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research papers
trans-Pentafluorogermanate dihydrogen fluoride represents the first quarternary phase in the system H–Na–Ge–F, and the third Na–Ge–F phase after the X-ray structure analyses of Na2GeF6 and CsNaGeF6. The crystal structure of trans-pentafluorogermanate dihydrogen fluoride consists of chains of [GeF6] octahedra and chains of pentagonal bipyramidal [NaF7] polyhedra. The Raman and IR spectra show the expected vibrational modes.
research communications
In the cation of the title compound, [Pt2(COD)2F(SbF6)2]SbF6·0.75HF, a fluorine atom bridges two platinum atoms. Each platinum atom is furthermore surrounded by a COD ligand and one fluorine atom of the octahedral SbF6 anion.
research communications
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The Xe atom in Xe(SO3F)2 is linearly bonded to two O atoms of the fluorosulfate unit.
catalysts
metal-organic compounds
The title salt, (C2H8NO3S)[SbF6], which contains the protonated form of taurine (2-aminoethanesulfonic acid), was synthesized in anhydrous hydrofluoric acid and recrystallized as colourless block-shaped crystals from liquid SO2. In the solid state, a three-dimensional network is observed. This is formed by intra- and intermolecular N-H
O, N-HF and O-HF hydrogen bonds.
O, N-HF and O-HF hydrogen bonds.
