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A new bis(dimethylglyoximato)cobalt(III) complex with a bulky chiral alkyl group bonded to the Co atom has been prepared, [Co(C4H7N2O2)2(C10H13O4)(C8H11N)]. The crystal was irradiated with a xenon lamp. Racemization of the crystalline state was not observed for the crystal since the reaction cavity for the chiral alkyl group appears to be too small.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, 1

fcf

Structure factor file (CIF format)
Contains datablock shelxl

CCDC reference: 126668

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