: _chemical_formula_sum  C72 H52 Ge Mn2 N12 O42 W12
           TEST: Compare cell contents of formula and atom_site data

           atom    Z*formula  cif sites diff
           C         72.00     72.00    0.00
           H         52.00     48.00    4.00
           Ge         1.00      1.00    0.00
           Mn         2.00      2.00    0.00
           N         12.00     12.00    0.00
           O         42.00     42.00    0.00
           W         12.00     12.00    0.00
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K

   0 ALERT level A = In general: serious problem
   7 ALERT level B = Potentially serious problem
  53 ALERT level C = Check and explain
   6 ALERT level G = General alerts; check

  34 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  23 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 2002); cell refinement: SMART; data reduction: SAINT (Bruker, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 2002); software used to prepare material for publication: SHELXTL.

Bis[tris(1,10-phenanthroline-κ²N,N')manganese(II)] dodecatungstogermanate dihydrate top

Crystal data top

[Mn(C₁₂H₈N₂)₃]₂[GeW₁₂O₄₀]·2H₂O	Z = 1
M_r = 4145.93	F(000) = 1874
Triclinic, P1	D_x = 3.061 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 12.4210 (15) Å	Cell parameters from 320 reflections
b = 13.8640 (16) Å	θ = 2.5–25°
c = 14.4979 (17) Å	µ = 15.97 mm⁻¹
α = 104.642 (2)°	T = 293 K
β = 109.256 (1)°	Block, brown
γ = 93.877 (2)°	0.18 × 0.16 × 0.15 mm
V = 2249.0 (5) Å³

Data collection top

Bruker APEXII CCD area-detector diffractometer	7765 independent reflections
Radiation source: fine-focus sealed tube	5537 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.032
ω scans	θ_max = 25.0°, θ_min = 2.1°
Absorption correction: multi-scan (SADABS; Bruker, 2002)	h = −14→14
T_min = 0.074, T_max = 0.091	k = −9→16
11641 measured reflections	l = −17→15

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.069	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.163	H-atom parameters constrained
S = 1.03	w = 1/[σ²(F_o²) + (0.0545P)² + 86.3193P] where P = (F_o² + 2F_c²)/3
7765 reflections	(Δ/σ)_max = 0.001
665 parameters	Δρ_max = 3.17 e Å⁻³
213 restraints	Δρ_min = −2.26 e Å⁻³

