Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807022143/bg2030sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536807022143/bg2030Isup2.hkl |
CCDC reference: 275625
Data collection: X-AREA (Stoe & Cie , 2006); cell refinement: X-AREA; data reduction: X-RED32 (Stoe & Cie, 2005); program(s) used to solve structure: DIRDIF (Beurskens et al., 1996); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 1996) and ATOMS (Dowty, 2006); software used to prepare material for publication: SHELXTL.
[Ag(C20H20N2)(C18H15P)2]NO3·1.36C2H3N·1.64CH4O·0.53C4H10O | Z = 2 |
Mr = 1130.66 | F(000) = 1179.6 |
Triclinic, P1 | Dx = 1.315 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 13.5727 (9) Å | Cell parameters from 5484 reflections |
b = 14.9626 (10) Å | θ = 1.7–29.7° |
c = 15.7828 (11) Å | µ = 0.46 mm−1 |
α = 80.578 (5)° | T = 140 K |
β = 82.201 (5)° | Prism, colourless |
γ = 64.867 (4)° | 0.71 × 0.32 × 0.23 mm |
V = 2854.7 (4) Å3 |
Stoe IPDS2 diffractometer | 14231 independent reflections |
Radiation source: sealed X-ray tube, 12 x 0.4 mm long-fine focus | 12840 reflections with I > 2σ(I) |
Plane graphite monochromator | Rint = 0.026 |
Detector resolution: 6.67 pixels mm-1 | θmax = 29.4°, θmin = 1.7° |
rotation method scans | h = −18→16 |
Absorption correction: integration (X-RED32; Stoe & Cie, 2005) | k = −20→20 |
Tmin = 0.804, Tmax = 0.914 | l = −21→21 |
27609 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.055 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.137 | H-atom parameters constrained |
S = 1.12 | w = 1/[σ2(Fo2) + (0.0456P)2 + 4.8514P] where P = (Fo2 + 2Fc2)/3 |
14231 reflections | (Δ/σ)max = 0.021 |
735 parameters | Δρmax = 1.19 e Å−3 |
17 restraints | Δρmin = −1.41 e Å−3 |
Experimental. νmax(KBr)/cm-1 1624 (C=N), 1345 (NO3). δH (CDCl3) 3.80 (s, 4H, NCH2CH2N); 6.56 (dd, 2H, –C=CHC); 6.89 (d, 2H, PhCH=C); 7.14–7.40 (m, 40H, 2Ph-C ArH); 8.40 (d, 2H, CH=N). UV-Vis λmax(nm)/ε(M-1cm-1) 277 (50470). |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Ag | 0.190066 (12) | 0.153494 (11) | 0.228681 (10) | 0.03259 (4) | |
C1 | 0.1232 (2) | 0.33276 (18) | 0.08066 (15) | 0.0443 (6) | |
H1A | 0.1019 | 0.4022 | 0.0581 | 0.053* | |
H1B | 0.0807 | 0.3074 | 0.0550 | 0.053* | |
C2 | 0.2441 (2) | 0.27421 (17) | 0.05780 (16) | 0.0438 (6) | |
H2A | 0.2596 | 0.2825 | −0.0041 | 0.053* | |
H2B | 0.2868 | 0.2985 | 0.0845 | 0.053* | |
N1 | 0.10188 (15) | 0.32365 (13) | 0.17378 (12) | 0.0382 (4) | |
C11 | 0.04005 (19) | 0.40267 (16) | 0.20860 (16) | 0.0413 (5) | |
H11 | 0.0131 | 0.4626 | 0.1731 | 0.050* | |
C12 | 0.01035 (19) | 0.40346 (16) | 0.29898 (16) | 0.0414 (5) | |
H12 | 0.0438 | 0.3460 | 0.3361 | 0.050* | |
C13 | −0.0651 (2) | 0.48556 (17) | 0.33164 (16) | 0.0435 (6) | |
H13 | −0.0936 | 0.5421 | 0.2924 | 0.052* | |
C14 | −0.10692 (19) | 0.49606 (16) | 0.42068 (16) | 0.0415 (5) | |
C15 | −0.1934 (2) | 0.58471 (18) | 0.44064 (19) | 0.0506 (7) | |
H15 | −0.2238 | 0.6354 | 0.3968 | 0.061* | |
C16 | −0.2341 (2) | 0.5978 (2) | 0.5249 (2) | 0.0582 (8) | |
H16 | −0.2917 | 0.6573 | 0.5372 | 0.070* | |
C17 | −0.1901 (2) | 0.52344 (19) | 0.59127 (19) | 0.0540 (7) | |
H17 | −0.2184 | 0.5323 | 0.6479 | 0.065* | |
C18 | −0.1034 (2) | 0.43543 (18) | 0.57237 (18) | 0.0503 (6) | |
H18 | −0.0727 | 0.3854 | 0.6166 | 0.060* | |
C19 | −0.0624 (2) | 0.42181 (16) | 0.48812 (17) | 0.0453 (6) | |
H19 | −0.0044 | 0.3624 | 0.4762 | 0.054* | |
N2 | 0.27298 (14) | 0.16942 (13) | 0.08851 (12) | 0.0373 (4) | |
C21 | 0.32450 (18) | 0.10447 (17) | 0.03595 (16) | 0.0413 (5) | |
H21 | 0.3456 | 0.1254 | −0.0195 | 0.050* | |
C22 | 0.35043 (18) | 0.00068 (17) | 0.06012 (16) | 0.0407 (5) | |
H22 | 0.3307 | −0.0205 | 0.1159 | 0.049* | |
