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Search query: square-planar coordination environment
544 articles match your search "square-planar coordination environment"Results 1 to 10, sorted by relevance:
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The AuIII atoms in the cationic pseudo-square-planar complex tetrakis(1-methyl-2,3-dihydro-1H-imidazole-2-thione-κS)gold(III) trichloride sesquihydrate reside at the corners of the unit cell on an inversion center and are bound by the S atoms of four methimazole ligands in a planar arrangement, with S—Au—S bond angles of approximately 90°.
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In the title compound, the mononuclear nickel(II) complex exhibits point group symmetry
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The coordination environment of the NiII atom is slightly distorted square planar, whereas the appearance of the whole molecule is twisted.
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The NiII atom in the title compound shows a distorted square-planar P2N2 coordination set provided by two bidentate ligands.
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The steric requirement resulting from the substituted methyl or phenyl group at the ortho-position of the coordinating quinoline-N atom in 8-(diphenylphosphanyl)quinoline enforces the square-planar coordination geometry of the dichloridopalladium(II) center to be highly distorted.
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In the cation of the title complex, the central palladium(II) atom is surrounded by two bidentate ligands, 2,2′-bipyridine and 4,4′-dimethoxy-2,2′-bipyridine, in a distorted square-planar environment.
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In the crystal structure of the title compound, the palladium(II) metal center is surrounded by a bidentate 2,2′-bipyridine ligand and two acetonitrile molecules in a distorted square-planar geometry.
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The properties of Hirshfeld surfaces around Cu(II) atoms in coordination complexes are sensitive to coordination geometry and weak interactions.
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A symmetrical dicarbonohydrazide was used to synthesize a centrosymmetric tetranuclear zinc(II) complex in which two of the zinc cations are pentacoordinated and the other two are hexacoordinated.
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The molecular PdII title complex exhibits a square-planar coordination about the central metal atom, provided by two trans-arranged chlorido ligands and two nitrogen atoms from the two neutral organic ligands.