Special details top

Experimental. Spectroscopic analysis, IR (KBr disk, cm^-1): 1634, 1521, 1424, 1342, 1224, 1147, 1106, 958, 881, 845, 814, 773.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Mn1	−0.28874 (19)	0.64849 (18)	0.30838 (18)	0.0167 (5)
Ge1	0.0000	0.0000	0.0000	0.0226 (5)
W1	−0.22922 (8)	0.09678 (7)	0.06487 (7)	0.0450 (3)
W2	−0.19250 (9)	0.11786 (7)	−0.15972 (7)	0.0521 (3)
W3	−0.28856 (8)	−0.12065 (7)	−0.14183 (7)	0.0504 (3)
W4	0.09786 (7)	0.23549 (6)	−0.02109 (8)	0.0451 (3)
W5	0.06115 (7)	0.21903 (6)	0.20648 (6)	0.0389 (2)
W6	−0.03464 (8)	−0.01671 (8)	0.22932 (7)	0.0478 (3)
O1	−0.3346 (12)	0.1437 (12)	0.0981 (14)	0.061 (5)
O2	−0.2810 (12)	0.1729 (10)	−0.2358 (10)	0.041 (3)
O3	−0.4217 (11)	−0.1776 (12)	−0.2082 (11)	0.054 (4)
O4	0.1451 (14)	0.3482 (11)	−0.0263 (13)	0.058 (4)
O5	0.0913 (17)	0.3221 (12)	0.3065 (13)	0.086 (6)
O6	−0.0541 (15)	−0.0226 (14)	0.3347 (13)	0.068 (5)
O7	−0.2904 (15)	−0.0134 (13)	−0.2045 (13)	0.065 (3)
O8	−0.2438 (15)	0.1519 (13)	−0.0447 (13)	0.066 (3)
O9	−0.3177 (15)	−0.0273 (14)	−0.0305 (13)	0.069 (3)
O10	−0.0622 (14)	0.2224 (13)	−0.0873 (12)	0.062 (3)
O11	0.1106 (14)	−0.0598 (14)	0.2462 (14)	0.081 (5)
O12	0.2122 (14)	0.1858 (18)	0.2271 (14)	0.088 (7)
O13	0.2386 (14)	0.2019 (17)	0.0548 (14)	0.079 (6)
O14	0.1080 (14)	0.1518 (14)	−0.1389 (15)	0.087 (5)
O15	0.0413 (13)	0.1190 (12)	0.2721 (12)	0.058 (3)
O16	−0.1750 (13)	0.0260 (12)	0.1641 (12)	0.058 (3)
O17	0.0683 (13)	0.2733 (16)	0.1027 (14)	0.073 (6)
O18	−0.1011 (13)	0.2046 (12)	0.1502 (12)	0.054 (3)
O19	−0.150 (2)	0.018 (2)	−0.046 (2)	0.043 (3)	0.50
O20	0.083 (2)	0.1120 (18)	0.0667 (19)	0.031 (4)	0.50
O21	0.004 (2)	−0.079 (2)	0.0834 (18)	0.036 (4)	0.50
O22	0.0336 (19)	−0.0619 (16)	−0.0979 (16)	0.0224 (9)	0.50
N1	−0.1146 (13)	0.7046 (12)	0.3468 (11)	0.034 (4)
N2	−0.2450 (15)	0.5364 (13)	0.2041 (13)	0.041 (4)
N3	−0.2585 (14)	0.5614 (11)	0.4115 (12)	0.036 (4)
N4	−0.4595 (14)	0.5743 (11)	0.2680 (12)	0.034 (4)
N5	−0.3118 (12)	0.7776 (11)	0.4079 (11)	0.029 (3)
N6	−0.3439 (14)	0.7326 (14)	0.2057 (13)	0.040 (4)
C1	−0.0528 (13)	0.7874 (16)	0.4194 (16)	0.041 (5)
H1A	−0.0869	0.8248	0.4617	0.049*
C2	0.0624 (13)	0.8203 (14)	0.4343 (15)	0.051 (6)
H2A	0.1041	0.8785	0.4860	0.061*
C3	0.1138 (14)	0.7648 (12)	0.3709 (13)	0.043 (5)
H3A	0.1903	0.7852	0.3798	0.051*
C4	0.0481 (12)	0.6779 (11)	0.2937 (12)	0.034 (5)
C5	−0.0664 (12)	0.6513 (15)	0.2850 (14)	0.031 (4)
C6	0.0926 (16)	0.6138 (13)	0.2284 (14)	0.046 (6)
H6A	0.1680	0.6323	0.2331	0.056*
C7	0.0276 (12)	0.5232 (14)	0.1566 (15)	0.044 (5)
H7A	0.0603	0.4816	0.1159	0.053*
C8	−0.0873 (13)	0.4956 (11)	0.1466 (12)	0.036 (5)
C9	−0.1336 (15)	0.5606 (13)	0.2093 (13)	0.029 (4)
C10	−0.1581 (13)	0.4064 (12)	0.0753 (14)	0.039 (5)
H10A	−0.1304	0.3629	0.0314	0.047*
C11	−0.2709 (14)	0.3850 (13)	0.0720 (14)	0.040 (5)
H11A	−0.3191	0.3254	0.0277	0.048*
C12	−0.3100 (17)	0.4545 (14)	0.1363 (15)	0.045 (5)
H12A	−0.3868	0.4417	0.1304	0.055*
C13	−0.1608 (19)	0.5534 (13)	0.4793 (14)	0.042 (5)
H13A	−0.0929	0.5921	0.4863	0.050*
C14	−0.1544 (15)	0.4894 (14)	0.5414 (15)	0.048 (6)
H14A	−0.0848	0.4864	0.5902	0.058*
C15	−0.2581 (14)	0.4305 (15)	0.5261 (16)	0.064 (8)
H15A	−0.2563	0.3850	0.5639	0.077*
C16	−0.3645 (13)	0.4371 (13)	0.4564 (14)	0.036 (5)
C17	−0.3580 (16)	0.5020 (12)	0.3976 (13)	0.031 (4)
C18	−0.4684 (14)	0.3791 (15)	0.4421 (15)	0.057 (7)
H18A	−0.4695	0.3373	0.4829	0.068*
C19	−0.5703 (16)	0.3843 (14)	0.3666 (14)	0.045 (5)
H19A	−0.6393	0.3441	0.3552	0.053*
C20	−0.5681 (12)	0.4503 (13)	0.3083 (13)	0.041 (5)
C21	−0.4635 (12)	0.5076 (13)	0.3228 (14)	0.029 (4)
C22	−0.6660 (14)	0.4579 (15)	0.2297 (14)	0.048 (6)
H22A	−0.7364	0.4187	0.2158	0.057*
C23	−0.6604 (14)	0.5231 (15)	0.1717 (15)	0.049 (6)
H23A	−0.7249	0.5297	0.1198	0.059*
C24	−0.5508 (13)	0.5776 (16)	0.1971 (15)	0.041 (5)
H24A	−0.5442	0.6204	0.1585	0.050*
C25	−0.2938 (18)	0.7953 (14)	0.5059 (15)	0.045 (5)
H25A	−0.2714	0.7453	0.5372	0.054*
C26	−0.308 (2)	0.8876 (13)	0.5639 (14)	0.058 (7)
H26A	−0.2950	0.8982	0.6329	0.070*
C27	−0.341 (2)	0.9639 (17)	0.5190 (14)	0.064 (7)
H27A	−0.3490	1.0258	0.5575	0.077*
C28	−0.3615 (19)	0.9452 (14)	0.4147 (14)	0.057 (7)
C29	−0.3470 (15)	0.8501 (13)	0.3623 (13)	0.039 (5)
C30	−0.398 (2)	1.0145 (17)	0.3595 (18)	0.076 (9)
H30A	−0.4081	1.0779	0.3930	0.091*
C31	−0.419 (2)	0.9893 (16)	0.2549 (18)	0.077 (9)
H31A	−0.4437	1.0361	0.2199	0.092*
C32	−0.4031 (17)	0.8951 (13)	0.2014 (12)	0.041 (5)
C33	−0.3663 (14)	0.8257 (15)	0.2555 (15)	0.037 (5)
C34	−0.428 (2)	0.8709 (18)	0.0966 (13)	0.064 (8)
H34A	−0.4562	0.9155	0.0597	0.077*
C35	−0.4077 (17)	0.7763 (17)	0.0496 (16)	0.060 (7)
H35A	−0.4215	0.7560	−0.0200	0.071*
C36	−0.3662 (18)	0.7126 (18)	0.1098 (15)	0.052 (6)
H36A	−0.3538	0.6499	0.0768	0.062*
O1W	−0.367 (3)	0.291 (3)	0.246 (3)	0.094 (16)	0.50
O2W	−0.404 (4)	0.236 (4)	−0.398 (4)	0.112 (18)	0.50