C23 | 0.40245 (18) | −0.06694 (18) | 0.00440 (16) | 0.0433 (5) | |
H23 | 0.4244 | −0.0437 | −0.0499 | 0.052* | |
C24 | 0.42807 (18) | −0.17360 (17) | 0.02054 (16) | 0.0418 (5) | |
C25 | 0.4813 (2) | −0.23274 (19) | −0.04555 (18) | 0.0492 (6) | |
H25 | 0.5015 | −0.2044 | −0.0981 | 0.059* | |
C26 | 0.5043 (2) | −0.3338 (2) | −0.0337 (2) | 0.0569 (7) | |
H26 | 0.5402 | −0.3727 | −0.0780 | 0.068* | |
C27 | 0.4739 (3) | −0.3758 (2) | 0.0437 (2) | 0.0628 (8) | |
H27 | 0.4894 | −0.4433 | 0.0520 | 0.075* | |
C28 | 0.4202 (3) | −0.3177 (2) | 0.1093 (2) | 0.0612 (8) | |
H28 | 0.3986 | −0.3461 | 0.1613 | 0.073* | |
C29 | 0.3983 (2) | −0.21773 (19) | 0.09800 (18) | 0.0521 (7) | |
H29 | 0.3632 | −0.1796 | 0.1429 | 0.063* | |
P1 | 0.05191 (4) | 0.08621 (4) | 0.23475 (4) | 0.03475 (12) | |
C100 | −0.05172 (17) | 0.13359 (16) | 0.32105 (15) | 0.0389 (5) | |
C101 | −0.07219 (19) | 0.07309 (19) | 0.39200 (16) | 0.0448 (6) | |
H101 | −0.0360 | 0.0043 | 0.3944 | 0.054* | |
C102 | −0.1463 (2) | 0.1155 (2) | 0.45869 (19) | 0.0560 (7) | |
H102 | −0.1589 | 0.0745 | 0.5059 | 0.067* | |
C103 | −0.2014 (2) | 0.2164 (2) | 0.45677 (19) | 0.0570 (7) | |
H103 | −0.2513 | 0.2436 | 0.5020 | 0.068* | |
C104 | −0.1822 (2) | 0.2776 (2) | 0.38686 (19) | 0.0529 (7) | |
H104 | −0.2192 | 0.3462 | 0.3852 | 0.063* | |
C105 | −0.1080 (2) | 0.23688 (18) | 0.31948 (17) | 0.0465 (6) | |
H105 | −0.0954 | 0.2784 | 0.2728 | 0.056* | |
C110 | −0.02536 (17) | 0.11844 (16) | 0.13994 (14) | 0.0376 (5) | |
C111 | 0.0316 (2) | 0.1137 (2) | 0.06008 (16) | 0.0476 (6) | |
H111 | 0.1059 | 0.0985 | 0.0563 | 0.057* | |
C112 | −0.0207 (2) | 0.1313 (2) | −0.01442 (17) | 0.0596 (7) | |
H112 | 0.0190 | 0.1263 | −0.0676 | 0.072* | |
C113 | −0.1299 (2) | 0.1560 (2) | −0.01001 (18) | 0.0612 (8) | |
H113 | −0.1646 | 0.1667 | −0.0600 | 0.073* | |
C114 | −0.1883 (2) | 0.1649 (3) | 0.0683 (2) | 0.0757 (10) | |
H114 | −0.2634 | 0.1839 | 0.0712 | 0.091* | |
C115 | −0.1362 (2) | 0.1456 (2) | 0.14379 (18) | 0.0606 (8) | |
H115 | −0.1763 | 0.1511 | 0.1968 | 0.073* | |
C120 | 0.10127 (17) | −0.04878 (16) | 0.25491 (13) | 0.0360 (5) | |
C121 | 0.20006 (18) | −0.10274 (17) | 0.29309 (15) | 0.0423 (5) | |
H121 | 0.2373 | −0.0693 | 0.3094 | 0.051* | |
C122 | 0.2431 (2) | −0.20568 (18) | 0.30680 (17) | 0.0478 (6) | |
H122 | 0.3089 | −0.2407 | 0.3322 | 0.057* | |
C123 | 0.1888 (2) | −0.25652 (18) | 0.28294 (16) | 0.0468 (6) | |
H123 | 0.2178 | −0.3256 | 0.2922 | 0.056* | |
C124 | 0.0910 (2) | −0.20388 (18) | 0.24519 (16) | 0.0465 (5) | |
H124 | 0.0545 | −0.2378 | 0.2285 | 0.056* | |
C125 | 0.04695 (18) | −0.10104 (17) | 0.23214 (15) | 0.0423 (5) | |
H125 | −0.0197 | −0.0664 | 0.2079 | 0.051* | |
P2 | 0.31868 (4) | 0.10423 (4) | 0.33928 (3) | 0.03233 (11) | |
C200 | 0.25579 (16) | 0.13118 (14) | 0.44680 (14) | 0.0332 (4) | |
C201 | 0.14675 (17) | 0.14712 (15) | 0.46507 (14) | 0.0360 (5) | |
H201 | 0.1069 | 0.1464 | 0.4219 | 0.043* | |
C202 | 0.09713 (18) | 0.16403 (16) | 0.54717 (15) | 0.0399 (5) | |
H202 | 0.0245 | 0.1738 | 0.5591 | 0.048* | |
C203 | 0.15573 (19) | 0.16642 (16) | 0.61159 (15) | 0.0405 (5) | |
H203 | 0.1223 | 0.1783 | 0.6665 | 0.049* | |
C204 | 0.26434 (19) | 0.15105 (17) | 0.59399 (15) | 0.0424 (5) | |
H204 | 0.3036 | 0.1524 | 0.6373 | 0.051* | |
C205 | 0.31431 (17) | 0.13380 (16) | 0.51249 (14) | 0.0385 (5) | |
H205 | 0.3870 | 0.1239 | 0.5010 | 0.046* | |
C210 | 0.41893 (17) | 0.15777 (15) | 0.32146 (13) | 0.0342 (4) | |
C211 | 0.38447 (19) | 0.25713 (16) | 0.28678 (14) | 0.0395 (5) | |
H211 | 0.3129 | 0.2931 | 0.2719 | 0.047* | |
C212 | 0.4564 (2) | 0.30275 (18) | 0.27424 (17) | 0.0479 (6) | |
H212 | 0.4326 | 0.3694 | 0.2520 | 0.057* | |
C213 | 0.5637 (2) | 0.2491 (2) | 0.29488 (18) | 0.0513 (6) | |
