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The title compounds, 2,4,6,8-tetraazabicyclo[3.3.1]nonane- 3,7-dione, (I) (C5H8N4O2), and 2,4,6,8-tetraacetyl-2,4,6,8- tetraazabicyclo[3.3.1]nonane-3,7-dione, (II) (C13H16N4O6), display similar conformations with the cyclic urea moieties and bridgehead atoms forming two mean planes having a dihedral angle of approximately 110°. The CO of each acetyl group is anti to the CO of the cyclic urea to which it is attached.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, I, II

hkl

Structure factor file (CIF format)
Contains datablock I

hkl

Structure factor file (CIF format)
Contains datablock II

CCDC references: 129141; 129142

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