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Mn1	0.0136 (12)	0.0169 (12)	0.0191 (12)	0.0043 (10)	0.0046 (10)	0.0057 (10)
Ge1	0.0245 (13)	0.0190 (13)	0.0215 (13)	0.0073 (11)	0.0025 (10)	0.0080 (11)
W1	0.0601 (6)	0.0382 (5)	0.0475 (5)	0.0199 (4)	0.0290 (5)	0.0149 (4)
W2	0.0708 (7)	0.0327 (5)	0.0349 (5)	0.0253 (5)	−0.0058 (4)	0.0083 (4)
W3	0.0481 (6)	0.0405 (5)	0.0453 (5)	−0.0135 (4)	−0.0040 (4)	0.0162 (4)
W4	0.0340 (5)	0.0245 (4)	0.0695 (6)	0.0032 (4)	0.0090 (4)	0.0146 (4)
W5	0.0431 (5)	0.0286 (5)	0.0377 (5)	0.0055 (4)	0.0104 (4)	0.0030 (4)
W6	0.0487 (5)	0.0679 (7)	0.0346 (5)	0.0254 (5)	0.0185 (4)	0.0193 (5)
O1	0.024 (8)	0.055 (10)	0.102 (13)	0.003 (7)	0.027 (8)	0.013 (9)
O2	0.043 (8)	0.040 (8)	0.046 (8)	0.021 (7)	0.011 (7)	0.026 (7)
O3	0.028 (7)	0.069 (11)	0.051 (9)	0.003 (7)	0.017 (7)	−0.007 (8)
O4	0.076 (11)	0.028 (8)	0.082 (12)	0.018 (8)	0.036 (10)	0.025 (8)
O5	0.108 (12)	0.041 (9)	0.057 (9)	0.040 (9)	−0.021 (9)	−0.012 (8)
O6	0.077 (12)	0.073 (12)	0.061 (11)	−0.006 (10)	0.020 (9)	0.041 (10)
O7	0.066 (3)	0.065 (3)	0.065 (3)	0.0104 (12)	0.0231 (14)	0.0191 (13)
O8	0.067 (3)	0.065 (3)	0.065 (3)	0.0107 (12)	0.0233 (14)	0.0192 (13)
O9	0.070 (3)	0.068 (3)	0.068 (3)	0.0109 (12)	0.0241 (15)	0.0200 (13)
O10	0.061 (3)	0.061 (3)	0.062 (3)	0.0110 (11)	0.0215 (14)	0.0165 (13)
O11	0.049 (7)	0.082 (8)	0.071 (8)	0.027 (7)	0.000 (7)	−0.022 (7)
O12	0.052 (10)	0.18 (2)	0.096 (14)	0.053 (12)	0.045 (10)	0.112 (15)
O13	0.060 (11)	0.148 (19)	0.080 (12)	0.064 (12)	0.038 (10)	0.091 (13)
O14	0.044 (7)	0.072 (8)	0.093 (8)	0.019 (7)	−0.007 (7)	−0.027 (8)
O15	0.049 (6)	0.059 (6)	0.063 (6)	0.008 (5)	0.007 (5)	0.031 (5)
O16	0.053 (6)	0.060 (6)	0.061 (6)	0.012 (5)	0.007 (5)	0.035 (5)
O17	0.038 (9)	0.132 (17)	0.099 (13)	0.051 (10)	0.039 (9)	0.090 (13)
O18	0.052 (6)	0.049 (6)	0.063 (6)	0.006 (5)	0.012 (5)	0.029 (5)
O19	0.043 (3)	0.042 (3)	0.042 (3)	0.0071 (11)	0.0152 (14)	0.0127 (13)
O20	0.028 (6)	0.022 (6)	0.045 (6)	0.008 (6)	0.017 (6)	0.007 (6)
O21	0.038 (8)	0.055 (9)	0.030 (8)	0.016 (8)	0.020 (7)	0.024 (7)
O22	0.0243 (17)	0.0190 (16)	0.0214 (16)	0.0072 (15)	0.0027 (15)	0.0080 (15)
N1	0.026 (8)	0.035 (9)	0.026 (8)	−0.002 (7)	−0.003 (7)	0.004 (7)
N2	0.042 (10)	0.037 (10)	0.045 (10)	0.004 (8)	0.014 (8)	0.016 (9)
N3	0.041 (10)	0.020 (8)	0.046 (10)	0.007 (7)	0.018 (8)	0.005 (7)
N4	0.039 (9)	0.025 (8)	0.039 (9)	0.006 (7)	0.017 (8)	0.007 (7)
N5	0.024 (8)	0.033 (9)	0.026 (8)	0.007 (7)	0.001 (6)	0.013 (7)
N6	0.032 (9)	0.048 (11)	0.040 (10)	−0.002 (8)	0.009 (8)	0.018 (9)
C1	0.029 (11)	0.041 (12)	0.049 (13)	0.009 (10)	0.005 (9)	0.019 (11)