H213 | 0.6119 | 0.2796 | 0.2860 | 0.062* | |
C214 | 0.59894 (19) | 0.1505 (2) | 0.32855 (18) | 0.0499 (6) | |
H214 | 0.6709 | 0.1147 | 0.3424 | 0.060* | |
C215 | 0.52729 (18) | 0.10481 (18) | 0.34179 (17) | 0.0447 (6) | |
H215 | 0.5516 | 0.0382 | 0.3644 | 0.054* | |
C220 | 0.40193 (16) | −0.03017 (15) | 0.35335 (15) | 0.0376 (5) | |
C221 | 0.40032 (18) | −0.08991 (16) | 0.43026 (17) | 0.0447 (6) | |
H221 | 0.3592 | −0.0613 | 0.4786 | 0.054* | |
C222 | 0.4602 (2) | −0.19288 (18) | 0.4354 (2) | 0.0566 (7) | |
H222 | 0.4585 | −0.2326 | 0.4870 | 0.068* | |
C223 | 0.5215 (2) | −0.23555 (19) | 0.3645 (2) | 0.0627 (8) | |
H223 | 0.5615 | −0.3040 | 0.3683 | 0.075* | |
C224 | 0.5240 (2) | −0.17719 (19) | 0.2873 (2) | 0.0598 (7) | |
H224 | 0.5656 | −0.2064 | 0.2394 | 0.072* | |
C225 | 0.46389 (19) | −0.07418 (18) | 0.28143 (18) | 0.0479 (6) | |
H225 | 0.4653 | −0.0350 | 0.2295 | 0.058* | |
N70 | 0.7384 (3) | 0.4857 (3) | 0.8263 (2) | 0.0980 (13) | |
C70 | 0.7839 (3) | 0.4512 (2) | 0.8863 (2) | 0.0673 (10) | |
C71 | 0.8433 (4) | 0.4077 (3) | 0.9642 (3) | 0.1058 (16) | |
O86 | 0.6682 (3) | 0.9376 (3) | 0.1847 (2) | 0.1259 (13) | |
C86 | 0.7365 (4) | 0.9882 (4) | 0.1720 (4) | 0.1223 (17) | |
N72 | 0.6782 (8) | 0.4076 (5) | 0.1688 (7) | 0.158 (7) | 0.362 (4) |
C72 | 0.6850 (7) | 0.4754 (5) | 0.1871 (7) | 0.087 (4) | 0.362 (4) |
C73 | 0.6845 (11) | 0.5601 (7) | 0.2306 (10) | 0.148 (7) | 0.362 (4) |
O88 | 0.7979 (4) | 0.5326 (4) | 0.1278 (3) | 0.127 (2) | 0.638 (4) |
C88 | 0.7127 (6) | 0.5233 (7) | 0.1877 (6) | 0.111 (3) | 0.638 (4) |
N3 | 0.8533 (3) | 0.7080 (3) | 0.1568 (2) | 0.0544 (11) | 0.609 (3) |
O31 | 0.7625 (4) | 0.7257 (4) | 0.1631 (3) | 0.1023 (16) | 0.609 (3) |
O32 | 0.8974 (4) | 0.6270 (3) | 0.1212 (2) | 0.0945 (18) | 0.609 (3) |
O33 | 0.9046 (4) | 0.7505 (5) | 0.1663 (6) | 0.157 (3) | 0.609 (3) |
N3A | 0.8402 (9) | 0.7542 (9) | 0.1758 (5) | 0.105 (3)* | 0.391 (3) |
O31A | 0.7711 (6) | 0.7238 (5) | 0.2024 (5) | 0.077 (2) | 0.391 (3) |
O32A | 0.8273 (7) | 0.8342 (6) | 0.1764 (5) | 0.106 (3) | 0.391 (3) |
O33A | 0.9300 (9) | 0.6797 (7) | 0.1542 (10) | 0.183 (6) | 0.391 (3) |
C401 | 0.4778 (10) | 0.4798 (9) | 0.4130 (6) | 0.169 (3)* | 0.533 (5) |
C402 | 0.4796 (11) | 0.5305 (11) | 0.3192 (6) | 0.169 (3)* | 0.533 (5) |
O400 | 0.5375 (7) | 0.5079 (7) | 0.4627 (4) | 0.169 (3)* | 0.533 (5) |
C403 | 0.5930 (11) | 0.4512 (10) | 0.5412 (7) | 0.169 (3)* | 0.533 (9) |
C404 | 0.5374 (13) | 0.4873 (12) | 0.6264 (6) | 0.169 (3)* | 0.533 (9) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Ag | 0.03019 (6) | 0.03412 (6) | 0.03248 (7) | −0.01010 (5) | −0.00884 (5) | −0.00482 (5) |
C1 | 0.0454 (11) | 0.0401 (10) | 0.0396 (11) | −0.0098 (9) | −0.0112 (10) | 0.0009 (9) |
C2 | 0.0464 (11) | 0.0409 (10) | 0.0414 (11) | −0.0170 (8) | −0.0007 (10) | −0.0021 (9) |
N1 | 0.0345 (8) | 0.0347 (8) | 0.0400 (9) | −0.0074 (6) | −0.0075 (8) | −0.0052 (7) |
C11 | 0.0386 (10) | 0.0322 (9) | 0.0461 (11) | −0.0076 (8) | −0.0094 (9) | −0.0006 (8) |
C12 | 0.0402 (10) | 0.0323 (9) | 0.0460 (11) | −0.0079 (8) | −0.0086 (10) | −0.0047 (8) |
C13 | 0.0426 (11) | 0.0340 (9) | 0.0461 (12) | −0.0072 (8) | −0.0072 (10) | −0.0047 (9) |
C14 | 0.0410 (10) | 0.0329 (9) | 0.0480 (12) | −0.0111 (8) | −0.0032 (10) | −0.0093 (8) |
C15 | 0.0487 (13) | 0.0364 (10) | 0.0571 (14) | −0.0066 (10) | −0.0052 (12) | −0.0092 (10) |
C16 | 0.0552 (15) | 0.0452 (12) | 0.0626 (16) | −0.0074 (11) | 0.0000 (14) | −0.0161 (11) |
C17 | 0.0575 (14) | 0.0514 (12) | 0.0546 (14) | −0.0232 (10) | 0.0059 (13) | −0.0159 (10) |
C18 | 0.0588 (13) | 0.0433 (10) | 0.0477 (13) | −0.0209 (10) | −0.0016 (12) | −0.0047 (9) |
C19 | 0.0470 (12) | 0.0325 (9) | 0.0516 (13) | −0.0115 (8) | −0.0027 (11) | −0.0064 (9) |
