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Search query: hybrid crystal
1284 articles match your search "hybrid crystal"Results 1 to 10, sorted by relevance:
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This study describes the synthesis, characterization, and Hirshfeld surface analysis of a small organic ammonium bromide salt. The analysis reveals a torsion angle of −64.8 (2)° between the ammonium group and the bromine substituent.
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Organic–inorganic hybrid hexachloridostannate(IV) with 2-methylimidazo[1,5-a]pyridin-2-ium cation
The asymmetric unit of the title compound, (C8H9N2)2[SnCl6], contains one cation in a general position and one-half of the dianion situated on an inversion centre. The octahedral SnCl62– dianion is almost undistorted. The crystal structure can be seen as an arrangement of alternating organic and inorganic layers with little support from C—H
Cl—Sn contacts.
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This work focused on characterizing the structure from a stereochemical point of view, discussing the PbII character. The XRD data were collected at 200 K.
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The inorganic part of the crystal structure of the 1-D hybrid compound (C4N2H12)2[PbI5]I·H2O contains corner-sharing [PbI6]4− octahedra running as zigzag chains along the a axis. The organic (piprazineH2)2+ cations are lodged around the anionic framework. Water molecules and isolated iodine ions play an important role in the structure connectivity.
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The crystal structure of this hybrid organic–inorganic material exhibits chains of lead chloride capped by 4-(dimethylamino)pyridinium and dimethylammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis.
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The 0-D hybrid salt (C8H9N2)2[MnCl4] with a pseudo-layered arrangement of the organic and inorganic sheets is isomorphous with the Zn and Cd analogues. According to the Hirshfeld surface analysis, non-conventional C—H
Cl—Mn hydrogen bonding is predominant in the crystal packing.
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Deuteration severely influences all temperature-dependent structural modifications in the hybrid perovskite FAPbBr3. It leads to partially-ordered temperature-dependent structural modifications in which two symmetry-independent molecule positions with additional dislocation of the molecular centre atom and molecular angle inclinations are present.
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A series of 12 inorganic–organic hybrid 4f-substituted arsenotungstates decorated with 3d-based complexes along with organic ligands (acetate and 1,10-phenanthroline) have been synthesized under open-air conditions and characterized by SC-XRD, PXRD, FT–IR, UV–Vis and thermogravimetric analysis.
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A twisted 2D layered anion structure is formed because of the infiltration of cations and the presence of hydrogen bonds. A band gap of ∼2.700 eV was found through experimental and theoretical studies.
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The title compound contains infinite linear zigzag vanadate (V2O6)2−chains, constructed from corner-sharing VO4 tetrahedra, running parallel to the a axis.