C2	0.032 (12)	0.028 (11)	0.062 (15)	−0.007 (9)	−0.014 (10)	0.005 (11)
C3	0.016 (9)	0.038 (12)	0.080 (16)	0.005 (9)	0.011 (10)	0.038 (12)
C4	0.037 (11)	0.029 (11)	0.041 (11)	0.008 (9)	0.006 (9)	0.027 (9)
C5	0.022 (9)	0.041 (12)	0.037 (11)	0.011 (9)	0.012 (8)	0.019 (9)
C6	0.031 (11)	0.051 (14)	0.079 (16)	0.014 (10)	0.027 (11)	0.043 (13)
C7	0.034 (11)	0.048 (13)	0.060 (14)	0.020 (10)	0.016 (10)	0.031 (12)
C8	0.045 (12)	0.035 (11)	0.046 (12)	0.014 (10)	0.027 (10)	0.027 (10)
C9	0.028 (10)	0.027 (10)	0.036 (10)	0.011 (8)	0.009 (8)	0.016 (9)
C10	0.052 (13)	0.030 (11)	0.044 (12)	0.023 (10)	0.023 (10)	0.013 (10)
C11	0.057 (14)	0.020 (10)	0.036 (11)	0.013 (10)	0.012 (10)	0.000 (9)
C12	0.033 (11)	0.031 (12)	0.065 (15)	0.010 (10)	0.014 (11)	0.005 (11)
C13	0.049 (13)	0.029 (11)	0.036 (11)	0.020 (10)	0.004 (10)	0.002 (9)
C14	0.044 (13)	0.043 (13)	0.047 (13)	0.026 (11)	−0.004 (10)	0.018 (11)
C15	0.11 (2)	0.019 (11)	0.056 (15)	−0.003 (13)	0.029 (16)	0.013 (11)
C16	0.049 (12)	0.029 (11)	0.046 (12)	0.013 (9)	0.018 (10)	0.033 (10)
C17	0.038 (11)	0.021 (9)	0.032 (10)	0.009 (8)	0.005 (8)	0.010 (8)
C18	0.09 (2)	0.033 (12)	0.055 (15)	−0.002 (13)	0.047 (15)	0.005 (11)
C19	0.041 (12)	0.042 (13)	0.044 (13)	−0.015 (10)	0.014 (10)	0.009 (10)
C20	0.053 (13)	0.029 (11)	0.040 (12)	−0.001 (10)	0.023 (10)	0.003 (9)
C21	0.017 (9)	0.030 (10)	0.035 (10)	0.002 (8)	0.005 (8)	0.008 (9)
C22	0.022 (10)	0.055 (14)	0.046 (13)	−0.011 (10)	−0.001 (9)	0.003 (11)
C23	0.045 (13)	0.062 (15)	0.040 (12)	0.022 (12)	0.012 (10)	0.013 (11)
C24	0.019 (10)	0.058 (14)	0.037 (11)	−0.015 (9)	−0.001 (9)	0.019 (10)
C25	0.047 (13)	0.046 (13)	0.034 (12)	0.003 (11)	0.016 (10)	−0.002 (10)
C26	0.067 (16)	0.059 (16)	0.022 (11)	−0.012 (13)	0.008 (11)	−0.017 (11)
C27	0.073 (18)	0.059 (17)	0.061 (17)	0.034 (14)	0.031 (14)	0.003 (14)
C28	0.041 (13)	0.048 (14)	0.075 (17)	0.027 (11)	0.020 (12)	0.000 (13)
C29	0.016 (9)	0.072 (15)	0.034 (11)	0.014 (10)	0.005 (8)	0.029 (11)
C30	0.09 (2)	0.039 (15)	0.12 (3)	0.029 (14)	0.039 (19)	0.038 (16)
C31	0.067 (18)	0.09 (2)	0.10 (2)	0.030 (16)	0.025 (17)	0.06 (2)
C32	0.041 (5)	0.041 (5)	0.041 (5)	0.0068 (13)	0.015 (2)	0.0124 (18)
C33	0.015 (9)	0.054 (14)	0.041 (11)	−0.009 (9)	0.003 (8)	0.026 (10)
C34	0.050 (15)	0.10 (2)	0.055 (16)	−0.004 (15)	0.017 (12)	0.047 (16)
C35	0.028 (12)	0.10 (2)	0.033 (12)	−0.013 (13)	−0.004 (9)	0.016 (14)
C36	0.055 (14)	0.074 (17)	0.030 (12)	−0.006 (13)	0.023 (10)	0.015 (11)
O1W	0.06 (2)	0.06 (2)	0.15 (4)	−0.020 (19)	0.08 (3)	−0.04 (2)
O2W	0.10 (3)	0.17 (5)	0.13 (4)	0.08 (3)	0.05 (3)	0.14 (4)