N2 | 0.0301 (8) | 0.0385 (8) | 0.0404 (9) | −0.0099 (6) | −0.0014 (7) | −0.0094 (7) |
C21 | 0.0331 (9) | 0.0492 (10) | 0.0424 (11) | −0.0171 (8) | −0.0015 (9) | −0.0083 (9) |
C22 | 0.0323 (9) | 0.0469 (10) | 0.0428 (11) | −0.0134 (8) | −0.0016 (9) | −0.0141 (8) |
C23 | 0.0332 (9) | 0.0527 (11) | 0.0456 (11) | −0.0163 (8) | 0.0014 (9) | −0.0172 (9) |
C24 | 0.0294 (9) | 0.0494 (10) | 0.0469 (11) | −0.0119 (8) | −0.0031 (9) | −0.0192 (9) |
C25 | 0.0352 (11) | 0.0544 (12) | 0.0550 (13) | −0.0113 (9) | 0.0025 (11) | −0.0238 (10) |
C26 | 0.0497 (14) | 0.0545 (12) | 0.0630 (15) | −0.0119 (11) | 0.0026 (13) | −0.0300 (11) |
C27 | 0.0693 (17) | 0.0477 (12) | 0.0699 (17) | −0.0174 (12) | −0.0046 (15) | −0.0224 (12) |
C28 | 0.0772 (18) | 0.0534 (13) | 0.0528 (15) | −0.0263 (12) | 0.0006 (14) | −0.0120 (11) |
C29 | 0.0544 (13) | 0.0492 (11) | 0.0517 (13) | −0.0151 (10) | −0.0049 (12) | −0.0201 (10) |
P1 | 0.0327 (2) | 0.0430 (2) | 0.0318 (2) | −0.01653 (18) | −0.0083 (2) | −0.00566 (19) |
C100 | 0.0358 (8) | 0.0491 (9) | 0.0383 (10) | −0.0217 (7) | −0.0078 (8) | −0.0066 (8) |
C101 | 0.0419 (10) | 0.0534 (11) | 0.0410 (11) | −0.0212 (9) | 0.0027 (10) | −0.0108 (9) |
C102 | 0.0553 (13) | 0.0697 (14) | 0.0458 (13) | −0.0300 (11) | 0.0061 (12) | −0.0103 (11) |
C103 | 0.0495 (13) | 0.0723 (15) | 0.0509 (14) | −0.0243 (11) | 0.0066 (12) | −0.0223 (12) |
C104 | 0.0451 (13) | 0.0532 (12) | 0.0568 (14) | −0.0142 (10) | 0.0031 (12) | −0.0197 (11) |
C105 | 0.0463 (11) | 0.0489 (11) | 0.0447 (12) | −0.0193 (9) | −0.0048 (10) | −0.0063 (9) |
C110 | 0.0334 (8) | 0.0450 (9) | 0.0368 (10) | −0.0158 (7) | −0.0088 (8) | −0.0077 (8) |
C111 | 0.0428 (10) | 0.0653 (13) | 0.0390 (11) | −0.0240 (9) | −0.0104 (9) | −0.0062 (10) |
C112 | 0.0611 (13) | 0.0855 (17) | 0.0385 (12) | −0.0333 (12) | −0.0163 (11) | −0.0050 (11) |
C113 | 0.0555 (12) | 0.0811 (17) | 0.0468 (12) | −0.0219 (12) | −0.0232 (11) | −0.0089 (12) |
C114 | 0.0381 (11) | 0.124 (2) | 0.0630 (16) | −0.0235 (14) | −0.0176 (12) | −0.0234 (16) |
C115 | 0.0378 (11) | 0.1002 (19) | 0.0457 (13) | −0.0251 (12) | −0.0074 (11) | −0.0191 (13) |
C120 | 0.0376 (9) | 0.0434 (9) | 0.0299 (9) | −0.0182 (7) | −0.0043 (8) | −0.0064 (7) |
C121 | 0.0412 (9) | 0.0480 (10) | 0.0434 (11) | −0.0217 (8) | −0.0099 (9) | −0.0058 (8) |
C122 | 0.0463 (11) | 0.0467 (11) | 0.0488 (13) | −0.0179 (9) | −0.0103 (10) | 0.0003 (10) |
C123 | 0.0522 (12) | 0.0436 (10) | 0.0432 (12) | −0.0193 (9) | −0.0001 (11) | −0.0057 (9) |
C124 | 0.0535 (11) | 0.0522 (10) | 0.0444 (12) | −0.0302 (9) | −0.0017 (10) | −0.0124 (9) |
C125 | 0.0420 (9) | 0.0498 (10) | 0.0412 (11) | −0.0224 (8) | −0.0084 (9) | −0.0079 (8) |
P2 | 0.0290 (2) | 0.0323 (2) | 0.0351 (2) | −0.00926 (17) | −0.01003 (19) | −0.00548 (18) |
C200 | 0.0330 (8) | 0.0284 (7) | 0.0369 (9) | −0.0089 (6) | −0.0117 (8) | −0.0032 (7) |
C201 | 0.0336 (8) | 0.0332 (8) | 0.0408 (10) | −0.0112 (7) | −0.0108 (8) | −0.0043 (7) |
C202 | 0.0359 (9) | 0.0392 (9) | 0.0430 (11) | −0.0142 (8) | −0.0039 (9) | −0.0030 (8) |
C203 | 0.0461 (11) | 0.0379 (9) | 0.0345 (10) | −0.0144 (8) | −0.0038 (9) | −0.0039 (8) |
C204 | 0.0458 (10) | 0.0458 (10) | 0.0366 (10) | −0.0164 (8) | −0.0141 (9) | −0.0053 (8) |
C205 | 0.0357 (9) | 0.0421 (9) | 0.0387 (10) | −0.0143 (7) | −0.0113 (8) | −0.0051 (8) |
C210 | 0.0343 (8) | 0.0375 (8) | 0.0315 (9) | −0.0132 (7) | −0.0060 (8) | −0.0078 (7) |
C211 | 0.0412 (10) | 0.0383 (9) | 0.0367 (10) | −0.0132 (8) | −0.0047 (9) | −0.0056 (8) |
C212 | 0.0586 (12) | 0.0438 (10) | 0.0441 (12) | −0.0253 (9) | −0.0006 (11) | −0.0040 (9) |
C213 | 0.0528 (11) | 0.0633 (12) | 0.0504 (13) | −0.0356 (9) | 0.0008 (11) | −0.0113 (10) |
