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Search query: hybrid crystal

1284 articles match your search "hybrid crystal"

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This study describes the synthesis, characterization, and Hirshfeld surface analysis of a small organic ammonium bromide salt. The analysis reveals a torsion angle of −64.8 (2)° between the ammonium group and the bromine substituent.

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The asymmetric unit of the title compound, (C8H9N2)2[SnCl6], contains one cation in a general position and one-half of the dianion situated on an inversion centre. The octa­hedral SnCl62– dianion is almost undistorted. The crystal structure can be seen as an arrangement of alternating organic and inorganic layers with little support from C—H...Cl—Sn contacts.

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This work focused on characterizing the structure from a stereochemical point of view, discussing the PbII character. The XRD data were collected at 200 K.

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The inorganic part of the crystal structure of the 1-D hybrid compound (C4N2H12)2[PbI5]I·H2O contains corner-sharing [PbI6]4− octa­hedra running as zigzag chains along the a axis. The organic (piprazineH2)2+ cations are lodged around the anionic framework. Water mol­ecules and isolated iodine ions play an important role in the structure connectivity.

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The crystal structure of this hybrid organic–inorganic material exhibits chains of lead chloride capped by 4-(di­methyl­amino)­pyridinium and di­methyl­ammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis.

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The 0-D hybrid salt (C8H9N2)2[MnCl4] with a pseudo-layered arrangement of the organic and inorganic sheets is isomorphous with the Zn and Cd analogues. According to the Hirshfeld surface analysis, non-conventional C—H...Cl—Mn hydrogen bonding is predominant in the crystal packing.

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Deuteration severely influences all temperature-dependent structural modifications in the hybrid perovskite FAPbBr3. It leads to partially-ordered temperature-dependent structural modifications in which two symmetry-independent molecule positions with additional dislocation of the molecular centre atom and molecular angle inclinations are present.

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A series of 12 inorganic–organic hybrid 4f-substituted arsenotungstates decorated with 3d-based complexes along with organic ligands (acetate and 1,10-phenanthroline) have been synthesized under open-air conditions and characterized by SC-XRD, PXRD, FT–IR, UV–Vis and thermogravimetric analysis.

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A twisted 2D layered anion structure is formed because of the infiltration of cations and the presence of hydrogen bonds. A band gap of ∼2.700 eV was found through experimental and theoretical studies.

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The title compound contains infinite linear zigzag vanadate (V2O6)2−chains, constructed from corner-sharing VO4 tetra­hedra, running parallel to the a axis.
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