Geometric parameters (Å, º) top

Ge1—O19	1.81 (3)	N2—C12	1.30 (2)
Ge1—O20	1.67 (2)	N2—C9	1.37 (2)
Ge1—O21	1.81 (2)	N3—C13	1.32 (2)
Ge1—O22	1.66 (2)	N3—C17	1.36 (2)
Ge1—O19ⁱ	1.81 (3)	N4—C24	1.27 (2)
Ge1—O20ⁱ	1.67 (2)	N4—C21	1.37 (2)
Ge1—O21ⁱ	1.81 (2)	N5—C25	1.32 (2)
Ge1—O22ⁱ	1.66 (2)	N5—C29	1.36 (2)
W1—O1	1.656 (14)	N6—C36	1.28 (2)
W2—O2	1.657 (12)	N6—C33	1.41 (3)
W3—O3	1.635 (13)	C1—C2	1.399 (10)
W4—O4	1.661 (14)	C1—H1A	0.9300
W5—O5	1.675 (15)	C2—C3	1.393 (10)
W6—O6	1.644 (16)	C2—H2A	0.9300
W1—O8	1.893 (17)	C3—C4	1.398 (10)
W1—O9	1.902 (18)	C3—H3A	0.9300
W1—O16	1.911 (14)	C4—C5	1.400 (10)
W1—O18	1.934 (15)	C4—C6	1.406 (10)
W2—O7	1.947 (17)	C5—C9	1.43 (2)
W2—O8	1.938 (17)	C6—C7	1.400 (10)
W2—O10	1.901 (17)	C6—H6A	0.9300
W2—O11ⁱ	1.923 (17)	C7—C8	1.402 (10)
W3—O7	1.926 (17)	C7—H7A	0.9300
W3—O9	1.951 (18)	C8—C9	1.403 (10)
W3—O12ⁱ	1.889 (19)	C8—C10	1.406 (10)
W3—O13ⁱ	1.882 (15)	C10—C11	1.395 (10)
W4—O10	1.873 (16)	C10—H10A	0.9300
W4—O13	1.894 (15)	C11—C12	1.393 (10)
W4—O14	1.854 (18)	C11—H11A	0.9300
W4—O17	1.902 (17)	C12—H12A	0.9300
W5—O12	1.907 (16)	C13—C14	1.404 (10)
W5—O15	1.914 (15)	C13—H13A	0.9300
W5—O17	1.868 (15)	C14—C15	1.398 (10)
W5—O18	1.884 (15)	C14—H14A	0.9300
W6—O11	1.897 (16)	C15—C16	1.400 (10)
W6—O14ⁱ	1.949 (17)	C15—H15A	0.9300
W6—O15	1.897 (16)	C16—C18	1.398 (10)
W6—O16	1.903 (15)	C16—C17	1.402 (10)
W1—O19	2.25 (3)	C17—C21	1.42 (2)
W1—O22ⁱ	2.42 (2)	C18—C19	1.394 (10)
W2—O19	2.37 (3)	C18—H18A	0.9300
W2—O21ⁱ	2.40 (2)	C19—C20	1.399 (10)
W3—O19	2.28 (3)	C19—H19A	0.9300
W3—O20ⁱ	2.41 (2)	C20—C22	1.397 (10)
W4—O20	2.41 (2)	C20—C21	1.400 (10)
W4—O21ⁱ	2.24 (3)	C22—C23	1.394 (10)
W5—O20	2.30 (2)	C22—H22A	0.9300
W5—O22ⁱ	2.30 (2)	C23—C24	1.396 (10)
W6—O21	2.29 (2)	C23—H23A	0.9300
W6—O22ⁱ	2.42 (2)	C24—H24A	0.9300
O11—W2ⁱ	1.923 (17)	C25—C26	1.400 (10)
O12—W3ⁱ	1.889 (19)	C25—H25A	0.9300
O13—W3ⁱ	1.882 (15)	C26—C27	1.393 (10)
O14—W6ⁱ	1.949 (17)	C26—H26A	0.9300
O20—O22ⁱ	1.80 (3)	C27—C28	1.400 (10)
O20—W3ⁱ	2.41 (2)	C27—H27A	0.9300
O21—W4ⁱ	2.24 (3)	C28—C29	1.401 (10)
O21—W2ⁱ	2.40 (2)	C28—C30	1.406 (10)
O22—O20ⁱ	1.80 (3)	C29—C33	1.43 (3)
O22—W5ⁱ	2.30 (2)	C30—C31	1.395 (10)
O22—W1ⁱ	2.42 (2)	C30—H30A	0.9300
O22—W6ⁱ	2.42 (2)	C31—C32	1.402 (10)
Mn1—N1	2.086 (15)	C31—H31A	0.9300
Mn1—N2	2.113 (17)	C32—C34	1.391 (10)
Mn1—N3	2.107 (17)	C32—C33	1.398 (10)
Mn1—N4	2.117 (16)	C34—C35	1.398 (10)
Mn1—N5	2.099 (15)	C34—H34A	0.9300
Mn1—N6	2.088 (17)	C35—C36	1.399 (10)
N1—C1	1.32 (2)	C35—H35A	0.9300
N1—C5	1.34 (2)	C36—H36A	0.9300