C214 | 0.0377 (10) | 0.0614 (12) | 0.0549 (14) | −0.0232 (9) | −0.0078 (10) | −0.0070 (11) |
C215 | 0.0355 (9) | 0.0450 (10) | 0.0545 (13) | −0.0153 (8) | −0.0135 (10) | −0.0034 (9) |
C220 | 0.0299 (8) | 0.0333 (8) | 0.0497 (11) | −0.0080 (7) | −0.0151 (8) | −0.0089 (8) |
C221 | 0.0430 (10) | 0.0356 (9) | 0.0560 (12) | −0.0128 (8) | −0.0200 (10) | −0.0025 (9) |
C222 | 0.0553 (12) | 0.0351 (10) | 0.0795 (17) | −0.0132 (9) | −0.0318 (12) | 0.0000 (10) |
C223 | 0.0466 (11) | 0.0373 (10) | 0.104 (2) | −0.0071 (9) | −0.0302 (13) | −0.0153 (12) |
C224 | 0.0376 (11) | 0.0498 (11) | 0.0911 (18) | −0.0062 (10) | −0.0119 (13) | −0.0337 (12) |
C225 | 0.0365 (10) | 0.0464 (10) | 0.0601 (13) | −0.0099 (9) | −0.0123 (10) | −0.0177 (10) |
N70 | 0.091 (2) | 0.085 (2) | 0.091 (2) | −0.0101 (18) | −0.015 (2) | −0.0054 (18) |
C70 | 0.0702 (19) | 0.0483 (13) | 0.073 (2) | −0.0172 (13) | 0.0048 (17) | −0.0081 (13) |
C71 | 0.140 (3) | 0.084 (2) | 0.092 (3) | −0.044 (2) | −0.039 (3) | 0.013 (2) |
O86 | 0.117 (2) | 0.157 (3) | 0.112 (3) | −0.0733 (19) | 0.001 (2) | 0.002 (2) |
C86 | 0.130 (3) | 0.159 (3) | 0.113 (4) | −0.099 (2) | −0.023 (3) | 0.015 (3) |
N72 | 0.201 (15) | 0.125 (10) | 0.110 (10) | −0.031 (10) | −0.017 (10) | −0.011 (8) |
C72 | 0.098 (7) | 0.053 (5) | 0.096 (7) | −0.016 (5) | −0.032 (6) | 0.007 (5) |
C73 | 0.119 (11) | 0.123 (10) | 0.213 (18) | −0.044 (9) | −0.001 (13) | −0.073 (11) |
O88 | 0.116 (4) | 0.116 (4) | 0.115 (4) | −0.002 (3) | −0.052 (3) | −0.015 (3) |
C88 | 0.100 (4) | 0.137 (5) | 0.122 (6) | −0.071 (4) | −0.033 (4) | −0.002 (5) |
N3 | 0.0407 (17) | 0.070 (2) | 0.0393 (17) | −0.0165 (16) | −0.0084 (15) | 0.0168 (16) |
O31 | 0.073 (2) | 0.160 (3) | 0.098 (3) | −0.060 (2) | 0.010 (2) | −0.058 (3) |
O32 | 0.120 (4) | 0.060 (2) | 0.053 (2) | 0.012 (2) | −0.015 (2) | −0.0019 (17) |
O33 | 0.084 (2) | 0.176 (4) | 0.252 (8) | −0.083 (3) | 0.007 (4) | −0.065 (5) |
O31A | 0.067 (4) | 0.067 (3) | 0.094 (5) | −0.032 (3) | 0.016 (4) | −0.011 (3) |
O32A | 0.157 (6) | 0.112 (5) | 0.069 (4) | −0.076 (4) | 0.005 (4) | −0.016 (3) |
O33A | 0.134 (7) | 0.073 (4) | 0.333 (17) | −0.050 (5) | −0.072 (9) | 0.065 (7) |
Ag—N1 | 2.3740 (17) | C112—H112 | 0.9300 |
Ag—N2 | 2.366 (2) | C113—C114 | 1.369 (4) |
Ag—P1 | 2.4621 (6) | C113—H113 | 0.9300 |
Ag—P2 | 2.4393 (6) | C114—C115 | 1.395 (4) |
N1—C1 | 1.454 (3) | C114—H114 | 0.9300 |
N1—C11 | 1.284 (3) | C115—H115 | 0.9300 |
N2—C2 | 1.459 (3) | C120—C125 | 1.392 (3) |
N2—C21 | 1.285 (3) | C120—C121 | 1.398 (3) |
C1—C2 | 1.521 (3) | C121—C122 | 1.386 (3) |
C1—H1A | 0.9700 | C121—H121 | 0.9300 |
C1—H1B | 0.9700 | C122—C123 | 1.382 (4) |
C2—H2A | 0.9700 | C122—H122 | 0.9300 |
C2—H2B | 0.9700 | C123—C124 | 1.383 (3) |
C11—C12 | 1.429 (3) | C123—H123 | 0.9300 |
C11—H11 | 0.9300 | C124—C125 | 1.384 (3) |
C12—C13 | 1.349 (3) | C124—H124 | 0.9300 |
C12—H12 | 0.9300 | C125—H125 | 0.9300 |
C13—C14 | 1.450 (4) | P2—C200 | 1.819 (2) |
C13—H13 | 0.9300 | P2—C210 | 1.822 (2) |
C14—C19 | 1.396 (3) | P2—C220 | 1.834 (2) |
C14—C15 | 1.396 (3) | C200—C201 | 1.392 (3) |
C15—C16 | 1.381 (4) | C200—C205 | 1.404 (3) |
C15—H15 | 0.9300 | C201—C202 | 1.386 (3) |
C16—C17 | 1.384 (4) | C201—H201 | 0.9300 |
C16—H16 | 0.9300 | C202—C203 | 1.387 (3) |
C17—C18 | 1.388 (3) | C202—H202 | 0.9300 |
C17—H17 | 0.9300 | C203—C204 | 1.387 (3) |
C18—C19 | 1.382 (4) | C203—H203 | 0.9300 |
C18—H18 | 0.9300 | C204—C205 | 1.380 (3) |
C19—H19 | 0.9300 | C204—H204 | 0.9300 |
C21—C22 | 1.435 (3) | C205—H205 | 0.9300 |
C21—H21 | 0.9300 | C210—C211 | 1.393 (3) |
C22—C23 | 1.346 (3) | C210—C215 | 1.396 (3) |
C22—H22 | 0.9300 | C211—C212 | 1.388 (4) |
C23—C24 | 1.467 (3) | C211—H211 | 0.9300 |
C23—H23 | 0.9300 | C212—C213 | 1.386 (4) |
C24—C29 | 1.386 (4) | C212—H212 | 0.9300 |
