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Acta Cryst. (2024). C80, 576-583
https://doi.org/10.1107/S2053229624007411

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Coordination variety of phenyltetrazolato and dimethylamido ligands in dimeric Ti, Zr, and Ta complexes

G. A. Bikzhanova and I. A. Guzei

The first example of a nonbridging η²-coordination of a tetrazolato ligand to a d-block element (Zr) is reported. Three related dinuclear 5-phenyltetrazolato complexes of Ti, Zr, and Ta are structurally characterized.

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Coordination variety of phenyl­tetra­zolato and di­methyl­amido ligands in dimeric Ti, Zr, and Ta com­plexes

Coordination variety of phenyltetrazolato and dimethylamido ligands in dimeric Ti, Zr, and Ta complexes