N1—Mn1—N6	92.9 (6)	W1—O8—W2	133.0 (10)
N1—Mn1—N5	92.4 (6)	W1—O9—W3	130.9 (9)
N6—Mn1—N5	81.2 (6)	W4—O10—W2	138.6 (10)
N1—Mn1—N3	95.2 (6)	W6—O11—W2ⁱ	137.1 (10)
N6—Mn1—N3	171.5 (6)	W3ⁱ—O12—W5	135.4 (11)
N5—Mn1—N3	95.9 (6)	W3ⁱ—O13—W4	138.3 (10)
N1—Mn1—N2	79.3 (6)	W4—O14—W6ⁱ	135.8 (13)
N6—Mn1—N2	93.4 (7)	W6—O15—W5	136.0 (9)
N5—Mn1—N2	169.9 (6)	W6—O16—W1	137.3 (9)
N3—Mn1—N2	90.7 (6)	W5—O17—W4	139.4 (11)
N1—Mn1—N4	173.1 (6)	W5—O18—W1	137.1 (9)
N6—Mn1—N4	91.8 (6)	Ge1—O19—W1	120.0 (13)
N5—Mn1—N4	93.2 (6)	Ge1—O19—W3	118.7 (14)
N3—Mn1—N4	80.3 (6)	W1—O19—W3	101.4 (11)
N2—Mn1—N4	95.5 (6)	Ge1—O19—W2	115.0 (13)
O22—Ge1—O22ⁱ	180 (2)	W1—O19—W2	99.0 (11)
O22—Ge1—O20ⁱ	65.5 (11)	W3—O19—W2	99.2 (10)
O22ⁱ—Ge1—O20ⁱ	114.5 (11)	Ge1—O20—O22ⁱ	57.0 (10)
O22—Ge1—O20	114.5 (11)	Ge1—O20—W5	124.2 (12)
O22ⁱ—Ge1—O20	65.5 (11)	O22ⁱ—O20—W5	67.2 (10)
O20ⁱ—Ge1—O20	180 (3)	Ge1—O20—W3ⁱ	119.2 (12)
O22—Ge1—O21ⁱ	70.7 (11)	O22ⁱ—O20—W3ⁱ	131.0 (15)
O22ⁱ—Ge1—O21ⁱ	109.3 (11)	W5—O20—W3ⁱ	96.6 (9)
O20ⁱ—Ge1—O21ⁱ	110.0 (12)	Ge1—O20—W4	118.8 (13)
O20—Ge1—O21ⁱ	70.0 (12)	O22ⁱ—O20—W4	132.2 (14)
O22—Ge1—O21	109.3 (11)	W5—O20—W4	97.4 (9)
O22ⁱ—Ge1—O21	70.7 (11)	W3ⁱ—O20—W4	94.2 (8)
O20ⁱ—Ge1—O21	70.0 (12)	Ge1—O21—W4ⁱ	120.5 (13)
O20—Ge1—O21	110.0 (12)	Ge1—O21—W6	119.2 (13)
O21ⁱ—Ge1—O21	180.0 (12)	W4ⁱ—O21—W6	101.9 (9)
O22—Ge1—O19	109.2 (11)	Ge1—O21—W2ⁱ	113.8 (11)
O22ⁱ—Ge1—O19	70.8 (11)	W4ⁱ—O21—W2ⁱ	99.1 (10)
O20ⁱ—Ge1—O19	71.0 (12)	W6—O21—W2ⁱ	98.5 (9)
O20—Ge1—O19	109.0 (12)	Ge1—O22—O20ⁱ	57.4 (10)
O21ⁱ—Ge1—O19	75.6 (12)	Ge1—O22—W5ⁱ	124.2 (12)
O21—Ge1—O19	104.4 (12)	O20ⁱ—O22—W5ⁱ	66.8 (10)
O22—Ge1—O19ⁱ	70.8 (11)	Ge1—O22—W1ⁱ	118.3 (10)
O22ⁱ—Ge1—O19ⁱ	109.2 (11)	O20ⁱ—O22—W1ⁱ	131.5 (13)
O20ⁱ—Ge1—O19ⁱ	109.0 (12)	W5ⁱ—O22—W1ⁱ	97.4 (8)
O20—Ge1—O19ⁱ	71.0 (12)	Ge1—O22—W6ⁱ	119.7 (11)
O21ⁱ—Ge1—O19ⁱ	104.4 (12)	O20ⁱ—O22—W6ⁱ	131.7 (13)
O21—Ge1—O19ⁱ	75.6 (12)	W5ⁱ—O22—W6ⁱ	96.7 (8)
O19—Ge1—O19ⁱ	180 (2)	W1ⁱ—O22—W6ⁱ	94.2 (8)
O1—W1—O8	98.1 (8)	C1—N1—C5	119.2 (16)
O1—W1—O9	97.9 (8)	C1—N1—Mn1	127.3 (13)
O8—W1—O9	89.5 (8)	C5—N1—Mn1	113.4 (11)
O1—W1—O16	100.0 (8)	C12—N2—C9	119.2 (17)
O8—W1—O16	161.9 (7)	C12—N2—Mn1	128.8 (13)
O9—W1—O16	88.8 (7)	C9—N2—Mn1	111.9 (12)
O1—W1—O18	100.0 (7)	C13—N3—C17	118.8 (16)
O8—W1—O18	88.5 (7)	C13—N3—Mn1	130.0 (13)
O9—W1—O18	162.1 (7)	C17—N3—Mn1	111.1 (11)
O16—W1—O18	87.6 (6)	C24—N4—C21	119.0 (16)
O1—W1—O19	154.8 (9)	C24—N4—Mn1	129.0 (13)
O8—W1—O19	65.6 (9)	C21—N4—Mn1	111.7 (11)
O9—W1—O19	64.5 (9)	C25—N5—C29	119.0 (16)
O16—W1—O19	97.6 (9)	C25—N5—Mn1	127.9 (13)