C24—C25 | 1.396 (3) | C213—C214 | 1.378 (4) |
C25—C26 | 1.392 (4) | C213—H213 | 0.9300 |
C25—H25 | 0.9300 | C214—C215 | 1.386 (4) |
C26—C27 | 1.375 (5) | C214—H214 | 0.9300 |
C26—H26 | 0.9300 | C215—H215 | 0.9300 |
C27—C28 | 1.381 (4) | C220—C221 | 1.388 (3) |
C27—H27 | 0.9300 | C220—C225 | 1.394 (3) |
C28—C29 | 1.381 (4) | C221—C222 | 1.398 (3) |
C28—H28 | 0.9300 | C221—H221 | 0.9300 |
C29—H29 | 0.9300 | C222—C223 | 1.372 (4) |
P1—C100 | 1.813 (2) | C222—H222 | 0.9300 |
P1—C120 | 1.824 (2) | C223—C224 | 1.383 (5) |
P1—C110 | 1.825 (2) | C223—H223 | 0.9300 |
C100—C101 | 1.396 (3) | C224—C225 | 1.398 (3) |
C100—C105 | 1.401 (3) | C224—H224 | 0.9300 |
C101—C102 | 1.382 (4) | C225—H225 | 0.9300 |
C101—H101 | 0.9300 | N70—C70 | 1.129 (5) |
C102—C103 | 1.368 (4) | C70—C71 | 1.465 (6) |
C102—H102 | 0.9300 | O86—C86 | 1.404 (7) |
C103—C104 | 1.385 (4) | N72—C72 | 1.142 (6) |
C103—H103 | 0.9300 | C72—C73 | 1.534 (7) |
C104—C105 | 1.384 (4) | O88—C88 | 1.431 (9) |
C104—H104 | 0.9300 | N3—O31 | 1.139 (6) |
C105—H105 | 0.9300 | N3—O33 | 1.160 (8) |
C110—C115 | 1.376 (3) | N3—O32 | 1.289 (6) |
C110—C111 | 1.382 (3) | N3A—O32A | 1.135 (14) |
C111—C112 | 1.386 (3) | N3A—O31A | 1.208 (14) |
C111—H111 | 0.9300 | N3A—O33A | 1.305 (15) |
C112—C113 | 1.362 (4) | ||
C1—N1—C11 | 117.97 (19) | C115—C110—P1 | 123.73 (19) |
C1—N1—Ag | 108.41 (13) | C111—C110—P1 | 117.67 (16) |
C11—N1—Ag | 133.56 (16) | C110—C111—C112 | 120.8 (2) |
C2—N2—C21 | 118.9 (2) | C110—C111—H111 | 119.6 |
C2—N2—Ag | 109.84 (14) | C112—C111—H111 | 119.6 |
C21—N2—Ag | 130.65 (17) | C113—C112—C111 | 120.3 (3) |
N1—Ag—N2 | 74.05 (6) | C113—C112—H112 | 119.9 |
N1—Ag—P1 | 105.17 (5) | C111—C112—H112 | 119.9 |
N1—Ag—P2 | 119.74 (5) | C112—C113—C114 | 119.7 (3) |
N2—Ag—P1 | 113.12 (5) | C112—C113—H113 | 120.2 |
N2—Ag—P2 | 112.10 (5) | C114—C113—H113 | 120.2 |
P1—Ag—P2 | 122.70 (2) | C113—C114—C115 | 120.4 (3) |
N1—C1—C2 | 109.38 (19) | C113—C114—H114 | 119.8 |
N1—C1—H1A | 109.8 | C115—C114—H114 | 119.8 |
C2—C1—H1A | 109.8 | C110—C115—C114 | 120.1 (3) |
N1—C1—H1B | 109.8 | C110—C115—H115 | 119.9 |
C2—C1—H1B | 109.8 | C114—C115—H115 | 119.9 |
H1A—C1—H1B | 108.2 | C125—C120—C121 | 118.3 (2) |
N2—C2—H2A | 109.9 | C125—C120—P1 | 123.32 (16) |
N2—C2—C1 | 108.8 (2) | C121—C120—P1 | 118.38 (18) |
C1—C2—H2A | 109.9 | C122—C121—C120 | 120.6 (2) |
N2—C2—H2B | 109.9 | C122—C121—H121 | 119.7 |
C1—C2—H2B | 109.9 | C120—C121—H121 | 119.7 |
H2A—C2—H2B | 108.3 | C123—C122—C121 | 120.4 (2) |
N1—C11—C12 | 123.5 (2) | C123—C122—H122 | 119.8 |
N1—C11—H11 | 118.2 | C121—C122—H122 | 119.8 |
C12—C11—H11 | 118.2 | C122—C123—C124 | 119.5 (2) |
C13—C12—C11 | 121.5 (2) | C122—C123—H123 | 120.3 |
C13—C12—H12 | 119.2 | C124—C123—H123 | 120.3 |
C11—C12—H12 | 119.2 | C123—C124—C125 | 120.4 (2) |
C12—C13—C14 | 127.7 (2) | C123—C124—H124 | 119.8 |
C12—C13—H13 | 116.2 | C125—C124—H124 | 119.8 |
C14—C13—H13 | 116.2 | C124—C125—C120 | 120.8 (2) |
C19—C14—C15 | 118.3 (2) | C124—C125—H125 | 119.6 |
C19—C14—C13 | 122.6 (2) | C120—C125—H125 | 119.6 |
C15—C14—C13 | 119.1 (2) | C200—P2—C210 | 104.38 (10) |
C16—C15—C14 | 120.6 (2) | C200—P2—C220 | 103.62 (10) |
C16—C15—H15 | 119.7 | C210—P2—C220 | 103.75 (10) |
C14—C15—H15 | 119.7 | C200—P2—Ag | 114.66 (7) |
C15—C16—C17 | 120.7 (2) | C210—P2—Ag | 116.46 (7) |
C15—C16—H16 | 119.6 | C220—P2—Ag | 112.57 (7) |
C17—C16—H16 | 119.6 | C201—C200—C205 | 119.0 (2) |
C16—C17—C18 | 119.2 (3) | C201—C200—P2 | 118.80 (16) |
C16—C17—H17 | 120.4 | C205—C200—P2 | 122.21 (16) |
C18—C17—H17 | 120.4 | C202—C201—C200 | 120.5 (2) |
C19—C18—C17 | 120.3 (2) | C202—C201—H201 | 119.8 |
C19—C18—H18 | 119.8 | C200—C201—H201 | 119.8 |
C17—C18—H18 | 119.8 | C201—C202—C203 | 120.0 (2) |
