metal-organic compounds
The title compound, μ-{N,N'-bis[trans-5-(methoxymethyl)-2-phenyl-1,3-dioxan-5-yl]ethanediamide(2-)}bis(triphenyltin), [Sn2(C6H5)6(C26H30N2O8)], was isolated from the products of the (triphenylstannyl)methylation of a 1:1 mixture of stereoisomers of N,N'-bis(5-hydroxymethyl-2-phenyl-1,3-dioxan-5-yl)ethanediamide. The molecule lies about an inversion centre and the unique Sn atom has distorted tetrahedral geometry, with Sn—Calkyl and Sn—Caryl distances of 2.154 (2) and 2.138 (2)–2.147 (3) Å, respectively, and C—Sn—C angles in the range 105.5 (1)-113.2 (1)°.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 127044