O18—W1—O19	98.6 (9)	C29—N5—Mn1	113.1 (11)
O1—W1—O22ⁱ	154.2 (8)	C36—N6—C33	117.3 (18)
O8—W1—O22ⁱ	98.6 (7)	C36—N6—Mn1	132.6 (16)
O9—W1—O22ⁱ	101.7 (7)	C33—N6—Mn1	110.0 (11)
O16—W1—O22ⁱ	64.2 (7)	N1—C1—C2	121.9 (19)
O18—W1—O22ⁱ	61.1 (7)	N1—C1—H1A	119.0
O19—W1—O22ⁱ	50.9 (9)	C2—C1—H1A	119.0
O2—W2—O10	101.7 (7)	C3—C2—C1	119.3 (17)
O2—W2—O11ⁱ	99.6 (8)	C3—C2—H2A	120.3
O10—W2—O11ⁱ	87.8 (7)	C1—C2—H2A	120.3
O2—W2—O8	99.5 (7)	C2—C3—C4	118.7 (15)
O10—W2—O8	89.9 (7)	C2—C3—H3A	120.7
O11ⁱ—W2—O8	160.9 (8)	C4—C3—H3A	120.7
O2—W2—O7	98.3 (7)	C3—C4—C5	117.7 (15)
O10—W2—O7	160.0 (7)	C3—C4—C6	123.5 (14)
O11ⁱ—W2—O7	88.4 (8)	C5—C4—C6	118.8 (15)
O8—W2—O7	87.4 (7)	N1—C5—C4	123.2 (16)
O2—W2—O19	153.3 (8)	N1—C5—C9	118.2 (13)
O10—W2—O19	98.0 (8)	C4—C5—C9	118.6 (15)
O11ⁱ—W2—O19	99.1 (9)	C7—C6—C4	122.5 (17)
O8—W2—O19	62.5 (8)	C7—C6—H6A	118.8
O7—W2—O19	63.3 (8)	C4—C6—H6A	118.8
O2—W2—O21ⁱ	151.1 (7)	C6—C7—C8	119.5 (17)
O10—W2—O21ⁱ	59.3 (8)	C6—C7—H7A	120.2
O11ⁱ—W2—O21ⁱ	60.9 (8)	C8—C7—H7A	120.2
O8—W2—O21ⁱ	101.8 (8)	C7—C8—C9	118.4 (15)
O7—W2—O21ⁱ	101.9 (8)	C7—C8—C10	122.6 (14)
O19—W2—O21ⁱ	55.6 (9)	C9—C8—C10	119.0 (14)
O3—W3—O13ⁱ	100.9 (9)	N2—C9—C8	120.9 (16)
O3—W3—O12ⁱ	100.4 (8)	N2—C9—C5	116.8 (14)
O13ⁱ—W3—O12ⁱ	90.8 (7)	C8—C9—C5	122.2 (15)
O3—W3—O7	97.7 (8)	C11—C10—C8	118.3 (15)
O13ⁱ—W3—O7	161.4 (8)	C11—C10—H10A	120.9
O12ⁱ—W3—O7	87.0 (7)	C8—C10—H10A	120.9
O3—W3—O9	98.1 (7)	C12—C11—C10	118.8 (17)
O13ⁱ—W3—O9	87.8 (8)	C12—C11—H11A	120.6
O12ⁱ—W3—O9	161.4 (8)	C10—C11—H11A	120.6
O7—W3—O9	88.5 (7)	N2—C12—C11	123.6 (18)
O3—W3—O19	153.8 (9)	N2—C12—H12A	118.2
O13ⁱ—W3—O19	96.7 (10)	C11—C12—H12A	118.2
O12ⁱ—W3—O19	98.7 (10)	N3—C13—C14	123.2 (19)
O7—W3—O19	65.5 (9)	N3—C13—H13A	118.4
O9—W3—O19	63.2 (9)	C14—C13—H13A	118.4
O3—W3—O20ⁱ	155.1 (8)	C15—C14—C13	116.5 (18)
O13ⁱ—W3—O20ⁱ	63.8 (8)	C15—C14—H14A	121.8
O12ⁱ—W3—O20ⁱ	62.4 (8)	C13—C14—H14A	121.8
O7—W3—O20ⁱ	99.1 (8)	C14—C15—C16	122.7 (17)
O9—W3—O20ⁱ	100.7 (8)	C14—C15—H15A	118.7
O19—W3—O20ⁱ	51.1 (9)	C16—C15—H15A	118.7
O4—W4—O14	101.1 (9)	C18—C16—C15	122.7 (14)
O4—W4—O10	102.0 (8)	C18—C16—C17	122.5 (16)
O14—W4—O10	89.9 (7)	C15—C16—C17	114.8 (16)
O4—W4—O13	100.3 (8)	N3—C17—C16	123.8 (16)
O14—W4—O13	88.7 (8)	N3—C17—C21	119.6 (13)
O10—W4—O13	157.4 (8)	C16—C17—C21	116.6 (15)
O4—W4—O17	100.4 (8)	C19—C18—C16	119.8 (18)
O14—W4—O17	158.5 (9)	C19—C18—H18A	120.1
O10—W4—O17	86.0 (7)	C16—C18—H18A	120.1
O13—W4—O17	87.1 (7)	C18—C19—C20	119.5 (17)
O4—W4—O21ⁱ	155.7 (8)	C18—C19—H19A	120.3
O14—W4—O21ⁱ	62.2 (9)	C20—C19—H19A	120.3