C18—C19—C14 | 120.9 (2) | C201—C202—H202 | 120.0 |
C18—C19—H19 | 119.6 | C203—C202—H202 | 120.0 |
C14—C19—H19 | 119.6 | C202—C203—C204 | 119.9 (2) |
N2—C21—C22 | 122.1 (2) | C202—C203—H203 | 120.0 |
N2—C21—H21 | 119.0 | C204—C203—H203 | 120.0 |
C22—C21—H21 | 119.0 | C205—C204—C203 | 120.3 (2) |
C23—C22—C21 | 122.0 (2) | C205—C204—H204 | 119.9 |
C23—C22—H22 | 119.0 | C203—C204—H204 | 119.9 |
C21—C22—H22 | 119.0 | C204—C205—C200 | 120.3 (2) |
C22—C23—C24 | 126.7 (2) | C204—C205—H205 | 119.9 |
C22—C23—H23 | 116.7 | C200—C205—H205 | 119.9 |
C24—C23—H23 | 116.7 | C211—C210—C215 | 118.8 (2) |
C29—C24—C25 | 118.4 (2) | C211—C210—P2 | 117.83 (16) |
C29—C24—C23 | 122.7 (2) | C215—C210—P2 | 123.40 (17) |
C25—C24—C23 | 118.9 (2) | C212—C211—C210 | 120.4 (2) |
C26—C25—C24 | 120.7 (3) | C212—C211—H211 | 119.8 |
C26—C25—H25 | 119.6 | C210—C211—H211 | 119.8 |
C24—C25—H25 | 119.6 | C213—C212—C211 | 120.1 (2) |
C27—C26—C25 | 119.8 (3) | C213—C212—H212 | 120.0 |
C27—C26—H26 | 120.1 | C211—C212—H212 | 120.0 |
C25—C26—H26 | 120.1 | C214—C213—C212 | 120.0 (3) |
C26—C27—C28 | 120.0 (3) | C214—C213—H213 | 120.0 |
C26—C27—H27 | 120.0 | C212—C213—H213 | 120.0 |
C28—C27—H27 | 120.0 | C213—C214—C215 | 120.1 (2) |
C29—C28—C27 | 120.3 (3) | C213—C214—H214 | 119.9 |
C29—C28—H28 | 119.8 | C215—C214—H214 | 119.9 |
C27—C28—H28 | 119.8 | C214—C215—C210 | 120.6 (2) |
C28—C29—C24 | 120.8 (3) | C214—C215—H215 | 119.7 |
C28—C29—H29 | 119.6 | C210—C215—H215 | 119.7 |
C24—C29—H29 | 119.6 | C221—C220—C225 | 119.2 (2) |
C100—P1—C120 | 105.48 (10) | C221—C220—P2 | 122.98 (17) |
C100—P1—C110 | 103.98 (10) | C225—C220—P2 | 117.72 (18) |
C120—P1—C110 | 103.49 (10) | C220—C221—C222 | 120.3 (2) |
C100—P1—Ag | 109.82 (8) | C220—C221—H221 | 119.8 |
C120—P1—Ag | 116.07 (7) | C222—C221—H221 | 119.8 |
C110—P1—Ag | 116.76 (8) | C223—C222—C221 | 120.2 (3) |
C101—C100—C105 | 118.5 (2) | C223—C222—H222 | 119.9 |
C101—C100—P1 | 123.45 (17) | C221—C222—H222 | 119.9 |
C105—C100—P1 | 117.90 (18) | C222—C223—C224 | 120.3 (2) |
C102—C101—C100 | 120.0 (2) | C222—C223—H223 | 119.8 |
C102—C101—H101 | 120.0 | C224—C223—H223 | 119.8 |
C100—C101—H101 | 120.0 | C223—C224—C225 | 119.9 (3) |
C103—C102—C101 | 121.4 (3) | C223—C224—H224 | 120.0 |
C103—C102—H102 | 119.3 | C225—C224—H224 | 120.0 |
C101—C102—H102 | 119.3 | C220—C225—C224 | 120.1 (3) |
C102—C103—C104 | 119.4 (3) | C220—C225—H225 | 120.0 |
C102—C103—H103 | 120.3 | C224—C225—H225 | 120.0 |
C104—C103—H103 | 120.3 | N70—C70—C71 | 179.2 (5) |
C105—C104—C103 | 120.2 (3) | N72—C72—C73 | 167.8 (13) |
C105—C104—H104 | 119.9 | O31—N3—O33 | 134.6 (6) |
C103—C104—H104 | 119.9 | O31—N3—O32 | 104.0 (5) |
C104—C105—C100 | 120.5 (2) | O33—N3—O32 | 120.8 (5) |
C104—C105—H105 | 119.7 | O32A—N3A—O31A | 123.2 (11) |
C100—C105—H105 | 119.7 | O32A—N3A—O33A | 127.8 (13) |
C115—C110—C111 | 118.6 (2) | O31A—N3A—O33A | 108.8 (11) |
N1—C1—C2—N2 | 62.3 (3) | C115—C110—C111—C112 | −3.0 (4) |
C2—C1—N1—C11 | 135.3 (2) | P1—C110—C111—C112 | 176.1 (2) |
C2—C1—N1—Ag | −47.1 (2) | C110—C111—C112—C113 | 1.5 (5) |
N2—Ag—N1—C11 | −165.0 (3) | C111—C112—C113—C114 | 1.1 (5) |
P2—Ag—N1—C11 | −58.3 (2) | C112—C113—C114—C115 | −2.2 (6) |
P1—Ag—N1—C11 | 84.8 (2) | C111—C110—C115—C114 | 1.9 (5) |
N2—Ag—N1—C1 | 17.88 (16) | P1—C110—C115—C114 | −177.2 (3) |
P2—Ag—N1—C1 | 124.58 (15) | C113—C114—C115—C110 | 0.7 (6) |
P1—Ag—N1—C1 | −92.34 (16) | C100—P1—C120—C125 | 80.8 (2) |
C1—N1—C11—C12 | 178.2 (2) | C110—P1—C120—C125 | −28.1 (2) |
Ag—N1—C11—C12 | 1.3 (4) | Ag—P1—C120—C125 | −157.38 (17) |
N1—C11—C12—C13 | −171.8 (3) | C100—P1—C120—C121 | −100.93 (19) |
C11—C12—C13—C14 | 176.9 (3) | C110—P1—C120—C121 | 150.15 (18) |
C12—C13—C14—C19 | 8.2 (5) | Ag—P1—C120—C121 | 20.9 (2) |
C12—C13—C14—C15 | −173.5 (3) | C125—C120—C121—C122 | 0.8 (3) |
C19—C14—C15—C16 | −0.6 (4) | P1—C120—C121—C122 | −177.58 (19) |
C13—C14—C15—C16 | −179.0 (3) | C120—C121—C122—C123 | 0.0 (4) |
C14—C15—C16—C17 | 0.0 (5) | C121—C122—C123—C124 | 0.0 (4) |
C15—C16—C17—C18 | 0.7 (5) | C122—C123—C124—C125 | −0.7 (4) |
C16—C17—C18—C19 | −0.9 (5) | C123—C124—C125—C120 | 1.4 (4) |
C17—C18—C19—C14 | 0.3 (4) | C121—C120—C125—C124 | −1.5 (3) |
C15—C14—C19—C18 | 0.5 (4) | P1—C120—C125—C124 | 176.80 (19) |
C13—C14—C19—C18 | 178.8 (3) | N2—Ag—P2—C200 | 159.81 (9) |
C1—C2—N2—C21 | 128.8 (2) | N1—Ag—P2—C200 | 76.10 (10) |
C1—C2—N2—Ag | −43.3 (2) | P1—Ag—P2—C200 | −60.36 (8) |
N1—Ag—N2—C21 | −156.7 (2) | N2—Ag—P2—C210 | 37.56 (9) |
P2—Ag—N2—C21 | 87.2 (2) | N1—Ag—P2—C210 | −46.15 (9) |
P1—Ag—N2—C21 | −56.7 (2) | P1—Ag—P2—C210 | 177.39 (7) |
N1—Ag—N2—C2 | 14.09 (15) | N2—Ag—P2—C220 | −82.07 (10) |
P2—Ag—N2—C2 | −102.06 (15) | N1—Ag—P2—C220 | −165.78 (10) |
P1—Ag—N2—C2 | 114.11 (15) | P1—Ag—P2—C220 | 57.76 (9) |
C2—N2—C21—C22 | −176.5 (2) | C210—P2—C200—C201 | 148.19 (16) |
Ag—N2—C21—C22 | −6.5 (3) | C220—P2—C200—C201 | −103.47 (17) |
N2—C21—C22—C23 | 178.6 (2) | Ag—P2—C200—C201 | 19.60 (18) |
C21—C22—C23—C24 | −176.7 (2) | C210—P2—C200—C205 | −33.55 (19) |
C22—C23—C24—C29 | 1.2 (4) | C220—P2—C200—C205 | 74.79 (19) |
C22—C23—C24—C25 | 179.0 (2) | Ag—P2—C200—C205 | −162.14 (15) |
C29—C24—C25—C26 | −0.3 (4) | C205—C200—C201—C202 | −0.8 (3) |
C23—C24—C25—C26 | −178.2 (2) | P2—C200—C201—C202 | 177.49 (16) |
C24—C25—C26—C27 | 0.4 (4) | C200—C201—C202—C203 | 0.8 (3) |
C25—C26—C27—C28 | 0.3 (5) | C201—C202—C203—C204 | −0.5 (3) |
C26—C27—C28—C29 | −1.0 (5) | C202—C203—C204—C205 | 0.3 (3) |
C27—C28—C29—C24 | 1.1 (5) | C203—C204—C205—C200 | −0.3 (3) |
C25—C24—C29—C28 | −0.4 (4) | C201—C200—C205—C204 | 0.6 (3) |
C23—C24—C29—C28 | 177.3 (3) | P2—C200—C205—C204 | −177.68 (17) |
N2—Ag—P1—C100 | −150.63 (8) | C200—P2—C210—C211 | −87.97 (18) |
N1—Ag—P1—C100 | −71.80 (9) | C220—P2—C210—C211 | 163.79 (17) |
P2—Ag—P1—C100 | 69.90 (8) | Ag—P2—C210—C211 | 39.52 (19) |
N2—Ag—P1—C120 | 89.88 (9) | C200—P2—C210—C215 | 91.2 (2) |
N1—Ag—P1—C120 | 168.71 (9) | C220—P2—C210—C215 | −17.1 (2) |
P2—Ag—P1—C120 | −49.59 (8) | Ag—P2—C210—C215 | −141.35 (18) |
N2—Ag—P1—C110 | −32.64 (9) | C215—C210—C211—C212 | −1.1 (3) |
N1—Ag—P1—C110 | 46.19 (9) | P2—C210—C211—C212 | 178.03 (18) |
P2—Ag—P1—C110 | −172.11 (8) | C210—C211—C212—C213 | 1.1 (4) |
C120—P1—C100—C101 | 8.2 (2) | C211—C212—C213—C214 | −0.5 (4) |
C110—P1—C100—C101 | 116.7 (2) | C212—C213—C214—C215 | 0.1 (4) |
Ag—P1—C100—C101 | −117.6 (2) | C213—C214—C215—C210 | −0.1 (4) |
C120—P1—C100—C105 | −177.03 (19) | C211—C210—C215—C214 | 0.7 (4) |
C110—P1—C100—C105 | −68.5 (2) | P2—C210—C215—C214 | −178.5 (2) |
Ag—P1—C100—C105 | 57.2 (2) | C200—P2—C220—C221 | 5.8 (2) |
C105—C100—C101—C102 | −0.2 (4) | C210—P2—C220—C221 | 114.6 (2) |
P1—C100—C101—C102 | 174.6 (2) | Ag—P2—C220—C221 | −118.63 (19) |
C100—C101—C102—C103 | 0.5 (4) | C200—P2—C220—C225 | −178.39 (19) |
C101—C102—C103—C104 | −0.4 (5) | C210—P2—C220—C225 | −69.6 (2) |
C102—C103—C104—C105 | 0.1 (5) | Ag—P2—C220—C225 | 57.2 (2) |
C103—C104—C105—C100 | 0.1 (4) | C225—C220—C221—C222 | 0.1 (4) |
C101—C100—C105—C104 | −0.1 (4) | P2—C220—C221—C222 | 175.8 (2) |
P1—C100—C105—C104 | −175.2 (2) | C220—C221—C222—C223 | 0.3 (4) |
C100—P1—C110—C115 | −16.2 (3) | C221—C222—C223—C224 | −0.4 (4) |
C120—P1—C110—C115 | 93.8 (2) | C222—C223—C224—C225 | 0.0 (4) |
Ag—P1—C110—C115 | −137.3 (2) | C221—C220—C225—C224 | −0.4 (4) |
C100—P1—C110—C111 | 164.8 (2) | P2—C220—C225—C224 | −176.4 (2) |
C120—P1—C110—C111 | −85.2 (2) | C223—C224—C225—C220 | 0.4 (4) |
Ag—P1—C110—C111 | 43.6 (2) |