O10—W4—O21ⁱ	62.9 (8)	C22—C20—C19	122.9 (15)
O13—W4—O21ⁱ	96.9 (9)	C22—C20—C21	116.8 (14)
O17—W4—O21ⁱ	97.5 (8)	C19—C20—C21	120.2 (15)
O4—W4—O20	153.5 (8)	N4—C21—C20	121.3 (15)
O14—W4—O20	99.5 (9)	N4—C21—C17	117.3 (13)
O10—W4—O20	94.5 (8)	C20—C21—C17	121.4 (15)
O13—W4—O20	63.6 (8)	C23—C22—C20	121.4 (16)
O17—W4—O20	60.0 (8)	C23—C22—H22A	119.3
O21ⁱ—W4—O20	50.7 (8)	C20—C22—H22A	119.3
O5—W5—O17	102.7 (10)	C22—C23—C24	115.1 (18)
O5—W5—O18	100.8 (8)	C22—C23—H23A	122.4
O17—W5—O18	88.3 (6)	C24—C23—H23A	122.4
O5—W5—O12	100.2 (10)	N4—C24—C23	126.1 (19)
O17—W5—O12	90.5 (6)	N4—C24—H24A	116.9
O18—W5—O12	158.7 (9)	C23—C24—H24A	116.9
O5—W5—O15	98.4 (9)	N5—C25—C26	121 (2)
O17—W5—O15	158.9 (8)	N5—C25—H25A	119.3
O18—W5—O15	87.9 (6)	C26—C25—H25A	119.3
O12—W5—O15	85.6 (7)	C27—C26—C25	120.5 (19)
O5—W5—O20	157.3 (10)	C27—C26—H26A	119.8
O17—W5—O20	62.8 (9)	C25—C26—H26A	119.8
O18—W5—O20	96.3 (8)	C26—C27—C28	118.5 (19)
O12—W5—O20	64.5 (9)	C26—C27—H27A	120.8
O15—W5—O20	97.0 (8)	C28—C27—H27A	120.8
O5—W5—O22ⁱ	156.6 (10)	C27—C28—C29	117.2 (17)
O17—W5—O22ⁱ	94.9 (9)	C27—C28—C30	124.3 (18)
O18—W5—O22ⁱ	64.2 (7)	C29—C28—C30	118.5 (18)
O12—W5—O22ⁱ	94.8 (9)	N5—C29—C28	123.5 (16)
O15—W5—O22ⁱ	64.8 (7)	N5—C29—C33	116.1 (15)
O20—W5—O22ⁱ	46.0 (8)	C28—C29—C33	120.4 (17)
O6—W6—O11	102.4 (9)	C31—C30—C28	121 (2)
O6—W6—O15	99.9 (8)	C31—C30—H30A	119.6
O11—W6—O15	88.9 (8)	C28—C30—H30A	119.6
O6—W6—O16	99.5 (8)	C30—C31—C32	122 (2)
O11—W6—O16	158.1 (8)	C30—C31—H31A	119.2
O15—W6—O16	88.8 (7)	C32—C31—H31A	119.2
O6—W6—O14ⁱ	101.1 (9)	C34—C32—C33	121.4 (18)
O11—W6—O14ⁱ	88.2 (7)	C34—C32—C31	120.3 (18)
O15—W6—O14ⁱ	159.0 (9)	C33—C32—C31	118.2 (18)
O16—W6—O14ⁱ	86.2 (7)	C32—C33—N6	119.9 (17)
O6—W6—O21	154.9 (9)	C32—C33—C29	120.5 (18)
O11—W6—O21	63.4 (8)	N6—C33—C29	119.6 (14)
O15—W6—O21	100.3 (9)	C32—C34—C35	117 (2)
O16—W6—O21	95.7 (8)	C32—C34—H34A	121.7
O14ⁱ—W6—O21	60.0 (10)	C35—C34—H34A	121.7
O6—W6—O22ⁱ	154.6 (8)	C34—C35—C36	119 (2)
O11—W6—O22ⁱ	95.6 (8)	C34—C35—H35A	120.7
O15—W6—O22ⁱ	62.4 (7)	C36—C35—H35A	120.7
O16—W6—O22ⁱ	64.2 (7)	N6—C36—C35	126 (2)
O14ⁱ—W6—O22ⁱ	97.2 (9)	N6—C36—H36A	116.9
O21—W6—O22ⁱ	50.4 (8)	C35—C36—H36A	116.9
W3—O7—W2	132.0 (9)

Symmetry code: (i) −x, −y, −z.

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Bis[tris­(1,10-phenanthroline-κ2N,N′)manganese(II)] dodeca­tungstogermanate dihydrate

Supporting information

Key indicators

checkCIF/PLATON results

Bis[tris(1,10-phenanthroline-κ²N,N′)manganese(II)] dodecatungstogermanate dihydrate